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城市住宅 2000年第6期7卷 74-76页

作者： Carl gouw Dick Liu gouw assets group

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实用居室㈡

城市住宅 2000年第6期7卷 77-81页

作者：梁庆坤弹浪 gouw assets group

不难看出这是一个中西给合风格的家居。业主既有传统的宗教信养,又有西化的生活方式,颇具代表性,设计师兼顾各种因素,设计完全满足了业主的各方面要求。造出了这个既舒适又具代表性的家居。

关键词：居室三室一厅 100m^2 室内设计中西结合风格

Synthesis, Crystal Structure, Antibacterial Activities and Theoretical Computation of 3-(2-Hydroxybenzly)-4-(4-isopropylbenzyl- ideneamino)-(1H)-1,2,4-triazole-5-thione

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Chinese Journal of Structural Chemistry 2006年第12期25卷 1435-1440页

作者：杨健国潘富友闫华 Office of assets Administration Taizhou University Department of Chemistry Taizhou University

The title compound C18H18N4OS has been synthesized by the reaction of 3-（2-hydroxy- benzyl）-4-amino-（1H）-1,2,4-triazole-5-thione with 4-isopropylbenzaldehyde in ethanol and characterized by IR, ^1H NMR spectra and elemental analysis. Its structure was determined by X-ray diffraction analysis. The crystal belongs to monoclinic, space group P21/c with a = 11.605（2）, b = 7.401（1）, c = 20.339（2） A, β= 103.05（2）°, V= 1701.8（4） A^3, Z = 4, Mr = 338.42,μ = 0.202 mm^-1, Dc = 1.321 g/cm^3 and F（000） = 712. The structure was solved by direct methods and refined to R = 0.0428 and wR = 0.1069. Due to the intramolecular O-H…N hydrogen bond and π-π stacking interactions between the benzene （C（1）～C（6）） and triazole rings, the two planes are essentially coplanar. Their biological activities have been measured, showing this type of compound has certain antibacterial activity for Staphylococous aureus and Bacillus subtilis. Based on the quantum chemistry calculation at the RHF/6-31G level, the frontier orbitals and electrostatic potential of the title compound were also discussed.

关键词： synthesis crystal structure 3-(2-hydroxybenzyl)-4-amino-(1H)-l,2,4-triazole-5-thione,theoretical computation antibacterial activities

Synthesis and Crystal Structure of a Ni(Ⅱ) Complex of 2'-[4-N,N'-(Dimethylaminobenzyl- idene)]-3,5-dihydroxybenzoylhydrazide and Its Spectral Properties

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Chinese Journal of Structural Chemistry 2009年第12期28卷 1635-1639页

作者：贾文平杨健国李芳潘富友 Department of Chemistry Taizhou University Office of assets Administration Taizhou University

A new nickel（II） complex [NiL2]（DMF）4 （HL = 2＇-[4-N,N＇-（dimethylamino- benzylidene）]-3,5-dihydroxybenzoylhydrazide） has been synthesized and its structure was characterized by IR,UV-Vis,1H NMR and elemental analysis. The fluorescence emission mechanism of the complex was discussed by fluorimetric spectra. The single-crystal structure was determined by X-ray diffraction analysis. The crystal belongs to the triclinic system,space group P1 with a = 0.9918（4）,b = 1.1297（4）,c = 1.1331（4） nm,α = 76.860（7）,β = 75.105（6）,γ = 89.022（7）°,V = 1.1936（8） nm^3,Z = 1,μ = 0.472 mm^-1,Dc = 1.319 g/cm^3,F（000） = 502 and Rint = 0.0913. In the title compound,the nickel（II） atom is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. The complex is centrosymmetric with nickel located at the center.

关键词： nickel(II) complex 2'-[4-N N'-(dimethylaminobenzylidene)]-3 5-dihydroxyben- zoylhydrazide crystal structure spectral properties

Synthesis, Crystal Structure and Antibacterial Activities of 3-[3-Methyl-(2-thienyl)methyl- enehydrazinocarbonyl]-(1H)-1,2,4-triazole

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Chinese Journal of Structural Chemistry 2005年第11期24卷 1286-1289页

作者： YANG Jian-Guo PAN Fu-You SHAO Hong Office of assets Administration Taizhou University Zhejiang 317000 China Department of Chemistry Taizhou University Zhejiang 317000 China

