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Study of inter-well interference in shale gas reservoirs by a robust production data analysis method based on deconvolution

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Petroleum science 2024年第4期21卷 2502-2519页

作者： Wen-Chao Liu Cheng-Cheng Qiao Ping Wang Wen-Song Huang Xiang-Wen Kong Yu-Ping Sun He-Dong Sun Yue-Peng Jia School of Civil and Resource Engineering University of Science and Technology Beijing PetroChina research institute of Petroleum Exploration and Development

In order to overcome the defects that the analysis of multi-well typical curves of shale gas reservoirs is rarely applied to engineering, this study proposes a robust production data analysis method based on deconvolution, which is used for multi-well inter-well interference research. In this study, a multi-well conceptual trilinear seepage model for multi-stage fractured horizontal wells was established, and its Laplace solutions under two different outer boundary conditions were obtained. Then, an improved pressure deconvolution algorithm was used to normalize the scattered production data. Furthermore, the typical curve fitting was carried out using the production data and the seepage model solution. Finally,some reservoir parameters and fracturing parameters were interpreted, and the intensity of inter-well interference was compared. The effectiveness of the method was verified by analyzing the production dynamic data of six shale gas wells in Duvernay area. The results showed that the fitting effect of typical curves was greatly improved due to the mutual restriction between deconvolution calculation parameter debugging and seepage model parameter debugging. Besides, by using the morphological characteristics of the log-log typical curves and the time corresponding to the intersection point of the log-log typical curves of two models under different outer boundary conditions, the strength of the interference between wells on the same well platform was well judged. This work can provide a reference for the optimization of well spacing and hydraulic fracturing measures for shale gas wells.

关键词： Shale gas Inter-well interference Deconvolution Production data analysis Typical curves Multi-stage fractured horizontal well

Correlation between hydration properties and electrochemical performances on Ln cation size effect in layered perovskite for protonic ceramic fuel cells

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Journal of Energy Chemistry 2024年第1期88卷 1-9,I0001页

作者： Inhyeok Cho Jiwon Yun Boseok Seong Junseok Kim Sun Hee Choi Ho-Il Ji Sihyuk Choi Department of Mechanical Engineering Kumoh National Institute of TechnologyGumi 39177GyeongbukRepublic of Korea Department of Aeronautics Mechanical and Electronic Convergence EngineeringKumoh National Institute of TechnologyGumi 39177GyeongbukRepublic of Korea Center for Energy Materials research Korea Institute of Science and Technology(KIST)Seoul 02792Republic of Korea Center for Hydrogen and Fuel Cell research Clean Technology Research DivisionKorea Institute of Science and Technology(KIST)Seoul 02792Republic of Korea Department of Energy and Environmental Engineering University of Science and TechnologySeoul 02792Republic of Korea Nanomaterials science and Engineering Korea University of Science and Technology(UST)KIST CampusSeoul 02792Republic of Korea

PrBa_(0.5)Sr_(0.5)Co_(1.5)Fe_(0.5)O_(5+δ)(PrBSCF) has attracted much research interest as a potential triple ionic and electronic conductor(TIEC) electrode for protonic ceramic fuel cells(PCFCs). The chemical formula for Pr BSCF is AA'B_(2)O_(5+δ), with Pr(A-site) and Ba/Sr(A'-site) alternately stacked along the c-axis. Due to these structural features, the bulk oxygen ion diffusivity is significantly enhanced through the disorder-free channels in the PrO layer;thus, the A site cations(lanthanide ions) play a pivotal role in determining the overall electrochemical properties of layered perovskites. Consequently, previous research has predominantly focused on the electrical properties and oxygen bulk/surface kinetics of Ln cation effects,whereas the hydration properties for PCFC systems remain unidentified. Here, we thoroughly examined the proton uptake behavior and thermodynamic parameters for the hydration reaction to conclusively determine the changes in the electrochemical performances depending on LnBa_(0.5)Sr_(0.5)Co_(1.5)Fe_(0.5)O_(5+δ)(LnBSCF,Ln=Pr, Nd, and Gd) cathodes. At 500 ℃, the quantitative proton concentration of PrBSCF was 2.04 mol% and progressively decreased as the Ln cation size decreased. Similarly, the Gibbs free energy indicated that less energy was required for the formation of protonic defects in the order of Pr BSCF < Nd BSCF < Gd BSCF. To elucidate the close relationship between hydration properties and electrochemical performances in LnBSCF cathodes, PCFC single cell measurements and analysis of the distribution of relaxation time were further investigated.

