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A Beautiful China Initiative Towards the Harmony between Humanity and the Nature

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Frontiers of Environmental Science & Engineering 2024年第6期18卷 33-41页

作者： Changbo Qin Qiang Xue Jiawei Zhang Lu Lu Shangao Xiong Yang Xiao Xiaojing Zhang Jinnan Wang institute of Strategic planning Chinese Academy of Environmental PlanningBeijing 100041China The Center for Beautiful China Chinese Academy of Environmental PlanningBeijing 100041China Chinese Academy of Environmental planning Beijing 100041China

The Beautiful China Initiative(BCI)is a vivid embodiment of the harmonious coexistence between humans and nature during *** the BCI is an effective method for achieving the goals of building a beautiful China,while offering a“Chinese solution”to global sustainable *** article summarizes the progress and main experiences of the BCI,as well as analyzing the primary challenges facing its future ***,five policy recommendations are proposed,which emphasize the importance of top-level design,coordinated planning,and a robust support system in the implementation of the BCI.

关键词： Beautiful China Initiative Ecological civilization Practice Policy suggestion

Recent Advances in Mechanistic Understanding of Metal-Free Carbon Thermocatalysis and Electrocatalysis with Model Molecules

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Nano-Micro Letters 2024年第7期16卷 74-97页

作者： Wei Guo Linhui Yu Ling Tang Yan Wan Yangming Lin CAS Key Laboratory of design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002People’s Republic of China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021People’s Republic of China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002People’s Republic of China institute of urban Environment Chinese Academy of SciencesXiamen 361021People’s Republic of China

Metal-free carbon,as the most representative heterogeneous metal-free catalysts,have received considerable interests in electro-and thermo-catalytic reac-tions due to their impressive performance and *** the past decade,well-designed carbon catalysts with tunable structures and heteroatom groups coupled with various characterization techniques have proposed numerous reaction ***,active sites,key intermediate species,precise structure-activity relationships and dynamic evolution processes of carbon catalysts are still rife with controversies due to the monotony and limitation of used experimental *** this Review,we sum-marize the extensive efforts on model catalysts since the 2000s,particularly in the past decade,to overcome the influences of material and structure limitations in metal-free carbon *** both nanomolecule model and bulk model,the real contribution of each alien species,defect and edge configuration to a series of fundamentally important reactions,such as thermocatalytic reactions,electrocatalytic reactions,were systematically *** with in situ techniques,isotope labeling and size control,the detailed reaction mechanisms,the precise 2D structure-activity relationships and the rate-determining steps were revealed at a molecular ***,the outlook of model carbon catalysis has also been proposed in this work.

关键词： Metal-free carbon catalysts Model catalyst Electrocatalysis Active site Reaction mechanisms

Assessing the socio-cultural impact of urban revitalisation using Relative Positive Impact Index(RPII)

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Built Heritage 2024年第1期8卷 67-83页

作者： Shahim Abdurahiman A.K.Kasthurba Affa Nuzhat Department of Architecture and planning National Institute of Technology CalicutKozhikodeKeralaIndia Faculty of Architecture Avani Institute of DesignThamarasseryKozhikodeKeralaIndia

urban heritage is a vital resource that connects communities to their local *** developments and rapid urbanisation often harm the authenticity of historic areas,disrupting the cultural fabric and altering their *** study introduces the Relative Positive Impact Index(RPll),a novel technique for assessing the socio-cultural impacts of urban *** significance of RPII lies in its ability to quantitatively evaluate the impacts on the cultural fabric and integrity of historic urban areas,which is crucial for sustainable urban *** study's objective is to apply RPII in evaluating qualitative socio-cultural characteristics in historic urban areas,with a focus on four main criteria and 16 sub-criteria,in the case of the Kuttichira *** methodology integrates the analysis of published literature,a quantitative survey mapping the stakeholders'perception,and qualitative *** approach facilitates an in-depth understanding of how urban revitalisation affects local socio-cultural dynamics,preserving the authenticity and character of historic *** study reveals that the revitalisation project in Kuttichira positively impacts the socio-cultural fabric of the area,maintaining cultural integrity and addressing social *** findings offer valuable insights for sustainable urban development and policymaking in historic *** study recommends the application of RPll in other urban precincts for comparative analysis and further development of urban development practices,contributing to informed urban policy and planning decisions.

