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Feasibility of using Vis-NIR spectroscopy and PXRF spectrometry to estimate regional soil cadmium concentration

Journal of environmental sciences 2024年第11期145卷 88-96页

作者： Mengxue Wan Fan Ya’nan Wentao Jiao Wenyou Hu Mingchao Lyu Weidong Li Chuanrong Zhang Biao Huang Key Laboratory of Soil Environment and Pollution Remediation Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China Research Center for Eco-environmental sciences Chinese Academy of SciencesBeijing 100085China Department of environmental science Zhejiang UniversityHangzhou 310058China guangdong provincial academy of environmental science Guangzhou 510045China Department of Geography University of ConnecticutStorrsCT 06269USA

Conventionally,soil cadmium(Cd)measurements in the laboratory are expensive and timeconsuming,involving complex processes of sample preparation and chemical *** study aimed to identify the feasibility of using sensor data of visible near-infrared reflectance(Vis-NIR)spectroscopy and portable X-ray fluorescence spectrometry(PXRF)to estimate regional soil Cd concentration in a time-and *** sensor data of Vis-NIR and PXRF,and Cd concentrations of 128 surface soils from Yunnan Province,China,were ***-product analysis(OPA)was used for synthesizing the sensor data and Granger-Ramanathan averaging(GRA)was applied to fuse the model *** neural network(ANN)models were built using Vis-NIR data,PXRF data,and OPA data,*** showed that:(1)ANN model based on PXRF data performed better than that based on Vis-NIR data for soil Cd estimation;(2)Fusion methods of both OPA and GRA had higher predictive power(R^(2))=0.89,ratios of performance to interquartile range(RPIQ)=4.14,and lower root mean squared error(RMSE)=0.06,in ANN model based on OPA fusion;R^(2)=0.88,RMSE=0.06,and RPIQ=3.53 in GRA model)than those based on either Vis-NIR data or PXRF *** conclusion,there exists a great potential for the combination of OPA fusion and ANN to estimate soil Cd concentration rapidly and accurately.

关键词： Artificial neural network Outer-product analysis Granger-Ramanathan averaging Soil Cd concentration Fusion method

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The effect of thermal treatment on the transformation and transportation of arsenic and cadmium in soil

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Journal of environmental sciences 2024年第11期145卷 205-215页

作者： Fengping Zhou Meina Guo Nan Zhao Qianting Xu Tuokun Zhao Weihua Zhang Rongliang Qiu guangdong provincial Key Laboratory of environmental Pollution and Remediation Technology Guangdong Provincial Engineering Research Center for Heavy Metal Contaminated Soil RemediationSchool of Environmental Science and EngineeringSun Yat-sen UniversityGuangzhou 510275China Shenzhen Research Institute Sun Yat-sen UniversityShenzhen 518057China National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and ManagementInstitute of Eco-environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China guangdong provincial Key Laboratory of Agricultural&Rural Pollution Abatement and environmental Safety School of Natural Resources and EnvironmentSouth China Agricultural UniversityGuangzhou 510642China Ganjiang Innovation academy Chinese Academy of SciencesGanzhou 341000China

Thermal treatment can effectively decontaminate soils but alter their *** research mainly focused on volatile organic compounds andmetals,***,neglecting nonvolatile metal(loid)*** study aimed to investigate Cd and As transformation during aerobic and anaerobic *** results showed that both aerobic and anaerobic calcination increased soil pH by reducing soil organic matter(SOM)content,which also influenced the cation exchange capacity(CEC)and the leaching behavior of Cd and As in the *** total concentrations of Cd and As in the calcined soils varied depending on the calcination temperature and *** the aerobic calcination temperature exceeded 700℃,Cd volatilized as CdCl_(2),while anaerobic calcination at relatively low temperatures(600℃)involved reductive reactions,resulting in the formation of metallic Cd with a lower boiling ***,As volatilized at 800℃aerobically and 600℃*** formation of As-based minerals,particularly Ca3(AsO4)2,hindered its gasification,whereas anaerobic calcination promoted volatilization efficiency through the generation of C-As(III)based gaseous components with lower boiling *** trends were observed in the TCLP-extractable Cd and As contents of the calcined *** 70%of TCLP-extractable Cd contents were suppressed after thermal treatment,attributed to the elevated pH and reduced CEC of the soil,as well as ***,TCLP-extractable As contents increased with elevated temperatures,likely due to the desorption of AsO43−and re-adsorption of gaseous As2O3 during *** findings have implications for assessing the environmental impact of thermal treatment and provide insights for remediation strategies concerning Cd and As-contaminated soils.

