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groundwater monitoring of an open-pit limestone quarry:Water-rock interaction and mixing estimation within the rock layers by geochemical and statistical analyses

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International Journal of Mining Science and Technology 2018年第6期28卷 849-857页

作者： Khy Eam Eang Toshifumi Igarashi Megumi Kondo Tsurugi Nakatani Carlito Baltazar Tabelin Ryota Fujinaga Laboratory of groundwater and Mass Transport Division of Sustainable Resources EngineeringGraduate School of EngineeringHokkaido UniversitySapporo 060-8628Japan Laboratory of groundwater and Mass Transport Division of Sustainable Resources EngineeringFaculty of EngineeringHokkaido UniversitySapporo 060-8628Japan Mitsubishi Materials Corporation Tokyo 1008117Japan Ryoko Lime Industry Co. Ltd.Chichibu-gunSaitama 3680072Japan Laboratory of Mineral Processing and Resources Recycling Division of Sustainable Resources EngineeringFaculty of EngineeringHokkaido UniversitySapporo 0608628Japan

Water-rock interaction and groundwater mixing are important phenomena in understanding hydrogeological systems and the stability of rock slopes especially those consisting largely of moderately watersoluble minerals like calcite. In this study, the hydrogeological and geochemical evolutions of groundwater in a limestone quarry composed of three strata: limestone layer(covering), interbedded layer under the covering layer, and slaty greenstone layer(basement) were investigated. Water-rock interaction in the open-pit limestone quarry was evaluated using PHREEQC, while hierarchical cluster analysis(HCA)and principal component analysis(PCA) were used to classify and identify water sources responsible for possible groundwater mixing within rock layers. In addition, Geochemist's Workbench was applied to estimate the mixing fractions to clarify sensitive zones that may affect rock slope stability. The results showed that the changes in Ca2+and HCO3àconcentrations of several groundwater samples along the interbedded layer could be attributed to mixing groundwater from the limestone layer and that from slaty greenstone layer. Based on the HCA and PCA results, groundwaters were classified into several types depending on their origin:(1) groundwater from the limestone layer(LO),(2) mixed groundwater flowing along the interbedded layer(e.g., groundwater samples L-7, L-11, S-3 and S-4), and(3) groundwater originating from the slaty greenstone layer(SO). The mixing fractions of 41% LO: 59% SO, 64% LO: 36% SO, 43%LO: 57% SOand 25% LO: 75% SOon the normal days corresponded to groundwaters L-7, L-11, S-3 and S-4,respectively, while the mixing fractions of groundwaters L-7 and L-11(61% LO: 39% SOand 93% LO: 7% SO,respectively) on rainy days became the majority of groundwater originating from the limestone *** indicate that groundwater along the interbedded layer significantly affected the stability of rock slopes by enlarging multi-breaking zones in the layer through calcite

关键词： Water-rock interaction groundwater mixing Interbedded layer Geochemist’s workbench Rock slope stability

Hydrochemistry for the Assessment of groundwater Quality in Korea

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Journal of Agricultural Chemistry and Environment 2017年第1期6卷 1-29页

作者： Jong Yeon Hwang Sunhwa Park Hyun-Koo Kim Moon-Su Kim Hun-Je Jo Ji-In Kim Gyeong-Mi Lee In-Kyu Shin Tae-Seung Kim Soil and groundwater Research division NIER Incheon Korea

Understanding of the aquifer hydraulic properties and hydrochemical characteristics of water is crucial for management plan and study skims in the target area, and flow motions and chemical species of groundwater are regarded as precious information on the geological history of the aquifers and the suitability of various usages. Cations and anions of groundwater are used to estimate the characteristics and origin of groundwater. In this study, we try to evaluate the quality of groundwater based on the comparison of the physiochemical characteristics and distribution of cations and anions in groundwater from rural areas. Therefore we focused on the evaluation of groundwater as some specific purposes such as agricultural and industrial use, general types of groundwater, lithological origin of chemical component in groundwater. In this point of view, major objectives of this study were grouped as following three categories: 1) quality assessment of groundwater as a special usage (agricultural, industrial);2) determination of groundwater types;3) tracing of ion sources of groundwater. The quality of agricultural water was evaluated using SAR, sodium (%), RSC, PI, SSP, MH, PS, and Kelly’s ratio, and was classified as SAR (Excellent (100%)), Sodium ((Excellent (34%), Good (55%), Permissible (9%), Doubtful (1.6%), Unsuitable (0.4%)), RSC (Good (95.7%), Medium (3.5%), Bad (0.8%)), PI((Excellent (40.6%), Good (59%), Unsuitable (0.4%)), SSP ((Excellent (26.3%), Good (59.8%), Fair (13.1%), Poor (0.8%)), MH ((Acceptable (94.4%), Non-Acceptable (5.6%)), Kelly’s Ratio ((Permissible (93%), Non-Permissible (7%)), PS ((Excellent to Good (98%), Good to Injurious (1.2%), and Injurious to Unsatisfactory (0.2%)). Evaluation based on the Wilcox diagram was classified as “excellent to good” or “good to permissible”, and the water quality evaluated using the U.S. salinity Laboratory’s Diagram was classified as C1S1 (Excellent/Excellent) and C2S1 (Good/Excellent). And, in the applications o