关键词： Protonic ceramic fuel cell Cathode Triple ionic and electronic conductor Hydration property Proton uptake Gibbs free energy

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A high-performance electrochromic device assembled with WO_(3)/Ag and TiO_(2)/NiO composite electrodes towards smart window

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Frontiers of Materials science 2024年第1期18卷 123-135页

作者： Haorui Liu Jikai Yang Decai Nie Chunlei Liu Liumenghan Zheng Yining Mu Weijun Chen Chongqing research institute Changchun University of Science and TechnologyChongqing 400000China School of Physics Changchun University of Science and TechnologyChangchun 130022China

The choice of cathode and anode materials for electrochromic devices plays a key role in the performance of electrochromic smart *** this research,WO_(3)/Ag and TiO_(2)/NiO composite thin films were separately prepared by the hydrothermal method combined with *** electrochromic properties of the single WO_(3) thin film were optimized,and TiO_(2)/NiO composite films showed better electrochromic performance than that of the single NiO ***_(3)/Ag and TiO_(2)/NiO composite films with excellent electrochromic properties were respectively chosen as the cathode and the anode to construct a WO_(3)/Ag‒TiO_(2)/NiO electrochromic *** response time(tc=4.08 s,tb=1.08 s),optical modulation range(35.91%),and coloration efficiency(30.37 cm^(2)·C^(-1))of this electrochromic device are better than those of WO_(3)-NiO and WO_(3)/Ag-NiO electrochromic *** work provides a novel research idea for the performance enhancement of electrochromic smart windows.

关键词： WO_(3)/Ag composite film TiO_(2)/NiO composite film electrochromic device

Predict the evolution of mechanical property of Al-Li alloys in a marine environment

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Defence technology（防务技术） 2024年第1期31卷 557-566页

作者： Wei Li Lin Xiang Guang Wu Hongli Si Jinyan Chen Yiming Jin Yan Su Jianquan Tao Chunyang Huang State Key Laboratory of Explosion science and technology Beijing Institute of TechnologyBeijing100036China Chongqing Innovation Center Beijing Institute of TechnologyChongqing400044China First research institute of the Ministry of Public Security for PR China Beijing100036China Southwest technology and Engineering research institute Chongqing400039China

The ocean is one of the essential fields of national defense in the future,and more and more attention is paid to the lightweight research of Marine equipment and *** study it is to develop a Machine learning(ML)-based prediction method to study the evolution of the mechanical properties of Al-Li alloys in the marine *** obtained the mechanical properties of Al-Li alloy samples under uniaxial tensile deformation at different exposure times through Marine exposure *** obtained the strain evolution by digital image correlation(DIC).The strain field images are voxelized using 2D-Convolutional Neural Networks(CNN)autoencoders as input data for Long Short-Term Memory(LSTM)neural ***,the output data of LSTM neural networks combined with corrosion features were input into the Back Propagation(BP)neural network to predict the mechanical properties of Al-Li *** main conclusions are as follows:*** variation law of mechanical properties of2297-T8 in the Marine atmosphere is *** the increase in outdoor exposure test time,the tensile elastic model of 2297-T8 changes slowly,within 10%,and the tensile yield stress changes significantly,with a maximum attenuation of 23.6%.*** prediction model can predict the strain evolution and mechanical response simultaneously with an error of less than 5%.*** study shows that a CNN/LSTM system based on machine learning can be built to capture the corrosion characteristics of Marine exposure *** results show that the relationship between corrosion characteristics and mechanical response can be predicted without considering the microstructure evolution of metal materials.

关键词： Marine environment Al-Li alloy Machine learning Corrosion

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Synergy enhancement of Co single atoms and asymmetric subnanoclusters for Fenton-like activation

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Nano research 2024年第9期17卷 7935-7944页

作者： Ming Ma Zhiyi Sun Ziwei Deng Xiang Li Fang Zhang Wenxing Chen School of Materials Key Laboratory of Cluster Science Ministry of EducationBeijing Key Laboratory of Photoelectronic/Electrophotonic Conversion MaterialsAdvanced Technologies Research Institute(Jinan)Advanced Research Institute of Multidisciplinary ScienceSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Energy and Catalysis Center School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Analysis and Testing Center Beijing Institute of TechnologyBeijing Institute of TechnologyBeijing 100081China

