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New Strategy for Boosting Cathodic Performance of Protonic Ceramic Fuel Cells Through Incorporating a Superior Hydronation Second Phase

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Energy & Environmental materials 2024年第4期7卷 83-92页

作者： Chuan Zhou Xixi Wang Dongliang Liu Meijuan Fei Jie Dai Daqin Guan Zhiwei Hu Linjuan Zhang Yu Wang Wei Wang Ryan O'Hayre San Ping Jiang Wei Zhou Meilin Liu Zongping Shao State Key Laboratory of materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Max Planck Institute for Chemical Physics of Solids Key Laboratory of interfacial Physics and Technology Shanghai Institute of Applied Physics Chinese Academy of Sciences Department of Metallurgical and materials Engineering Colorado School of Mines WA School of Mines: Minerals Energy and Chemical Engineering (WASM-MECE) Curtin University Suzhou Laboratory School of materials Science and Engineering Georgia Institute of Technology

For protonic ceramic fuel cells,it is key to develop material with high intrinsic activity for oxygen activation and bulk proton conductivity enabling water formation at entire electrode ***,a higher water content which benefitting for the increasing proton conductivity will not only dilute the oxygen in the gas,but also suppress the O2adsorption on the electrode surface.

关键词： cathode high-hydrating capability proton conductivity protonic ceramic fuel cells

interfacial growth of N,S-codoped mesoporous carbon onto biomass-derived carbon for superior potassium-ion storage

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Nano Research 2024年第4期17卷 2619-2627页

作者： Na Huang Cheng Tang Hao Jiang Jie Sun Aijun Du Haijiao Zhang Institute of Nanochemistry and Nanobiology School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444China School of Chemistry and Physics and Centre for materials Science Queensland University of TechnologyBrisbaneQLD 4001Australia Shanghai Engineering Research Center of Hierarchical Nanomaterials Frontiers Science Center for Materiobiology and Dynamic ChemistrySchool of Materials Science and EngineeringEast China University of Science and TechnologyShanghai 200237China

Carbonaceous materials have been recognized as one of the most promising anode materials for potassium-ion batteries(PIBs)due to their abundant raw materials,controllable structure,superior conductivity,and good chemical ***,the large radius of K ions and the low potassium content of intercalation compounds result in the sluggish storage kinetics and low reversible capacity of carbon *** this work,we present a unique heteroatom-doped carbon composite(denoted as NS-MC/SC)through a facile interfacial assembly route and simple heat-treatment process,where NS-MC is well grafted onto the biomass-derived spore carbon(SC).This unique structural design endows it with abundant mesoporous channels,expanded layer spacing,and highly doped N and *** these merits,the NS-MC/SC anode in PIBs exhibits a high reversible capacity of 350.4 mAh·g^(-1) at 100 mA·g^(-1) after 300 cycles,and an outstanding cycling ***,in-situ Raman spectra further verify the high reversibility of K ions insertion/***,theoretical simulations also reveal that the N,S dual-doping is an efficient approach for improving the potassium-ion storage performance of NS-MC/SC.

关键词： mesoporous carbon(MC) biomass-derived carbon(BC) N S co-doping interfacial assembly potassium-ion batteries(PIBs)

Hydrogen-rich surface of MoC catalysts for efficient CO_(2) hydrogenation induced by a coupled hydrogen donator

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Nano Research 2024年第8期17卷 7762-7767页

作者： Dong Xu Si-Yuan Xia Qi-Yuan Li Jie-Sheng Chen Xin-Hao Li School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong UniversityShanghai 200240China

Direct CO_(2) hydrogenation offers an important strategy for promoting the global carbon balance,but high thermodynamic and kinetic stability of CO_(2) has restricted its applicability to only a handful of industrial ***,we introduce a proof-of-concept application of the electron-rich Pt surface to promote hydrogen donation for electron-rich MoC particles acting as hydrogen acceptors,thereby constructing hydrogen-rich surface of MoC active ***,the formed hydrogen-rich and electronrich surface could greatly decrease reaction activation energy to boost the efficient CO_(2) hydrogenation into formic acid over the MoC *** optimized MoC@NC/Pt-0.1(NC:nitrogen-doped carbon)catalyst exhibits a high turnover frequency(TOF)value of 1.2 h^(−1) at a lower temperature of 60℃and a TOF of 24.2 h^(−1) under standard reaction conditions widely used in the literature,exceeding 7 times of MoC@NC catalyst and surpassing the benchmark classical non-noble metal active center-based heterogeneous catalyst.