关键词： Thermal treatment Soil Cadmium Arsenic Transformation

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Multiple isotopes reveal the driving mechanism of high NO_(3)^(-) level and key processes of nitrogen cycling in the lower reaches of Yellow River

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Journal of environmental sciences 2024年第4期138卷 597-606页

作者： Qianqian Zhang Huiwei Wang Lu Liu Tianlun Zhai Xueqing Zhang Hebei and China Geological Survey Key Laboratory of Groundwater Remediation Institute of Hydrogeology and Environmental GeologyChinese Academy of Geological SciencesHebei 050061China Geo-environmental Monitoring Institute of Hebei Province Hebei 050011China Hebei provincial Laboratory of Water environmental science Hebei 050037China Hebei provincial academy of Ecological environmental science Hebei 050037China

The continuous increase of nitrate(NO_(3)^(-))level in rivers is a hot issue in the ***,the driving mechanism of high NO_(3)^(-)level in large rivers is still lacking,which has limited the use of river water and increased the cost of water *** this study,multiple isotopes and source resolution models are applied to identify the driving mechanism of high NO_(3)^(-)level and key processes of nitrogen cycling in the lower reaches of the Yellow River(LRYR).The major sources of NO_(3)^(-)were sewage and manure(SAM)in the low-flow season and soil nitrogen(SN)and chemical fertilizer(CF)in the high-flow *** was the most key process of nitrogen cycling in the ***,in the biological removal processes,denitrification may not occur *** temporal variation of contributions of NO_(3)^(-)sources were estimated by a source resolution model in the *** proportional contributions of SAM and CF to NO_(3)^(-)in the low-flow and high-flow season were 32.5%-52.3%,44.2%-46.2%and 36.0%-40.8%,54.9%-56.9%,*** driving mechanisms of high NO_(3)^(-)level were unreasonable sewage discharge,intensity rainfall runoff,nitrification and lack of nitrate removal *** control the NO_(3)^(-)concentration,targeted measures should be implemented to improve the capacity of sewage and wastewater treatment,increase the utilization efficiency of nitrogen fertilizer and construct ecological *** study deepens the understanding of the driving mechanism of high nitrate level and provides a vital reference for nitrogen pollution control in rivers to other area of the world.

关键词： Nitrate Driving mechanism Nitrogen cycle Source apportionment Transformation Yellow River

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Recycling of waste aluminum scraps to fabricate sulfidated zero-valent iron-aluminum particles for enhanced chromate removal

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Journal of environmental sciences 2024年第4期138卷 650-659页

作者： Yahui Zhang Liguo Zhang Jiajia Zeng Shuqun Xu Jianyu Pan Wenzhuo Huang Jianliang Sun Feng Jiang guangdong provincial Key Laboratory of Chemical Pollution and environmental Safety&MOE Key Laboratory of Theoretical Chemistry of Environment School of EnvironmentSouth China Normal UniversityGuangzhou 510006China guangdong provincial Key Lab of environmental Pollution Control and Remediation Technology School of Environmental Science&EngineeringSun Yat-Sen UniversityGuangzhou 510275China

Massive waste aluminum scraps produced from the spent aluminum products have high electron capacity and can be recycled as an attractive alternative to materials based on zerovalent iron(Fe^(0))for the removal of oxidative contaminants from *** study thus proposed an approach to fabricate micron-sized sulfidated zero-valent iron-aluminum particles(S-Al^(0)@Fe^(0))with high reactivity,electron selectivity and capacity using recycled waste aluminum scraps.S-Al^(0)@Fe^(0)with a three-layer structure contained zero-valent aluminum(Al^(0))core,Fe^(0) middle layer and iron sulfide(FeS)*** rates of chromate(Cr(Ⅵ))removal by S-Al^(0)@Fe^(0)at pH 5.0-9.0 were 1.6-5.9 times greater than that by sulfidated zero-valent iron(S-Fe^(0)).The Cr(Ⅵ)removal capacity of S-Al^(0)@Fe^(0)was 8.2-,11.3-and 46.9-fold greater than those of S-Fe0,zero-valent iron-aluminum(Al^(0)-Fe^(0))and Fe^(0),*** chemical cost of S-Al^(0)@Fe^(0) for the equivalent Cr(Ⅵ)removal was 78.5%lower than that of S-Fe^(0).Negligible release of soluble aluminum during the Cr(Ⅵ)removal was *** significant enhancement in the reactivity and capacity of S-Al^(0)@Fe^(0)was partially ascribed to the higher reactivity and electron density of the Al0core than Fe^(0).More importantly,S-Al^(0)@Fe^(0) served as an electric cell to harness the persistent and selective electron transfer from the Al^(0)-Fe^(0) core to Cr(Ⅵ)at the surface via coupling Fe^(0)-Fe^(2+)-Fe^(3+)redox cycles,resulting in a higher electron utilization ***,S-Al^(0)@Fe^(0) fabricated using recycled waste aluminum scraps can be a cost-effective and environmentally-friendly alternative to S-Fe^(0) for the enhanced removal of oxidative contaminants in industrial wastewater.

