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Reversible Mn^(2+)/Mn^(4+)double-electron redox in P3-type layer-structured sodium-ion cathode

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Journal of Energy Chemistry 2024年第2期89卷 79-88,I0004页

作者： Jie Zeng Jian Bao Ya Zhang Xun-Lu Li Cui Ma Rui-Jie Luo Chong-Yu Du Xuan Xu Zhe Mei Zhe Qian Yong-Ning Zhou Department of Materials Science Fudan UniversityShanghai 200433China Shanghai Xuanyi New Energy Development Co. LtdShanghai 201800China global Institute of Future Technology Shanghai Jiao Tong UniversityShanghai 200240China

The balance between cationic redox and oxygen redox in layer-structured cathode materials is an important issue for sodium batteries to obtain high energy density and considerable cycle *** redox can contribute extra capacity to increase energy density,but results in lattice instability and capacity fading caused by lattice oxygen gliding and oxygen *** this work,reversible Mn^(2+)/Mn^(4+)redox is realized in a P3-Na_(0.65)Li_(0.2)Co_(0.05)Mn_(0.75)O_(2)cathode material with high specific capacity and structure stability via Co *** contribution of oxygen redox is suppressed significantly by reversible Mn^(2+)/Mn^(4+)redox without sacrificing capacity,thus reducing lattice oxygen release and improving the structure *** X-ray techniques reveal that P3 phase is well maintained in a wide voltage window of 1.5-4.5 V ***^(+)/Na even at 10 C and after long-term *** is disclosed that charge compensation from Co/Mn-ions contributes to the voltage region below 4.2 V and O-ions contribute to the whole voltage *** synergistic contributions of Mn^(2+)/Mn^(4+),Co^(2+)/Co^(3+),and O^(2-)/(O_n)^(2-)redox in P3-Na_(0.65)Li_(0.2)Co_(0.05)Mn_(0.75)O_(2)lead to a high reversible capacity of 215.0 m A h g^(-1)at 0.1 C with considerable cycle *** strategy opens up new opportunities for the design of high capacity cathode materials for rechargeable batteries.

关键词： Sodium batteries Cathode materials Layered structure Co substitution

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A General Authentication and Key Agreement Framework for Industrial Control System

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Chinese Journal of Electronics 2024年第4期33卷 1046-1062页

作者： Shan GAO Junjie CHEN Bingsheng ZHANG Kui REN Xiaohua YE Yongsheng SHEN School of Cyber Science and Technology Zhejiang University Hangzhou global Scientific and Technological Innovation Center Zhejiang University Zhejiang Provincial Key Laboratory of Blockchain and Cyberspace Governance Hangzhou City Brain Co. Ltd

In modern industrial control systems(ICSs), when user retrieving the data stored in field device like smart sensor, there exists two main problems: one is lack of the verification for identification of user and field device;the other is that user and field device need exchange a key to encrypt sensitive data transmitted over the *** propose a comprehensive authentication and key agreement framework that enables all connected devices in an ICS to mutually authenticate each other and establish a peer-to-peer session key. The framework combines two types of protocols for authentication and session key agreement: The first one is an asymmetric cryptographic key agreement protocol based on transport layer security handshake protocol used for Internet access, while the second one is a newly designed lightweight symmetric cryptographic key agreement protocol specifically for field devices. This proposed lightweight protocol imposes very light computational load and merely employs simple operations like one-way hash function and exclusive-or(XOR) operation. In comparison to other lightweight protocols, our protocol requires the field device to perform fewer computational operations during the authentication phase. The simulation results obtained using Open SSL demonstrates that each authentication and key agreement process in the lightweight protocol requires only 0.005 ms. Our lightweight key agreement protocol satisfies several essential security features, including session key secrecy, identity anonymity, untraceability, integrity, forward secrecy, and mutual authentication. It is capable of resisting impersonation, man-in-the-middle, and replay attacks. We have employed the Gong-NeedhamYahalom(GNY) logic and automated validation of Internet security protocols and application tool to verify the security of our symmetric cryptographic key agreement protocol.

