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Insights into adsorbent tortuosity across aqueous adsorption systems

Particuology 2024年第5期88卷 71-88页

作者： Ackmez Mudhoo Marta Otero Khim Hoong Chu Department of Chemical and Environmental Engineering Faculty of EngineeringUniversity of MauritiusRéduit 80837Mauritius Department of Applied Chemistry and Physics Universidad de LeónCampus de Vegazana 24071 LeónSpain Department of Chemical Engineering Faculty of EngineeringUniversity of MalayaKuala Lumpur 50603Malaysia

Pore network,pore connectivity,and the resulting effective adsorbate pore diffusivity within an adsorbent are critical physical considerations in mass transport modeling of aqueous *** to these three adsorbent features are the adsorbent tortuosity and tortuosity factor *** concepts encompass the collective hindrance to intra-adsorbent adsorbate transport arising because of a disorderly adsorbent porous *** is crucial for materials scientists,chemists,chemical engineers,and water treatment specialists to understand the complex and variable connections among adsorbate chemistry,adsorbent chemistry,adsorbent porosity,pore shape,size,and tortuosity,pore wall effect,adsorbate-adsorbent interactions,and adsorbate-adsorbate interactions in competitively contaminated aqueous *** tortuosity has been sporadically studied in aqueous adsorption *** the small population of these studies,insightful observations and inferences have been ***,as it appears,no review has been published to compile,compare,and contrast these ***,this review concisely brings up those observations and interpretations around adsorbent tortuosity for aqueous adsorption *** notion of an adsorbent's tortuosity being single-valued is argued to be ***,perspectives are aired on possible research and development directions for elucidating the dynamic attributes of adsorbent tortuosity and applying them in real-scale adsorption-oriented water *** data acquired by filling in these research gaps can enable the design of adsorbents more adapted for real-scale water purification.

关键词： Adsorbent Tortuosity Porosity Pore diffusion models Aqueous systems

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Recapturing meaning: Toward a new material-based design theory for architecture

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Frontiers of Architectural Research 2022年第4期11卷 609-617页

作者： Christopher Bardt faculty of architecture Rhode Island School of DesignRhode IslandUSA

Architects and students of architecture today are less physically engaged with modeling and drawing representations of proposed things and increasingly rely on digital means and methods that are transforming their embodied interactions with actual materials. The result is that meaning, which makes architecture so central to our cultures, is being diminished. It is being replaced by a misplaced belief that "better" buildings and architecture result from increased use of digital tools. To recapture meaning will require a new design theory for architecture that builds on material engagement theory and the critical role of resistance and sensuous reasoning in the design process, which material has historically provided.

关键词： architecture design Material engagement Material-based design Meaning Digital tools

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Reversible solid-liquid conversion enabled by self-capture effect for stable non-flow zinc-bromine batteries

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Green Energy & Environment 2024年第6期9卷 1035-1044页

作者： Xixi Zhang Xiaoke Wang Guangmeng Qu Tairan Wang Xiliang Zhao Jun Fan Cuiping Han Xijin Xu Chunyi Zhi Hongfei Li School of Physics and Technology University of JinanShandong250022China Songshan Lake Materials Laboratory DongguanGuangdong523808China Department of Materials Science and Engineering City University of Hong Kong83 Tat Chee AvenueHong KongChina faculty of Materials Science and Engineering and Low Dimensional Energy Materials Research Center Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhenGuangdong518055China School of System design and Intelligent Manufacturing Southern University of Science and TechnologyShenzhenGuangdong518055China