关键词： electron-rich Pt nanoparticles hydrogen donation hydrogen-rich MoC nanoparticles CO_(2) hydrogenation formic acid

Improved Efficiency and Stability of Organic Solar Cells by Interface Modification Using Atomic Layer Deposition of Ultrathin Aluminum Oxide

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Energy & Environmental materials 2024年第3期7卷 286-294页

作者： Ai Lan Yiqun Li Huiwen Zhu Jintao Zhu Hong Lu Hainam Do Yifan Lv Yonghua Chen Zhikuan Chen Fei Chen Wei Huang School of Flexible Electronics(Future Technologies) and Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)Nanjing Tech University Department of Chemical and Environmental Engineering University of Nottingham Ningbo China Key Laboratory of Flexible Electronics of Zhejiang Province Ningbo Institute of Northwestern Polytechnical University frontiers Science Center for Flexible Electronics Xi'an Institute of Flexible Electronics (IFE) and Xi'an Institute of Biomedical Materials & EngineeringNorthwestern Polytechnical University

The interfacial contacts between the electron transporting layers （ETLs） and the photoactive layers are crucial to device performance and stability for OSCs with inverted ***,atomic layer deposition （ALD）fabricated ultrathin Al2O3layers are applied to modify the ETLs/active blends （PM6:BTP-BO-4F） interfaces of OSCs,thus improving device *** ALD-Al2O3thin layers on ZnO significantly improved its surface morphology,which led to the decreased work function of ZnO and reduced recombination losses in *** simultaneous increase in opencircuit voltage (VOC),short-circuit current density (JSC) and fill factor （FF）were achieved for the OSCs incorporated with ALD-Al2O3interlayers of a certain thickness,which produced a maximum PCE of 16.61%.Moreover,the ALD-Al2O3interlayers had significantly enhanced device stability by suppressing degradation of the photoactive layers induced by the photocatalytic activity of ZnO and passivating surface defects of ZnO that may play the role of active sites for the adsorption of oxygen and moisture.

关键词： atomic layer deposition interface modification organic solar cells stability

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Engineering Fronts 2023 announced engineering fronts in fields of Energy and Electrical Science and Technology

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frontiers in Energy 2024年第1期18卷 4-7页

作者： Ruiqin LIU Liang YIN Lingxiao FU Editorial Office of frontiers in Energy Shanghai Jiao Tong UniversityShanghai 200240China

1 Introduction An engineering front refers to important directions that have a significant impact on and lead the future innovation of engineering science and *** is characterized by its forward looking,leading,and exploratory *** 2017,the Chinese Academy of Engineering(CAE)has annually organized a project known as“global Engineering Fronts,”identifying and releasing engineering research fronts and engineering development fronts,tracking the trends in engineering science and technology,and actively guiding the academic development and promoting innovation in engineering science and technology.

关键词： technology. annually looking

Highly selective and efficient photocatalytic NO removal:Charge carrier kinetics and interface molecular process

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Nano Research 2024年第3期17卷 1003-1026页

作者： Huan Shang Hongbao Jia Pengpeng Li Hao Li Wenbin Zhang Shuangjun Li Qing Wang Shuning Xiao Ding Wang Guisheng Li Dieqing Zhang School of materials and Chemistry University of Shanghai for Science and TechnologyShanghai 200093China The Education Ministry Key Lab of Resource Chemistry Joint International Research Laboratory of Resource Chemistry of Ministry of EducationShanghai Key Laboratory of Rare Earth Functional Materialsand Shanghai Frontiers Science Center of Biomimetic CatalysisShanghai Normal UniversityShanghai 200234China School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China

The widespread nitrogen oxides(NOx,mainly in NO)in the atmosphere have threatened human health and ecological *** dilute NO(ppb)is difficult to efficiently remove via the traditional process due to its characteristics of low concentration,wide range,large total amount,*** can utilize solar energy to purify NO pollutants under mild conditions,but its application is limited due to the low selectivity of nitrate and poor activity of NO *** underlying reason is that the interface mechanism of NO oxidation is not clearly understood,which leads to the inability to accurately regulate the NO oxidation ***,the recent advances in the photocatalytic oxidation of NO are ***,the common strategies to effectively regulate carrier dynamics such as morphology control,facet engineering,defect engineering,plasma coupling,heterojunction and single-atom catalysts are ***,the progress of enhancing the adsorption and activation of reactants such as NO and O_(2) during NO oxidation is described in detail,and the corresponding NO oxidation mechanisms are ***,the challenges and prospects of photocatalytic NO oxidation are presented in term of nanotechnology for air pollution *** review can shed light on the interface mechanism of NO oxidation and provide illuminating information on designing novel catalysts for efficient NOx control.

关键词： nitrogen oxide(NO)oxidation photocatalysis NO/O_(2)activation charge carrier kinetics interfacial mechanism

具有三明治结构的MXene/聚酰亚胺复合泡沫用于多尺度微波吸收

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Science China materials 2024年第1期67卷 272-278页

作者：张亚君韩美康胡荣祥张培根潘龙孙正明 Key Laboratory of Advanced Metallic materials of Jiangsu Province School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China Institute of Optoelectronics and Shanghai frontiers Science Research Base of Intelligent Optoelectronics and Perception Fudan UniversityShanghai 200433China

三维多孔结构可促进电磁波在材料内部的多重反射,是提升微波吸收性能的有效方法.然而,传统的三维多孔结构中,多重反射仅发生在孔内.扩大多重反射的范围应能进一步提升材料的吸收性能.因此,本文开发了一种孔壁为三明治结构的三维多孔复... 详细信息

