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Chinese chemical Letters 2024年第7期35卷 188-191页

作者： Wenhao Wang Guangpu Zhang Qiufeng Wang Fancang Meng Hongbin Jia Wei Jiang Qingmin Ji Herbert Gleiter Institute for Nanoscience School of Materials Science and Engineering Nanjing University of Science and TechnologyNanjing 210094China School of chemical Engineering Nanjing University of Science&TechnologyNanjing 210094China Nantong Junjiang material science and technology Co. Ltd.Haimen 226136China

TiO_(2)-based films are one of the most attractive photocatalysts owing to their highly cost-effective ***,most TiO_(2)-based photocatalytic films for dye degradation are in the form of robust films(without flexibility),TiO_(2)coatings on carbon matrix(with leakage risk),or surface-covered TiO_(2)hybrids(not favorite to contact with external molecules).Therefore,the development of durable and highly efficient TiO_(2)photocatalytic films for dye degradation is still ***,we fabricated soft photocatalytic hybrid membranes(TANFs)from TiO_(2)nanotubes(Ti NT)and aramid nanofiber(ANF)by a facile vacuum filtration *** similar morphology and dimension of Ti NT and ANF enable them intricately intertwine with each other in the membrane *** an appropriate mixing ratio,the TANF exhibited significantly improved optical and mechanical *** used for dye degradation,the membrane showed excellent photocatalytic performance and could keep stable activity and integrated state for repeated usage.

关键词： Titanium dioxide nanotube Aramid nanofiber Flexible hybrid membrane Photocatalysis Dye degradation

Controllable CPL response driven by achiral UV-photosensitive dichroic dye through cholesteric liquid crystals

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science China Chemistry 2024年第4期67卷 1250-1255页

作者： Yihan Chen Yang Li Hang Li Lulu Li Yiwu Quan Yixiang Cheng State Key Laboratory of Analytical Chemistry for Life science School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China Key Laboratory of High-Performance Polymer material and technology of Ministry of Education School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China School of Environmental and chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

Versatile stimuli-responsive circularly polarized luminescent(CPL)materials have potential applications in information storage,security encryption,and intelligent *** this study,the Z/E isomerization of ultraviolet(UV)-photosensitive achiralα-cyanostilbene derivative was used as an achiral dichroic dye(Switch)to drive the controllable CPL-active response in cholesteric liquid crystals(CLCs).Under irradiation by 365 nm UV light,the resulting CLCs-Z-Switch underwent a Z-to-E configuration isomerization as CLCs-E-Switch,accompanied by a decrease in its dichroic order parameter(SFvalue)from 0.15to *** the quantum yield(QY)of CLCs-E-Switch increased from 8.1%(CLCs-Z-Switch)to 16.8%,the corresponding glumvalues of CPL emission decreased from+0.55/-0.57 to+0.37/-0.39 due to a decrease in the order of helical arrangement of E-Switch in E7 *** study enables photosensitive CLCs-Switch to be applied for optical information storage devices.

关键词： circularly polarized luminescent photosensitive dichroic dye cholesteric liquid crystals chiral induction

Accelerated water harvesting from vapor via a bio-inspired hydrogel pattern

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National science Review 2024年第3期11卷 48-49页

作者： Lianbin Zhang Peng Wang State Key Laboratory of material Processing and Die&Mould technology Key Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology(HUST) School of Environmental science and Engineering Sun Yat-sen University

Water and energy sustainability are integral parts of resource sustainability of the world. Due to water molecules' superior capability of serving as both hydrogenbond donor and acceptor, phase change of water, especially between liquid and vapor, underpins global water cycles,facilitates energy transformation and transfer, and thus helps shape the unique local weather and global climate patterns.

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Recovery of scandium from silicate minerals by high-pressure leaching in sulfuric acid

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Journal of Rare Earths 2024年第7期42卷 1375-1384,I0007页

作者： Peng Yan Xiaoming Chen Likun Gao Bo Yang faculty of Metallurgical and Energy Engineering Kunming University of Science and TechnologyKunming650093China faculty of Land Resources Engineering Kunming University of Science and TechnologyKunming650093China School of Chemistry and chemical Engineering Kunming UniversityKunming650214China

This study investigated the leaching of scandium from a Sc-bearing silicate *** Sc concentrate obtained by beneficiation pre-enrichment has 1.03×10^(−4) wt%Sc and 14.66 wt%*** main Sc-bearing minerals are limonite,chlorite,sericite,and hornblende,in the form of ***-pressure leaching(HPL)with sulfuric acid(98 wt%)and NaF was used to dispose this *** Sc leaching efficiency of 91.82%was obtained under the optimum conditions,which are pressure of 5.0×10^(5) Pa,A/O value of 1.1,L/S value of 1.8,NaF dosage of 2 wt%,at 130℃ for 6 *** X-ray diffraction(XRD)and scanning electron microscopy(SEM)results show that the residue is mainly quartz phase in the multihole *** with ordinary leaching for silicate,high-pressure leaching has significant advantages in saving acid and energy consumption.

