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Petrogenesis and tectonic implications of the Silurian adakitic granitoids in the eastern segment of the Qilian Orogenic Belt,Northwest China

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Acta Geochimica 2024年第1期43卷 72-86页

作者： Jiao-Long Zhao Xiao-Jun Huang Pei-Qing Hu Zhen-Xi Yang Ying Fan Er-Teng Wang Fu-Bo Yang Jing-Yu Zhang School of Earth Sciences Key Laboratory of Mineral Resources in Western China(Gansu Province)Lanzhou UniversityLanzhou 730000China Nuclear Industry 247 Brigade Tianjin North China Geological Survey BureauTianjin 301800China Fourth Institute of geological and mineral exploration of Gansu Provincial bureau of geology and mineral Resources Jiuquan 735000China

Geodynamic mechanism responsible for the generation of Silurian granitoids and the tectonic evolution of the Qilian orogenic belt remains controversial. In this study, we report the results of zircon U–Pb age, and systematic whole-rock geochemical data for the Haoquangou and Liujiaxia granitoids within the North Qilian orogenic belt and the Qilian Block, respectively, to constrain their petrogenesis, and the Silurian tectonic evolution of the Qilian orogenic belt. Zircon U–Pb ages indicate that the Haoquangou and Liujiaxia intrusions were emplaced at423 ± 3 Ma and 432 ± 4 Ma, respectively. The Haoquangou granodiorites are calc-alkaline, while the Liujiaxia granites belong to the high-K calc-alkaline series.Both are peraluminous in composition and have relatively depleted Nd isotopic [ε_(Nd)(t) =(-3.9 – + 0.6)] characteristics compared with regional basement rocks, implying their derivation from a juvenile lower crust. They show adakitic geochemical characteristics and were generated by partial melting of thickened lower continental crust. Postcollisional extensional regime related to lithospheric delamination was the most likely geodynamic mechanism for the generation of the Haoquangou granodiorite, while the Liujiaxia granites were generated in a compressive setting during continental collision between the Qaidam and Qilian blocks.

关键词： Silurian adakitic granitoids Petrogenesis Tectonic setting Qilian Orogenic Belt

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Zircon Hf Isotope Mapping for Understanding Crustal Architecture and Its Controls on mineralization during Early Cretaceous in the Southern Great Xing'an Range,NE China

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Journal of Earth Science 2024年第1期35卷 41-50页

作者： Feng Yuan Huanan Liu Shengjin Zhao Mingjing Fan State Key Laboratory of geological Processes and mineral Resources Collaborative Innovation Center for Exploration of Strategic Mineral ResourcesSchool of Earth ResourcesChina University of GeosciencesWuhan 430074China State Key Laboratory of geological Processes and mineral Resources School of Earth Sciences and ResourcesChina University of GeosciencesBeijing100083China No.10 Institute of geological exploration Inner Mongolia Bureau of Geology and Mineral ResourcesChifeng 024000China Key Laboratory of Metallogeny and mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China

Voluminous Early Cretaceous granitoids and associated large-scale ore deposits are distributed within the southern Great Xing'an Range(SGXR),NE China.Based on previously published geochronology and zircon Hf-isotope data,Hf isotope mapping is undertaken to improve our understanding of crustal architecture and its controls on ore deposits.The ore-related Early Cretaceous granitoids were sourced predominantly from juvenile crust,with the involvement of variable proportions of ancient crustal materials.The crustal architecture,as inferred from Hf isotopic contour maps,indicates two distinct Hf isotopic domains in SGXR,including(1)a higher-ε_(Hf)(+7 to+11)juvenile crust containing minor ancient crustal material,and(2)a lower-ε_(Hf)(+2 to+6)juvenile crust containing a greater proportion of ancient crustal materials.The Hf isotopic maps identify links between crustal architecture and regional metallogeny.Copper deposits and other deposits with significant Cu production are restricted mainly to the higher-ε_(Hf)juvenile crustal regions in the northern and eastern SGXR.Deposits dominated by other metals(e.g.,Mo,Sn,W,Pb,Zn,and Ag)occur mainly in the lower-ε_(Hf)juvenile crustal regions in the southern and western SGXR.Interaction between juvenile crust-derived melts and ancient crustal components played an important role on the distribution of various ore metals.

