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Elucidating the Role of Mass Transfer in Electrochemical Redox Reactions on Electrospun Fibers

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Transactions of Tianjin University 2023年第5期29卷 313-320页

作者： Yan Li Ziwang Kan Lina Jia Dan Zhang Yan Hong Jingjing Liu Haibo Huang Siqi Li Song Liu College of Chemistry Chemical Engineering and Resource UtilizationNortheast Forestry UniversityHarbin 150040China department of Materials Science and engineering Northeast Forestry UniversityHarbin 150040China

Mass transfer can tune the surface concentration of reactants and products and subsequently infl uence the catalytic perfor-mance.The morphology of nanomaterials plays an important role in the mass transfer of reaction microdomains,but related studies are lacking.Herein,a facile electrospinning technique utilizing cellulose was employed to fabricate a series of carbon nanofi bers with diff erent diameters,which exhibited excellent electrochemical nitrate reduction reaction and oxygen evolu-tion reaction activities.Furthermore,the microstructure of electrocatalysts could infl uence the gas-liquid-solid interfacial mass transfer,resulting in diff erent electrochemical performances.

关键词： Mass transfer Electrospinning Electrochemical nitrate reduction reaction Oxygen evolution reaction

Repairing of rutin to the toxicity of combined F-53B and chromium pollution on the biofilm formed by Pseudomonas aeruginosa

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Journal of Environmental Sciences 2023年第5期127卷 158-168页

作者： Yunhao Zhang Yi Qian Ming Zhang Weichuan Qiao department of Environmental engineering College of Biology and the EnvironmentNanjing Forestry UniversityNanjing 210037China

The wastewater discharge from the process of chrome plating,which contains 6:2 chlorinated polyfluorinated ether sulfonate(F-53B)and chromium(Cr),may be toxic to biofilm.In this study we found that the biofilm formed by Pseudomonas aeruginosa PAO1 was inhibited by exposure to a combination of F-53B and Cr(VI).The combined pollution damaged the cell membranes and the structure of the biofilm,and inhibited the production of the Pseudomonas quinolone-based signal,which affected biofilm formation.Moreover,the secretion of extracellular polymeric substances decreased as a result of this combined exposure.Exposure to F-53B and Cr(VI)individually or in combination could induce the excessive accumulation of intracellular reactive oxygen species(ROS),and the ROS positive rate of the bacteria increased under the treatment with 0.2 mmol/L of Cr(VI)and 250 nmol/L of F-53B,respectively.In addition,the activities of superoxide dismutase(SOD)and catalase(CAT)were enhanced for scavenging ROS in the bacteria that were exposed to Cr(VI)and F-53B.As an antioxidant,rutin was used to repair the toxicity of Cr(VI)and F-53B towards the biofilm formed by the bacteria.When rutin was added to the bacteria medium,with either Cr(VI)or F-53B as pollutant,or with the combined pollutants,the extracellular protein content of the bacteria recovered to 0.84,0.94,and 0.85 times that of the control,respectively.Meanwhile,the accumulation of ROS and the activities of SOD and CAT decreased,which indicated that the addition of rutin can alleviate the oxidative stress and promote the antioxidant stress system.

关键词： F-53B Chromium(Cr) Rutin Biofilm Toxic effect Repair

Effects of precommercial thinning on growth parameters in Pinus nigra Arn.subsp.pallasiana(Lamb.)Holmboe stand

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Journal of forestry Research 2020年第5期31卷 1803-1811页

作者： Esra Bayar Ayse Deligoz department of forestry engineering Faculty of ForestryIsparta University of Applied SciencesIsparta 32260Turkey

We investigated the effects of precommercial thinning(PCT)applied at different levels on the growth parameters of natural Anatolian black pine stand.The experimental site was located in the province of Isparta in southern Turkey.PCT was set up using a randomized complete block design with three replicates and three treatments(control,2–2.5 m×–2.5 m and 3–3.5 m×–3.5 m spacing).The experimental plots were established in March 2014.At the end of the growing seasons for three years(2014–2016),growth parameters such as diameter,height and crown radius were measured.PCT was found to be significantly effective on diameter,height,individual tree basal area,and crown radius increment at the end of the third year(p<0.05).While diameter,individual tree basal area and crown radius increment increased with increasing PCT intensity,height increment was higher in control than PCT.Although the PCT treatments applied with 3–3.5 m spacing affected individual tree development positively,we need long-term results on wood quality and yield.According to the short-term results,it is thought that it is better to lower the stand closeness gradually,so,it may be advisable to apply PCT by 2–2.5 m×–2.5 m spacing.