关键词： Silicate minerals Scandium High-pressure Leaching Concentrated sulfuric acid Rare earths

Synthesis of multifunctional additives for solid propellants:Structure,properties and mechanism

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Defence technology（防务技术） 2024年第3期33卷 308-316页

作者： Pingan Zhang Lina Sun Jianmin Yuan Jianru Deng College of Chemistry and chemical Engineering Hunan UniversityChangsha 410082PR China College of material science and Engineering Hunan UniversityChangsha 410082PR China Hu Bei Sanjiang Aerospace Jianghe chemical technology Co. LtdYichang 444200PR China

To simplify the composite propellant formulation and address the current issue of the single-functionality present in existing additives,the multi-cyano,amine-based polybutadiene(AEHTPB-CN)was prepared based on AEHTPB by adopting appropriate synthesis *** replacing 10% of HTPB binder in the propellant formulation,it can effectively enhance the interfacial bond strength between the propellant binder matrix and solid fillers(AP(ammonium perchlorate)and RDX(cyclotrimethylene-trinitramine)),the mechanical properties of the HTPB/AP/RDX/Al propellant were superior to blank control propellant with an improvement of 35.4% in tensile strength,62.0% enhancement in elongation at break,and reduce the propellant burn rate by 10.7% with any energy *** function mechanism of AEHTPB-CN was systematically elucidated through experiments and computer simulation *** results show that the tertiary amine group in AEHTPB-CN can react with AP to form ammonium ionic bonds,and the hydroxyl and cyano groups can form hydrogen bonding interactions with AP,which enables AEHTPB-CN to be firmly adsorbed on the AP surface through chemical and physical *** RDX,the interfacial bonding effect of AEHTPB-CN is attributed to their ability to form C-H···N≡C weak hydrogen bonding interaction between the cyano group and RDX methylene group.

关键词： Hydroxyl-terminated polybutadiene(HTPB) HTPB propellant chemical modification Bonding agent Mechanism

Ultrafast Response and Threshold Adjustable Intelligent Thermoelectric Systems for Next‑Generation Self‑Powered Remote IoT Fire Warning

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Nano-Micro Letters 2024年第11期16卷 413-428页

作者： Zhaofu Ding Gang Li Yejun Wang Chunyu Du Zhenqiang Ye Lirong Liang Long‑Cheng Tang Guangming Chen College of materials science and Engineering&College of Civil and Transportation Engineering Shenzhen UniversityShenzhen 518055People’s Republic of China College of material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material Technology of MoEHangzhou Normal UniversityHangzhou 311121People’s Republic of China

Fire warning is vital to human life,economy and ***,the development of effective warning systems faces great challenges of fast response,adjustable threshold and remote ***,we propose an intelligent self-powered remote IoT fire warning system,by employing single-walled carbon nanotube/titanium carbide thermoelectric composite *** flexible films,prepared by a convenient solution mixing,display p-type characteristic with excellent high-temperature stability,flame retardancy and TE(power factor of 239.7±15.8μW m^(-1) K^(-2))*** comprehensive morphology and structural analyses shed light on the underlying *** the assembled TE devices(TEDs)exhibit fast fire warning with adjustable warning threshold voltages(1–10 mV).Excitingly,an ultrafast fire warning response time of~0.1 s at 1 mV threshold voltage is achieved,rivaling many state-of-the-art ***,TE fire warning systems reveal outstanding stability after 50 repeated cycles and desired durability even undergoing 180 days of air ***,a TED-based wireless intelligent fire warning system has been developed by coupling an amplifier,analogto-digital converter and Bluetooth *** combining TE characteristics,high-temperature stability and flame retardancy with wireless IoT signal transmission,TE-based hybrid system developed here is promising for next-generation self-powered remote IoT fire warning applications.