关键词： Geochemical Characteristics Piper Diagram Gibbs Diagram Wilcox Diagram US Salinity Laboratory’s Diagram Chadah Diagram Rock-Water Deduction

Climate change and groundwater resources in Myanmar

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Journal of groundwater Science and Engineering 2017年第1期5卷 59-66页

作者： Than Zaw Maung Maung Than groundwater division Head Office Irrigation and Water Utilization Management Department Ministry of Agriculture Bago Regional Office Irrigation and Water Utilization Management Department Ministry of Agriculture

Myanmar is located in Southeast Asia within the Mekong River Basin. The estimated annual surface and groundwater potentials are 1 081 km^3 and 494 km^3, respectively. Based on geological conditions, 11 different types of aquifers have been classified in Myanmar. The recent alluvial formation, Irrawaddy formation, Upper Pegu Group and Plateau limestone formation are the major water-bearing geologic formations of the country. In Myanmar, 89% of the groundwater is used for agriculture, approximately 8% is used for domestic consumption, and 3% is used for industrial purposes. Climate change projections for Myanmar from 2001 to 2100 predict general increases in temperature, clear-sky days, rainfall variability and flooding risks and a greater occurrence and intensity of extreme weather events across the country. Additional technology and investments are required to achieve groundwater resource security in response to climate changes. In addition, methods of ensuring the sustainability of groundwater resources must be implemented via collaborations with other countries and international sources.

关键词： Mekong River Basin Myanmar groundwater resource Aquifer Climate change Sustainability

Hydrogeochemical evaluation and statistical analysis of groundwater of Sylhet, north-eastern Bangladesh

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Acta Geochimica 2019年第3期38卷 440-455页

作者： Nasir Ahmed Md.Bodrud-Doza S.M.Didar-Ul Islam Manzoor Ahmad Choudhry Md.Iftakharul Muhib Anwar Zahid Shahadat Hossain Md.Moniruzzaman Nipa Deb Md.Abdul Quaiyum Bhuiyan Isotope Hydrology division Institute of Nuclear Science and Technology Atomic Energy Research Establishment Department of Environmental Sciences Jahangirnagar University Isotope Hydrology Section Department of Nuclear Sciences and Applications International Atomic Energy Agency groundwater Hydrology Bangladesh Water Development Board

To investigate the hydrogeochemical characteristics of groundwater 23 shallow, 30 intermediate and 38 deep wells samples were collected from Sylhet district of Bangladesh, and analyzed for temperature, pH, Eh, EC,DO, DOC, Na^+, K^+, Ca^(2+), Mg^(2+), Cl^-, SO_4^(2-), NO_3^-,HCO_3^-, SiO_2^-, Fe, Mn and As. Besides, 12 surface water samples from Surma and Kushiyara Rivers were also collected and analyzed to understand the influence into aquifers. Results revealed that, most of the groundwater samples are acidic in nature, and Na–HCO_3 is the dominant groundwater type. The mean value of temperature, EC,Na^+, K^+, Ca^(2+), Mg^(2+), Cl^-, NO_3^- and SO_4^(2-) were found within the range of permissible limits, while most of the samples exceeds the allowable limits of Fe, Mn and As concentrations. However, relatively higher concentration of Fe and Mn were found in deep water samples and reverse trend was found in case of As. The mean concentrations of As in shallow, intermediate and deep wells were 39.3, 25.3and 21.4 lg/L respectively, which varied from 0.03 to148 lg/L. From spatial distribution, it was found that Fe,Mn and As concentrations are high but patchy in northern,north-western, and south-western part of Sylhet region. The most influential geochemical process in study area were identified as silicate weathering, characterized by active cation exchange process and carbonate weathering, which thereby can enhance the elemental concentrations in groundwater. Pearson's correlation matrix, principal component analysis and cluster analysis were also employed to evaluate the controlling factors, and it was found that, both natural and anthropogenic sources were influencing the groundwater chemistry of the aquifers. However, surface water has no significant role to contaminate the aquifers,rather geogenic factors affecting the trace elemental contamination. Thus it is expected that, outcomes of this study will provide useful insights for future groundwater monitoring and

