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Unveiling the intrinsic properties of single NiZnFeO_x entity for promoting electrocatalytic oxygen evolution

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Chinese Chemical Letters 2024年第4期35卷 181-186页

作者： Zhihao Gu Jiabo Le Hehe Wei Zehui Sun Mahmoud Elsayed Hafez Wei Ma Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research CenterFrontiers Science Center for Materiobiology and Dynamic ChemistrySchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201China Department of chemistry Faculty of ScienceBeni-Suef UniversityBeni-Suef 62511Egypt

Although considerable research efforts have been devoted to the design and development of non-noble electrocatalysts for oxygen evolution reaction(OER), substantial enhancement of OER performance with commercial-scale water electrolysis remains a big challenge. This could result from the difficulties in detecting the intrinsic properties and overlooking the assembly process for electrochemical OER process. Here, we employ a microjet collision method to investigate the intrinsic OER activities of individual NiZnFeO_x entities with and without a moderate magnetic field. Our results demonstrate that single NiZnFeO_x nanoparticles(NPs) show the excellent OER performance with a lowest onset potential(~1.35 V vs. RHE) and a greatest magnetic enhancement(~118%) among bulk materials, single agglomerations and NPs. Furthermore, we explore the utility of theoretical investigation by density functional theory(DFT)calculations for studying OER process on NiZnFeO_x surfaces without and with spin alignment, indicating monodispersed NiZnFeO_xNPs with totally spin alignment facilitates the OER process under the external magnetic field. It is found that the well-dispersion of NiZnFeO_x NPs would increase the electrical conductivity and the surface spin state, resulting in promoting their OER activities. This work provides a test for uncovering the essential roles of NPs assembly to a significant promotion of their magnet-assisted OER.

关键词： Single entity OER Magnetic enhancement Electrocatalysis Well-dispersion

Infective Endocarditis in Chronic Hemodialysis Patients: Specificities and Therapeutic Management

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Open Journal of Internal Medicine 2024年第2期14卷 247-258页

作者： Imane Saidi Amal Zniber Mina Agrou Tarik Bouattar Naima Ouzeddoun Loubna Benamar Department of Nephrology Dialysis and Renal Transplantation Ibn Sina University Hospital Rabat Morocco faculty of Medicine and Pharmacy Mohammed V University Rabat Rabat Morocco Acute Medical Unit Ibn Sina University Hospital Rabat Morocco

Infective endocarditis (IE) is a frequent complication in chronic hemodialysis patients (CHD). The repeated placement and manipulation of central venous catheters, underlying valvulopathies, and immunosuppression are the main predisposing factors for these patients to develop IE. We aimed to highlight the clinical and microbiological specificities of IE in CHD patients, detail the therapeutic management in these patients and identify the risk factors for in-hospital mortality. We included 28 CHD patients in whom the diagnosis of IE was established according to modified Duke criteria. The mean age was 47 ± 17 years. Among them, 57% were hypertensive and 39% were diabetic. The average duration of hemodialysis was 3.5 ± 7 years. The vascular access was a tunnelled jugular catheter, arteriovenous fistula, and temporary catheter in 54%, 28%, and 18% of patients, respectively. Half of the patients presented with heart failure at admission. Methicillin-sensitive Staphylococcus is the most commonly implicated pathogen. Transthoracic echocardiography revealed vegetation in all patients. In 60% of cases, the lesion is located on the mitral valve, and in 35% it is on the tricuspid valve. Patients initially received empirical antibiotic therapy, which was adjusted according to bacteriological results. Valve surgery was indicated in 12 patients, with aortic valve replacement being the most performed procedure followed by tricuspid annuloplasty. The in-hospital mortality rate was 32%. Factors associated with mortality were severe mitral insufficiency (p = 0.036), heart failure (p = 0.043), and the presence of Methicillin-resistant Staphylococcus in blood cultures (p = 0.047). IE is a complication with high morbidity and mortality. Its increasing incidence, specificities in chronic CHD patients, and the complexity of its management require a rigorous preventive strategy. A multidisciplinary collaboration between nephrologists, infectious disease specialists, cardiologists, and sur