关键词： Recycled waste aluminum scraps Oxidative contaminants Cr(Ⅵ)reduction Sulfidated Al^(0)@Fe^(0)particle Electron transfer

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Mechanistic insights into the synergetic remediation and amendment effects of zeolite/biochar composite on heavy metal-polluted red soil

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Frontiers of environmental science & Engineering 2024年第9期18卷 105-114页

作者： Jing Li Dazhong Yang Wensong Zou Xuezhen Feng Ranhao Wang Renji Zheng Siyuan Luo Zheting Chu Hong Chen State environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution ControlSchool of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China

Red soil,the most critical soil resource in tropical/subtropical regions worldwide,faces tremendous threats,including nutrient deficiency,acidification,and heavy metal *** is a great demand for multifunctional eco-materials capable of modifying this ***,we used widely distributed soil and biomass to develop a zeolite/biochar composite for synergistic red soil remediation and *** the composite material,the Pb2+and Cd2+remediation efficiencies reached 92.8%and 92.9%,respectively,in stems under optimal ***,the acidity and nutrient deficiency conditions of red soil significantly *** atomic-scale interaction mechanism during the remediation and amendment process was elucidated with complementary characterization methods,which revealed that in the zeolite/biochar composite material,zeolite contributes to longterm heavy metal remediation ***,biochar is responsible for soil quality amendment and short-term heavy metal ***,for the first time,single-atom heavy metal ions were observed on biochar during the remediation process,indicating the broad distribution of single atoms in the natural environment.

关键词： Red soil Heavy metal pollution Zeolite/biochar composite Soil remediation Soil amendment

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In situ formed Mg(BH_(4))_(2) for improving hydrolysis properties of MgH_(2)

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Journal of Magnesium and Alloys 2024年第3期12卷 1204-1214页

作者： Yongyang Zhu Mili Liu liming Zeng Yin Wang Daifeng Wu Rui Li Qing Zhou Renheng Tang Fangming Xiao Institute of Resources Utilization and Rare Earth Development Guangdong Provincial Key Laboratory of Rare Earth Development and ApplicationGuangdong Academy of SciencesGuangzhou 510650China School of Materials science and Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage MaterialsSouth China University of TechnologyGuangzhou 510641China

The hydrolysis of MgH_(2) delivers high hydrogen capacity(15.2 wt%),which is very attractive for real-time hydrogen ***,the formation of a surface passivation Mg(OH)_(2) layer and the large excess of H_(2)O required to ensure complete hydrolysis are two key challenges for the MgH_(2) hydrolysis ***,a low-cost method is reported to synthesize MgH_(2)@Mg(BH_(4))_(2) composite via ball-milling MgH_(2) with cheap and widely available B_(2)O_(3)(or B(OH)_(3)).By adding small amounts of B_(2)O_(3),the in-situ formed Mg(BH_(4))_(2) could significantly promote the hydrolysis of MgH_(2).In particular,the MgH_(2)–10 wt%B_(2)O_(3) composite releases 1330.7 mL·g^(−1) H_(2)(close to 80%theoretical hydrogen generation H_(2))in H_(2)O and 1520.4 mL·g^(−1) H_(2)(about 95%)in 0.5 M MgCl_(2) in 60 min at 26℃ with hydrolysis rate of 736.9 mL·g^(−1)·min^(−1) and 960.9 mL·g^(−1)·min^(−1) H_(2) during the first minute of the hydrolysis,*** addition,the MgCl_(2) solution allows repeated use by filtering and exhibits high cycle stability(20 cycles),therefore leading to much reduced capacity loss caused by the excess H_(2)*** show that by introducing B_(2)O_(3) and recycling the 0.5 M MgCl_(2) solution,the system hydrogen capacity can approach 5.9 wt%,providing a promising hydrogen generation scheme to supply hydrogen to the fuel cells.