关键词： Arsenic groundwater Hydrogeochemistry Multivariate statistics Spatial distribution

Determination of Water Saturation （SW%） by Using P-wave Velocities for Saturated Sandstone

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Journal of Environmental Science and Engineering 2011年第3期5卷 253-255页

作者： A.S. AI-Zubedi Geophysics division Ministry of Water Resource-General Commission of Groundwater BP： 19155 AL-Tubate Baghdad Iraq

The seismic velocities are strongly influenced by porosity and degree of water saturation, as well as other petrophysical properties, such as density and elastic properties of the rocks. In this paper, the saturation of water percentage for sandstones （SW%） has been calculated by mathematical equation, which is based on the relation between the seismic velocity of water to the seismic velocity obtained in the field （for p-wave velocity only）. The results of this equation which ranged between （30% to 100%） are connected with the results of seismic velocity-porosity relation for saturated sandstone through model, this model can be used for determining the porosity （Φ） and water saturation percentage （SW%） of the sandstones in the same time.

关键词： Water saturation (SW%) seismic velocities porosity (Φ).

Mapping Potential Infiltration Patterns Using Digital Elevation Model

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Journal of Geographic Information System 2014年第4期6卷 345-357页

作者： Haris Hasan Khan Arina Khan P. D. Sreedevi Shakeel Ahmed Department of Earth Sciences Pondicherry University Pondicherry India Hydrogeology Lab Department of Geology Aligarh Muslim University Aligarh India Indo-French Centre for groundwater Research (IFCGR) Groundwater Division National Geophysical Research Institute (NGRI) Hyderabad India

This study attempts to simulate the spatial heterogeneity of infiltration in a drainage basin using digital elevation models. Infiltration capacity is one of the controlling factors in the formation of stream channels. Channel formation is also a function of the slope and the contributing area. Natural stream channels, if properly graded and adjusted to the present climate, reflect the interactions of local slope, contributing area, and permeability of surface materials. Channel networks can be delineated from a Digital Elevation Model (DEM) using a variety of algorithms using different thresholds for channel initiation. These algorithms delineate a channel network on the basis of local slope, curvature, and contributing area, without considering the permeability of surface cover. Hence, the difference in the structure of the two drainage networks,?i.e.?the surveyed drainage network obtained from field observation and the simulated network generated from the DEM, is indicative of the spatial heterogeneities in the permeability of the surface cover as shown in this paper. Spatially variable drainage density maps corresponding to the two networks have been used here to obtain normalized difference maps that characterize the potential infiltration anomalies within the catchment. The simulated spatial pattern is compared with the actual infiltration measurements in the field using infiltration tests. Strong positive correlation between the observed and modeled infiltration confirms the effectiveness of this technique in the rapid assessment of potential infiltration variability.

关键词： DEM Permeability Infiltration Capacity Drainage Density Autocorrelation

Enhanced formation of trihalomethane disinfection byproducts from halobenzoquinones under combined UV/chlorine conditions

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Frontiers of Environmental Science & Engineering 2022年第6期16卷 109-119页

作者： He Zhao Ching-Hua Huang Chen Zhong Penghui Du Peizhe Sun Beijing Engineering Research Center of Process Pollution Control Division of Environment Technology and EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Civil and Environmental Engineering Georgia Institute of TechnologyAtlantaGA 30332USA State Environmental Protection Key Laboratory of Integrated Surface Water-groundwater Pollution Control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China School of Environmental Science and Engineering Tianjin UniversityTianjin 300072China

Halobenzoquinones(HBQs)are highly toxic disinfection byproducts(DBPs)and are also precursors of other DBPs such as trihalomethanes(THMs).The formation of THMs from HBQs during chlorine-only and UV/chlorine processes with or without bromide was investigated *** functional theory(DFT)reactivity descriptors were also applied to predict the nucleophilic/electrophilic reactive sites on HBQs and *** results were combined to explain the different behaviors of 2,6-dichloro-1,4-benzoquinone(2,6-DCBQ)and tetrachloro-1,4-benzoquinone(TCBQ)and to propose mechanism for the promoting roles of UV and hydroxylation of HBQs in THMs *** UV/chlorine,UV significantly enhanced THMs formation from 2,6-DCBQ compared to chlorine-only,mainly due to the production of OH-DCBQ^(*).Excited 2,6-DCBQ^(*)by UV benefited nucleophilic hydrolysis to produce OH-DCBQ^(*),which favored electrophilic attack by chlorine,thereby inducing more THMs ***/chlorine modestly promoted THMs formation from TCBQ compared to *** of TCBQ and UV irradiation were both important in promoting THMs formation due to the high electrophilic property of OH-TCBQ and TCBQ^(*).Meanwhile,hydroxylation of HBQs and CHCl3 formation were enhanced at higher *** work suggested that enhanced formation of THMs from HBQs should be considered in the application of combined UV and chlorine processes.