关键词： Infective Endocarditis Infectious Complications Chronic Hemodialysis Patients

纳米二氧化硅负载FeCl_3作为一种高效多相催化剂用于合成1,2,4-三嗪衍生物(英文)

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催化学报 2015年第4期36卷 620-625页

作者： Davood Habibi Somayyeh Vakili Department of Organic chemistry Faculty of Chemistry Bu-Ali Sina University

The one-pot synthesis of a series of 1,2,4-triazines from the reactions of semicarbazide or thiosemi-carbazide with various α,β-dicarbonyl compounds under reflux conditions in a EtO H-H2O (9:1) mixture as solvent and catalyzed by nano-sized silica supported FeCl3(FeCl3@SiO 2) was investigat-ed. The FeCl3 content of the catalyst was measured by atomic absorption to get the adsorption ca-pacity. The reactions gave high yields of the product and the catalyst was easily separated and re-used for successive reaction runs without significant loss of activity.

关键词：多相催化剂三嗪衍生物纳米尺寸合成三氯化铁原子吸收测定连续反应羰基化合物

Enhanced degradation of refractory organics in ORR-EO system with a blue TiO_(2)nanotube array modified Ti-based Ni-Sb co-doped SnO_(2)anode

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Chinese Chemical Letters 2024年第8期35卷 391-395页

作者： Yifen He Chao Qu Na Ren Dawei Liang Department of Materials chemistry School of Materials Science&EngineeringBeihang UniversityBeijing 102206China Department of Environmental Science Faculty of Environment&LifeBeijing University of TechnologyBeijing 100124China

Recently,a novel 2-electron oxygen reduction reaction(ORR)based electro-oxidation(EO)system was developed,which utilizes a H_(2)O_(2)generation cathode instead of H_(2)evolution cathode.A Ti-based Ni-Sb co-doped SnO_(2)(Ti/NATO)anode was selected for efficient degradation of refractory organics and O_(3)*** synergistic reaction of O3/H_(2)O_(2)further accelerated the generation of hydroxyl radicals(·OH)in the ORR-EO ***,the catalytic activity and long-term effectiveness of the Ti/NATO anode limited the large-scale application of the ORR-EO *** this study,a blue TiO_(2)nanotube array(blue-TiO_(2)-NTA)inter-layer was introduced into the fabrication process between the Ti substrate and NATO catalyst *** to the Ti/NATO anode,the Ti/blue-TiO_(2)-NTA/NATO anode achieved higher efficiency of organic removal and O_(3)***,the accelerated lifetime of the Ti/blue-TiO_(2)-NTA/NATO anode was increased by 7 times compared to the Ti/NATO *** combined with CNTs-C/PTFE air cathode in ORR-EO system,all anodic oxidation and O_(3)/H_(2)O_(2)processes achieved higher•OH *** 92%of TOC in leachate bio-effluent was effectively eliminated with a relatively low energy cost of 45 kWh/t.

关键词： Electro-oxidation Blue TiO_(2)nanotube array O_(3)/H_(2)O_(2)process Refractory organics Leachate bio-effluent

Neotectonics of the Avaj region(NW Iran): left-lateral strike-slip and range-parallel reverse faults

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Journal of Mountain Science 2020年第4期17卷 838-850页

作者： Reza aliPOOR Amir Hossein SADR Sahar GHAMARIAN Geology Department Faculty of Basic ScienceBu-Ali Sina UniversityHamedan 009881Iran