关键词： Precommercial thinning Anatolian black pine Diameter increment Height increment

Effects of stand types on recreational preferences of society in the Sub-Alpine Zone,northern Turkey

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Journal of Mountain Science 2022年第11期19卷 3246-3256页

作者： Tuğrul VAROL Halil BarışÖZEL Ferhat KARA İlkimÇAVUŞKARA Sezgin AYAN Bartın University Faculty of ForestryDepartment of Forest EngineeringBartın 74100Turkey Kastamonu University Faculty of ForestryDepartment of Forest EngineeringKastamonu 37150Turkey Kastamonu-Ilgaz Mountain National Park Directorate Kastamonu 37100Turkey

The main objective of this study was to examine how different stand types influenced the tendency of visitors for varying recreational activities(i.e.,hiking,trekking,camping and hunting)from 1993 to 2018 in the surrounding areas of Uluyayla Natural Recreation Site in Bart1n,northern Turkey.A total of 627 visitors were selected on a voluntary basis,and questioned in the form of questionnaire.Most of the participants were in the age of 21-40 years old,and they were mostly(62.4%)male.Most of the participants(82.7%)lived in cities,while 62.8%of them were tourists when visiting the site.In determining the preferences of the visitors regarding the stand types for different recreational activities,several images of each stand were shared with them,and they were asked which stand type they would prefer for a given recreation activity(i.e.,hiking,tracking,camping and hunting).A range of options from 1 to 5 in Likert's scale was used in evaluating the given responses.The degree of positive and negative effects was examined via trend analysis.It was found that stand type had influence on the preferences of visitors regarding the recreational activities.In general,unmanaged and moderately treated stands were more preferred by visitors for the recreational purposes,compared to the previously managed stands.On the other hand,visitors'preference for the activities were different during two periods(i.e.,1993-2005 and 2006-2018).For each recreational activity,there was an increasing trend from 1993 to 2018.There had been a continuous increase for hunting since 1996,and for trekking and camping after 1999.The increases between 1993-1996 and 1996-1999 were likely due to the increasing awareness of the society as a result of the training and consciousness raising activities for nature conservation.The demand on the recreational activities continuously increased in unmanaged and moderately treated stands,while no significant changes were examined in the previously managed stands.The study points out that forest planning and manageme

关键词： Camping Hunting National Park Recreation Subalpine Silviculture

Modelling height-diameter relationships in complex tropical rain forest ecosystems using deep learning algorithm

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Journal of forestry Research 2022年第3期33卷 883-898页

作者： Friday Nwabueze Ogana Ilker Ercanli department of Social and Environmental forestry Faculty of Renewable Natural ResourcesUniversity of IbadanIbadanOyo200284Nigeria department of Forest engineering Faculty of ForestryÇankiri Karatekin UniversityÇankiri18200Turkey

Modelling tree height-diameter relationships in complex tropical rain forest ecosystems remains a challenge because of characteristics of multi-species, multi-layers, and indeterminate age composition. Effective modelling of such complex systems required innovative techniques to improve prediction of tree heights for use for aboveground biomass estimations. Therefore, in this study, deep learning algorithm (DLA) models based on artificial intelligence were trained for predicting tree heights in a tropical rain forest of Nigeria. The data consisted of 1736 individual trees representing 116 species, and measured from 52 0.25 ha sample plots. A K-means clustering was used to classify the species into three groups based on height-diameter ratios. The DLA models were trained for each species-group in which diameter at beast height, quadratic mean diameter and number of trees per ha were used as input variables. Predictions by the DLA models were compared with those developed by nonlinear least squares (NLS) and nonlinear mixed-effects (NLME) using different evaluation statistics and equivalence test. In addition, the predicted heights by the models were used to estimate aboveground biomass. The results showed that the DLA models with 100 neurons in 6 hidden layers, 100 neurons in 9 hidden layers and 100 neurons in 7 hidden layers for groups 1, 2, and 3, respectively, outperformed the NLS and NLME models. The root mean square error for the DLA models ranged from 1.939 to 3.887 m. The results also showed that using height predicted by the DLA models for aboveground biomass estimation brought about more than 30% reduction in error relative to NLS and NLME. Consequently, minimal errors were created in aboveground biomass estimation compared to those of the classical methods.

关键词： Artificial intelligence Height-diameter model Mixed-effects Nonlinear least squares Tropical mixed forest

Combining bioactive compounds and antioxidant activity profiling provide insights into assessment of geographical features of Chinese jujube

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Food Bioscience 2022年第2期46卷 605-616页

作者： Cheng Wang Rui Wang Chendan Fu Xiaoxuan Jiang Xingang Li Gang Han Jingfang Zhang department of forestry engineering College of ForestryNorthwest A&F UniversityYanglingShaanxi712100China Center for Jujube engineering and Technology of State forestry Administration Northwest A&F UniversityYanglingShaanxi712100China