关键词： Hf isotope mapping crustal architecture large-scale Early Cretaceous granitoids distribution of ore deposits southern Great Xing'an Range zircon

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Hydrochemical Characterization,Controlling Factors and Water Quality of Surface Water in Shandong Province,North China

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Journal of Earth Science 2024年第1期35卷 155-166页

作者： Ran An Jiutan Liu Zongjun Gao Changsuo Li Yuming Peng School of Earth Sciences and Resources China University of GeosciencesBeijing 100083China College of Earth Science and Engineering Shandong University of Science and TechnologyQingdao 266590China 801 Institute of Hydrogeology and Engineering geology Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Key Laboratory of Groundwater Resources and Environment Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Shandong Engineering Research Center for Groundwater Environmental Protection and Remediation Jinan 250014China

In this study,90 surface water samples were collected from Shandong Province(SDP)in the dry and wet seasons and analyzed using statistical analysis,hydrochemical methods and water quality index(WQI).The content of main ions showed seasonal variations,with a higher average value in the dry season than in the wet season.Sampling points exhibiting high contents of the main chemical components were mainly distributed in areas southwest of SDP,north of Weifang,and around Jinan.The saturation index of carbonate minerals was greater than zero,while that of evaporite minerals was less than zero.The hydrochemical characteristics of surface water are mainly dominated by rock weathering as well as cation exchange.In addition,surface water in SDP has significantly been affected by anthropogenic factors.Most of the surface water could be classified as weakly alkaline soft-fresh water,with the hydrochemical types of SO_(4)·Cl-Ca·Mg and SO_(4)·Cl-Na.In terms of WQI,47.88% and 37.88% of the water samples in SDP were classified as poor water in the dry and wet seasons,respectively.On the whole,the water quality is higher in the wet season than in the dry season,and surface water in SDP is generally suitable for agricultural irrigation.

关键词： surface water hydrochemical characteristics controlling factors water quality Shandong Province

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Three-dimensional Modeling of Ore-forming Elements and mineralization Prognosis for the Yechangping Mo Deposit,Henan Province,China

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 736-752页

作者： DING Gaoming JI Genyuan YAN Guolong XU Yongzhong WANG Kunming XIAO Chun WANG Quanle GUO Dongbao China National Administration of Coal geology Beijing 100038China MNR Key Laboratory of Metallogeny and mineral Assessment Institute of Mineral ResourcesCAGSBeijing 100037China China Gold Group geological Co. Ltd.Beijing 100011China China Gold Group ZhongYuan Mining Co. Ltd.SanmenxiaHenan 472000China Lanzhou mineral exploration Institute of Gansu Nonferrous Metal geological exploration bureau Lanzhou 730046China

Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration.

关键词： 3D geochemical model ore-forming elements geostatistics deep mineralization prediction Yechangping Mo deposit

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A wave-shaped electrode flexible sensor capable of sensitively responding to wrinkle excitation for a multifunctional human-computer interaction system

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Nano Research 2024年第5期17卷 4454-4461页

作者： Yongyang Chen Zhiyi Wu Chengcheng Han Zhi Cao Yiran Hu Ping Zhao Yuanyu Wang College of Materials and Metallurgy Guizhou UniversityGuizhou 550025China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China geological Brigade 105 Bureau of Geology and Mineral Exploration and Development of Guizhou ProvinceGuiyang 550018China

Human-machine interactions(HMIs)have advanced rapidly in recent decades in the fields of healthcare,work,and life.However,people with disabilities and other mobility problems do not have corresponding high-tech aids for them to enjoy the convenience of HMIs.In this paper,we propose a sensor with a wave-shaped(corrugated)electrode embedded in a friction layer,which exhibits high sensitivity to skin fold excitation and enormous potential in HMIs.Attributing to the wave-shaped electrode design,it has no built-in cavities,and its small size allows it to flexibly cope with folds at different angles.By specifying the carbon nanotube hybrid silicone film as the electrode layer material and silicone film as the friction layer,good electrical output performance,tensile properties,and biocompatibility can be achieved.Then,the sensor is tested on various joints and skin folds of the human body,the output signals of which can be distinguished between normal physiological behavior and test behavior.Based on this sensor,we designed a medical alarm system,a robotic arm assistive system,and a cell phone application control system for the disabled to help them in the fields of healthcare,work,and life.In conclusion,our research presents a feasible technology to enhance HMIs and makes a valuable contribution to the development of high-tech aids for the disabled.