Non-flow aqueous zinc-bromine batteries without auxiliary components(e.g.,pumps,pipes,storage tanks)and ion-selective membranes represent a cost-effective and promising technology for large-scale energy ***,they generally suffer from serious diffusion and shuttle of polybromide(Br^(-),Br^(3-))due to the weak physical adsorption between soluble polybromide and host carbon materials,which results in low energy efficiency and poor cycling ***,we develop a novel self-capture organic bromine material(1,10-bis[3-(trimethylammonio)propyl]-4,4'-bipyridinium bromine,NVBr4)to successfully realize reversible solid complexation of bromide components for stable non-flow zinc-bromine battery *** quaternary ammonium groups(NV^(4+)ions)can effectively capture the soluble polybromide species based on strong chemical interaction and realize reversible solid complexation confined within the porous electrodes,which transforms the conventional“liquid-liquid”conversion of soluble bromide components into“liquid-solid”model and effectively suppresses the shuttle ***,the developed non-flow zinc-bromide battery provides an outstanding voltage platform at 1.7 V with a notable specific capacity of 325 mAh g^(-1)NVBr4(1 A g^(-1)),excellent rate capability(200 mAh g^(-1)NVBr4 at 20 A g^(-1)),outstanding energy density of 469.6 Wh kg^(-1)and super-stable cycle life(20,000 cycles with 100%Coulombic efficiency),which outperforms most of reported zinc-halogen *** mechanism analysis and DFT calculations demonstrate that the chemical interaction of quaternary ammonium groups and bromide species is the main reason for suppressing the shuttle *** developed strategy can be extended to other halogen batteries to obtain stable charge storage.

关键词： Solid-liquid conversion Self-capture Non-ﬂow zinc-bromine batteries Quaternary ammonium

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定向凝固条件下Ti_(3)Al合金中梯度纳米结构的形成机制与力学行为——原子尺度研究

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Transactions of Nonferrous Metals Society of China 2024年第5期34卷 1507-1519页

作者：邹鹏飞李昌侯兆阳 Jia-yi SUN 高全华李克凡王真 Ke-jun DONG 长安大学理学院西安710064 faculty of Natural Mathematics&Engineering SciencesKing’s College LondonLondonWC2R 2LSUnited Kingdom School of Engineering Design and Built EnvironmentWestern Sydney UniversityPenrithNSW 2751Australia

通过分子动力学(MD)模拟方法对Ti_(3)Al合金在定向凝固条件下的生长机理进行系统研究,并通过对比纳米晶(NG)、粗晶(CG)和梯度纳米晶(GNG)合金,研究Ti_(3)Al合金的结构力学性能。结果表明,在凝固过程中Ti_(3)Al相优先生长为等轴晶组织,... 详细信息

通过分子动力学(MD)模拟方法对Ti_(3)Al合金在定向凝固条件下的生长机理进行系统研究,并通过对比纳米晶(NG)、粗晶(CG)和梯度纳米晶(GNG)合金,研究Ti_(3)Al合金的结构力学性能。结果表明,在凝固过程中Ti_(3)Al相优先生长为等轴晶组织,随后逐渐演变为柱状粒,并最终形成梯度纳米晶结构。此时,晶粒在与凝固方向平行的方向优先生长。此外,研究还发现,相较于NG和CG结构,GNG结构定向凝固合金具有更高的抗拉强度和更好的延展性。GNG结构不仅有效抑制了小晶粒区域的应变局域化和晶粒生长,而且促进了较大晶粒区域的位错形成,从而获得更好的力学性能。

关键词：定向凝固 Ti_(3)Al合金分子动力学模拟梯度纳米结构

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Modified DS np Chart Using Generalized Multiple Dependent State Sampling under Time Truncated Life Test

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Computer Modeling in Engineering & Sciences 2024年第3期138卷 2471-2495页

作者： Wimonmas Bamrungsetthapong Pramote Charongrattanasakul Division of Applied Statistics Department of Mathematics and Computer ScienceFaculty of Science and TechnologyRajamangala University of Technology ThanyaburiPathum Thani12110Thailand Division of Mathematics Department of Mathematics and Computer ScienceFaculty of Science and TechnologyRajamangala University of Technology KrungthepBangkok10120Thailand

This study presents the design of a modified attributed control chart based on a double sampling(DS)np chart applied in combination with generalized multiple dependent state(GMDS)sampling to monitor the mean life of the product based on the time truncated life test employing theWeibull *** control chart developed supports the examination of the mean lifespan variation for a particular product in the process of *** control limit levels are used:the warning control limit,inner control limit,and outer control ***,they enhance the capability for variation detection.A genetic algorithm can be used for optimization during the in-control process,whereby the optimal parameters can be established for the proposed control *** control chart performance is assessed using the average run length,while the influence of the model parameters upon the control chart solution is assessed via sensitivity analysis based on an orthogonal experimental design withmultiple linear regression.A comparative study was conducted based on the out-of-control average run length,in which the developed control chart offered greater sensitivity in the detection of process shifts while making use of smaller samples on average than is the case for existing control ***,to exhibit the utility of the developed control chart,this paper presents its application using simulated data with parameters drawn from the real set of data.

