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Hybrid structure of iron single atoms and metallic titanium for photothermal ethanol steam reforming

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Science China Chemistry 2024年第3期67卷 848-854页

作者： Dachao Yuan Guanda Han Zhixuan Wang Jianguo Zhao Kailuan Li Pengfei Wang Jianjun Hao Yaguang Li Jinhua Ye College of Mechanical and Electrical Engineering Technology Innovation Center of Intelligent Agricultural EquipmentHebei Agricultural UniversityBaoding 071001China research center for Solar Driven Carbon Neutrality The College of Physics Science and TechnologyInstitute of Life Science and Green DevelopmentHebei UniversityBaoding 071002China International center for materials Nanoarchitectonics(WPI-MANA) National Institute for Materials Science(NIMS)1-1 NamikiTsukubaIbaraki 305-0044Japan graduate School of Chemical Science and Engineering Hokkaido UniversitySapporo 060-0814Japan

Photothermal ethanol steam reforming(ESR) is currently limited by low intrinsic activity and strong solar energy ***,we synthesized Fe single atoms supported on CeO_(2)(SA Fe-CeO_(2)) to exhibit excellent low-temperature ESR activity with a hydrogen production rate of 512 mmol g^(-1)h^(-1) at 350℃,becuase of the high oxidation state of Fe single atoms to weaken the reaction barrier of ethanol ***,a heterostructure of SA Fe-CeO_(2) and Ti foil could eliminate 66% of infrared radiation via the size effect,thus achieving a 3.5 sun-driven temperature of 347℃.Consequently,the heterostructure of SA Fe-CeO_(2) and Ti foil shows a hydrogen generation rate of 984 mmol g^(-1)h^(-1) of ESR and 11.31% of solar-to-hydrogen energy conversion efficiency,which outperforms other photothermal ethanol-hydrogen production *** study provides a new path for designing active catalytic sites and trapping light energy of photothermal catalysts.

关键词： photothermal catalysis single atoms heterostructure ethanol steam reforming iron

Mechanical robust and self-healing flexible perovskite solar cells with efficiency exceeding 23%

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Science China Chemistry 2024年第8期67卷 2670-2678页

作者： Yaohua Wang Ruikun Cao Yuanyuan Meng Bin Han Ruijia Tian Xiaoyi Lu Zhenhua Song Shuncheng Yang Congda Lu Chang Liu Ziyi Ge College of Mechanical Engineering Zhejiang University of TechnologyHangzhou 310014China Zhejiang Provincial Engineering research center of Energy Optoelectronic materials and Devices Ningbo Institute of Materials TechnologyEngineeringChinese Academy of SciencesNingbo 315201China center of materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049China

Flexible perovskite solar cells(f-PSCs) have experienced rapid advancements due to the light-weight, flexibility, and solution processability of the perovskite materials, which prompted the power conversion efficiency(PCE) to 24.08%. However, f-PSCs still face challenges in terms of mechanical and environmental stability. This is primarily due to their inherent brittleness, the presence of residual tensile strain, and the high density of defects along the boundaries of perovskite grains. To this end, we carefully developed a cross-linkable elastomers 3-[(3-acrylamidopropyl)dimethylammonium] propanoate(ADP) with electrostatic dynamic bond, which could be in-situ cross-linked and coordinate with [Pb I6]4-to regulate the crystallization process of perovskite. The cross-linked elastomers attached to the perovskite grain boundaries could release the remaining tensile strains and mechanical stresses, leading to enhanced stability and flexibility of the f-PSCs. More importantly, the electrostatic interaction between positive and negative groups of cross-linked elastomers and hydrogen bond formation between N–H and C=O accelerate the cross-linking of ADP, endowing the flexible perovskite films with self-healing ability under mild treating conditions(60 °C for 30 min). As a result, the device achieves a remarkable PCE of 23.53%(certified 23.16%). Additionally, the device exhibits impressive mechanical sustainability and durability, retaining over 90% of initial PCE even after undergoing8,000 bending cycles.

关键词： Mechanical robust and self-healing flexible perovskite solar cells with efficiency exceeding 23

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Engineering of oxygen vacancy and bismuth cluster assisted ultrathin Bi_(12)O_(17)Cl_(2)nanosheets with efficient and selective photoreduction of CO_(2)to CO

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Carbon Energy 2024年第4期6卷 1-11页

作者： Meili Guan Ni Lu Xuan Zhang Qiuwan Wang Jian Bao Guiye Chen Hao Yu Huaming Li Jiexiang Xia Xuezhong Gong College of Chemical and Biological Engineering Shandong University of Science and TechnologyQingdaoShandongChina Institute for Energy research Jiangsu UniversityZhenjiangJiangsuChina National center of International Joint research for Hybrid materials Technology Institute of Hybrid MaterialsCollege of Materials Science andEngineeringNational Base of International Science and Technology Cooperation on Hybrid MaterialsQingdao UniversityQingdaoShandongChina