关键词： urban revitalisation socio-cultural impact relative positive impact index urban heritage sustainability

Exploring device physics of perovskite solar cell via machine learning with limited samples

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Journal of Energy Chemistry 2024年第7期94卷 441-448页

作者： Shanshan Zhao Jie Wang Zhongli Guo Hongqiang Luo Lihua Lu Yuanyuan Tian Zhuoying Jiang Jing Zhang Mengyu Chen Lin Li Cheng Li School of Electronic Science and Engineering Xiamen UniversityXiamen 361005FujianChina Future Display institute of Xiamen Xiamen 361005FujianChina

Perovskite solar cells(PsCs)have developed tremendously over the past ***,the key factors influencing the power conversion efficiency(PCE)of PSCs remain incompletely understood,due to the complexity and coupling of these structural and compositional *** this research,we demon-strate an effective approach to optimize PSCs performance via machine learning(ML).To address chal-lenges posed by limited samples,we propose a feature mask(FM)method,which augments training samples through feature transformation rather than synthetic *** this approach,squeeze-and-excitation residual network(SEResNet)model achieves an accuracy with a root-mean-square-error(RMSE)of 0.833%and a Pearson's correlation coefficient(r)of ***,we employ the permu-tation importance(PI)algorithm to investigate key features for ***,we predict PCE through high-throughput screenings,in which we study the relationship between PCE and chemical *** that,we conduct experiments to validate the consistency between predicted results by ML and experimental *** this work,ML demonstrates the capability to predict device performance,extract key parameters from complex systems,and accelerate the transition from laboratory findings to commercialapplications.

关键词： Perovskite solar cell Machine learning Device physics Performance prediction Limited samples

Mechanical responses of underground carriageway structures due to construction of metro tunnels beneath the existing structure:A case study

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Deep Underground Science and Engineering 2024年第2期3卷 231-246页

作者： Xin Han Fei Ye Xingbo Han Chao Ren Jing Song Ruliang Zhao School of Highway Chang'an UniversityXi'anChina Shandong Province Transportation planning and design institute JinanChina China Water Resources Beifang Investigation Design and Research Co.Ltd.TianjinChina

To understand the mechanical response pattern of the existing structure and ground due to the construction of metro tunnels underneath,the finite difference method is adopted to study the torsional deformation and stress variation of the existing structure and the effect of underground carriageway structures on the surface *** curves of the maximum differential subsidence,torsion angle,and distortion of the cross-section of the existing structure show two peaks in succession during traversing of two metro tunnels beneath *** torsion angle of the existing structure changes when the two tunnels traverse beneath it in opposite *** first traversing of the shield tunnel mainly induces the magnitude variation in torsional deformation of the existing structure,but the second traversing of the subsurface tunnel may cause a dynamic change in the magnitude and form of torsional deformation in the existing *** shielding effect can reduce the surface subsidence caused by metro tunnel excavation to a certain extent,and the development trend of subsidence becomes slower as the excavation continues.