关键词： Performance evaluation Protocols Costs Industrial control Internet security Authentication Time measurement

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Oncology Research 2024年第2期32卷 421-432页

作者： SEUNG-HEE GWAK JUHYUN LEE EUNJI OH DOHYUN LEE WONSHIK HAN JONGMIN KIM KYONG-TAI KIM Department of Life Sciences Pohang University of Science and TechnologyPohang37673Korea R&D Center NovMetaPharma Co.Ltd.Pohang37668Korea Department of Surgery and Cancer Research Institute Seoul National University College of MedicineSeoul03080Korea Generative Genomics Research Center Global Green Research&Development CenterHandong Global UniversityPohang37554Korea

Genetic information is transcribed from genomic DNA to mRNA,which is then translated into threedimensional *** can undergo various post-transcriptional modifications,including RNA editing that alters mRNA sequences,ultimately affecting protein *** this study,RNA editing was identified at the 499th base(c.499)of human vaccinia-related kinase 2(VRK2).This RNA editing changes the amino acid in the catalytic domain of VRK2 from isoleucine(with adenine base)to valine(with guanine base).Isoleucine-containing VRK2 has higher kinase activity than the valine-containing VRK2,which leads to an increase in tumor cell *** we reported that VRK2 directly interacts with dystrobrevin-binding protein(dysbindin)and results in reducing its ***,we demonstrate that isoleucine-containing VRK2 decreases the level of dysbindin than valinecontaining *** interacts with cyclin D and thereby regulates its expression and *** reduction in the level of dysbindin by isoleucine-containing VRK2 further enhances the cyclin D expression,resulting in increased tumor growth and reduction in survival *** has also been observed that in patient samples,VRK2 level was elevated in breast cancer tissue compared to normal breast ***,the isoleucine form of VRK2 exhibited a greater increase in breast cancer ***,it is concluded that VRK2,especially dependent on the 167th variant amino acid,can be one of the indexes of tumor progression and proliferation.

关键词： VRK2 Kinase activity Breast cancer Tumor RNA editing Cell proliferation Cell growth

Advanced System-Level Model Reduction Method for Multi-Converter DC Power Systems

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CSEE Journal of Power and Energy Systems 2024年第4期10卷 1550-1562页

作者： Lin Zhu Xueshen Zhao Xialin Li Li Guo Bo Zhao Zhanfeng Deng Hao Lu Chengshan Wang the Key Laboratory of Smart Grid of Ministry of Education Tianjin UniversityTianjin 300072China the Research Institute of State Grid Zhejiang Electric Power Co. Ltd.Hangzhou 310014China the State Grid global Energy Interconnection Research Institute Beijing 102209China

For dynamic stability analysis and instability mechanism understanding of multi-converter medium voltage DC power systems with droop-based double-loop control,an advanced system-level model reduction method is *** this method,mathematical relationships of control parameters(e.g.,current and voltage control parameters)between the system and its equivalent reduced-order model are ***,open-loop and closed-loop equivalent reduced-order models of current control loop considering dynamic interaction among converters are *** instability mechanism(e.g.,unreasonable current control parameters)of the system can be revealed *** guidance for adjustment of current control parameters can also be ***,considering dynamic interaction of current control among converters,open-loop and closed-loop equivalent reduced-order models of voltage control loop are *** frequency and damping factor of DC bus voltage in a wide oscillation frequency range(e.g.,10–50 Hz)can be evaluated *** importantly,accuracy of advanced system-level model reduction method is not compromised,even for MVDC power systems with inconsistent control parameters and different number of ***,experiments in RT-BOX hardware-in-the-loop experimental platform are conducted to validate the advanced system-level model reduction method.

关键词： Closed-loop reduced-order model instability mechanism open-loop reduced-order model stability analysis system-level model reduction method

To improve robustness of mechanical properties of semi-solid cast A356 alloy using taguchi design method

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China Foundry 2024年第2期21卷 175-184页

作者： Yi-wu Xu Hong-yi Zhan Wei Tong Jin-ping Li Le-peng Zhang De-jiang Li Xiao-qin Zeng School of Materials Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China China Science Lab General Motors Global Research&DevelopmentShanghai 201206China General Motors(China)Investment Co. Ltd.Shanghai 201206China China International Intellectech Corporation(CIIC) Beijing 100004China