关键词： Hydrolysis MgH_(2) Mg(BH_(4))_(2) Hydrogen generation B_(2)O_(3) MgCl_(2)

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Iodine enrichment in the groundwater in South China and its hydrogeochemical control

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Journal of environmental sciences 2024年第8期142卷 226-235页

作者： Fengping Zhou Qianting Xu Yuyun Chen Weihua Zhang Rongliang Qiu guangdong provincial Key Laboratory of environmental Pollution and Remediation Technology Guangdong Provincial Engineering Research Center for Heavy Metal Contaminated Soil RemediationSchool of Environmental Science and EngineeringSun Yat-sen UniversityGuangzhou 510275China Shenzhen Research Institute Sun Yat-sen UniversityShenzhen 518057China guangdong provincial Key Laboratory of Agricultural&Rural Pollution Abatement and environmental Safety School of Natural Resources and EnvironmentSouth China Agricultural UniversityGuangzhou 510642China guangdong Laboratory for Lingnan Modern Agriculture Guangzhou 510642China

In North China,iodine-rich groundwater has been extensively studied,but few in South *** study aimed to investigate the characteristics of iodine-rich groundwater in South China and identify potential contamination *** results revealed that the average concentration of iodine in groundwater was 890μg/L,with a maximumconcentration of 6350μg/L,exceeding the permitted levels recommended by the World Health Organization(5–300μg/L).Notably,the enrichment of iodide occurred in acidic conditions(pH=6.6)and a relatively low Eh environment(Eh=198.4 mV).Pearson correlation and cluster analyses suggested that the enrichment of iodide could be attributed to the intensified redox process involving Mn(II),iodine(I_(2)),or iodate(IO_(3)^(−))in the *** strong affinity between Mn(II)and I_(2)/IO_(3)^(−)facilitated their interaction,resulting in the formation and mobilization of I^(−)from the soil to the *** experiments further confirmed that reducing substances(such as sodium sulfides,ascorbic acids,and fulvic acids)in the soil with low dissolved oxygen(DO)levels(3.8 mg/L)promoted the oxidation of I^(−)into I_(2)or IO_(3)^(−),leading to its *** research provides new insights into the characteristics and mechanisms of I^(−)enrichment in groundwater in South China,and emphasizes the significance of the redox reactions involving Mn(II)and I_(2)/IO_(3)^(−),as well as the influence of soil properties in regulating the occurrence and transportation of iodine species within groundwater systems.

关键词： Iodine enrichment Acid environment Groundwater South China Manganese

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The main strategies for soil pollution apportionment:A review of the numerical methods

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Journal of environmental sciences 2024年第2期136卷 95-109页

作者： Bin Shi Jing Meng TieyuWang Qianqian Li Qifan Zhang Guijin Su Research Center for Eco-environmental sciences Chinese Academy of SciencesBeijing 100085China University of Chinese academy of sciences Beijing 100049China guangdong provincial Key Laboratory of Marine Disaster Prediction and Prevention Shantou UniversityShantou 515063China

Nowadays,a large number of compounds with different physical and chemical properties have been determined in *** behaviors and source identification of pollutants in soil are the foundation of soil pollution *** and quantitative analysis of potential pollution sources are the prerequisites for its prevention and *** efforts have made to develop methods for identifying the sources of soil *** efforts have involved the measurement of source and receptor parameters and the analysis of their relationships via numerical statistics *** have comprehensively reviewed the progress made in the development of source apportionment methodologies to date and present our *** numerical methods,such as spatial geostatistics analysis,receptor models,and machine learning methods are addressed in *** most cases,however,the effectiveness of any single approach for source apportionment remains *** multiple methods to address soil quality problems can reduce uncertainty about the sources of soil *** review also constructively highlights the key strategies of combining mathematical models with the assessment of chemical profiles to provide more accurate source *** review intends to provide a comprehensive summary of source apportionment methodologies to help promote further development.

