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Highly efficient recovery of waste LiNi_(x)Co_(y)Mn_(z)O_(2) cathode materials using a process involving pyrometallurgy and hydrometallurgy

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Frontiers of Environmental science & Engineering 2024年第2期18卷 149-160页

作者： Tianwei Zhang Juanye Dao Jinsong Wang Yuzhong Guo Rundong Wan Chengping Li Xian Zhou Zhengfu Zhang faculty of Materials science and Engineering Kunming University of Science and TechnologyKunming 650093China

Substantial environmental and economic benefits can be achieved by recycling used lithium-ion batteries. Hydrometallurgy is often employed to recover waste LiNi_(x)Co_(y)Mn_(z)O_(2) cathode materials. As Ni, Co and Mn are transition metals, they exhibit similar properties;therefore, separating them is difficult. Thus, most researchers have focused on leaching processes, while minimal attention has been devoted to the separation of valuable metals from waste LiNi_(x)Co_(y)Mn_(z)O_(2) cathode materials. Herein, we propose an environment-friendly, gentle process involving the usage of pyrometallurgy and hydrometallurgy to gradually leach valuable metals and effectively separate them. Interestingly, Li is recovered through a reduction roasting and water leaching process using natural graphite powder, Ni and Co are recovered through ammonia leaching and extraction processes and Mn is recovered through acid leaching and evaporation–crystallization processes. Results show that ~87% Li, 97.01% Co, 97.08% Ni and 99% Mn can be leached using water, ammonia and acid leaching processes. The result obtained using the response surface methodology shows that the concentration of (NH4)2SO3 is a notable factor affecting the leaching of transition metals. Under optimal conditions, ~97.01% Co, 97.08% Ni and 0.64% Mn can be leached out. The decomposition of LiNi_(x)Co_(y)Mn_(z)O_(2) is a two-step process. This study provides valuable insights to develop an environment-friendly, gentle leaching process for efficiently recycling valuable metals, which is vital for the lithium-ion battery recycling industry.

关键词： Waste LiNixCoyMnzO2 cathode materials Leaching Effective separation Series process

Microstructures and Properties of Biomedical Mg-Zn-Sn-Zr Rolled Alloys

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Journal of Wuhan University of technology(Materials science) 2024年第3期39卷 766-773页

作者：周生刚 ZHANG Daxin XU Yang DUAN Jihao LI Tao LIU Junfeng WANG Peng 曹勇 faculty of Material science and Engineering Kunming University of Science and TechnologyKunming 650093China

The as-cast Mg-2.0Zn-1.5Sn-xZr(x=0,0.4,0.6,0.8,1.0 wt%)alloy was rolled with the pressure less than 5%each *** microstructure,mechanical properties,corrosion properties and biocompatibility of the alloy were *** microstructure of the alloy was observed and analyzed by scanning electron microscope,and the tensile test was carried out by universal tensile *** corrosion resistance of the alloy in Hank's solution was studied by hydrogen evolution experiment and electrochemical test,and the biocompatibility of the alloy was tested by L929 *** results show that Mg-2Zn-1.5Sn-xZr alloy has excellent mechanical *** elongation of Mg-2Zn-1.5Sn-xZr alloy decreases with the increase of Zr content,but the tensile strength first increases and then decreases with the increase of Zr *** the Zr content is 0.8 wt%,the maximum tensile strength of the alloy is 235 *** results of hydrogen evolution experiment and electrochemical analysis show that the corrosion resistance of the alloy is the best when the Zr content is 0.8 wt%,and all the five alloys have high *** conclusion,the rolled alloy has good properties and has broad application prospects in the field of biomaterials.

关键词： magnesium alloy corrosion performance mechanical properties biocompatibility

Capturing and visualizing the phase transition mediated thermal stress of thermal barrier coating materials via a cross-scale integrated computational approach

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Journal of Advanced Ceramics 2024年第4期13卷 413-428页

作者： Mengdi Gan Tianlong Lu Wei Yu Jing Feng Xiaoyu Chong faculty of Materials science and Engineering Kunming University of Science and TechnologyKunming 650093China