Mechanical properties of semi-solid casting are dependent on multiple processing parameters,and improper processing parameters will not only reduce mean data but also increase *** present study investigated the impact of parameters in slurry preparation and heat treatment on the yield strength and ductility of T6 heat-treated A356 Al-Si alloy using rapid slurry forming(RSF)semi-solid *** focus was primarily on the robustness of mechanical properties based on Taguchi design *** analyzing signal-to-noise ratio and minimum value calculated from-3S,the optimum slurry preparation parameters and heat treatment parameters were determined to be no quench,enthalpy exchange material(EEM)temperature of 140℃,EEM-to-melt ratio of 6mass%,stirring time of 18 s,solution heat treated at 520℃ for 2 h,and ageing heat treated at 190℃ for 6 *** a small batch validation,the-3S yield strength and-3S elongation reach 256.1 MPa and 5.03% respectively,showing a satisfactory *** hardness and microstructure of heat-treated samples with the best and worst properties were characterized to gain insight into the underlying mechanisms affecting the mean value and variations of mechanical properties.

关键词： semi-solid casting taguchi design method signal-to-noise ratio mechanical property microstructure

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Manufacturing task data chain-driven production logistics trajectory analysis and optimization decision making method

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Advances in Manufacturing 2024年第1期12卷 185-206页

作者： Lin Ling Zhe-Ming Song Xi Zhang Peng-Zhou Cao Xiao-Qiao Wang Cong-Hu Liu Ming-Zhou Liu School of Mechanical Engineering Hefei University of TechnologyHefei230009People’s Republic of China Guobo Electronics Co.ltd. Nanjing211111People’s Republic of China School of Mechanical and Electronic Engineering Suzhou UniversitySuzhou234000AnhuiPeople’s Republic of China Sino-US global Logistics Institute Shanghai Jiao Tong UniversityShanghai200030People’s Republic of China

Production logistics(PL)is considered as a critical factor that affects the efficiency and cost of production operations in discrete manufacturing *** effectively utilize manufacturing big data to improve PL efficiency and promote job shop floor economic benefits,this study proposes a PL trajectory analysis and optimization decision making method driven by a manufacturing task data chain(MTDC).First,the manufacturing task chain(MTC)is defined to characterize the discrete production process of a *** handle manufacturing big data,the MTC data paradigm is designed,and the MTDC is ***,the logistics trajectory model is presented,where the various types of logistics trajectories are extracted using the MTC as the search engine for the *** on this,a logistics efficiency evaluation indicator system is proposed to support the optimization decision making for the ***,a case study is applied to verify the proposed method,and the method determines the PL optimization decisions for PL efficiency without changing the layout and workshop equipment,which can assist managers in implementing the optimization decisions.

关键词： Production logistics(PL) Logistics trajectory analysis Logistics optimization Data driven Manufacturing task data chain(MTDC)

Study on green power supply modes for heavy load in Remote Areas

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global Energy Interconnection 2024年第4期7卷 475-485页

作者： Yu Li Yixi Cuomu Yiming Gao Guoqin Lv Weiwei Lin Sirui Li Changchun Zhou State Grid Xizang Electric Power Co. Ltd.Lhasa 850010Tibet Autonomous RegionP.R.China global Energy Interconnection Development and Cooperation Organization Beijing 100031P.R.China State Grid Fujian Power Economic Research Institute Fuzhou 350012P.R.China Eindhoven University of Technology Eindhoven.5621 AENetherlands

In this study,the present situation and characteristics of power supply in remote areas are *** studying the cases of power supply projects in remote areas,the experience is analyzed and described,and the applicability of related technologies,such as grid-forming storage and power load management,is studied,including grid-connection technologies,such as grid-forming converters and power load *** this basis,three power-supply modes were *** application scenarios and advantages of the three modes were compared and *** on the local development situation,the temporal sequences of the three schemes are described,and a case study was *** study of the heavy-load power supply mode in remote areas contributes to solving the problem of heavy-load green power consumption in remote areas and promoting the further development of renewable energy.

