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Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao Wu Xiaoling Liu Biao Meng Tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Single atom catalyst Synergy effect Carbon catalyst Electrocatalysis

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ZrB_(2)-SiC ceramics toughened with oriented paper-derived graphite for a sustainable approach

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Journal of Advanced Ceramics 2024年第2期13卷 207-219页

作者： Luca Zoli Francesca Servadei Simone Failla Matteo Mor Antonio Vinci Pietro Galizia Diletta Sciti CNR-ISSMC Institute of ScienceTechnology and Sustainability for CeramicsFaenza I-48018Italy

Carbon fibre-reinforced ultra-high temperature ceramics(UHTCs)are considered a class of promising materials for several applications,the most appealing ones being in the aerospace *** is necessary to overcome the brittleness and low thermal shock resistance of ceramics and is often provided through the addition of carbon fibres or other carbon-based phases,such as nanotubes,graphene,and *** present work is focused on the toughening of UHTCs through incorporation of 30-50 vol% thin,ordered graphite layers from conventional filter paper followed by hot pressing *** filter paper was selected because it undergoes thermolysis with no melting stage forming a strong carbonaceous residue that can be used as *** and mechanical properties of toughened composites were compared to those of other materials reinforced with short carbon fibres and the effect of different distribution of graphite was *** of graphite allowed toughness to be increased from 3−4 MPa·m^(1/2)(for unreinforced materials)to 5.1−5.5 MPa·m^(1/2),similar to results obtained with short fibre *** high-temperature properties,such as strength and toughness as well as oxidation resistance at 1500℃,were also examined.

关键词： borides paper-derived graphite microstructure toughness sustainability

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Textural and geochemical characteristics of off shore sediment of North Bay of Bengal:A statistical approach for marine metal pollution

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International Journal of Sediment Research 2015年第3期30卷 208-222页

作者： Sanghamitra Palleyi Sabnam Banoo Rabi Narayan Kar Chitta Ranjan Panda Environment & sustainability Department CSIR-Institute of Minerals and Materials Technology

Metal pollution study on sediments of North Bay of Bengal sediments presented in this paper is based on existing Lithostratigraphy of upstream,mineralogy and geochemical analysis of 42 sediment *** statistical analysis identifies the metal pollution as well as its apparent source in the off shore *** were analyzed for grain size,organic content and heavy metals(Fe,Mn,Cr,Cu,Ni,Pb,Cd,Zn and Co) using the sequential extraction method to evaluate geochemical processes and pollution *** an effort to surmise anthropogenic input,several approaches including classification by quantitative indexes such as enrichment factor,contamination factor,degree of pollution,pollution load index and geo accumulation index,were *** speciation results indicate high%of Cd in exchangeable fraction of Mahanadi transect sediments where as a considerable amount of oxidizable fraction of Cr was detected at *** indexes place North Bay of Bengal under moderately polluted zone due to high level of *** of metals to Fe indicated relatively high enrichment factors for Cd and *** analysis identified seven possible types of geochemical associations where sediment pH plays a major role for the heavy metal *** higher Cd concentration in exchangeable fraction as well as the higher EF for Cd and Cr present in sediment may pose a risk of secondary water pollution under slightest disturbance in the geo-chemistry of *** study with available data of near costal zones and upstream stratigraphy revealed that open cast mining,overburden dumping,mineral based industrial effluents were the major source of pollution for catchment area *** of Bengal is likely to face a serious threat of metal pollution with the present deposition rates unless rigorous pollution control norms are applied.

关键词： North Bay of Bengal Heavy metals Sequential extraction Quantitative index Factor analysis

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Data-driven integrated assessment of global wild-caught seafood exported to Hong Kong by 2030 in different representative concentration and shared socioeconomic pathways

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Advances in Climate Change Research 2022年第4期13卷 554-563页

作者： Zhongming LU Division of Environment and sustainability Hong Kong University of Science and TechnologyHong KongChina

Wild-caught seafood is an important commodity traded *** elimate change and socioeconomic development is affecting global marine capture fisheries,the impact on regional supply remains unexplored,especially for areas like Hong Kong relying on global trading to meet high seafood ***,it is challenging to assess the global marine capture fisheries production using complex process-based *** this study,a data-driven integrated assessment approach was developed to evaluate the change of global seafood supply from wild *** the catch data available from 1990 to 2014,machine learning models were trained and tested including environmental,socioeconomic,geographic,and technological features to estimate the catch by ocean grid cells for individual *** popular seafood categories in Hong Kong were studied,which include 68 species in *** input features for estimating the catch were compared across species and the impacts of these input features were interpreted using partial dependence *** global marine wild catch of the 68 species by countries and the export to Hong Kong were projected by 2030 in RCP2.6-SSPi,RCP4.5-SSP2,RCP7.0-SSP3,and *** of machine learning models demonstrate the reliability of data-driven methods to estimate the catch by ocean grid *** importance of geographic features rank top for the estimate while that of climate change and socioeconomic development varies significantly across *** projection reflects a drop of squid exported to Hong Kong due to the reduction of squid supply from China's mainland during *** export of wild-caught seafood of the nine categories to Hong Kong willhave a slight decline by about 16%from the 2020 level by *** projection also suggests no significant differences among the four climatic-socioeconomically interrelated scenarios regarding the export to Hong Kong before *** producers include China's mainland,United State