The title compound, C9H9N5OS, was synthesized by the reaction of 3-（1H）-1,2,4 -triazole hydrazine with 3-methyl-2-thiophenecarboxaldehyde in ethanol. The single crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group P2 1/n with a = 9.5550（10）, b = 11.9847（12）, c = 10.1074（11） A,β= 112.995（2）° V= 1065.47（19） A^3, Z = 4,μ = 0.290 mm^-1, Mr= 235.27, Dc = 1.467 g/cm^3 and F（000） = 488. The structure was solved by direct methods and refined to R = 0.0449. The crystal structure involves intermolecular hydrogen bonds of N-H…O and N-H…N as well as intramolecular hydrogen bond of N-H…N. Its biological activity has also been determined showing this type of compounds has certain antibacterial activity.

关键词： synthesis crystal structure antibacterial activities (1H)-1,2,4-triazole

Synthesis and Crystal Structure of 3-(2-Hydroxybenzly)-4-(4-Hydroxybenzylideneamino)-(1H) -1,2,4-Triazole-5-Thione and Its Antibacterial Activities

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Chinese Journal of Structural Chemistry 2005年第12期24卷 1403-1407页

作者： YANG Jian-Guo PAN Fu-You Office of assets Administration Taizhou University Zhejiang 317000 China Department of Chemistry Taizhou University Zhejiang 317000 China

The title compound C15H12N4O2S was synthesized by the reaction of 3-（2-hydroxybenzyl）-4-amino-（1H）-1,2,4-triazole-5-thione with 4-hydroxybenzaldehyde in ethanol and characterized by IR, ^1H NMR spectra and elemental analysis. Its structure has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic, space group C2/c with a = 27.990（3）, b = 13.1326（14）, c = 7.9770（8） A, β= 105.787（2）°, V = 2821.6（5）A^3, Z = 8, Mr= 312.35,μ= 0.243 mm^-1, Dc = 1.471 g/cm^3 and F（000） = 1296. The structure was solved by direct *** refined to a Rint value of 0.0388. The crystal structure involving in intermolecular N-H…S and O-H…S hydrogen bonds is observed, meanwhile intramolecular O-H…N hydrogen bond is also found. Their biological activities have been measured. The results show that this type of compound has certain antibacterial activity for Staphylococous aureus and Bacillus subtilis.

关键词： 1,2,4-triazole-5-thione X-ray diffraction crystal structure,synthesis antibacterial activities

Synthesis, Characterization, Crystal Structure and Antibacterial Activities of a Nickel(Ⅱ) Complex with 2'-(2-Thienylidene)-hydroxybenzoylhydrazide

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Chinese Journal of Structural Chemistry 2007年第9期26卷 1071-1075页

作者： YANG Jian-Guo LI Fang PAN Fu-You JIA Wen-Ping Office of assets Administration Taizhou University Taizhou 317000 China Department of Chemistry Taizhou University Taizhou 317000 China

In the ethanol solvent, a nickel（Ⅱ） complex Ni（C12H10N2O2S）2 upon reaction of 2＇-（2-thienylidene）-hydroxybenzoylhydrazide with nickel acetate was synthesized, and its structure was characterized by IR, UV, elemental analysis and X-ray diffraction analysis. The crystal belongs to monoclinic system, space group C2/c with a = 22.052（3）, b = 5.9681（6）, c = 18.522（2）A , β = 110.679（4）°, V = 2280.6（4）A^3, Z = 4, Mr = 551.27, μ = 1.606 mm^-1, Dc = 1.075 g/cm^3, F（000） = 1136 and Rint = 0.0556. The nickel（Ⅱ ） atom in the compound is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. The biological activities have been measured, show- ing the compound exhibits better anti-bacterial activity than the ligand.