关键词： flexible sensors multifunctionality wrinkle excitation triboelectric nanogenerator human-machine interaction

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Structural Control of the Getang Carlin-Type Gold Deposit in Southwest China

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Journal of Earth Science 2024年第2期35卷 536-552页

作者： Guoping Zeng Xinlu Hu Diwei Luo Jianzhong Liu Shuzhen Yao Yongjie Jin Wuhan Center China Geological SurveyWuhan430205China Central South China Innovation Center for Geosciences Wuhan430205China Faculty of Earth Resources China University of GeosciencesWuhan430074China geological Party 105 Guizhou Bureau of Geology and Mineral Exploration&DevelopmentGuiyang550018China

The Getang is a representative Carlin-type gold deposit in Southwest China.It has a proven reserve of about 30 tonnes at an average grade of 5.1 g/t Au.The orebodies occur as strat-abound lenses,and are structurally controlled by shallow NWW-and NE-trending fold-fault systems and the unconformity between the Upper and Middle Permian.In this study,the regional-and deposit-scale structural investigations,joints and finite strain measurements,and stress and dynamic analysis were conducted with an aim to reveal the structural process of the Getang gold deposit and clarify the relationship between the gold mineralization and structures.Three phases of deformation were identified in the deposit:(1)paleokarst was generated by a crustal uplift when the Youjiang Basin experienced extension at the end of the Middle Permian,laying the foundation for the unconformity;(2)the NW-trending structures were formed under a NNE-SSW compression during the Indochina-South China collision(Indosinian orogeny)in Triassic;(3)the NE-trending structures were generated or reactivated under a NW-SE-oriented compression during the Yanshanian intracontinental orogeny.The unconformity recorded two episodes of tectonic evolution in the NNE-SSW and NW-SE directions.Structural analyses and geochronology data suggest that the Getang gold deposit was formed as a result of tectonic transition from compression to extension during the Yanshanian intracontinental orogeny.

关键词： Carlin-type gold deposit structural features finite strain Getang Southwest China economy geology geochemistry

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Texture and Geochemistry of Multi-stage Hydrothermal Scheelite in the Mamupu Cu-Au-Mo(-W)Deposit,Eastern Tibet:Implications for Tungsten mineralization in the Yulong Belt

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 701-716页

作者： ZHANG Xiaoxu TANG Juxing LIN Bin WANG Qin HE Liang YAN Gang SHAO Rui WU Qiang DU Qiu ZHAXI Pingcuo Chengdu Center China Geological Survey(Geosciences Innovation Center of Southwest China)Chengdu 610081China MNR Key Laboratory of Metallogeny and mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China SinoProbe Laboratory Chinese Academy of Geological SciencesBeijing 100094China Earth Sciences College Chengdu University of TechnologyChengdu 610059China No.6 geological Party Tibetan Bureau of Geology and Mineral Exploration and DevelopmentLhasa 851400China Tibet Shengyuan Mining Group Co. Ltd.Lhasa 851400China

Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace element and Sr isotope analyses of Mamupu scheelite samples,undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore-forming fluids.Three different types of scheelite are identified in the Mamupu deposit:scheelite A(Sch A)mainly occurs in breccias during the prograde stage,scheelite B(Sch B)forms in the chlorite-epidote alteration zone in the retrograde stage,while scheelite C(Sch C)occurs in distal quartz sulfide veins.The extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde stage.Compared with ore-related porphyries,Sch A has a similar REE pattern,but with higher ΣREE,more depleted HREE and slightly lower(^(87)Sr/^(86)Sr)i ratios.These features suggest that Sch A is genetically related to ore-related porphyries,but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic composition.Sch B shows dark(Sch B-I)and light(Sch B-II)domains under CL imaging.From Sch B-I to Sch B-II,LREEs are gradually depleted,with MREEs being gradually enriched.Sch C has the highest LREE/HREE ratio,which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE-rich minerals,such as diopside and garnet,in the early prograde stage.The Mo content in Sch B and Sch C gradually decreased,indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later,the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen fugacity.The extensive interaction of magmatic-hydrothermal fluids and carbonate provides the necessary Ca^(2+)for the precipitation of scheelite in the Mamupu deposit.