关键词： Soil pollutants Source attribution Methodologies Chemical profiles Mathematical models

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Efficient reduction and adsorption of Cr(Ⅵ)using FeCl_(3)-modified biochar:Synergistic roles of persistent free radicals and Fe(Ⅱ)

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Journal of environmental sciences 2024年第3期137卷 626-638页

作者： Shujie Hu Chengshuai Liu Hongling Bu Manjia Chen Ying-heng Fei National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and ManagementInstitute of Eco-environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China State Key Laboratory of environmental Geochemistry Institute of GeochemistryChinese Academy of ScienceGuiyang 550081China School of Environment science and Engineering Guangzhou UniversityGuangzhou 510006China College of Resources and Environment Chongqing SchoolUniversity of Chinese Academy of SciencesChongqing 400714China School of environmental science and Engineering Guangdong University of TechnologyGuangzhou 510006China

Transition metal iron and persistent free radicals(PFRs)both affect the redox properties of biochar,but the electron transfer relationship between them and the coupling reduction mechanism of Cr(Ⅵ)requires further *** untangle the interplay between iron and PFRs in biochar and the infuences on redox properties,FeCl_(3)-modified rice husk biochar(FBCs)was prepared and its reduction mechanism for Cr(Ⅵ)without light was *** FBCs had higher surface positive charges,oxygen-containing functional groups,and PFRs compared with pristine rice husk biochar(BC).Phenoxyl PFRs with high electrondonating capability formed in *** pronounced electron paramagnetic resonance signals showed that the PFRs preferred to form at lower Fe(Ⅲ)*** a high concentration of Fe(Ⅲ)would be reduced to Fe(Ⅱ)and consumed the formed *** kinetics and X-ray photoelectron spectroscopy analysis indicated that the FBCs effectively enhanced the Cr(Ⅵ)removal efficiency by 1.54-8.20 fold and the Cr(Ⅵ)reduction efficiency by 1.88-9.29 fold compared to those of *** quenching and competitive reductant addition experiments revealed that the higher Cr(Ⅵ)reduction performance of FBCs was mainly attributed to the formed PFRs,which could contribute to~74.0%of Cr(Ⅵ)reduction by direct or indirect electron *** PFRs on FBCs surfaces could promote the Fe(Ⅲ)/Fe(Ⅱ)cycle through single electron transfer and synergistically accelerate~52.3%of Cr(Ⅵ)*** study provides an improved understanding of the reduction mechanism of iron-modified biochar PFRs on Cr(Ⅵ)in environments.

关键词： Biochar Iron-modification Cr(Ⅵ) Electron transfer Reduction mechanism

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An in-situ self-etching enabled high-power electrode for aqueous zinc-ion batteries

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Journal of Energy Chemistry 2024年第1期88卷 399-408,I0009页

作者： Shuang Hou Dingtao Ma Yanyi Wang Kefeng Ouyang Sicheng Shen Hongwei Mi Lingzhi Zhao Peixin Zhang College of Chemistry and environmental Engineering Shenzhen UniversityShenzhen 518060GuangdongChina guangdong provincial Engineering Technology Research Center for Low Carbon and Advanced Energy Materials School of Semiconductor Science and TechnologySouth China Normal UniversityFoshan 528225GuangdongChina SCNU Qingyuan Institute of science and Technology Innovation Co. Ltd.Qingyuan 511517GuangdongChina

Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Palm tree-like vanadium oxide/carbon nanofiber membrane(P-VO/C)as a robust freestanding *** investigations including the finite element simulation,in-situ X-ray diffraction,and in-situ electrochemical impedance spectroscopy disclosed it an electrochemically induced phase transformation mechanism from VO to layered Zn_(x)V_(2)O_5·nH_(2)O,as well as superior storage kinetics with ultrahigh pseudocapacitive *** demonstrated,such electrode can remain a specific capacity of 285 mA h g^(-1)after 100 cycles at 1 A g^(-1),144.4 mA h g^(-1)after 1500 cycles at 30 A g^(-1),and even 97 mA h g^(-1)after 3000 cycles at 60 A g^(-1),***,an impressive power density of 78.9 kW kg^(-1)at the super-high current density of 100 A g^(-1)also can be *** design concept of in-situ self-etching free-standing electrode can provide a brand-new insight into extending the pseudocapacitive storage limit,so as to promote the development of high-power energy storage devices including but not limited to AZIBs.

关键词： In-situ self-etching Free-standing electrode Pseudocapacitive storage High-power Zinc-ion batteries

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