The aim of this study is the geomorphological analysis of neotectonic deformation in the Avaj region in the NW part of the Iranian Plateau. We use observations from detailed field surveys and the analysis of digital elevation model(DEM) and satellite images(Landsat-7 ETM+, 30-m resolution) to explore a new E-W trending strike-slip fault system in the study area. The major active faults of the Avaj region are the NW-SE trending Avaj and Hassanabad fault zones. The Avaj Fault is a SWdipping reverse fault with a transport toward NE and the Hassanabad Fault is a NE-dipping reverse fault that has moved Paleozoic rocks over Cenozoic sedimentary units. Moreover, there are some E-W trending left-lateral strike-slip faults which cut Late Quaternary deposits. The relationship between the NW-SE and E-W faults indicates that the slip at the termination of the NW-SE faults changes from reverse to left-lateral strike-slip faults. The activity of the left-lateral faults has formed a series of offsets and displacements in drainage paths. These left-lateral faults probably initiated in 5±2 Ma because of the convergence between the Central Iran and the South Caspian blocks.

关键词： Active tectonic Offset Earthquake Geomorphology Avaj Fault South Caspian

Gradient-structure-enhanced dielectric energy storage performance of flexible nanocomposites containing controlled preparation of defective TiO_(2) and ferroelectric KNbO_(3) nanosheets

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Nano Research 2024年第5期17卷 4079-4088页

作者： Yan Wang Lili Zhao Ruicong Chen Wenhui Zhao Dengwei Hu Haoran Wang Bin Cui Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education Shaanxi Key Laboratory of Physico–Inorganic chemistry Xi’an Key Laboratory of Functional Supramolecular Structure and MaterialsCollege of Chemistry and Materials ScienceNorthwest UniversityXi’an 710127China School of Information Science and Technology Northwest UniversityXi’an 710127China Engineering Research Center for Titanium Based Functional Materials and Devices in Universities of Shaanxi Province Faculty of Chemistry and Chemical EngineeringBaoji University of Arts and SciencesBaoji 721013China

Next generation power system needs dielectrics with increased dielectric energy ***,the low energy density of dielectrics limits their ***,an asymmetric trilayered nanocomposite,with a transition layer(TL),an insulation layer(IL),and a polarization layer(PL),is designed based on poly(vinylidene fluoride)-polymethyl methacrylate(PVDF-PMMA)matrix using KNbO_(3)(KN)and TiO_(2)(TO)as the *** morphology and defect control of the two-dimensional nano KN and nano TO fillers are realized via a hydrothermal method to increase the composite breakdown strength(E_(b))and the composite energy density(U_(e)).The asymmetric trilayered structure leads to a gradient electric field distribution,and the KN and TO nanosheets block charges transfer along z *** a result,the development path of the electrical trees is greatly curved,and E_(b) is effectively *** the Ue value of the nanocomposites reaches 17.79 J·cm^(-3) at 523 MV·m^(-1).On the basis,the composite Ue is further improved by defect control in TO *** nanocomposite KN/TO/PVDF-PMMA containing TO with less oxygen vacancy concentration(calcined at oxygen atmosphere)acquires a high Ue of 21.61 J·cm^(-3) at 548 MV·m^(-1).This study provides an idea for improving the energy storage performance by combining the design of the composite dielectric structure and the control of nanofillers’defect and morphology.

关键词： asymmetric trilayered structure two-dimensional energy density oxygen vacancies breakdown strength dielectric

Prominent removal of trace lead(Ⅱ)ions from polluted water by terephthalic acid reformed Al/Zn metal organic nanoflakes

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Particuology 2024年第1期84卷 81-88页

作者： Junhua Li Lingshu Gao Junmao Hong Xiaofeng Shi Sifang Kong Jingyu Wang Hassan Algadi Benbin Xu Zhanhu Guo School of chemistry and Chemical Engineering North University of ChinaTaiyuan030051China School of Traffic&Environment Shenzhen Institute of Information TechnologyShenzhen518172China Department of Electrical Engineering Faculty of EngineeringNajran UniversityNajran11001Saudi Arabia Mechanical and Construction Engineering Faculty of Engineering and EnvironmentNorthumbria UniversityNewcastle Upon TyneNE18STUK

Terephthalic acid reformed Al/Zn metal organic nanoflake was prepared and functionalized with trie-thylamine(T-AlZn).Without adding terephthalic acid,there was no product of metal organic nanoflake.T-AlZn has a remarkable performance in removing trace lead(Ⅱ)ions(Pb^(2+)).The adsorption equipoise with the removal rate≥97%was reached within 35 *** removal rates of T-AlZn for Pb^(2+)declined by only 16.73%after four *** adsorption of T-AlZn for Pb^(2+)follows the Langmuir isotherms model and pseudo-second-order dynamics *** utmost adsorption competence was calculated as 215.27 mg g^(-1).The T-AlZn adsorbent exhibits a bright prospect in the adsorption for Pb^(2+)and is a considerable candidate in the disposal of industrial sewage.

