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Prussian Blue Analogue‑Templated Nanocomposites for Alkali‑Ion Batteries:Progress and Perspective

Nano-Micro Letters 2025年第1期17卷 216-261页

作者： Jian‑En Zhou Yilin Li Xiaoming Lin Jiaye Ye Key Laboratory of Theoretical chemistry of Environment Ministry of EducationSchool of ChemistrySouth China Normal UniversityGuangzhou 510006People’s Republic of China School of chemistry and Physics Faculty of ScienceQueensland University of Technology2 George StreetBrisbaneQLD 4000Australia Centre for Materials Science Queensland University of Technology2 George StreetBrisbaneQLD 4000Australia

Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries(AIBs)including sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).Owing to larger ion sizes of Na^(+)and K^(+)compared with Li^(+),nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium *** enticing open rigid framework structures,Prussian blue analogues(PBAs)remain promising self-sacrificial templates for the preparation of various nanocomposites,whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal *** review focuses on the recent progress of PBA-derived nanocomposites from their fabrication,lithium/sodium/potassium storage mechanism,and applications in AIBs(LIBs,SIBs,and PIBs).To distinguish various PBA derivatives,the working mechanism and applications of PBA-templated metal oxides,metal chalcogenides,metal phosphides,and other nanocomposites are systematically evaluated,facilitating the establishment of a structure–activity correlation for these *** on the fruitful achievements of PBA-derived nanocomposites,perspectives for their future development are envisioned,aiming to narrow down the gap between laboratory study and industrial reality.

关键词： Prussian blue analogues Self-sacrificial template Lithium-ion batteries Sodium-ion batteries Potassium-ion batteries

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Synergistic effect of bonding heterogeneity and phonon localization in introducing excellent thermoelectric properties in layered heteroanionic NdZnSbO material

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Journal of Energy chemistry 2025年第01期 259-272页

作者： Da Wan Shuwei Tang Shulin Bai Xiaodong Li Peng Ai Wanrong Guo Tuo Zheng College of Materials Science and Engineering Liaoning Technical University faculty of chemistry Northeast Normal University

Layered rare-earth metal oxides, harnessing the dual properties of oxides and two-dimensional layered materials, exhibit remarkable thermal stability and quantum confinement effects. Therefore, this work adopts the first-principles calculation combined with the Boltzmann transport theory to predict the thermoelectric properties of NdZnSbO compound. The coexistence of weak interlayer van der Waals interactions, robust intralayer ionic bonding, and partial covalent bonding leads to remarkable bonding heterogeneity, which engenders pronounced phonon scattering and imposes constraints on thermal transport along the out-of-plane direction. The weakened chemical bonds induced by the antibonding states, together with the rattling-like behavior of the Zn atom, culminate in the profound anharmonicity in the layered NdZnSbO compound. The weakening bond and heavy element contribute to the softness of phonon modes, which significantly diminishes the phonon group velocity. The redistribution-dominated four-phonon scattering process spans a large optical gap, which effectively reduces the lattice thermal conductivity. The NdZnSbO compound exhibits direct semiconductor characteristic with a bandgap of 0.73 e V by adopting the Heyd-Scuseria-Ernzerhof(HSE06) functional in combination with spin–orbit coupling(SOC) effect. The multi-valley feature of NdZnSbO compound augur favorably for band degeneracy, thus amplifying the power factor. Consequently, an optimal figure-of-merit(ZT) of 3.40 at 900 K is achieved for the n-type NdZnSbO compound. The present study delves deeply insights into the origins for the low thermal conductivity of NdZnSbO compound and proposes an optimization scheme to enhance overall thermoelectric performance.

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Olfactory receptors in neural regeneration in the central nervous system

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Neural Regeneration Research 2025年第9期20卷 2480-2494页

作者： Rafael Franco Claudia Garrigós Toni Capó Joan Serrano-Marín Rafael Rivas-Santisteban Jaume Lillo Molecular Neurobiology Laboratory Department of Biochemistry and Molecular BiomedicineFacultat de BiologiaUniversitat de BarcelonaBarcelonaSpain CiberNed Network Center for Biomedical Research in Neurodegenerative Diseases Spanish National Health Institute Carlos ⅢMadridSpain School of chemistry Universitat de BarcelonaBarcelonaSpain Department of Biochemistry and Physiology School of Pharmacy and Food SciencesUniversitat de BarcelonaBarcelonaSpain Laboratory of Computational Medicine Biostatistics UnitFaculty of MedicineAutonomous University of BarcelonaCampus BellaterraBarcelonaSpain

