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Quality assessment and hydr.geochemical characteristics of groundwater in Agastheeswaram taluk, Kanyakumari district, Tamil Nadu, India

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Chinese Journal Of Geochemistry 2014年第3期33卷 221-235页

作者： Srinivas Y Hudson Oliver D Stanley Raj A Chandr.sekar N Centre for GeoTechnology Manonmaniam Sundaranar University Vel Tech dr. RR & dr. SR Technical University Avadi Chennai

The present study investigates the hydr.geochemical characteristics of groundwater quality in Agastheeswaram taluk of Kanyakumari district, Tamil Nadu, India. A total of 69 groundwater samples were collected during pre- and post-monsoon periods of 2011–2012. The groundwater quality assessment has been carried out by evaluating the physicochemical parameters such as pH, EC, TDS, HCO3-, Cl-, SO42-, Ca2+, Mg2+, Na+ and K+ for both the seasons. Based on these parameters, groundwater has been assessed in favor of its suitability for dr.nking and irrigation purpose. Dominant cations for both the seasons are in the order of Na+ > Ca2+ > Mg2+ > K+ while the dominant anions for post monsoon and pre monsoon have the trends of Cl- > HCO3- > SO42- and HCO3- > Cl- > SO42-, respectively. Analytical results observed from various indices reveal that the groundwater quality is fairly good in some places. Analytical results of few samples show that they are severely polluted and incidentally found to be near the coasts, estuaries and salt pans in the study area. The Gibbs plot indicates that the majority of groundwater samples fall in rock dominant region, which indicates rock water interaction in the study area. The United States salinity(USSL) diagram shows that the groundwater is free from sodium hazards but the salinity hazard varies from low to very high throughout the study area. This reveals that the groundwater is moderately suitable for agricultural activities. The observed chemical variations in pre-monsoon and post-monsoon seasons may be the effect to rock-water interactions, ion-exchange reactions, and runoff of fertilizers from the surrounding agricultural lands.

关键词：地下水质量评价地下水水质水文特性马里印度水岩相互作用物理化学参数研究区域

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Anti-synchronization of Four-wing Chaotic Systems via Sliding Mode Control

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International Journal of Automation and computing 2012年第3期9卷 274-279页

作者： Sundarapandian Vaidyanathan Sivaperumal Sampath Vel Tech dr. RR & dr. SR Technical University Faculty of Technology CMJ University

Sliding mode control is an important method used in nonlinear control systems. In robust control systems, the sliding mode control is often adopted due to its inherent advantages of easy realization, fast response and good transient performance as well as its insensitivity to parameter uncertainties and disturbances. In this paper, we derive new results based on the sliding mode control for the anti-synchronization of identical Qi three-dimensional (3D) four-wing chaotic systems (2008) and identical Liu 3D four-wing chaotic systems (2009). The stability results for the anti-synchronization schemes derived in this paper using sliding mode control (SMC) are established using Lyapunov stability theory. Since the Lyapunov exponents are not required for these calculations, the SMC method is very effective and convenient to achieve global chaos anti-synchronization of the identical Qi four-wing chaotic systems and identical Liu four-wing chaotic systems. Numerical simulations are shown to illustrate and validate the synchronization schemes derived in this paper.

关键词： Hybrid synchronization chaos sliding control Qi four-wing chaotic system Liu four-wing chaotic system

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Time lag between reduction of sediment supply and coastal erosion

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International Journal of Sediment Research 2011年第1期26卷 27-35页

作者： HUANG Guangwei~1 University of Tokyo,Japan, [a] dr. University of Tokyo Japan

The disruption of sediment supply from river to coast by dam development has been a topic of global *** Japan,among the top 30 dams in terms of height,14 dams were constructed prior to 1970 and another 6 dams before ***,the coastline erosion did not surface up as a grievous problem until the *** to the River Bureau of Japan,the overall erosion rate along the coastline of Japan was 0.72×10~6 m~2/yr prior to 1980,but sharply increased to 1.6×10~6 m~2/yr since ***,there was a time lag between the disruption of sediment supply by dam and beach *** paper presents a case study on what may have delayed the response of beach to the effect of dam construction.

关键词： Erosion Sediment supply Dam Sand mining Time lag

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Study of deposition of fine sediment within the pores of a coarse sediment bed stream

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International Journal of Sediment Research 2013年第2期28卷 210-219页

作者： N.K.KHULLAR U.C.KOTHYARI K.G.Ranga RAJU Department of Civil Engineering PAU Ludhiana-India Prof.Dr. Department of Civil Engineering IIT Roorkee-India Prof.Dr. Department of Civil Engineering IIT Roorkee-India Formerly Prof.Dr.