关键词： Modified DS np chart generalizedmultiple dependent state sampling time truncated life test Weibull distribution average run length average sample size

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Big data challenge for monitoring quality in higher education institutions using business intelligence dashboards

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Journal of Electronic Science and Technology 2024年第1期22卷 25-41页

作者： Ali Sorour Anthony S.Atkins faculty of Digital TechnologyInnovationand BusinessStaffordshire UniversityStoke-on-TrentST42DEUnited Kingdom

As big data becomes an apparent challenge to handle when building a business intelligence(BI)system,there is a motivation to handle this challenging issue in higher education institutions(HEIs).Monitoring quality in HEIs encompasses handling huge amounts of data coming from different *** paper reviews big data and analyses the cases from the literature regarding quality assurance(QA)in *** also outlines a framework that can address the big data challenge in HEIs to handle QA monitoring using BI dashboards and a prototype dashboard is presented in this *** dashboard was developed using a utilisation tool to monitor QA in HEIs to provide visual representations of big *** prototype dashboard enables stakeholders to monitor compliance with QA standards while addressing the big data challenge associated with the substantial volume of data managed by HEIs’QA *** paper also outlines how the developed system integrates big data from social media into the monitoring dashboard.

关键词： Big data Business intelligence(BI) Dashboards Higher education(HE) Quality assurance(QA) Social media

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Transient responses of double-curved sandwich two-layer shells resting on Kerr's foundations with laminated three-phase polymer/GNP/fiber surface and auxetic honeycomb core subjected to the blast load

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Defence Technology（防务技术） 2024年第5期35卷 222-247页

作者： Nguyen Thi Hai Van Thi Hong Nguyen Researcher&Lecturer Faculty of Industrial EducationThe University of Danang-University of Technology and Education48 Cao ThangDanang550000Viet Nam Researcher&Lecturer Faculty of Mechanical EngineeringThuyloi University175 Tay SonDong DaHanoi100000Viet Nam

This work uses refined first-order shear theory to analyze the free vibration and transient responses of double-curved sandwich two-layer shells made of auxetic honeycomb core and laminated three-phase polymer/GNP/fiber surface subjected to the blast *** of the two layers that make up the double-curved shell structure is made up of an auxetic honeycomb core and two laminated sheets of three-phase polymer/GNP/*** exterior is supported by a Kerr elastic foundation with three *** key innovation of the proposed theory is that the transverse shear stresses are zero at two free surfaces of each *** contrast to previous first-order shear deformation theories,no shear correction factor is ***'s exact solution was used to treat the double-curved shell problem with a single title boundary,while the finite element technique and an eight-node quadrilateral were used to address the other boundary *** ensure the accuracy of these results,a thorough comparison technique is employed in conjunction with credible *** problem model's edge cases allow for this kind of *** study's findings may be used in the post-construction evaluation of military and civil works structures for their ability to sustain explosive *** addition,this is also an important basis for the calculation and design of shell structures made of smart materials when subjected to shock waves or explosive loads.

关键词： Blast load Two-layer shell Polymer/GNP/Fiber surface Auxetic honeycomb Shear connectors

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Free-electron crystals for enhanced X-ray radiation

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Light(Science & Applications) 2024年第7期13卷 1299-1309页