As the largest jujube cultivating areas of the world,the market price and quality of Chinese jujube are obviously affected by its producing regions in China.Therefore,traceability of Chinese jujube has become an important issue.To search the suitable geographical labels of Chinese jujube,26 major cultivars from five geographical regions of China were investigated by evaluating their bioactive compounds and antioxidant activity profiling.Multivariate statistical techniques(e,g.,PCA,PLS,VIP value)applied to the above-obtained data were further used to identify geographical origin in different areas of Chinese jujube.The results indicated that the highest median contents of total phenols(TP)and flavonoids(TF)of Chinese jujube were originated from Ningxia and Henan provinces,both of which also exhibited the stronger bioactivity.p-Hydroxybenzoic acid and rutin exhibited the highest contents among the all detected individual phenolic compounds.The highest median contents of cyclic adenosine monophosphate(cAMP),cyclic guanosine monophosphate(cGMP)and polysaccharides were all found in Chinese jujube samples of Xinjiang province.In particular,p-hydroxybenzoic acid,rutin,cAMP,cGMP and polysaccharides can be regarded as the potential biomarkers in distinguishing the geographical origin of Chinese jujube.Additionally,the high altitude and latitude might be benefit for the accumulation of cAMP,cGMP and polysaccharides(primary metabolites),and high longitude and annual precipitation maybe improve the contents of TP and TF(secondary metabolites).These information could provide an effective methods in distinguishing the geographical features of Chinese jujube,and also be benefit for the products development.

关键词： Chinese jujube Geographical features Bioactive constituents Antioxidant activity

Clonal propagation of mastic tree(Pistacia lentiscus var.chia Duham.) in outdoor beds using different rootstock and grafting techniques

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Journal of forestry Research 2018年第4期29卷 1052-1058页

作者： Salih Parlak department of Forest engineering Faculty of ForestryBursa Technical University

We assessed different rootstocks and grafting techniques to clonally propagate mastic tree （Pistacia lentiscus var. chia）. Mastic tree is a dioecious tree but the quantity and quality of the resin secreted by female trees are very low; therefore, male trees that are clonally propagated are used to establish commercial plantations for mastic production. Conventional long branch cuttings for clonal production requires too much materials and has a very low rooting rate. Rooting with tissue culture and green cuttings has also failed outdoors. Grafting of mastic on other Pistacia species has not been tried so far; therefore, this study was aimed at developing grafting methods for the clonal propagation of mastic. P. atlantica and P. lentiscus rootstocks were grafted from 15 February to 15 October every 15 days using three grafting methods and a two-factor randomized block trial design. Early spring （15 February-15 March） proved to be the best time for grafting using either of the rootstocks. The highest grafting success was attained using the scions grafted on P. atlantica from 15 February to 15 March. The best bud-burst percentage was obtained using P. atlantica and P. lentiscus rootstocks.

关键词： Pistacia lentiscus var chia Grafting Budding Rootstock

Optimization of CNC cutting parameters using design of experiment(DOE) and desirability function

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Journal of forestry Research 2018年第5期29卷 1423-1434页

作者： Ender Hazir Emine Seda Erdinler Kücük Hüseyin Koc department of Forest Industrial engineering Faculty of ForestryIstanbul University

In this study,2~5 （five factors at two-level factorial design） design of experiment was applied to investigate a set of optimal machining parameters to achieve a minimum surface roughness value for Abies nordmanniana.Wood specimens were prepared using different values of spindle speed,feed rate,depth of cut,tool radius,and cutting directions.Average surface roughness （R_z） values were applied using a stylus.The objectives were to：（1）obtain the effective variables of wood surface roughness;（2） analyze which of these factors had an impact on variability in the CNC machining process;（3） evaluate the optimal cutting values within the range of different cutting levels of machining parameters.The results indicate that the design of experiment（DOE） based on the desirability function approach determined the optimal machining parameters successfully,leading to minimum R_a compared to the observed value.Minimum surface roughness values of tangential and radial cutting directions were 3.58 and 3.21 μm,respectively.

关键词： Wood surface roughness Optimization CNC Desirability function Pareto analysis

Analytical Investigation into the Rotational Performance of Glulam Bolted Beam-Column Connections under Coupled Bending Moment and Shear Force

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Journal of Renewable Materials 2023年第4期11卷 2033-2054页

作者： Xiaofeng Zhang Lisheng Luo Youfu Sun Xinyue Cui Yongqiang Zhang department of Wooden Structure Construction College of Materials Science and EngineeringNanjing Forestry UniversityNanjingChina department of Civil engineering College of Civil Engineering and ArchitectureHainan UniversityHaikouChina

Considering the glulam beam-column connection form and the number of bolts,monotonic loading test and finite element analysis was carried out on 9 connection specimens in 3 groups to study the rotational performance and failure mode of the connection.The test results revealed that compared with U-shaped connectors,T-shaped connectors can effectively improve the ductility of connections,and the increase in the number of bolts can reduce the initial stiffness and ductility of connections.By theoretical analysis,formulas for calculating the initial stiffness and ultimate moment of connections were deduced.Subsequently,the moment-rotation theoretical model of connections was established based on the formulas,which were validated according to the test data and simulation results.The proposed model can not only improve the current theoretical system of heavy-duty glulam beam-column structure but also provide a theoretical basis for calculating the mechanical properties of the glulam beam-column connection.

关键词： Beam-column connection mechanical properties stiffness ultimate moment