三维多孔结构可促进电磁波在材料内部的多重反射,是提升微波吸收性能的有效方法.然而,传统的三维多孔结构中,多重反射仅发生在孔内.扩大多重反射的范围应能进一步提升材料的吸收性能.因此,本文开发了一种孔壁为三明治结构的三维多孔复合泡沫,在亚毫米尺度孔和亚微米尺度孔壁中同时发生多重反射,实现多尺度微波吸收.本研究采用聚多巴胺修饰的聚酰亚胺泡沫(PDA@PIF)作为三维多孔骨架,在其孔壁表面负载Ti_(3)C_(2)T_(x).所得的Ti_(3)C_(2)T_(x)@PDA@PIF能够在整个X波段吸收超过90%的入射波.这得益于多尺度多重反射、电导损耗和界面极化.同时,该复合泡沫具有优异的柔性和低密度(~30 mg cm^(-3)).该工作为实现轻质、柔性、宽频的吸波材料提供了一种可行的方法,丰富了电磁防护的有效结构.

关键词：三明治结构聚酰亚胺泡沫多重反射微米尺度微波吸收复合泡沫电磁防护吸收性能

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可持续液态金属诱导的导电贝壳

Science Bulletin 2024年第7期69卷 913-921页

作者：严佳周天柱彭景淞王华高江雷程群峰 School of Chemistry Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of EducationBeihang UniversityBeijing 100191China School of Chemistry and materials Science University of Science and Technology of ChinaHefei 230026China Suzhou Institute for Advanced Research University of Science and Technology of ChinaSuzhou 215123China Key Laboratory of Bio-inspired materials and interfacial Science Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Institute of Energy materials Science(IEMS) University of Shanghai for Science and TechnologyShanghai 200093China

Nacre has inspired research to fabricate tough bulk composites for practical applications using inorganic nanomaterials as building ***,with the considerable pressure to reduce global carbon emissions,preparing nacre-inspired composites remains a significant challenge using more economical and environmentally friendly building *** we demonstrate tough and conductive nacre by assembling aragonite platelets exfoliated from natural nacre,with liquid metal and sodium alginate used as the “mortar”.The formation of Ga-O-C coordination bonding between the gallium ions and sodium alginate molecules reduces the voids and improves *** resultant conductive nacre exhibits much higher mechanical properties than natural *** also shows excellent impact resistance attributed to the synergistic strengthening and toughening fracture mechanisms induced by liquid metal and sodium ***,our conductive nacre exhibits exceptional self-monitoring sensitivity for maintaining structural *** proposed strategy provides a novel avenue for turning natural nacre into a valuable green composite.

关键词： Aragonite platelet Liquid metal Mechanical properties Self-monitoring Sustainable

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Construction of robust and durable Cu_(2)Se-V_(2)O_(5) nanosheet electrocatalyst for alkaline oxygen evolution reaction

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frontiers of Chemical Science and Engineering 2024年第6期18卷 71-83页

作者： Tauseef Munawar Ambreen Bashir Khalid Mujasam Batoo Saman Fatima Faisal Mukhtar Sajjad Hussain Sumaira Manzoor Muhammad Naeem Ashiq Shoukat Alim Khan Muammer Koc Faisal Iqbal Institute of Physics The Islamia University of BahawalpurBahawalpur 63100Pakistan King Abdullah Institute for Nanotechnology King Saud UniversityRiyadh 11451Saudi Arabia hybrid materials Center(HMC) Sejong UniversitySeoul 05006Republic of Korea Department of Nanotechnology and Advanced materials Engineering Sejong UniversitySeoul 05006Republic of Korea Institute of Chemical Sciences Bahauddin Zakariya UniversityMultan 60800Pakistan Division of Sustainable Development College of Science and EngineeringHamad Bin Khalifa UniversityQatar FoundationDoha 34110Qatar

Reducing the production costs of clean energy carriers such as hydrogen through scalable water electrolysis is a potential solution for advancing the hydrogen *** the various material candidates,our group demonstrated transition-metal-based materials with tunable electronic characteristics,various phases,and ***,electrochemical water oxidation using Cu_(2)Se-V_(2)O_(5) as a non-precious metallic electrocatalyst via a hydrothermal approach is *** water-splitting performance of all the fabricated electrocatalysts was evaluated after direct growth on a stainless-steel *** electrochemically tuned Cu_(2)Se-V_(2)O_(5) catalyst exhibited a reduced overpotential of 128 mV and provided a reduced Tafel slope of 57 mV·dec^(−1) to meet the maximum current density of 250 mA·cm^(−2).The optimized strategy for interfacial coupling of the fabricated Cu_(2)Se-V_(2)O_(5) catalyst resulted in a porous structure with accessible active sites,which enabled adsorption of the intermediates and afforded an effective charge transfer rate for promoting the oxygen evolution ***,the combined effect of the catalyst components provided long-term stability for over 110 h in an alkaline solution,which makes the catalyst promising for large-scale practical *** aforementioned advantages of the composite catalyst overcome the limitations of low conductivity,agglomeration,and poor stability of the pure catalysts(Cu2Se and V2O5).

关键词： oxygen evolution reaction Cu_(2)Se-V_(2)O_(5)composite nanosheets metal-diffused ions accessible adsorption sites