As a new water treatment technology,Fenton-like reaction has great *** this study,we successfully prepared an excellent Fenton-like catalyst,which is composed of cobalt monoatoms and asymmetric subnanoclusters(labeled CoSA/Clu-C_(2)N),and exhibits excellent peroxymonosulfate(PMS)activation *** directly comparing the catalytic properties of CoSA-C_(2)N and CoSA/Clu-C_(2)N,the synergistic effects of coasymmetric Co subclusters and Co atoms on the activation of PMS and degradation of organic micropollutants were *** results showed that CoSA/Clu-C_(2)N had higher degradation rates of carbamazepine(CBZ),antipyrine(AT)and chlorobenzoic acid(CA)when combined with active oxidant *** cyclic frequency of CBZ was 5.4 min^(-1),which was twice as high as the catalytic constant of CoSA-C_(2)N(2.4 min^(-1)).The results show that CoSA/Clu-C_(2)N cobalt subnanoclusters and cobalt single atom can synergistically improve the catalytic performance of activated PMS oxidation of micropollutants in *** addition,electron paramagnetic resonance(EPR)technology has proved that the introduction of Co subnano clusters in CoSA/Clu-C_(2)N is conducive to the production of singlet oxygen(1O_(2)),thereby improving the efficiency of pollutant *** work lays a solid foundation for the future design of advanced multifunctional catalysts by carefully regulating and combining monmetallic atoms and metal subnanoclusters.

关键词： carbamazepine Fenton-like reaction Co single atoms asymmetrical sub-nanoclusters peroxymonosulfate synergy enhancement

Automatic modulation recognition of radiation source signals based on two-dimensional data matrix and improved residual neural network

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Defence technology（防务技术） 2024年第3期33卷 364-373页

作者： Guanghua Yi Xinhong Hao Xiaopeng Yan Jian Dai Yangtian Liu Yanwen Han science and technology on Electromechanical Dynamic Control Laboratory School of Mechatronical EngineeringBeijing Institute of TechnologyBeijing 100081China BIT Tangshan research institute Beijing 100081China

Automatic modulation recognition(AMR)of radiation source signals is a research focus in the field of cognitive ***,the AMR of radiation source signals at low SNRs still faces a great ***,the AMR method of radiation source signals based on two-dimensional data matrix and improved residual neural network is proposed in this ***,the time series of the radiation source signals are reconstructed into two-dimensional data matrix,which greatly simplifies the signal preprocessing ***,the depthwise convolution and large-size convolutional kernels based residual neural network(DLRNet)is proposed to improve the feature extraction capability of the AMR ***,the model performs feature extraction and classification on the two-dimensional data matrix to obtain the recognition vector that represents the signal modulation *** analysis and simulation results show that the AMR method based on two-dimensional data matrix and improved residual network can significantly improve the accuracy of the AMR *** recognition accuracy of the proposed method maintains a high level greater than 90% even at -14 dB SNR.

关键词： Automatic modulation recognition Radiation source signals Two-dimensional data matrix Residual neural network Depthwise convolution

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Bio-inspired surface manipulation of halloysite nanotubes for highperformance flame retardant polylactic acid nanocomposites

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Nano research 2024年第3期17卷 1595-1606页

作者： Yaru Sun Bin Yu Yan Liu Junbo Yan Zixi Xu Bo Cheng Fenglei Huang Jun Wang State Key Laboratory of Explosion science and technology Beijing Institute of TechnologyBeijing 100081China State Key Laboratory of Fire science University of Science and Technology of ChinaHefei 230026China Beijing institute of technology Chongqing Innovation Center Chongqing 401120China National Engineering research Center of Flame Retardant Materials Beijing Institute of TechnologyBeijing 100081China

High-performance flame-retardant polylactic acid(PLA)bio-composites based on biobased fillers to meet usage requirements represents a promising direction for creating a sustainable *** flame retardant PLA composites have been reported extensively,it still remains a huge challenge to develop mechanically *** flame retardant PLA composites due to plastication effect of organic flame retardants and poor compatibility of organic fillers with the matrix lead to the severe deterioration in mechanical *** this work,a bio-inspired surface manipulation strategy for halloysite nanotubes(HNTs)was proposed via a facile and green self-assembly *** structure and morphology of bio-inspired HNTs(b-HNTs)proved that biomass nanofillers(PA-NA-Fe)grew well both within the lumen and on the surface of *** growth of biomass on the inner and outer surfaces of HNTs was inspired from wooden towards enhancing the interface compatibility and imparting multi-properties to PLA *** mechanical properties(tensile,thermomechanical and anti-impact mechanical),great fire safety(heat release and smoke emission),thermostability and improved electromagnetic interference shielding effectiveness of this well-designed PLA nanocomposite were *** mechanisms of the enhanced performances of the PLA bio-composites by loading b-HNTs were *** work presents a facile and environmentally-friendly bio-inspired modification strategy for HNTs to fabricate high-performance,multi-functional polymer composites,which is also suitable for surface modification of many other nanomaterials,including nanofibers,nanotubes,nanowires,and nanosheets.

