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Synergistic effect of bonding heterogeneity and phonon localization in introducing excellent thermoelectric properties in layered heteroanionic NdZnSbO material

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Journal of energy Chemistry 2025年第1期100卷 259-272页

作者： Da Wan Shuwei Tang Shulin Bai Xiaodong Li Peng Ai Wanrong Guo Tuo Zheng College of Materials Science and engineering Liaoning Technical University faculty of Chemistry Northeast Normal University

Layered rare-earth metal oxides, harnessing the dual properties of oxides and two-dimensional layered materials, exhibit remarkable thermal stability and quantum confinement effects. Therefore, this work adopts the first-principles calculation combined with the Boltzmann transport theory to predict the thermoelectric properties of NdZnSbO compound. The coexistence of weak interlayer van der Waals interactions, robust intralayer ionic bonding, and partial covalent bonding leads to remarkable bonding heterogeneity, which engenders pronounced phonon scattering and imposes constraints on thermal transport along the out-of-plane direction. The weakened chemical bonds induced by the antibonding states, together with the rattling-like behavior of the Zn atom, culminate in the profound anharmonicity in the layered NdZnSbO compound. The weakening bond and heavy element contribute to the softness of phonon modes, which significantly diminishes the phonon group velocity. The redistribution-dominated four-phonon scattering process spans a large optical gap, which effectively reduces the lattice thermal conductivity. The NdZnSbO compound exhibits direct semiconductor characteristic with a bandgap of 0.73 e V by adopting the Heyd-Scuseria-Ernzerhof(HSE06) functional in combination with spin–orbit coupling(SOC) effect. The multi-valley feature of NdZnSbO compound augur favorably for band degeneracy, thus amplifying the power factor. Consequently, an optimal figure-of-merit(ZT) of 3.40 at 900 K is achieved for the n-type NdZnSbO compound. The present study delves deeply insights into the origins for the low thermal conductivity of NdZnSbO compound and proposes an optimization scheme to enhance overall thermoelectric performance.

关键词： Bond strength (chemical)

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Alternative Strategy for Development of Dielectric Calcium Copper Titanate‑Based Electrolytes for Low‑Temperature Solid Oxide Fuel Cells

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Nano-Micro Letters 2025年第1期17卷 310-332页

作者： Sajid Rauf Muhammad Bilal Hanif Zuhra Tayyab Matej Veis MAKYousaf Shah Naveed Mushtaq Dmitry Medvedev Yibin Tian Chen Xia Martin Motola Bin Zhu College of Mechatronics and Control engineering Shenzhen UniversityShenzhen 518060People’s Republic of China Department of Inorganic Chemistry Faculty of Natural SciencesComenius University BratislavaIlkovicova684215 BratislavaSlovakia energy Storage Joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing 210096People’s Republic of China Hydrogen energy Laboratory Ural Federal University620002 EkaterinburgRussia Laboratory of Electrochemical Devices Based on Solid Oxide Proton Electrolytes Institute of High Temperature Electrochemistry620066 EkaterinburgRussia School of Microelectronics Hubei UniversityWuhan 430062People’s Republic of China

The development of low-temperature solid oxide fuel cells(LT-SOFCs)is of significant importance for realizing the widespread application of *** has stimulated a substantial materials research effort in developing high oxide-ion conductivity in the electrolyte layer of *** this context,for the first time,a dielectric material,CaCu_(3)Ti_(4)O_(12)(CCTO)is designed for LT-SOFCs electrolyte application in this *** individual CCTO and its heterostructure materials with a p-type Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ)(NCAL)semiconductor are evaluated as alternative electrolytes in LT-SOFC at 450–550℃.The single cell with the individual CCTO electrolyte exhibits a power output of approximately 263 mW cm^(-2) and an open-circuit voltage(OCV)of 0.95 V at 550℃,while the cell with the CCTO–NCAL heterostructure electrolyte capably delivers an improved power output of approximately 605 mW cm^(-2) along with a higher OCV over 1.0 V,which indicates the introduction of high hole-conducting NCAL into the CCTO could enhance the cell performance rather than inducing any potential short-circuiting *** is found that these promising outcomes are due to the interplay of the dielectric material,its structure,and overall properties that led to improve electrochemical mechanism in CCTO–***,density functional theory calculations provide the detailed information about the electronic and structural properties of the CCTO and NCAL and their heterostructure CCTO–*** study thus provides a new approach for developing new advanced electrolytes for LT-SOFCs.