关键词： Metal organic complex Nanoflake Trace level Pb^(2+) Adsorption

Efficient degradation of dye pollutant via Z-scheme ball milled ZnO-LaO-S powder photocatalyst

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Transactions of Nonferrous Metals Society of China 2024年

作者： Saeid ZAREI Hossein RAANAEI Sara AHMADI Saeed KAMali Department of Physics， faculty of Nano and Bio Science and Technology， Persian Gulf university chemistry Department， faculty of Science， university of Malaya Department of Physics and Astronomy， Middle Tennessee State university

This investigation aimed to analyze the degradation of Eriochrome Black T （EBT） dye using a semiconductor photocatalyst synthesized through mechanical alloying. Various characterization methods， including X-ray diffraction （XRD）， energy-dispersive X-ray spectroscopy （EDX）， and X-ray photoelectron spectroscopy （XPS）， were employed to study the properties of the photocatalysts. After 35 h of milling， a ball milled mixed metal oxides was formed as confirmed by XRD analysis. EDX and XPS analyses revealed significant differences in adsorption features with and without light exposure. The band gap of the 35 h ball milled sample was determined to be 4.08 eV. To optimize the EBT degradation， artificial neural network genetic algorithms were used to determine the optimal values for ZnO-La2O3dosage， lamp power， and pH， which were found to be 0.43， 52.06， and 3， respectively. The Z-scheme mechanism， supported by band gap， Fermi level， and work function analysis， was found to be responsible for the photocatalytic process. The photocatalysts demonstrated good reusability and high stability. Overall， the results suggest that the synthesized photocatalyst holds promising potential for the degradation of EBT dye in wastewater treatment.

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High Impact Polylactide Based on Organosilicon Nucleation Agent

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Chinese Journal of Polymer Science 2024年第6期42卷 787-797页

作者： Daria Pakuła Bogna Sztorch Eliza Romańczuk-Ruszuk Bogdan Marciniec Robert E.Przekop faculty of chemistry Adam Mickiewicz University in PoznańUniwersytetu Poznańskiego 861-614PoznańPoland Centre for Advanced Technologies Adam Mickiewicz University in PoznańUniwersytetu Poznańskiego 1061-614PoznańPoland Institute of Biomedical Engineering Faculty of Mechanical EngineeringBialystok University of TechnologyWiejska 45C15-351BialystokPoland

Various sectors of the industry are searching for new materials with specific requirements,providing improved *** study presents novel composite materials based on polylactide that have been modified with the organosilicon compound,(3-thiopropyl)polysilsesquioxane(SSQ-SH).The SSQ-SH compound is a mixture of cage structures and not fully condensed random *** composite materials were obtained through injection *** study includes a comprehensive characterization of the new materials that analyze their functional properties,such as rheology(MFR),mechanical strength(tensile strength,Charpy impact strength),and thermal *** microscopic photos were also taken to analyze the microstructure of the *** addition of a 5%by-weight organosilicon compound to polylactide resulted in a significant increase in MFR by 73.8%compared to the neat *** greatest improvement in impact strength was achieved for the 5%SSQ-SH/PLA composite,increasing it by 32.0 kJ/m^(2)compared to PLA,which represents an increase of up to 187%.The conducted research confirms the possibility of modifying the properties of the polymer by employing organosilicon compounds.

关键词： Octa(3-thiopropyl)silsesquioxane 8SH-POSS Polylactide(PLA) Injection moulding Composites