The photocatalytic conversion of CO_(2)into solar‐powered fuels is viewed as a forward‐looking strategy to address energy scarcity and global *** work demonstrated the selective photoreduction of CO_(2)to CO using ultrathin Bi_(12)O_(17)Cl_(2)nanosheets decorated with hydrothermally synthesized bismuth clusters and oxygen vacancies(OVs).The characterizations revealed that the coexistences of OVs and Bi clusters generated in situ contributed to the high efficiency of CO_(2)–CO conversion(64.3μmol g^(−1)h^(−1))and perfect *** OVs on the facet(001)of the ultrathin Bi_(12)O_(17)Cl_(2)nanosheets serve as sites for CO_(2)adsorption and activation sites,capturing photoexcited electrons and prolonging light absorption due to defect *** addition,the Bi‐cluster generated in situ offers the ability to trap holes and the surface plasmonic resonance *** study offers great potential for the construction of semiconductor hybrids as multiphotocatalysts,capable of being used for the elimination and conversion of CO_(2)in terms of energy and environment.

关键词： Bi cluster Bi_(12)O_(17)Cl_(2)nanosheet oxygen vacancy photocatalytic CO_(2)reduction

Defects in the grain interiors of 3 mol%yttria-stabilized tetragonal zirconia polycrystal ceramics with 0.25 wt%alumina

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Journal of Advanced Ceramics 2024年第4期13卷 469-477页

作者： Yan Xiong Lian Luo Yao Cheng Zhi Liu Qi Liu Weimin Wang Wei Ji School of materials&Chemical Engineering Hubei Province Key Laboratory of Green Materials for Light IndustryHubei University of TechnologyWuhan 430068China Fujian Institute of research on the Structure of Mater Chinese Academy of SciencesFuzhou 350002China Jiangxi Provincial Engineering research center for Multifunction Zirconia materials Jiangxi Size Materials Co.Ltd.Jiujiang 332500China State Key Laboratory of Advance Technology for materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The presence of high-density defects is rarely observed in bulk 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TZP)ceramics obtained through conventional pressureless *** the present work,fine-grained dense 147 nm 3Y-TZP ceramics were prepared by pressureless sintering of commercial 0.25 wt%alumina-doped zirconia powders at 1300℃.A novel discovery was reported in which large amounts of defects were present in the grain interiors of the *** phenomenon was further examined using three types of powder samples,and the reasons for defect formation were investigated by microstructural characterization using high-resolution transmission electron microscopy(HRTEM)analysis and Rietveld *** results confirmed the essential dependence of the defect formation on the alumina *** authors attributed the defect formation to the significant difference in ionic radii of the solvent and solute during the dissolution of alumina into the zirconia *** sintering kinetics were proposed to be enhanced by the presence of substantial defects,which consequently favored the low-temperature sintering of the alumina-doped zirconia ceramics.

关键词： 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TzP)ceramics alumina addition microstructure defect

Revealing the Void Formation Mechanism during Superplastic Deformation of a Fine-Grained Ni-Co-Base Superalloy

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Acta Metallurgica Sinica(English Letters) 2024年第5期37卷 915-920页

作者： Rashad AAl-Hammadi Rui Zhang Chuanyong Cui Zijian Zhou Yizhou Zhou Shi-Changxu Innovation center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China

The mechanism behind void formation during superplasticity remains a subject of *** study presented a novel insight into the void formation in a fine-grained Ni-Co-based superalloy during *** was observed that the dissolution ofγ′-particles resulted in the creation of vacancies due to differences in atomic size between the matrix and the *** vacancies acted as inclusions,leading to the formation of ***,excessive void formation correlated with higher particle dissolution was experimentally observed,highlighting a direct relationship between void formation and particle dissolution.

关键词： Superplasticity Void formation Ni-Co-based superalloy Microstructure

High-Speed Rubbing Behavior of Abrasive Coating Coated on Titanium Alloy Blade Tips

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Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 749-762页

作者： Wenshuang Gu Shuai Yang Shiyi Zhang Zhiliang Pei Weihai Xue Deli Duan Jun Gong Chao Sun Shi-Changxu Innovation center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang110016China School of materials Science and Engineering University of Science and Technology of ChinaShenyang110016China

In aero-engines, abrasive coatings are typically utilized to protect the blade tip from excessive wear caused by the harder abradable sealing coating and thereby improve the sealing performance of engines. Therefore, a Ni/cBN abrasive coating was prepared on titanium alloy using electrodeposition. The high-speed rubbing tests with a linear velocity of 350 m/s and different incursion rates were performed to investigate the effect of the Ni/cBN abrasive coating on the wear behavior against NiCrAl/diatomite seal coating. Results showed that melting wear and adhesive transfer occurred on the bare blades, causing the bare blade to suffer excessive wear. While the Ni/cBN abrasive coating exhibited superior wear resistance and cutting performance. The cBN grits pullout, the abrasion of Ni matrix and transfer of seal coating to the cBN grits were the main wear mechanism of the Ni/cBN abrasive coating. Additionally, it was found that the relationship between the incursion rate and high-speed rubbing behavior is quite different for the bare blade and Ni/cBN coating. The reason for the difference in wear behavior of bare blade and Ni/cBN coating at different incursion rates was discussed in detail.