关键词： nickel(Ⅱ) complex 2'-(2-thienylidene)-hydroxybenzoylhydrazide,crystal structure antibacterial activities

Synthesis, Crystal Structure and Antibacterial Activities of 3-[(2-Hydroxy-4-diethylamino-phenyl)methylenehydrazinocarbonyl]-4-hydroxy-6-methyl-2(1H)-pyridinones

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Chinese Journal of Structural Chemistry 2006年第5期25卷 626-630页

作者： LI Fang PAN Fu-You YANG Jian-Guo GE Chang-Hua Department of Chemistry Taizhou University Zhejiang 317000 China Office of assets Administration Taizhou University Zhejiang 317000 China

The title compound C18H22N4O4 was synthesized by the reaction of 3-hydrazine-4-hydroxy-6-methyl-2（1H）-pyridinones with 2-hydroxy-4-diethylaminobenzaldehyde in ethanol and characteri- zed by IR, tH NMR and elemental analysis. The single-crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to the triclinic system, space group P1^- with a = 10.1930（14）, b = 12.5200（17）, c = 15.1863（19） A, α= 96.292（3）, β= 96.450（3）, γ= 102.443（3）°, V= 1862.6（4） A^3, Z= 4, Mr = 358.40, μ = 0.092 mm^-1, D c= 1.278 g/cm^3, F（000） = 760 and R = 0.0803. The crystal structure involves intermolcular N-H…O as well as intramolcular O-H…N, O-H…O and N-H…O hydrogen bonds. The title compound shows no antibacterial activity.

关键词： 2(1H)-pyridinones X-ray diffraction crystal structure synthesis antibacterial activities

Synthesis, Crystal Structure and Antibacterial Activities of 3-[3-Methyl-(2-thienyl)methyl- enehydrazinocarbonyl]-(1H)-1,2,4-triazole

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Chinese Journal of Structural Chemistry 2005年第11期 68-71+9页

作者： YANG Jian-Guoa PAN Fu-Youb② SHAO Hongb a (Office of assets Administration, Taizhou University, Zhejiang 317000, China) b (Department of Chemistry, Taizhou University, Zhejiang 317000, China) Office of assets Administration， Taizhou University， Zhejiang 317000， China Department of Chemistry， Taizhou University， Zhejiang 317000， China

The title compound, C9H9N5OS, was synthesized by the reaction of 3-(1H)-1,2,4 -triazole hydrazine with 3-methyl-2-thiophenecarboxaldehyde in ethanol. The single crystal struc- ture has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group P21/n with a = 9.5550(10), b = 11.9847(12), c = 10.1074(11) ?, β = 112.995(2)°, V = 1065.47(19) ?3, Z = 4, μ = 0.290 mm-1, Mr = 235.27, Dc = 1.467 g/cm3 and F(000) = 488. The structure was solved by direct methods and refined to R = 0.0449. The crystal structure involves intermolecular hydrogen bonds of N–H…O and N–H…N as well as intramolecular hydrogen bond of N–H…N. Its biological activity has also been determined showing this type of compounds has certain antibacterial activity.

关键词： synthesis crystal structure antibacterial activities (1H)-1 2 4-triazole

Codon Optimization of SMAP-29 Gene and Its Expression in Pichia pastoris

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Agricultural Biotechnology 2012年第4期1卷 49-53页

作者： Yaojun REN Enpeng HE Xinhua WANG Xinwen BO assets Department Xinjiang Normal University The Breed & Biotechnology Key Laboratory of Sheep in Reproduction & Construction group of Xinjiang Key Laboratory of Sports Human Science Xinjiang Normal University

[ Objective] This study aimed to optimize the cedon of antimicrobial peptide SMAP-29 gene and express SMAP-29 in Pichia pastoris. [ Method] Ac- cording to the published amino acid sequence of SMAP-29, a gene encoding SMAP-29 （sheep myeloid antibacterial peptides-29） mature peptide was synthesized and was biased codon usage of Pichia pastoris. The synthesized gene was inserted into Pichia pastoris expression vector pPIC3.5K, transformed into Pichia pastoris strain GSll5 by electmporation, and screened with G418 for high-copy recombinants. The methanol utility plus phenotype （Mut ＋） was selected with MM, MD and PCR. The correctly constructed recombinant strain was induced with methanol. Expression of SMAP-29 was analyzed by lysing the induced yeast cells with Tricine- SDS-PAGE. [ Result] After induced with methanol for 2 d, a 3.2 kD induced band was detected in the cell lysate which was consistent to the predicted molecular weight of SMAP-29 ; the expression products purified with gel filtration chromatography showed significant antibacterial effect against Staphyloccocus aureus and Mo- nilia albican but no significant antibacterial effect against Escherichia coli. [ Conclusion] This study laid the foundation for the application of SMAP-29 in biomedi- cine, agriculture and other fields.

关键词： SMAP-29 Pichia pastoris Intracellular expression Antibacterial activity