关键词： LT-SOFCs Dielectric CaCu_(3)Ti_(4)O_(12) Semiconductor Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ) Ionic conductivity Heterostructure electrolyte

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Nanosecond pulse and dual-wavelength Q-switched 1.5 μm fiber laser using MAX phase Cr2TiAlC2 saturable absorber

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Optoelectronics Letters 2025年第1期21卷 7-12页

作者： Ahmed Shakir AL-HITI Hiba HASSAN Department of Electrical engineering Faculty of Engineering University of Anbar Department of Laser and Optoelectronics engineering University of Technology-Iraq

We demonstrated a new type of MAX phase material, chromium titanium aluminum carbide（Cr2TiAlC2） polymer film, to generate a passively Q-switched erbium-doped fiber laser（EDFL）. The film thickness was measured to be around 45 μm, which was fabricated using the embedding method with polyvinyl alcohol（PVA） polymer as hoster. The saturable absorber（SA） film demonstrates a dual-wavelength passively Q-switched EDFL which operates at 1 531 nm and 1 560.19 nm, respectively. The Q-switching pulse duration could be varied from 2.46 μs to 770 ns, while the repetition rate varied from 92.76 kHz to 106.6 kHz with an increasing input pumping range from 154 mW to 300 mW. The maximum output power and pulse energy of 15.05 mW and 141.18 nJ were obtained at the maximum input power of 300 mW, respectively.

关键词： Saturable absorbers

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Characterization of ultraviolet communication in a mixed aerosol environment

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Optoelectronics Letters 2025年第2期 77-84页

作者： ZHAO Taifei SUN Yuxin WANG Wuxin ZHANG Haijun PAN Feixiang WU Hao Artificial Intelligence Key Laboratory of Sichuan Province Sichuan University of Science & Engineering faculty of Automation and Information engineering Xi'an University of Technology

Wireless ultraviolet (UV) has strong scattering characteristics and can communicate through non-direct *** UV signals are transmitted in the atmosphere,they are affected by the absorption and scattering effects of atmospheric particles and atmospheric turbulence,resulting in attenuation of UV signal energy and reduced reliability of the communication *** paper focuses on the channel model of UV non-direct-view single scattering communication,and simulates and analyzes the communication characteristics of UV light in atmospheric turbulence and mixed aerosol environment under horizontal,vertical and oblique range communication *** results show that at equal relative humidity,the wireless UV non-directive scattering communication performance for vertical communication scenarios is more affected by the mixed aerosol environment and the communication performance is worse.

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NUMERICAL AND EXPERIMENTAL INVESTIGATION OF BEVELED TRAILING EDGE FLOW FIELDS

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Journal of Hydrodynamics 2008年第3期20卷 273-279页

作者： MOSALLEM M.M. Department of Mechanical Power engineering and energy Faculty of EngineeringMinia University

The characteristics of flow past beveled trailing edges attached to flat plates have been investigated numerically and experimentally. The test models used in the present study were two 2D blunt-faced flat plates having asymmetric beveled trailing edges of angles 27° and 60°. The numerical simulation results display an asymmetric wake behind the 27° beveled trailing edge and von karmen street vortices behind the 60° beveled trailing edge. The flow visualization using cavitation technique showed the same observations of the numerical simulation. Therefore, it is obvious that the trailing edge geometry has a pronounced effect on the wake development and vortex shedding. Also, it is concluded that the cavitation phenomenon can be used as a visualization technique at high flow velocities.

关键词： cavitation technique visualization beveled trailing edge vortex shedding

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Scale adaptive simulation of vortex structures past a square cylinder

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Journal of Hydrodynamics 2018年第4期30卷 657-671页

作者： Javad Aminian faculty of Mechanical and energy engineering Shahid Beheshti University

The scale adaptive simulation（SAS） turbulence model is evaluated on a turbulent flow past a square cylinder using the open-source CFD package OpenF OAM 2.3.0. Two and three-dimensional simulations are performed to determine global quantities like drag and lift coefficients and Strouhal number in addition to mean and fluctuating velocity profiles in the recirculation and wake regions. SAS model is evaluated against the Shear Stress Transport k-ω（SST） model and also compared with previously reported results based on DES, LES and DNS turbulence approaches. Results show that global quantities along with mean velocity profiles are well-captured by 2-D SAS model. The 3-D SAS model also succeeded in providing comparable results with recently published DES study on Reynolds shear stress and velocity fluctuation components using about 12 times lower computational cost. It is shown that large values of the SAS model constant result in too dissipative behavior, so that proper calibration of the SAS model constant for different turbulent flows is vital.