关键词： metro tunnel numerical simulation structural deformation surface subsidence underground carriageway structure

Atmospheric oxidation capacity and O_(3) formation in a coastal city of southeast China:Results from simulation based on four-season observation

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Journal of Environmental Sciences 2024年第2期136卷 68-80页

作者： Gaojie Chen Taotao Liu Jinsheng Chen Lingling Xu Baoye Hu Chen Yang Xiaolong Fan Mengren Li Youwei Hong Xiaoting Ji Jinfang Chen Fuwang Zhang Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Lab of urban Environment and Health Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China University of Chinese Academy of Sciences Beijing 100049China Minnan Normal University Zhangzhou 363000China College of Harbour and Coastal Engineering Jimei UniversityXiamen 361021China Environmental Monitoring Center of fujian Fuzhou 350013China

The pollution of atmospheric ozone in China shows an obvious upward trend in the past ***,the studies on the atmospheric oxidation capacity and O_(3)formation in four seasons in the southeastern coastal region of China with the rapid urbanization remain ***,a four-season field observation was carried out in a coastal city of southeast China,using an observation-based model combining with the Master Chemical Mechanism,to explore the atmospheric oxidation capacity(AOC),radical chemistry,O_(3)formation pathways and *** results showed that the average net O_(3)production rate(14.55 ppbv/hr)in summer was the strongest,but the average O_(3)concentrations in autumn was *** AOC and ROx levels presented an obvious seasonal pattern with the maximum value in summer,while the OH reactivity in winter was the highest with an average value of 22.75 sec^(-1).The OH reactivity was dominated by oxygenated VOCs(OVOCs)(30.6%-42.8%),CO(23.2%-26.8%),NO_(2)(13.6%-22.0%),and alkenes(8.4%-12.5%)in different *** photolysis dominated OH primary source on daytime in winter,while in other seasons,HONO photolysis in the morning and ozone photolysis in the afternoon contributed *** analysis indicated that O_(3)production was controlled by VOCs in spring,autumn and winter,but a VOC-limited and NOx-limited regime in summer,and alkene and aromatic species were the major controlling factors to O_(3)***,the study characterized the atmospheric oxidation capacity and elucidated the controlling factors for O_(3)production in the coastal area with the rapid urbanization in China.

关键词： Atmospheric oxidation capacity Radical chemistry Ozone production Sensitivity analysis

Leafhopper salivary carboxylesterase suppresses JA-Ile synthesis to facilitate initial arbovirus transmission in rice phloem

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Plant Communications 2024年第9期5卷 116-135页

作者： Yunhua Chi Hongxiang Zhang Siyu Chen Yu Cheng Xiaofeng Zhang Dongsheng Jia Qian Chen Hongyan Chen Taiyun Wei Vector-borne Virus Research Center Fujian Province Key Laboratory of Plant VirologyInstitute of Plant VirologyFujian Agriculture and Forestry UniversityFuzhouFujian 350002China

Plant jasmonoyl-L-isoleucine(JA-Ile)is a major defense signal against insect feeding,but whether or how insect salivary effectors suppress JA-Ile synthesis and thus facilitate viral transmission in the plant phloem remains *** carboxylesterases(CarEs)are the third major family of detoxification ***,we identify a new leafhopper CarE,CarE10,that is specifically expressed in salivary glands and is secreted into the rice phloem as a saliva *** CarE10 directly binds to rice jasmonate resistant 1(JAR1)and promotes its degradation by the proteasome ***,the direct association of CarE10 with JAR1 clearly impairs JAR1 enzyme activity for conversion of JA to JA-Ile in an in vitro JAIle synthesis system.A devastating rice reovirus activates and promotes the co-secretion of virions and CarE10 via virus-induced vesicles into the saliva-storing salivary cavities of the leafhopper vector and ultimately into the rice phloem to establish initial ***,a virus-mediated increase in CarE10 secretion or overexpression of CarE10 in transgenic rice plants causes reduced levels of JAR1 and thus suppresses JA-Ile synthesis,promoting host attractiveness to insect vectors and facilitating initial viral *** findings provide insight into how the insect salivary protein CarE10 suppresses host JA-Ile synthesis to promote initial virus transmission in the rice phloem.