作者： Lee Wei Wesley Wong Xihang Shi Aviv Karnieli Jeremy Lim Suraj Kumar Sergio Carbajo Ido Kaminer Liang Jie Wong School of Electrical and Electronic Engineering Nanyang Technological University50 Nanyang AvenueSingapore 639798Singapore. Solid State Institute and faculty of Electrical and Computer Engineering Technion–Israel Institute of TechnologyHaifa 3200003Israel. School of Electrical Engineering Fleischman Faculty of EngineeringTel Aviv UniversityTel Aviv 69978Israel Department of Applied Physics Stanford UniversityStanfordCA 94305USA. Science Mathematics and TechnologySingapore University of Technology and Design8 Somapah RoadSingapore 487372Singapore. Electrical and Computer Engineering Department UCLA420 WestwoodLos AngelesCA 90095USA. Physics and Astronomy Department UCLA475 Portola PlazaLos AngelesCA 90095USA. SLAC National Accelerator Laboratory Stanford University2575 Sand Hill RoadMenlo ParkCA 94025USA

Bremsstrahlung—the spontaneous emission of broadband radiation from free electrons that are deflected by atomic nuclei—contributes to the majority of X-rays emitted from X-ray tubes and used in applications ranging from medical imaging to semiconductor chip ***,we show that the bremsstrahlung intensity can be enhanced significantly—by more than three orders of magnitude—through shaping the electron wavefunction to periodically overlap with atoms in crystalline ***,we show how to shape the bremsstrahlung X-ray emission pattern into arbitrary angular emission profiles for purposes such as unidirectionality and ***,we find that these enhancements and shaped emission profiles cannot be attributed solely to the spatial overlap between the electron probability distribution and the atomic centers,as predicted by the paraxial and nonrecoil theory for free electron light *** work highlights an unprecedented regime of free electron light emission where electron waveshaping provides multi-dimensional control over practical radiation processes like *** results pave the way towards greater versatility in table-top X-ray sources and improved fundamental understanding of quantum electron-light interactions.

关键词： overlap attributed arbitrary

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Visual Representation and Cognitive Models in Information Visualization

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Journal of Electronic Research and Application 2024年第4期8卷 115-120页

作者： Yingquan Wang Mustaffa Halabi Azahari City Graduate School City University MalaysiaKuala Lumpur 46100Malaysia College of design and Fine Arts Qingdao Huanghai UniversityQingdao 266427China faculty of Creative Industries City University MalaysiaKuala Lumpur 46100Malaysia

As a branch of computer science,information visualization aims to help users understand and analyze complex data through graphical interfaces and interactive *** visualization primarily includes various visual structures such as time-series structures,spatial relationship structures,statistical distribution structures,and geographic map structures,each with unique functions and application *** better explain the cognitive process of visualization,researchers have proposed various cognitive models based on interaction mechanisms,visual perception steps,and novice use of *** models help understand user cognition in information visualization,enhancing the effectiveness of data analysis and decision-making.

关键词： Information visualization Visual structures Cognitive models Interaction design

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Novel design of a compact tunable dual band wireless power transfer(TDB-WPT)system for multiple WPT applications

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Frontiers of Information Technology & Electronic Engineering 2024年第4期25卷 616-628页

作者： Hany A.ATALLAH Rasha Hussein AHMED Adel B.ABDEL-RAHMAN Department of Communications and Electronics Faculty of EngineeringSouth Valley UniversityQena 83523Egypt Egypt-Japan University of Science and Technology Alexandria 21934Egypt

In this study we present the design and realization of a tunable dual band wireless power transfer(TDB-WPT)coupled resonator *** frequency response of the tunable band can be controlled using a surface-mounted *** transmitter(Tx)and the receiver(Rx)circuits are *** top layer contains a feed line with an impedance of 50Ω.Two identical half rings defected ground structures(HR-DGSs)are loaded on the bottom using a varactor *** propose a solution for restricted WPT systems working at a single band application according to the operating *** effects of geometry,orientation,relative distance,and misalignments on the coupling coefficients were *** validate the simulation results,the proposed TDB-WPT system was fabricated and *** system occupied a space of 40 mm×40 *** can deliver power to the receiver with an average coupling efficiency of 98%at the tuned band from 817 to 1018 MHz and an efficiency of 95%at a fixed band of 1.6 GHz at a significant transmission distance of 22 *** results of the measurements accorded well with those of an equivalent model and the simulation.

关键词： Defected ground structure(DGS) Surface-mounted Tunable dual band wireless power transfer(TDB-WPT) Varactor

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