Elaborate experiments were performed in a 30 m long,0.5 m deep and 0.2 m wide laboratory flume to study the process of infiltration of fine sediment into the pores of coarse sediment forming the channel bed *** concentrations of suspended load of fine sediment of size 0.064 mm were passed over the channel bed made up of three different types of coarse sediments;two uniform and one *** proportion of fine sediment infiltrated into the pores of bed material for each equilibrium concentration of suspended load of fine sediment in the flow was studied during several experimental *** proportion of fine sediment within the pores of bed material increased with an increase in the equilibrium concentration of suspended load of fine sediment in the *** process continued till the pores within the coarse sediment bed were filled up to the capacity with the fine sediment transported by the flow in *** theoretical value was identified for limit for maximum proportion of fine sediment that can be present within the pores of bed *** further increase in the concentration of suspended load of fine sediment in the flow,deposition of fine sediment occurs on the surface of the flume bed in the form of ripples of the fine *** condition is defined as ’depositional condition’.Experimental observations on these and related aspects are presented herein.

关键词： Fine sediment Flume experiment Bed material Concentration of suspended sediment Deposition condition

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Dielectric, piezoelectric, and ferroelectric properties of lanthanum-modified PZTFN ceramics

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International Journal of Minerals,Metallurgy and Materials 2014年第10期21卷 1019-1027页

作者： Arvind Kumar S.K.Mishra Research and Technology Development Centre Sharda University dr. Harisingh Gour University

Specimens of Pb1-1.5xLax（Zr0.53 Ti0.47）1-y-zFeyNb2O3 （x = 0, 0.004, 0.008, 0.012, and 0.016, y = z = 0.01）（PZTFN） ceramics were synthesized by a semi-wet route. In the present study, the effect of La doping was investigated on the structural, microstructural, dielectric, piezoelectric, and ferroelectric properties of the ceramics. The results show that, the tetragonal （space group P4mm） and rhombohedr.l （space group R3c） phases are observed to coexist in the sample at x = 0.012. Microstructural investigations of all the samples reveal that La doping inhibits grain growth. Doping of La into PZTFN improves the dielectric, ferroelectric, and piezoelectric properties of the ceramics. The hys- teresis loops of all specimens exhibit nonlinear behavior. The dielectric, piezoelectric and ferroelectric properties show a maximum response atx 〉 0.012, which corresponds to the morphotropic phase boundary （MPB）.

关键词： ceramics lanthanum doping dielectric properties piezoelectricity ferroelectricity Rietveld refinement hysteresis loops

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Impedance and ferroelectric properties of Sr^(2+) modified PZT-PMN ceramics

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International Journal of Minerals,Metallurgy and Materials 2014年第6期21卷 595-603页

作者： Arvind Kumar S.K.Mishra Research and Technology Development Centre Sharda University dr. Harisingh Gour University

Sr^2＋ modified polycrystalline PZT-PMN ceramics were synthesized by a semi-wet route. Impedance spectroscopy studies indicate the bulk and grain boundary effects of PZT-PMN material along with the negative temperature coefficient of resistance. The bulk conductiv-ity exhibits an Arrhenius-type thermally activated hopping process which is supported by the AC conductivity behavior as a function of fre-quency and temperature. It is observed that the remnant polarization increases with an increase in the Sr2＋content in PZT-PMN.

关键词： piezoelectric ceramics ferroelectric materials ferroelectricity electrochemical properties strontium

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1,2,3-Triazole incorporated coumarin derivatives as potential antifungal and antioxidant agents

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Chinese Chemical Letters 2016年第2期27卷 295-301页

作者： Mubarak H.Shaikh Dnyaneshwar D.Subhedar Firoz A.Kalam Khan Jaiprakash N.Sangshetti Bapurao B.Shingate Department of Chemistry Dr. Babasaheb Ambedkar Marathwada University Department of Pharmaceutical Chemistry Y. B. Chavan College of Pharmacy Dr. Rafiq Zakaria Campus

A series of novel ethyl-7-（（1-（benzyl）-1H-1,2,3-triazol-4-yl）methoxy）-2-oxo-2H-chromene-3-carboxylates 8a-h as potential antifungal agents were synthesized via click chemistry. The antifungal activity was evaluated against five human pathogenic fungal strains, such as Candida albicans, Fusarium oxysporum, Aspergillus flavus, Aspergillus niger and Cryptococcus neoformans. Compound 8c, 8d, 8e and 8h were found to be equipotent against C. albicans when compared with miconazole and compound 8f was found to be two-fold more active compared with miconazole and equipotent to fluconazole against ***. The coumarin-based triazole derivatives were also evaluated for antioxidant activity and compound 8a was found to be potent antioxidant when compared with standard dr.g. Furthermore,molecular docking study of the newly synthesized compounds was performed and results showed good binding mode in the active site of fungal C. albicans enzyme P450 cytochrome lanosterol 14 ademethylase. Moreover, the synthesized compounds were also analyzed for ADME properties and showed potential to build up as good oral dr.g candidates.