The generation and evaluation of severely high thermal stress(σ)is known to be responsible for failure of thermal barrier coatings(TBCs)during thermal *** is crucial and challenging to capture fluctuations inσcaused by the phase transition,which has motivated us to develop a high-throughput multiscale evaluation method forσin TBCs that considers the phase transition of the top ceramic materials by coupling first-principles calculations with finite element *** method quantitatively evaluates and visualizesσof the real TBC structure under thermal cycling by multifield ***,the thermophysical properties calculated by the first-principles calculations consider the effects of temperature and phase transition,which not only reduces the cost of obtaining data but also has a more physical *** this work,rare earth tantalites(RETaO_(4))are introduced as ceramic layers,and the results demonstrate thatσundergoes a rapid escalation near the phase transition temperature(T_(t)),particularly in the TBCs_GdTaO_(4) system,where it rises from 224 to 435 *** discontinuity inσmay originate from the significant alterations in Young’s modulus(increase by 27%–78%)and thermal conductivity(increase by 53%–146%)near T_(t).The TBCs_NdTaO_(4) and TBCs_SmTaO_(4) systems exhibit noteworthy temperature drop gradients and minimalσfluctuations,which are beneficial for extending service lifetime of *** approach facilitates the prediction of failure mechanisms and provides theoretical guidance for the reverse design of TBC materials to obtain low thermal stress systems.

关键词： thermal conductivity first-principles calculations thermodynamics thermal stress thermophysical properties

Highly enhanced thermoelectric and mechanical performance of copper sulfides via natural mineral in-situ phase separation

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Journal of Advanced Ceramics 2024年第5期13卷 641-651页

作者： Xi Yan Hongjiang Pan Yixin Zhang Tianyu Yang Yangwei Wang Kun Huang Chongyu Wang Jing Feng Zhenhua Ge faculty of Materials science and Engineering Kunming University of Science and TechnologyKunming 650093China

In situ phase separation precipitates play an important role in enhancing the thermoelectric properties of copper sulfides by suppressing phonon *** this study,Cu1.8S composites were fabricated by melting reactions and spark plasma *** complex structures,namely,micron-PbS,Sb_(2)S_(3),nano-FeS,and multiscale pores,originate from the introduction of FePb_(4)Sb_(6)S_(14)into the Cu1.8S *** effective element(Fe)doping and multiscale precipitates,the Cu_(1.8)S+0.5 wt%FePb_(4)Sb_(6)S_(14)bulk composite reached a high dimensionless figure of merit(ZT)value of 1.1 at 773 ***,the modulus obtained for this sample was approximately 40.27 GPa,which was higher than that of the pristine *** study provides a novel strategy for realizing heterovalent doping while forming various precipitates via in situ phase separation by natural minerals,which has been proven to be effective in improving the thermoelectric and mechanical performance of copper sulfides and is worth promoting in other thermoelectric systems.

关键词： in situ precipitates jamesonite natural mineral thermoelectric copper sulfides

Effect of Sc on Al_(3)Fe phase and mechanical properties of as-cast AA5052 aluminum alloy

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China Foundry 2024年第3期21卷 257-264页

作者： Yang Li Qing Yu Feng-feng Chen Jia-wen He Hong-mei Yang Meng-nie Li faculty of Materials science and Engineering Kunming University of Science and TechnologyKunming 650093China

The AA5052 aluminum alloy is widely used in automobile and aerospace manufacturing,and with the development of light-weight alloys,it is required that these materials exhibit better mechanical *** studies have demonstrated that the addition of Sc to aluminum alloys can improve both the microstructure and properties of the *** this study,the effect of Sc on the Fe-rich phase and properties of the AA5052 aluminum alloy was studied by adding 0%,0.05%,0.2%,and 0.3%*** results show that with the increase of Sc,the coarse needle-like Fe-rich phase gradually transforms into Chinese-script and then nearly spherical particles,reduce the size of Fe-rich phase,and refine the grain with increase of high angle grain boundaries(HAGBs).These microstructure changes enhance the strength of the AA5052 alloy through Sc *** ductility of the alloy is obviously improved because the addition of a lower amount of Sc changes the morphology of Fe-rich phase from needle-like into a Chinese-script,and it is subsequently reduced as a result of significant increase in HAGBs with increasing Sc content.

关键词： AA5052 aluminum alloy Al3Fe phase mechanical properties grain boundary

Single-photon scattering and quantum entanglement of two giant atoms with azimuthal angle differences in a waveguide system

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Chinese Physics B 2024年第5期33卷 337-342页

作者：黄劲松黄红武李艳玲徐中辉 School of Information Engineering Jiangxi University of Science and TechnologyGanzhou 341000China faculty of science Jiangxi University of Science and TechnologyGanzhou 341000China

We theoretically investigate coherent scattering of single photons and quantum entanglement of two giant atoms with azimuthal angle differences in a waveguide *** the real-space Hamiltonian,analytical expressions are derived for the transport spectra scattered by these two giant atoms with four azimuthal ***-like resonance can be exhibited in the scattering spectra by adjusting the azimuthal angle *** concurrence of the entangled state for two atoms can be implemented in a wide angle-difference range,and the entanglement of the atomic states can be switched on/off by modulating the additional azimuthal angle differences from the giant *** suggests a novel handle to effectively control the single-photon scattering and quantum entanglement.