Olfactory receptors are crucial for detecting odors and play a vital role in our sense of smell,influencing behaviors from food choices to emotional *** receptors also contribute to our perception of flavor and have potential applications in medical diagnostics and environmental *** ability of the olfactory system to regenerate its sensory neurons provides a unique model to study neural regeneration,a phenomenon largely absent in the central nervous *** gained from how olfactory neurons continuously replace themselves and reestablish functional connections can provide strategies to promote similar regenerative processes in the central nervous system,where damage often results in permanent *** the molecular and cellular mechanisms underpinning olfactory neuron regeneration could pave the way for developing therapeutic approaches to treat spinal co rd injuries and neurodegenerative diseases like Alzheimer's *** ctory receptors are found in almost any cell of eve ry orga n/tissue of the mammalian *** ectopic expression provides insights into the chemical structures that can activate olfactory *** addition to odors,olfactory receptors in ectopic expression may respond to endogenous compounds and molecules produced by mucosal colonizing *** analysis of the function of olfactory receptors in ectopic expression provides valuable information on the signaling pathway engaged upon receptor activation and the receptor's role in proliferation and cell differentiation *** review explo res the ectopic expression of olfa ctory receptors and the role they may play in neural regeneration within the central nervous system,with particular attention to compounds that can activate these receptors to initiate regenerative *** suggests that olfactory receptors could serve as potential therapeutic targets for enhancing neural repair and recovery following central nervous syste

关键词： adenosine receptors adrenergic receptors ectopic expression G proteincoupled receptors glia neurons

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Controlling the reaction network of Ni/silica derived conversion of bio-oil surrogate guaiacol

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Carbon Resources Conversion 2024年第1期7卷 39-60页

作者： Nils Kretzschmar Oliver Busse Markus Seifert Technische Universität Dresden Faculty of Chemistry and Food Chemistry01062 DresdenGermany

Replacing fossil carbon sources with green bio-oils is a promising route to switch to a sustainable chemical industry,although their high oxygen contents are *** hydrodeoxygenation is a favored route to upgrade bio-oils to renewable fuels and basic *** this work,we investigated Ni/SiO2 catalysts with differing metal dispersity in continuous mode conversion of guaiacol with a statistical experimental design for 250℃to 400℃,2 h up to 5 h time on stream(ToS)and subsequently different residence time besides other *** low temperature(250℃)promotes cyclohexanol formation from guaiacol,high temperature(400℃)inhibits hydrogenation,leading to phenol and *** medium temperature(340℃),the selectivity for cyclohexanone *** and cyclohexanone(KA-oil)are the industrial basis for polyamide ***,we clarified the role of 2-methoxycyclohexanol(2MC)in the reaction network towards KA-oil for continuous-mode *** analysis was used to predict and optimize product selectivity and yield,leading to the best yield of cyclohexanone/-ol at 327.5℃,low ToS,medium residence time,high particle dispersity,and medium hydrogen pressure(15 bar(g)).

关键词： Hydrodeoxygenation Design of experiments Bio-oil Nickel silica catalyst Continuous mode flow reactor KA-oil Cyclohexanol Cyclohexanone

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Kinetic and spectral studies of EHPG systems using chemi-and electrochemiluminescence methods

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Journal of Rare Earths 2010年第6期28卷 868-873页

作者： S. Lis M. Kaczmarek K. Staninski S. Krompiec N. Kuznik faculty of chemistry Adam Mickiewicz University Institute of chemistry University of Silesia faculty of chemistry Silesian Technical University