关键词： ADME prediction Antifungal Antioxidant Docking study 1,2,3-Triazole

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Risk factors in patients with type 2 diabetes in Bengaluru: A retrospective study

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World Journal of Diabetes 2019年第4期10卷 241-248页

作者： Jagadeesha Aravinda dr. Aravind’s Diabetes Centre

BACKGROUND Risk factors such as hereditary, ecological, and metabolic are interrelated and contribute to the development of type 2 diabetes mellitus. Family history(FH) of diabetes mellitus, age, obesity, and physical inactivity are some of the risk factors for the development of type 2 *** To study various aetiological determinants and risk factors for type 2 diabetes in Bangalore, India. This retrospective study examined questionnaire from patients attending the Diabetes *** Data on various parameters were obtained through a questionnaire from 533 patients on the first visit to the diabetes clinic. Data regarding various aetiological determinants and risk factors viz.: Genetic risk factor and few modifiable risk factors were collected. Chi-squared test was used for statistical *** A higher incidence of type 2 diabetes in males and younger population was observed in Bangalore, India. Obesity and FH were significant risk factors for not only type 2 diabetes but also early onset of diabetes. In addition, maternal history of type 2 diabetes and consanguinity increased incidence of early onset type 2 *** Risk factors such as obesity and FH(maternal history of type 2 diabetes) and consanguinity may play an important role in screening of family members of type 2 diabetes patients which may lead to early intervention and reduced risk of subsequent complications. Moreover, susceptible population can be counselled for the management of the type 2 diabetes including periodic investigation of blood glucose levels and lifestyle changes.

关键词： Type 2 diabetess mellitus Young onset diabetes Family history Consanguinity Diabetes risk factors Obesity

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PREPARATION AND CHARACTERIZATION OF SCHIFF BASE POLYMERS DERIVED FROM 4,4'-METHYLENEBIS(CINNAMALDEHYDE)

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Chinese Journal of Polymer Science 2007年第4期25卷 399-407页

作者： M.Y. Khuhawar A. Shah M.A. Mughal dr. M.A. Kazi Institute of Chemistry University of SindhJamshoroSindhPakistan

New Schiff base polymers poly[4,4＇-methylenebis（cinnamaldehyde）ethylenediimine] （PMBCen）, poly[4,4＇- methylenebis（cinnamaldehyde）1,2-propylenediimine] （PMBCPn）, poly[4,4＇-methylenebis（cinnamaldehyde）1,3-propylenediimine] （PMBCPR）, poly[4,4＇-methylenebis（cinnamaldehyde） 1,2-phenylenediimine] （PMBCPh）, poly[4,4＇-methylenebis（cinnamaldehyde）meso-stilbenediimine] （PMBCS）, poly[4,4＇-methylenebis（cinnamaldehyde）urea] （PMBCUR）, poly[4,4＇- methylenebis（cinnamaldehyde）semicarbazone] （PMBCSc）, poly[4,4＇-methylenebis（cinnamaldehyde）thiosemicarbazone] （PMBCTSc） and poly[4,4＇-methylenebis（cinnamaldehyde）hydr.zone] （PMBCH） were formed by polycondensation of 4,4＇- methylenebis（cinnamaldehyde） with ethylenediamine, 1,2-propylenediamine, 1,3-propylenediamine, 1,2-phenylenediamine, meso-stilbenediamine, urea, semicarbazide, thiosemicarbazide and hydr.zine, respectively. The dialdehyde and polymers have been characterized through elemental micro-analysis, IR, UV-Vis and ^1H-NMR spectroscopic techniques. Thermoanalytical studies and viscous flow of dilute solutions of dialdehyde and its polymers have been examined and compared.

关键词： Schiff base polymers Synthesis Characterization Infrared spectroscopy Ultraviolet-visible spectroscopy Nuclear magnetic resonance Thermogravimetric analysis Differential thermal analysis.

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Facile and Rapid Access to Poly Functionalized Pyridine Derivatives

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Chinese Journal of Chemistry 2011年第5期29卷 1049-1054页

作者： Shinde Pravin V. Shingate Bapurao B. Shingare Murlidhar S. Department of Chemistry Dr. Babasaheb Ambedkar Marathwada University Aurangabad-431004 India

An efficient and greener protocol for the synthesis of poly functionalized pyridines using tetra-n-butyl ammonium fluoride （TBAF） in water is established. Remarkable advantages of the present synthetic strategy over the others are shorter reaction times, higher isolated yields, reuse of catalytic system, simple work-up procedure and more especially its applicability to heteryl and aliphatic aldehydes.

关键词： green chemistry pyridines tetra-n-butyl ammonium fluoride (TBAF) water chemistry

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