关键词： quantum transport quantum entanglement scattering theory optical waveguide

Attaining synergetic equilibrium of electrical conductivity and tensile strength in GQDs@GN/Cu composites through multi-scale intragranular and intergranular reinforcements

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Rare Metals 2024年第1期43卷 366-379页

作者： Shuang-Yin Zhang Liang Liu Rui Bao Jian-Hong Yi Sheng-Da Guo faculty of Materials science and Engineering Kunming University of Science and TechnologyKunming 650093China Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and TechnologyKunming 650093China faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and TechnologyGanzhou 341000China

The configuration and quality of reinforcements, as well as the robustness of interfacial bonding,holding a critical significance in determining the concurrence between electrical conductivity and mechanical strength in metal matrix composites. In this study, citric acid was employed as the precursor for synthesizing multiscale carbon nanomaterials(graphene quantum dots and graphene, abbreviated as GQDs and GN). The GQDs@GN/Cu composites were fabricated through a segmented ball milling process in conjunction with subsequent spark plasma sintering(SPS). The intragranular GQDs and intergranular GQDs@GN had synergistically reinforced Cu composites through Orowan strengthening, load transfer strengthening and refinement strengthening. Furthermore,the robust interface bonding between GQDs@GN and Cu effectively mitigated interfacial impedance stemming from electron-boundary scattering. The yield strength and ultimate tensile strength of the GQDs@GN/Cu composites were recorded as 270 and 314 MPa, respectively, representing an improvement of 92 and 28% over pure Cu, while maintaining electrical conductivity at a level comparable to that of pure Cu. This study advances the understanding of the possibility of realizing a synergistic compatibility between electrical conductivity and mechanical strength in Cu composites.

关键词： Cu matrix composites Interface bonding Mechanical property Graphene quantum dots(GQDs) Electrical conductivity

Frequency-tunable single-photon router based on a microresonator containing a driven three-level emitter

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Chinese Physics B 2024年第6期33卷 377-381页

作者：黄劲松胡菁兰李艳玲徐中辉 School of Information Engineering Jiangxi University of Science and TechnologyGanzhou 341000China faculty of science Jiangxi University of Science and TechnologyGanzhou 341000China

We propose a frequency-tunable router of single photons with high routing efficiency, which is constructed by two waveguides mediately linked by a single-mode whispering gallery resonator with a driven three-level emitter. Quantum routing probability in the output port is obtained via the real-space Hamiltonian. By adjusting the resonator–emitter coupling and the drive, the desired continuous central frequencies for the resonance peaks of routing photons can be manipulated nearly linearly, with the assistance of Rabi splitting effect and optical Stark shift. The proposed routing system may provide potential applications in designing other frequency-modulation quantum optical devices, such as multiplexers,filters, and so on.

关键词： quantum routing scattering theory optical waveguide microresonator

Modified DS np Chart Using Generalized Multiple Dependent State Sampling under Time Truncated Life Test

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Computer Modeling in Engineering & sciences 2024年第3期138卷 2471-2495页

作者： Wimonmas Bamrungsetthapong Pramote Charongrattanasakul Division of Applied Statistics Department of Mathematics and Computer ScienceFaculty of Science and TechnologyRajamangala University of Technology ThanyaburiPathum Thani12110Thailand Division of Mathematics Department of Mathematics and Computer ScienceFaculty of Science and TechnologyRajamangala University of Technology KrungthepBangkok10120Thailand

This study presents the design of a modified attributed control chart based on a double sampling(DS)np chart applied in combination with generalized multiple dependent state(GMDS)sampling to monitor the mean life of the product based on the time truncated life test employing theWeibull *** control chart developed supports the examination of the mean lifespan variation for a particular product in the process of *** control limit levels are used:the warning control limit,inner control limit,and outer control ***,they enhance the capability for variation detection.A genetic algorithm can be used for optimization during the in-control process,whereby the optimal parameters can be established for the proposed control *** control chart performance is assessed using the average run length,while the influence of the model parameters upon the control chart solution is assessed via sensitivity analysis based on an orthogonal experimental design withmultiple linear regression.A comparative study was conducted based on the out-of-control average run length,in which the developed control chart offered greater sensitivity in the detection of process shifts while making use of smaller samples on average than is the case for existing control ***,to exhibit the utility of the developed control chart,this paper presents its application using simulated data with parameters drawn from the real set of data.

关键词： Modified DS np chart generalizedmultiple dependent state sampling time truncated life test Weibull distribution average run length average sample size