关键词： Scale adaptive simulation (SAS) turbulence model bluff body mean and fluctuating properties anisotropic turbulence computational costs

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Tribological characteristics of new series of Al-Sn-Si alloys

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中国有色金属学会会刊：英文版 2003年第4期13卷 774-780页

作者：袁鸽成张新明娄燕雄黎祚坚 faculty of Material and energy School of Materials Science and engineering

Tribological characteristics of new series of Al Sn Si alloys were investigated by means of pin disk types of wear testing machines, OM, SEM and EDAX. Rules about the influence of Sn, Si content and load on the friction and wear characteristics of the alloys were ascertained. The friction factor and wear rate of the alloys decrease with increasing Sn content, the wear rate decreases but the friction factor varies hardly with increasing Si content. The friction factor of the alloys increases slightly and the wear rate increases observably with increasing load in the range of 1080 N. The wear mechanism of Al Sn Si alloys consists of ‘plough’ action and abrasive wear below 30 N; the adhesive and delamination mechanism are shown in the range of 3080 N. The tribological characteristics of Al Sn Si system are superior to those of Al Sn or Al Si systems due to their “peritectic type” island shape microstructure of Si surrounded with Sn.

关键词： Al-Sn-Si合金铝合金磨损摩擦 SEM

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Application of ionic liquids in hydrometallurgy of nonferrous metals

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Transactions of Nonferrous Metals Society of China 2010年第3期20卷 513-520页

作者：田国才李坚华一新 faculty of Metallurgical and energy engineering Kunming University of Science and Technology

Ionic liquids as green solvents have shown important application in the extraction and separation of nonferrous *** new application perspective,the important fundamental and the applied studies of the extraction and separation of nonferrous metals in ionic liquids,including the dissolution and corrosion of metal and metal oxide,hydrometallurgy of chalcopyrite and metallic oxidized ore,and extraction and separation of metal ions,are introduced.

关键词： ionic liquids hydrometallurgy nonferrous metals metal oxides mineral processing extraction and separation of metal ions

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Pressure leaching of zinc silicate ore in sulfuric acid medium

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Transactions of Nonferrous Metals Society of China 2010年第5期20卷 918-923页

作者：李存兄徐红胜邓志敢李兴彬李旻廷魏昶 faculty of Metallurgical and energy engineering Kunming University of Science and Technology

Zinc silicate ore was characterized mineralogically and the results showed that zinc exists mainly as hemimorphite and smithsonite in the *** acid pressure leaching of zinc silicate ore was carried out to assess the effect of particle size,sulfuric acid concentration,pressure,reaction time and temperature on the extraction of zinc and the dissolution of *** the optimum conditions employed,up to 99.25% of zinc extraction and 0.20% silica dissolution are *** main minerals in leaching residue are quartz and small amounts of undissolved oxide minerals of iron,lead and aluminum are associated with quartz.

关键词： zinc silicate ore sulfuric acid pressure leaching extraction of zinc dissolution of silica

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Pressure acid leaching of black shale for extraction of vanadium

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Transactions of Nonferrous Metals Society of China 2010年第S1期20卷 112-117页

作者：李旻廷魏昶樊刚李存兄邓志敢李兴彬 faculty of Metallurgical and energy engineering Kunming University of Science and Technology

Extraction of vanadium from black shale was attempted in pressure acid *** chemical components of the sample obtained from Guizhou Province of China show that it contains 3.258%V2O5,52.880%SiO2 and 16.140%*** analyses of vanadium indicates vanadium mainly exists in the free oxide and *** contents in the two phases are 18%and 53%, *** contents of V3 +,V 4+and V 5+are almost *** the optimum parameters of one-step leaching(reaction time of 3 h,sulfuric addition of 25%,temperature of 150℃,liquid to solid ratio of 1.2 mL/g,catalyst(FeSO4)addition of 5%and size of 85%particle 0.074 mm),about 77%of vanadium is *** two-step countercurrent leaching,the leach recovery of vanadium can reach above 90%.Air replacing oxygen is completely *** impurity metals can dissolve into solution in different degrees.

关键词： pressure acid leaching black shale vanadium catalyst

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