关键词： mechanical properties thermostability fire safety electromagnetic interference shielding biomass

Quantitative analysis on resistant forces at oil-surfactant-rock interfaces with dynamic wettability characterization

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Energy Geoscience 2024年第3期5卷 305-312页

作者： Qiaoyu Ge Tao Ma Guanli Xu Zengmin Lun science and technology Experimental research Center Petroleum Exploration and Production Research InstituteSINOPECBeijingChina

Adhesion of oil at rock surface plays an important role in the liberation of oil from micro-/nano-pores,especially for heavy oil that has extremely high *** molecular dynamics simulation is widely used to study the interfacial interaction for some specific oil-water-rock systems,experimental measurements provide more realistic and reliable *** this work,we propose a dynamic wettability characterization method to indirectly measure resistant forces at oil-surfactant-rock interfaces,including frictional force,wettability hysteresis force,and viscous force,which are parallel with the oil-solid *** adhesive force,which is normal to the oil-solid interface is calculated through measurement of work of *** results show that work of adhesion instead of contact angle can better describe the adhesion of oil at solid *** effect of surfactant concentration on work of adhesion is different for water-wet and oil-wet ***,average viscous forces are calculated through force analysis on oil drops moving along solid surface in different surfactant *** is found that viscous force has a magnitude comparable to the frictional force during the movement,while the wettability hysteresis force is *** the other hand,the adhesive force calculated from the work of adhesion is also comparable to the viscous ***,both the resistant forces parallel with and normal to the oil-solid interface should be minimized for the liberation of oil from rock *** work proposes a simple method to evaluate the wetting capability of different surfactants and measure the adhesive force between heavy oil and rock surfaces indirectly,which provides insight into the adhesion of heavy oil at rock surface and would be valuable for the development of surfactant-based oil recovery methods.

关键词： Work of adhesion Wettability characterization Adhesive force Viscous force Surfactant

Mixed-dimensional stacked nanocomposite structures for a specific wavelength-selectable ambipolar photoresponse

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Nano research 2024年第6期17卷 5549-5558页

作者： Young Jae Park Jaeho Shim Joo Song Lee Kyu Seung Lee Ji-Yeon Kim Kang Bok Ko Sang-Youp Yim Seongjun Kim Hoon-Kyu Shin Donghee Park Yong Ju Yun Dong Ick Son institute of Advanced Composite Materials Korea Institute of Science and TechnologyJeollabuk-do 55324Republic of Korea National institute for Nanomaterials technology Pohang University of Science and TechnologyGyeongsangbuk-do 37673Republic of Korea Department of Semiconductor science and technology Semiconductor Physics Research CenterJeonbuk National UniversityJeonju 54896Republic of Korea Advanced Photonics research institute Gwangju Institute of Science and TechnologyGwangju 61005Republic of Korea Center for Opto-Electronic Materials and Devices Post-Silicon Semiconductor InstituteKorea Institute of Science and TechnologySeoul 02792Republic of Korea Graduate School of Energy and Environment(KU-KIST Green School) Korea UniversitySeoul 02841Republic of Korea KIST School Department of Nanomaterials and Nano ScienceUniversity of Science and Technology(UST)Daejeon 34113Republic of Korea

Mixed-dimensional composite structures using zero-dimensional(0D)quantum dots(QDs)and two-dimensional(2D)transition metal dichalcogenides(TMDs)materials are expected to attract great interest in optoelectronics due to the potential to generate new optical ***,we report on the unique optical characteristics of a devices with mixed dimensional vertically stacked structures based on tungsten diselenide(WSe_(2))/CdSeS QDs monolayer/molybdenum disulfide(MoS_(2))(2D/0D/2D).Specifically,it exhibits an ambipolar photoresponse characteristic,with a negative photoresponse observed in the 400-600 nm wavelength range and a positive photoresponse appeared at 700 nm *** resulted in the high negative responsivity of up to 52.22 mA·W^(−1)under 400 nm,which is 163 times higher than that of the photodetector without CdSeS *** also demonstrated the negative photoresponse,which could be due to increased carrier collision probability and non-radiative *** modeling and simulation reveal that Auger recombination among the types of non-radiative recombination is the main cause of negative photocurrent ***,we discovered ambipolar photoresponse near a specific wavelength corresponding to the energy of quantum *** study revealed interesting phenomenon in the mixed low-dimensional stacked structure and paved the way to exploit it for the development of innovative photodetection materials as well as for optoelectronic applications.

关键词： mixed-dimension quantum dot heterostructure photodetector ambipolar photoresponse