关键词： Machine learning Integrated assessment Wild-caught seafood Export to Hong Kong Climate change Socioeconomic development

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Dielectric-ion-conductive ZnNb2O6 layer enabling rapid desolvation and diffusion for dendrite-free Zn metal batteries

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Journal of Energy Chemistry 2025年第1期100卷 693-701页

作者： Haifeng Yang Jian Wang Panpan Zhang Xiaomin Cheng Qinghua Guan Jing Dong Bixian Chen Lujie Jia Jing Zhang Yongzheng Zhang Yunjian Liu Hongzhen Lin School of Materials Science and Engineering Jiangsu University i-Lab & CAS Key Laboratory of Nanophotonic Materials and Devices Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of Sciences Helmholtz Institute Ulm (HIU) Karlsruhe Institute of technology (KIT) School of Materials Science and Engineering Xi'an University of Technology State Key Laboratory of Chemical Engineering East China University of Science and Technology

Rechargeable aqueous zinc-metal batteries （AZMBs） are promising candidates for large-scale energy storage systems due to their low cost and high ***,their performance and sustainability are significantly hindered by the sluggish desolvation kinetics at the electrode/electrolyte interface and the corresponding hydrogen evolution reaction where active water molecules tightly participate in the Zn（H2O）62+solvation ***,learnt from self-generated solid electrolyte interphase （SEI） in anodes,the dielectric but ion-conductive zinc niobate nanoparticles artificial layer is constructed on metallic Zn surface （ZNB@Zn）,acting as a rapid desolvation *** zincophilic and dielectric-conductive properties of ZNB layer accelerate interfacial desolvation/diffusion and suppress surface corrosion or dendrite formation,achieving uniform Zn plating/stripping behavior,as confirmed by electronic/optical microscopies and interface spectroscopical measurements together with theoretical ***,the as-prepared ZNB@Zn electrode exhibits excellent cycling stability of over 2000 h and robust reversibility （99.54%） even under high current density and depth of discharge ***,the assembled ZNB@Zn-based full cell displays high capacity-retention rate of 80.21%after 3000 cycles at 5 A g-1and outstanding rate performance up to 10 A *** large-areal pouch cell is stabilized for hundreds of cycles,highlighting the bright prospects of the dielectric but ion-conductive layer in further application of AZMBs.

关键词： Zn metal battery Dielectric artificial layer Rapid ion diffusion Zincophilic diffusion Active water inhibition

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A novel approach for manufacturing of layered,ultra-refractory composites using pliable,short fibre-reinforced ceramic sheets

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Journal of Advanced Ceramics 2023年第1期12卷 155-168页

作者： Matteo MOR Antonio VINCI Simone FAILLA Pietro GALIZIA Luca ZOLI Diletta SCITI ISSMC-CNR Institute of ScienceTechnology and Sustainability for CeramicsVia Granarolo 6448018 Faenza(RA)Italy

A new additive technique for manufacturing of short fibre-reinforced ultra-refractory ceramics is *** technique allows the fabrication of solvent-free,thin(~100µm),flexible,and easy-to-handle sheets suitable for fabricating homogeneous or layered structures.A large range of compositions,in terms of matrix and fibre volumetric contents,from 0%to 100%is *** amount of short carbon fibres incorporated in the sheets ranged from 20 to 50 vol%,whereas the fibre length ranged from 3 to 5 *** matrix composition investigated with this technique consisted of ZrB_(2)/SiC/Y_(2)O_(3).By increasing the fibre amount from 35 to 50 vol%,an improvement of mechanical properties was ***-point flexural strength(σ)ranged from 107 to 140 MPa,depending on the amount of carbon fibres(Cf).The same holds true for the work of fracture,ranging from 108 to 253 J/m^(2).Functionally graded composites were fabricated by overlapping sheets with a fibre gradient(0%-50%).