关键词： Gas turbine sealing Abrasive coating High-speed rubbing Material transfer Abradable coating

Stable ultraviolet ultrafast laser based on all-polarizationmaintaining fiber femtosecond laser

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Chinese Optics Letters 2024年第3期22卷 76-82页

作者：田昊朱喆林巍李子豪温俊鹏修昊范怡衡韦池一韦小明杨中民 School of Physics and Optoelectronics/State Key Laboratory of Luminescent materials and Devices Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and DevicesGuangdong Provincial Key Laboratory of Fiber Laser Materials and Applied TechniquesSouth China University of TechnologyGuangzhou 510640China research Institute of Future Technology South China Normal UniversityGuangzhou 510006China

We report a high-stability ultrafast ultraviolet(UV)laser source at 352 nm by exploring an all-fiber,all-polarizationmaintaining(all-PM),Yb-doped femtosecond fiber laser at 1060 *** output power,pulse width,and optical spectrum width of the fiber laser are 6 W,244 fs,and 17.5 nm,*** UV ultrashort pulses at a repetition rate of 28.9 MHz are generated by leveraging single-pass second-harmonic generation in a 1.3-mm-long BiB_(3)O_(6)(BIBO)and sum frequency generation in a 5.1-mm-long *** maximum UV output power is 596 *** root mean square error of the output power of UV pulses is 0.54%.This laser,with promising stability,is expected to be a nice source for frontier applications in the UV wavelength window.

关键词： all-polarization-maintaining fiber ultrafast fiber laser UV laser

Microstructural Evolutions and Mechanical Properties of Energetic Al_(1) (TiZrNbTaMoCr)_(15) High-Entropy Alloys

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Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 620-632页

作者： Xuan-Hong Cai Zhen-Hua Wang Ben Niu Jin-Feng Li Qing Wang Show authors Key Laboratory of materials Modification By Laser Ion and Electron Beams(Ministry of Education)Engineering Research Center of High Entropy Alloy Materials(Liaoning Province)School of Materials Science and EngineeringDalian University of TechnologyDalian116024China Institute of materials China Academy of Engineering PhysicsMianyang621908China

The present study focuses on investigating the microstructural evolutions and mechanical properties of energetic Al_(1)(TiZrNbTaMoCr)_(15) refractory high-entropy alloys with the different heat treatments at low Al content state. It is found that even with a reduction in the Al content, the strength of these alloys remains unaffected at room temperature and high temperature, while the plasticity improves significantly. In particular, the coherent BCC/B_(2) microstructure with needle-like B_(2) nanoprecipitates dispersed into the BCC matrix is formed in 873 K-aged Al_(1)Ti_(6)Zr_(2)Nb_(3)Ta_(3)Mo_(0.5)Cr_(0.5) alloy. Therefore, this alloy exhibits the highest compression yield strength (σ_(YS) = 1333 and 717 MPa) at room temperature and 1073 K, respectively. After 973 K-aged, the coherent BCC/B_(2) microstructure underwent destabilization, and the B_(2) phase transforms into the brittle Zr5Al3 phase which then coarsens and dominates the microstructure of S3-AlTa_(3) alloy after 1073 K-aged. Moreover, these current alloys exhibit exceptionally high theoretical exothermic enthalpy (ΔH), surpassing 11606 J·g^(−1), which highlights their significant potential as innovative high-performance energetic structural materials.

关键词： Refractory high-entropy alloy Coherent microstructure Mechanical property Exothermic enthalpy

Boosting propane dehydrogenation of defective S-1 stabilized singleatom Pt and ZnO catalysts via coordination environment regulation

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Nano research 2024年第7期17卷 5884-5896页

作者： Fuwen Yang Jie Zhang Jinwei Chen Gang Wang Tong Yu Qian Li Zongbo Shi Qiushi Sun Runsheng Zhuo Ruilin Wang College of materials Science and Engineering Sichuan UniversityChengdu 610065China Engineering research center of Alternative Energy materials&Devices Ministry of EducationSichuan UniversityChengdu 610065China REZEL Catalysts Corporation Shanghai 200120China

Pt single atoms catalysts with precise coordination environment and high stability are expected to achieve high performance of propane dehydrogenation(PDH).In this work,an innovative synthetic strategy is proposed to construct the S-1@0.1Pt9Zn@DPS-1 nanocomposite as a highly efficient PDH *** engineering is applied to induce the formation of defective porous silicalite-1(DPS-1),which is favorable for achieving the uniformly distributed ZnO *** ZnO nanoclusters were further served as anchoring sites to stabilize the isolated Pt *** structural characterization revealed that penta-O coordinated Pt single atom coupled with ZnO nanoclusters decorated on the ***,the atomically dispersed Pt atoms with the ideal coordination environment could act as the predominant active sites for PDH *** expected,the optimal S-1@0.1Pt9Zn@DPS-1 catalyst delivered an excellent PDH performance(propane conversion of 40.7%,propylene selectivity of 97.5%)and good cycling regeneration *** work provides a new way for improving the activity and stability of catalysts in the field of industrial catalysts.

关键词： defect engineering single platinum atom coordination environment propane dehydrogenation propylene