关键词： Halobenzoquinone Trihalomethane Chlorine disinfection UV irradiation Disinfection byproducts Combined UV/chlorine

Immunotoxic effects of an industrial waste incineration site on groundwater in rainbow trout (Oncorhynchus mykiss)

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Journal of Environmental Sciences 2014年第5期26卷 981-990页

作者： Nadjet Benchalgo Franois Gagn Michel Fournier INRS-Institut Armand-Frappier Emerging Methods Aquatic Contaminant Research Division

The discharge of organic waste from the petrochemical industry into the Mercier lagoons caused major groundwater contamination. The objective of this study was to determine the immunotoxic potential of three groundwater wells at increasing distance from the incinerator dumping site （1.17, 2.74 and 5.40 km）. Rainbow Trout were exposed to increasing concentrations of water from three groundwater wells for 14 days. Immunocompetence was characterized by phagocytosis, mitogen-stimulated proliferation of lymphocytes, cell cycle analysis and apoptosis. A significant increase in innate （phagocytosis） and specific immune response （B lymphocyte proliferation） was observed in trout exposed to water collected from the well at 2.74 km. However, phagocytosis activity was suppressed in groups at 1.17 and 5.40 km. The proportion of lymphocytes in S phase was significantly increased in groups at 2.74 and 5.40 kin, while lymphocytes in G0/G1 phase were decreased in all three exposure groups. Additionally, dexamethasone （DEX）-induced apoptosis of lymphocytes was significantly reduced in the group at 2.74 km, which suggests decreased lymphocyte turnover. Furthermore, the ratio of DEX- induced apoptosis/apoptosis was lower in the groups at 2.74 and 5.40 km. In summary, our experiments have shown that exposure to the mixture of organic compounds present in Mercier groundwater modulates phagocytosis and cell proliferation, disrupts the cell cycle and reduces the ratio of DEX- induced apoptosis/apoptosis. It is concluded that groundwater collected in the vicinity of an incinerator containment field could impact immunocompetence in fish.

关键词： groundwater phagocytosis lymphocyte proliferation cell cycle apoptosis rainbow trout

Analysis of Aquifer Characteristics and groundwater Quality in Southwest Punjab, India

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Journal of Earth Science and Engineering 2014年第10期4卷 597-604页

作者： Rajinder Pal Singh Chopra Gopal Krishan Hydro-geological and Hydro-chemical division Punjab Water Resources and Environment Directorate Chandigarh 160017India Hydrological lnvestigations division National Institute of Hydrology Roorkee 247667 Uttarakhand lndia IGB-groundwater Resilience Project British Geological Survey NERC Nottingham NG12 5GG UK

A study was conducted in eight districts, viz., Faridkot, Moga, Ferozepur, Muktsar, Bathinda, Mansa, Barnala and Sangrur in south-western part of the Punjab, India to characterize aquifer strata by preparing a fence diagram depicting sub-surface strata and distribution of groundwater quality. The sub-surface lithology drilled upto a depth of 60 m reveal the presence of top most layer of impervious strata comprising of clay upto the depth of 2 m to 5 m which impedes the percolation of surface runoff into the soil leading to surface flooding and water logging even in areas having saturated zone beyond the depth of 5 m. Thick pervious strata of 45 m to 50 m thickness is encountered in central and south-sentral part of the study area comprising of Bathinda, Muktsar and Mansa districts which at certain places are separated by one or two thin layers of impervious or semi-pervious strata comprising of clay and sand occasionally associated with ＂kankar＂ of thickness ranging between 2 m to 5 m. The northern, western and eastern parts, however, exhibit three to four layered pervious zones ranging in thickness from 5 m to 25 m separated by thin layers of impervious and semi pervious strata. The groundwater quality in about 6% of the study area in eight districts is fit, 18% is marginal and 76% is unfit for irrigation purpose.

关键词： groundwater aquifer characteristics quality depth southwest Punjab.