The systems containing EHPG, EHPG-OCH3 and EHPG-NH-Ac and Tb(Ⅲ) ions were used to study chemiluminescence (CL) and electrochemiluminescence (ECL) processes. In the CL studies the Fenton system (Fe(Ⅱ)/(Ⅲ)-H2O2) was used as a source of reactive oxygen species (ROS). Kinetic CL curves and CL spectral distributions were recorded. On the basis of the results obtained, it was demonstrated that Tb(Ⅲ) acted as a sensitizer. Similarly obtained CL decays in the systems of Fe(Ⅱ)/(Ⅲ)-EHPG (or its derivatives)-H2O2 and Fe(Ⅱ)/(Ⅲ)-EHPG (or its derivatives)-Tb(Ⅲ)-H2O2, independently on the Tb(Ⅲ) concentration, showed that the lanthanide ions did not influence the kinetics of the oxidation of EHPG (or its derivatives) in the Fenton systems. The CL intensity increased with the increasing concentration of Tb(Ⅲ) ions, which were the main emitters in the reaction systems. Spectrophotometric and luminescent studies of the systems before and after the additions of hydrogen peroxide proved that the excitation of the lanthanide ion was a result of energy transfer from the excited products of the oxidation of EHPG or its derivatives to the uncomplexed Tb(Ⅲ) ions. ECL was generated on the surface of a nonstructural modified aluminum electrode with the use of K2S2O8, H2O2 or KN3 as coreactants in aqueous solution. In these studies we employed Al electrodes covered with a 2-4 nm layer of Al2O3 doted with Tb(Ⅲ) or Dy(Ⅲ) ions. The electrodes were polarized using cathodic and anodic pulses of various amplitude and frequency. The relative ECL efficiencies were determined as a function of electric pulse parameters, electrolyte compositions and the thickness of barrier or porous layer of the Al2O3 electrode.

关键词： chemiluminescence lanthanides EHPG complexes rare earths

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POLYROTAXANE WITH π-CONJUGATED PORPHYRIN AND POLYAZOMETHINE SYSTEMS PREPARED FROM A TYPE OF PORPHYRIN-DIALDEHYDE AND COMPLEX OF β-CYCLODEXTRIN WITH 1,4-PHENYLENEDIAMINE

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Chinese Journal of Polymer Science 2013年第1期31卷 139-147页

作者： Raziyeh Akbarzadeh Hossein Dehghani Department of Inorganic chemistry Faculty of ChemistryUniversity of Kashan

The synthesis of 5,15-bis[4-（methoxycarbonyl）phenyl]-10,20-diphenylporphyrin （2） and its reduction to 5,15- bis[4-（hydroxymethyl）phenyl]-10,20-diphenylporphyrin （3）, and so its oxidation to provide 5,15-bis（4-formylphenyl）-10,20- diphenylporphyrin （4） are reported. The copolymer possessing β-cyclodextrin （fl-CD）, n-conjugated porphyrin and polyazomethine systems was synthesized by the polycondensation of porphyrin-dialdehyde monomer （4） and ,β- cyclodextrin/1,4-phenylenediamine complex （5）. The monomers and the copolymer were characterized by UV-Vis, ^1H-NMR and IR spectra. Furthermore, ^1H-NMR and FT-IR spectra confirmed locating the aromatic ring of 1,4-phenylenediamine molecule in the center of β-cyclodextrin cavity.

关键词： Polymer Porphyrin 1,4-Phenylenediamine Imine Cyclodextrin.

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Yttrium-iron garnet and yttrium orthoferrite nanocrystals:Hydrothermal synthesis, magnetic property and phase transformation study

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Journal of Rare Earths 2018年第12期36卷 1292-1298页

作者： Mohammadreza Mansournia Mahsa Orae Department of Inorganic chemistry faculty of chemistry University of Kashan

In this work,we present a new and fast method to obtain the single phase YFeO(YIG,cubic) and YFeO(YIP, orthorhombic) nanocrystals based on hydrothermal technique. The influence of initial Y/Fe mole ratio and calcination temperature on the nature, purity, phase structure, and morphology of the product was investigated by X-ray diffraction(XRD), Fourier-transform infrared(FT-IR) spectroscopy,energy-dispersive(EDX) X-ray spectroscopy, and field emission scanning electron microscopy(FESEM).The results show that the transformation of the as-synthesized YIG from amorphous to orthorhombic and finally to cubic phase occurs with the increase of annealing temperature. On this basis, the pure cubic phase YIG can be obtained by calcination(at 1100℃) of the precursor which is prepared using the hydrothermal treatment of mole ratio of Y:Fe = 1:1.5 exposure to an ammonia atmosphere. Also, the initial Y/Fe mole ratio of 1:1 and calcination temperature of 1000 ℃ are the optimal conditions to form single-phase nanocrystalline YIP. Further, vibrating sample magnetometry(VSM) measurements illustrate the average magnetic saturation, coercivity and remanence of 2.73 and 15.00 emu/g, 42.74 and40.02 Oe, and 1.65 and 4.30 emu/g for YIP and YIG nanocrystals, revealing their soft ferromagnetic character.