关键词： ultra-high-temperature ceramics(UHTCs) ceramic matrix composites(CMCs) short carbon fibres mechanical properties

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Creative Industries Agglomeration,Regional Innovation and Productivity Growth in China

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Chinese Geographical Science 2014年第2期24卷 258-268页

作者： HONG Jin YU Wentao GUO Xiumei ZHAO Dingtao School of Management University of Science and Technology of China Curtin University sustainability Policy Institute Curtin University 3. Pakenham St

This paper falls into the broad area of economic geography and economics of creativity,and it presents an alternative approach to explain why total factor productivity(TFP)growth is different across China′s *** establishes an empirical model to estimate the spatial agglomeration effects of creative industries on regional TFP growth,using China′s provincial panel data during the period of 2003 to *** found that the creative industries agglomeration(CIA)has significant and positive impact on regional TFP *** result also implies that the CIA can facilitate regional TFP growth through promoting regional innovation instead of improving regional ***,we argue that policy makers should take some measures to retain and establish more creative zones.

关键词： creative industries spatial externality creativity industries agglomeration(CIA) total factor productivity(TFP) economic growth

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Magnetically separated and N, S co-doped mesoporous carbon microspheres for the removal of mercury ions

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Chinese Chemical Letters 2016年第5期27卷 795-800页

作者： Ming-Xian Liu Xiang-Xiang Deng Da-Zhang Zhu Hui Duan Wei Xiong Zi-Jie Xu Li-Hua Gan Shanghai Key Lab of Chemical Assessment and sustainability Department of Chemistry Tongji University School of Chemistry and Environmental Engineering Wuhan Institute of Technology

Magnetically separated and N, S co-doped mesoporous carbon microspheres （NIS-MCMs/Fe304） are fabricated by encapsulating Si02 nanoparticles within N, S-containing polymer microspheres which were prepared using resorcinol/formaldehyde as the carbon source and cysteine as the nitrogen and sulfur co-precursors, followed by the carbonization process, silica template removal, and the introduction of Fe3O4 into the carbon mesopores. N/S-MCMs/Fe3O4 exhibits an enhanced Hg2＋ adsorption capacity of 74.5 rag/g, and the adsorbent can be conveniently and rapidly separated from wastewater using an external magnetic field. This study opens up new opportunities to synthesize well- developed, carbon-based materials as an adsorbent for potential applications in the removal of mercury ions from wastewater.

关键词： N S co-doped mesoporous carbonmicrospheres MagnetiteAdsorption Mercury ion Magnetic separation

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Zinc tartrate oriented hydrothermal synthesis of microporous carbons for high performance supercapacitor electrodes

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Chinese Chemical Letters 2016年第3期27卷 399-404页

作者： Ming-Xian Liu Ling-Yan Chen Da-Zhang Zhu Hui Duan Wei Xiong Zi-Jie Xu Li-Hua Gan Long-Wu Chen Shanghai Key Lab of Chemical Assessment and sustainability Department of ChemistryTongji University School of Chemistry and Environmental Engineering Wuhan Institute of Technology

A novel zinc tartrate oriented hydrothermal synthesis of microporous carbons was reported. Zinc–organic complex obtained via a simple chelation reaction of zinc ions and tartaric acid is introduced into the networks of resorcinol/formaldehyde polymer under hydrothermal condition. After carbonization process, the resultant microporous carbons achieve high surface area（up to 1255 m^2/g） and large mean pore size（1.99 nm） which guarantee both high specific capacitance（225 F/g at 1.0 A/g） and fast charge/discharge operation（20 A/g） when used as a supercapacitor electrode. Besides, the carbon electrode shows good cycling stability, with 93% capacitance retention at 1.0 A/g after 1000 cycles. The welldesigned and high-performance microporous carbons provide important prospects for supercapacitor applications.

关键词： Zinc tartrate Hydrothermal synthesis Microporous carbon Supercapacitor Electrode

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Take back and treatment of discarded electronics： a scientific update

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Frontiers of Environmental Science & Engineering 2013年第4期7卷 475-482页

作者： Ab STEVELS Jaco HUISMAN Feng WANG Jinhui LI Boyang LI Huabo DUAN Design for sustainability Lab Delft University of Technology Delft 2600 The Netherlands Department of Environmental Science and Engineering Tsinghua University Beijing 100084 China

This paper indicates that the performance of tack-back and treatment of electronic waste （e-waste） system can be improved substantially. This can be reached by better taking into account in a better way the big variety in material composition and potential toxicity of electrical and electronic products - from a technical, organizational and regulatory perspective. Realizing that there is no ＇one size fit for all＇ and combining smart tailor made solutions with economic of sale will result in the best environmental gain/cost ratio. Several examples show how science and engineering have supported or will support this approach.

关键词： e-waste take back treatment substantially

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