关键词： scheelite geochemistry Mamupu Cu deposit Yulong porphyry copper belt eastern Tibet

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Stratigraphic framework and sedimentary evolution during the Cryogenian-Ediacaran transition in northeastern Sichuan Basin,South China

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Petroleum Science 2024年第2期21卷 823-835页

作者： Yi Zhang Hong-Wei Kuang Yong-Qing Liu Qiang Shi Dong-Ge Wang Ke-Ning Qi Yu-Chong Wang Da-Wei Qiao Xiao-Shuai Chen Li-Zhi Wu Meng Tian Long Chen Yi Wei Liao-Yuan Song Jian Li Zi-Gang Wu Yun-Qian Liu Xuan-Chun Liu An-Qing Chen Zhi-Wei Liao Institute of geology Chinese Academy of Geological SciencesBeijing100037China State Key Laboratory of Coal Mine Disaster Dynamics and Control School of Resources and Safety EngineeringChongqing UniversityChongqing400044China No.205 geological team Chongqing Bureau of Geology and Minerals ExplorationChongqing401121China Chongqing Institute of geological Survey Chongqing401122China Key Laboratory of Deep-time Geography and Environment Reconstruction and Applications of Ministry of Natural Resources Chengdu University of TechnologyChengdu610059SichuanChina

The northeastern Sichuan area in the northern Yangtze margin has unique Ediacaran geological records,especially the Doushantuo Formation(DST),and become a hot research area in recent years.However,the Cryogenian-Ediacaran(C-E)boundary has not been precisely identified,which restricts the in-depth study of geological information during this crucial transitional period and is unfavorable for a systematic and complete understanding of the Yangtze Block and even the global paleogeographic pattern.This study conducted stratigraphy,sedimentology,and chronostratigraphy to establish the stratigraphic framework and sedimentary evolution of the C-E transition strata in northeastern Sichuan.The results showed that the Ediacaran sediments,without the cap dolomite,unconformably overlaid the Cryogenian sediments in the studied area.The Member II of the DST,characterized by 50-160 m of red-green sandstone(approximately equivalent to the original Chengkou“Guanyinya Formation”),directly overlaid the Cryogenian sediments and displayed a 623±2.3 Ma maximum depositional age from the detrital zircon U-Pb dating.Regional stratigraphic correlations indicate that the C-E transition strata in northeastern Sichuan had a consistent lithological association and sedimentary sequence characteristics but differed from the Three Gorges.Typically,the upper Nantuo massive glacial diamictites transition to the icebergs rafted lonestone-bearing mudstones at the top,then change upward to DST barrier coast sandstones.The proposed DST of the northeastern Sichuan Basin was divided into three lithostratigraphic members without the regional Member I cap dolomite:(i)Member II purple-red,gray-green sandstone strata,(ii)MemberⅢblack mudstone strata,and(iii)Member IV P-Mn bearing strata.During the C-E transition,the study area experienced(i)the global deglaciation stage in the terminal Marinoan glaciation and(ii)the filling-leveling up stage with clastic rocks in the early Ediacaran.Overall,the early Ediacaran of northeastern Sichuan succeeded the paleogeogr

关键词： Marinoan glaciation Doushantuo formation Cap dolomite Deglacial and coastal deposits Detrital zircon U-Pb dating

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Evolution of Diagenetic Fluid of the Dawsonite-Bearing Sandstone in the Jiyang Depression,Eastern China

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Journal of Ocean University of China 2024年第1期23卷 80-98页

作者： LI Fulai MA Wenkuan ZHANG Chun WANG Kaining National Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao 266580China Laboratory for Marine mineral Resources Qingdao National Laboratory for Marine Science and TechnologyQingdao 266071China Shandong geological exploration Institute of China Chemical geology and Mine bureau Jinan 250013China