关键词： Remote area Renewable energy Grid-forming storage Power load management Power supply mode

Simple-structured hydrophilic sensors for sweat uric acid detection with laser-engraved polyimide electrodes and cellulose paper substrates

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Chinese Chemical Letters 2024年第3期35卷 443-448页

作者： Linhe Xu Xueshan Hu Shuang Zhou Ze Zhang Junxian Zhang Chao Li Daxian Zuo Hao Liu Gang Chen Jiayu Wan Jinsong Tao State Key Lab of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510640China Future Battery Research Center Global Institute of Future TechnologyShanghai Jiao Tong UniversityShanghai 200240China

Accurate detection of uric acid(UA)is crucial for diagnosing gout,yet traditional sweat-based UA sensors continue to face challenges posed by complex and costly electrode fabrication methods,as well as weakly hydrophilic ***,we designed and developed simple,low-cost,and hydrophilic sweat UA detection sensors constructed by carbon electrodes and cellulose paper *** carbon electrodes were made by carbonized polyimide films through a simple,one-step laser engraving *** electrodes are porous,possess a large specific surface area,and are flexible and *** substrates were composed of highly hydrophilic cellulose paper that can effectively collect,store,and transport *** constructed electrodes demonstrate high sensitivity of 0.4μA Lμmol^(-1)cm^(-2),wide linear range of 2–100μmol/*** addition,our electrodes demonstrate high selectivity,excellent reproducibility,high flexibility,and outstanding stability against mechanical bending,temperature variations,and extended storage ***,our sensors have been proven to provide reliable results when detecting UA levels in real sweat and on real human *** envision that these sensors hold enormous potential for use in the prognosis,diagnosis,and treatment of gout.

关键词： Laser-engraved carbon Polyimide Cellulose paper Hydrophilicity Sweat uric acid

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Quantification of In Vivo Epidermal Keratinocyte Architecture Associated with the Signs of Skin Aging and the Skin Benefit Evaluation by Application of Galactomyces Ferment Filtrate (Pitera)-Containing Skin Care Product

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Journal of Cosmetics, Dermatological Sciences and Applications 2024年第1期14卷 12-28页

作者： Kukizo Miyamoto Yoko Munakata Keisuke Fujii Chenlu Lei Ley Yang Suda Sudarsana Masutaka Furue Research and Development Kobe Innovation Center Procter and Gamble Innovation GK Kobe Japan global Scientific Communications P & G Guangzhou Ltd. Guangzhou China Department of Dermatology Graduate School of Medical Sciences Kyushu University Fukuoka Japan

Background: Aged skin exhibits visual alterations such as wrinkles, rough texture, pore dilation, and dull skin tone, as well as physiological aging, namely, decreased hydration and increased transepidermal water loss (TEWL). Recent advances in coherence tomography have also revealed that skin aging affects in vivo epidermal keratinocyte architecture. However, the interconnectivity between spatial architectural aging and visual/physiological aging parameters remains largely unknown. Purpose: To elucidate whether the tomographic keratinocyte architectural aging is correlated with visual and physiological skin aging parameters and to quantitatively evaluate the improvements of the architectural, visual, and physiological aging parameters by the daily treatment of the skin care formula containing Galactomyces Ferment Filtrate (GFF, 8X PiteraTM). Method: We measured the in vivo keratinocyte cellular architecture with two-photon stereoscopic tomography obtaining by-layer epidermal section images in 78 Asian females of various ages. Visual aging parameters were analyzed using a portable image capture system. Hydration and TEWL were also assessed. The anti-aging effects of GFF-containing skin moisturizer (SK-II LXP CreamTM) were also examined in two studies after twice-daily application for 2 (N = 35) and 4 (N = 32) weeks. Results: As for the keratinocyte cellular architecture, skin aging was significantly associated with decreased cell density and increased cell uniformity. These architectural aging parameters were significantly correlated with visual and physiological aging parameters, namely, rough texture, wrinkles, pore dilation, dull skin tone, dehydration, and increased TEWL. The strong interconnectivity allowed us to develop formulae to estimate the keratinocyte architecture from visual aging parameters. Moreover, twice-daily application of SK-II significantly improved the keratinocyte architecture associated with multiple skin aging visual an

关键词： Facial Skin Aging In Vivo Keratinocyte Cellular Architecture Visual Aging Pa-rameter Dehydration Interconnectivity New Trajectory Galactomyces Fer-ment Filtrate PiteraTM SK-II LXP CreamTM