关键词： Yttrium-iron garnet Yttrium orthoferrite Ammonia atmosphere Nanoparticles Magnetic materials Phase transformation

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Novel Conductive PANI/Hydrophilic Thiacalix[4]arene Nanocomposites: Synthesis, Characterization and Investigation of Properties

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Chinese Journal of Polymer Science 2014年第2期32卷 218-229页

作者： Rafieh-Sadat Norouzian Moslem M.Lakouraj Ehsan N.Zare Polymer chemistry Research Laboratory Department of Organic Chemistry Faculty of Chemistry University of Mazandaran

Nanocomposites of polyaniline （PANI） and the macrocycle thiacalix[4]arene tetra sulfonate （TCAS） were successfully synthesized in feed ratios of 1：0.25, 1：0.50 and 1：0.75 by three prevail synthetic methods, i.e. in situ polymerization, emulsion polymerization and solution casting technique. The structures of the nanocomposites were confirmed by FTIR, UV-Vis, XRD, SEM, and TEM techniques. The conductivity was measured by a four probe method. The conductivity was recorded to be as high as 105 x 10-2 ***-~ for the nanocomposite with a nanometer size structure and homogeneously distributed morphology. The electroactivity of the nanocomposites was approved by cyclic voltammetry （CV） and impedance spectroscopy technique （EIS）. The antioxidant ability and thermal property of the composites were further studied. Preliminary studies have evidenced the production of conductive nanocomposites with good thermal property and relatively good solubility in N-methyl 2-pyrrolidone （NMP）, with the antioxidant activity reaching up to 80%.

关键词： Thiacalixarene Nanocomposite Polyaniline Conductivity Antioxidant.

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Unlocking hypoglycemia–associated brain microvascular dysfunction:critical insights from proteomic analysis

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Neural Regeneration Research 2025年第6期20卷 1707-1708页

作者： Siva S.V.P.Sakamuri Anil Sakamuri Department of chemistry Auburn University at MontgomeryMontgomeryALUSA Vascular Biology Center and Department of Medicine Medical College of Georgia at Augusta UniversityAugustaGAUSA

Hypoglycemia-a critical complication linked to worsened brain function in diabetic subjects:Hypoglycemia is characterized by a decline in circulatory glucose levels below sta nda rd physiological *** hypoglycemia,classified as level 1 hypoglycemia,is defined by blood glucose levels below 70 mg/dL and can be effectively addressed through carbohydrate *** hypoglycemia,denoted by blood glucose levels less than 54 mg/dL,poses a life-threatening risk if left *** with type 1 and type 2 diabetes undergoing insulin treatment are particularly susceptible to hypoglycemia due to impaired counterregulatory mechanisms.

关键词： impaired intake critical

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Sensitive Voltammetric Determination of Captopril Using a Carbon Paste Electrode Modified with Nano-TiO_2/Ferrocene Carboxylic Acid

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催化学报 2011年第11期32卷 1685-1692页

作者： Jahan Bakhsh RAOOF Reza OJANI Mehdi BAGHAYERI Electroanalytical chemistry Research Laboratory Department of Analytical Chemistry Faculty of Chemistry Mazandaran University Babolsar 47416-95447 Iran

A carbon paste electrode (CPE) modified with ferrocene carboxylic acid (FcCA) and TiO2 nanoparticles was constructed by incorporating TiO2 nanoparticles and ferrocene carboxylic acid into the carbon paste matrix. The electrochemical behavior of captopril (CAP) at the surface of the modified electrode was investigated using electroanalytical methods. The modified electrode showed excellent electrocatalytic activity for the oxidation of CAP in aqueous solutions at physiological pH values. Cyclic voltammetric curves showed that the oxidation of CAP at the surface of the modified electrode reduced its overpotential by more than 290 mV. The modified electrode was used for detecting captopril using cyclic voltammetry and square wave voltammetry techniques. A calibration curve in the range of 0.03 to 2400 μmol/L was obtained that had a detection limit of 0.0096 μmol/L (3?) under the optimized conditions. The modified electrode was successfully used for the determination of captopril in pharmaceutical and biological samples.

关键词： electrocatalysis modified electrode nano-TiO2 ferrocene carboxylic acid captopril cyclic voltammetry

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