Based on the petrology,isotope geochemistry and fluid inclusions analysis,we established the evolutionary mode of the diagenetic fluid of dawsonite-bearing sandstone in the Jiyang Depression.Dawsonite-bearing sandstone is characterized by double injection of CO_(2)and oil-gas in the Jiyang Depression that have experienced a relatively complex diagenetic fluid evolution process.The diagenetic sequence of secondary minerals involves secondary enlargement of quartz,kaolinite,first-stage calcite,dawsonite,second-stage calcite,ferrocalcite,dolomite and ankerite.Hydrocarbon charging in the dawsonite-bearing sandstone occurred at around 2.6–0 Myr.The CO_(2)charging event occurred during Dongying tectonism,forming the Pingfangwang CO_(2)gas reservoir,which provided an abundant carbon source for dawsonite precipitation.Carbon and oxygen isotopic compositions of dawsonite demonstrate that CO_(2)forming the dawsonite was of an inorganic origin derived from the mantle,and that water mediating the proc-ess during dawsonite precipitation was sequestered brine with a fluid temperature of 82℃.The evolutionary sequence of the diagenetic fluid in the dawsonite-bearing sandstone was:alkaline syngenetic fluids,weak alkaline fluids during organic acid forma-tion,acidic fluids in the early stage of CO_(2)injection,alkaline fluids in the late stage of CO_(2)injection,and weak alkaline fluids during oil and gas charging.The mode indicates an increase in-HCO_(3)because of the CO_(2)injection,and the loss of Ca^(2+)and Mg^(2+)due to the precipitation of carbonate minerals.Therefore,the evolutionary mode of diagenetic fluids is in good agreement with high HCO_(3)^(-),low Ca^(2+)and low Mg^(2+)composition of the present formation water in the dawsonite-bearing sandstone.

关键词： evolution of diagenetic fluid dawsonite CO_(2)injection and hydrocarbon charging mineral diagenetic sequence iso-topic geochemistry fluid inclusions

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Triassic integrative stratigraphy,biotas,and paleogeographical evolution of the Qinghai-Tibetan Plateau and its surrounding areas

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Science China Earth Sciences 2024年第4期67卷 1152-1194页

作者： Guichun WU Zhansheng JI Gary GLASH Qinggao ZENG Jianxin YAO Key Laboratory of Stratigraphy and Palaeontology Ministry of Natural ResourcesInstitute of GeologyChinese Academy of Geological SciencesBeijing 100037China SinoProbe Laboratory Chinese Academy of Geological SciencesBeijing 100094China Department of geology and Environmental Sciences State University of New York-FredoniaFredoniaNY 14063USA Xizang Autonomous Region geological and mineral exploration and Development Burea Lhasa 850010China

Rocks of the Qinghai-Tibetan Plateau(QTP)host abundant Triassic fossils.So far,the well established marine fossil sequences based on ammonoids,conodonts,bivalves,brachiopods,radiolarians,and terrestrial spora-pollen sequence have become standard for biostratigraphic correlation of the QTP.For much of Triassic time,the QTP occupied a marine setting as suggested by the dominance of marine deposits.The main sedimentary types represented in the Triassic successions include littoral to shallow marine clastic rocks,shallow marine carbonate platform carbonates,bathyal to abyssal slope carbonates intercalated with clastic and siliceous deposits,coal-bearing clastic strata contained within paralic facies deposits,and littoral and terrestrial volcaniclastic rocks.These deposits are organized into four stages in ascending order:(1)Early Triassic deposits that record marine transgression,including extensive shallow marine carbonate platform strata.(2)Middle Triassic Ladinian to Late Triassic Carnian deposits,including thin-bedded limestone,fine clastics,and siliceous rocks,that accumulated at greater depths than underlying Early Triassic strata and reflect the peak of the transgression.Magmatic activity appears to have occurred in some areas during this stage.(3)Late Triassic Norian deposits that record the onset of marine regression as suggested by the widespread occurrence of platform carbonates.It is noteworthy that stage 3 deposits of the Qin-Qi-Kun area in the northernmost region of the QPT is dominated by terrestrial strata and displays evidence of local erosion.(4)Late Triassic Rhaetian littoral and shallow marine clastic and coal-bearing deposits that preserve the record of continued marine regression continued.The Indus-Yarlungzangbo Suture Zone(IYSZ)appears to have been the rifting axis during Triassic time as suggested by sedimentary facies trends that reflect deepening to south and north.Thus,the Himalaya Block to the south of the IYSZ was part of the passive margin of Gondwana whereas the north side of the IYSZ,

关键词： Qinghai-Tibetan Plateau Triassic Biostratigraphy Lithostratigraphy Palaeobiogeography Sedimentary palaeogeography

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