关键词： leafhopper salivary protein CarE10 JAR1 degradation JA-Ile synthesis rice phloem initial viral transmission

Synergic catalysis of W and Ni originating from substitution of trivacant phosphotungstate for the selective oxidation of aniline to azoxybenzene

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Chinese Chemical Letters 2024年第2期35卷 558-563页

作者： Sheng Cai Xiao-Yuan Wu Weiming Wu Sa-Sa Wang Can-Zhong Lu CAS Key Laboratory of design and Assembly of Functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350117China Xiamen institute of Rare Earth Materials Chinese Academy of SciencesXiamen 361021China University of Chinese Academy of Sciences Beijing 100049China

Partial substitution of polyoxometalate(POM)is an efficient route to modulate the catalytic property of maternal *** this work,a new Keggin type POM involving{Ni 6}cluster,{[Ni(H_(2)O)_(2)(Dach)_(2)][Ni(Dach)_(2)]_(2)}{[Ni_(6)Cl(μ-OH)_(3)(H_(2)O)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))][Ni_(6)(μ-OH)_(3)(H_(2)O)_(2)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))]}Cl·27H_(2)O,(1,Dach=1,2-diaminocyclohexane)was *** 1 shows excellent catalytic performance in the selective oxidation of aniline to azoxybenzene(AOB)in *** apparently different results from that with the matrix{PW_(9)O_(34)}({PW9})suggest the successful regulation of the catalytic property of{PW9}by the introduction of the{Ni6}cluster into the *** experimental results indicate that the highlighted performance of 1 is contributed by the synergy of W and Ni sites,which are respectively responsible for the oxidation and condensation steps in the production of *** good selectivity to AOB is essentially attributed to the effective modulation of the reaction rates of oxidation and condensation steps by W and Ni sites,respectively.

关键词： Polyoxometalate {Ni_(6)}cluster Modulated catalytic property Aniline oxidation Azoxybenzene

Experimental study on mix proportion optimization of anti-calcium dissolution shotcrete for tunnels based on response surface methodology

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Underground Space 2024年第2期15卷 203-220页

作者： Chongming Tian Yueping Tong Junyuan Zhang Fei Ye Guifeng Song Yin Jiang Meng Zhao School of Highway Chang’an UniversityXi’an 710064China Yunnan Laman Expressway Co. Ltd.Yunnan Xishuangbanna 666300China Hebei Traffic planning design institute Shijiazhuang 050035China

Aiming at the issue of crystallization and blockage of drainage system due to the massive calcium loss from the tunnel shotcrete,a selfdesigned tunnel seepage crystallization modelling system was *** system was produced in conjunction with the initial tunnel support shotcrete construction and drainage pipe installation,and is capable of simulating both the seepage process of groundwater in the shotcrete and the process of crystallization in the drainage *** on three different mechanisms of anti-crystallization,which include absorbing free calcium,reducing the porosity and increasing hydrophobicity,antialkali agent,nano-calcium carbonate,and silane were selected to test,***,the suitable dosing ranges of these three external admixtures for resisting calcium loss in shotcrete were determined by single factor tests,which were 7%–11%,4%–8%,and 0.3%–0.5%,***,the response surface method was employed to evaluate the interaction of antialkali agent,nano-calcium carbonate and silane on calcium loss in shotcrete,and to establish the relationship between them,and thus to determine the admixture ratio that can effectively reduce calcium loss crystallization in shotcrete,with the optimal admixture amounts of antialkali agent being 9.242%,nano-calcium carbonate 4.889%and silane 0.366%.Lastly,the reliability of the model test results was verified by the microscopic analysis,and the results showed that the total amount of calcium dissolution in the optimized group could be reduced by 75%compared with the blank control group,and was basically consistent with that derived from the response surface regression model,validating the high accuracy of the buildup response surface regression *** present study can provide some ideas and references for reducing the seepage crystallization behavior of groundwater in the initial tunnel support shotcrete.

关键词： Tunnel engineering Calcium loss Crystallization blockage Model test Response surface methodology Interaction effect