关键词： Thermoelectric Self-powered IoT fire warning Ultrafast response Threshold adjustable

Superior Latent Heat Eutectic Salt Na_(2)CO_(3)-Li_(2)CO_(3)-LiF for Thermal Energy Storage:Preparation and Performance Investigation

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Journal of Thermal science 2024年第2期33卷 501-508页

作者： LI Weiwei MIAO Qi ZHANG Yelong DING Hongliang YANG Sa LAI Yuan FENG Daili DING Yulong JIN Yi TAN Linghua School of Chemistry and chemical Engineering Nanjing University of Science&TechnologyNanjing210094China National Special Superfine Powder Engineering Research Center Nanjing University of Science and TechnologyNanjing210094China Nanjing Jinhe Energy material Co. LtdNanjing210047China School of chemical Engineering University of BirminghamBirminghamB152TTUK School of Energy&Environmental Engineering University of Science and Technology BeijingBeijing100083China

In this paper,a novel ternary eutectic salt Na_(2)CO_(3)-Li_(2)CO_(3)-LiF was designed and investigated for concentrated solar power(CSP).The FactSage software was used to predict the composition and eutectic point of Na_(2)CO_(3)-Li_(2)CO_(3)-*** microstructure,thermophysical properties,and thermal stability of eutectic salts were experimentally measured using various analytical *** a mass ratio of 57%:32%:11%,the eutectic salt exhibited excellent thermal storage properties with a fusion enthalpy of 413 J/g and a melting point of 426.8℃.The excellent thermal stability of the eutectic salt was reflected by a weight loss of only 0.8% at 600℃.

关键词： phase change materials ternary eutectic salt latent heat thermal stability

Deep Insight of Design,Mechanism,and Cancer Theranostic Strategy of Nanozymes

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Nano-Micro Letters 2024年第2期16卷 165-217页

作者： Lu Yang Shuming Dong Shili Gai Dan Yang He Ding Lili Feng Guixin Yang Ziaur Rehman Piaoping Yang Key Laboratory of Superlight materials and Surface technology Ministry of EducationCollege of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001People’s Republic of China Yantai Research Institute Harbin Engineering UniversityYantai 264000People’s Republic of China Key Laboratory of Green chemical Engineering and technology of Heilongjiang Province College of Material Science and Chemical EngineeringHarbin University of Science and TechnologyHarbin 150040People’s Republic of China Department of Chemistry Quaid-i-Azam UniversityIslamabad 45320Pakistan

Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale ***,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side ***,various nanozymes have been developed and used for tumor *** this review,more than 270 research articles are discussed systematically to present progress in the past five ***,the discovery and development of nanozymes are ***,classification and catalytic mechanism of nanozymes are ***,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical ***,synergistic theranostic strategy of nanozymes are ***,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities.

关键词： Nanozymes Classification Prediction and design Catalytic mechanism Tumor theranostics

A single atom photocatalyst co-doped with potassium and gallium for enhancing photocatalytic hydrogen peroxide synthesis

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Nano Research 2024年第8期17卷 7027-7038页

作者： Wenan Cai Yuichiro Tanaka Xing Zhu Teruhisa Ohno Department of Applied Chemistry Faculty of EngineeringKyushu Institute of TechnologyKitakyushu 804-8550Japan College of Bioresources chemical and materials Engineering Shaanxi University of Science&TechnologyXi’an 710021China

Polymer carbon nitride(PCN)is widely used in ***,pristine PCN has disadvantages such as insufficient visible light absorption and low photogenerated carrier separation efficiency that greatly limited the photocatalytic *** a non-toxic metal,gallium has the potential to solve the defects of *** ions coordinated with nitrogen in carbon nitride to form Ga-N active sites and improved the photocatalytic *** doped potassium ions form a transmission channel for charge redistribution and transfer between adjacent layers,which is beneficial for better separation of photoexcited *** this study,a series of PCN co-doped with gallium and potassium(Ga-K-PCN)were *** experimental results indicated photocatalytic generation of hydrogen peroxide proceeds through the 2e−oxygen reduction reaction ***,Nyquist plots and photocurrent results further proved that the presence of Ga-N sites and potassium ion doping could significantly improve the separation/transfer of intra-planar and interlayer charge carriers and thus enhance photocatalytic *** Ga10-K3-PCN photocatalysts promoted yield of H_(2)O_(2),with reactivity at 28.2μmol/(g·h)and solar-to-chemical conversion efficiency at 0.64%,surpassed that of a typical photo-catalyst based on PCN(0.18%).

关键词： photocatalysis gallium oxygen reduction reaction H_(2)O_(2) production

Adaptive Optimal Discrete-Time Output-Feedback Using an Internal Model Principle and Adaptive Dynamic Programming

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IEEE/CAA Journal of Automatica Sinica 2024年第1期11卷 131-140页

作者： Zhongyang Wang Youqing Wang Zdzisław Kowalczuk the College of Information science and technology Beijing University of Chemical TechnologyBeijing 100029China IEEE the Department of Robotics and Decision Systems Faculty of ElectronicsTelecommunications and InformaticsGdańsk University of TechnologyGdansk 80-233Poland

In order to address the output feedback issue for linear discrete-time systems, this work suggests a brand-new adaptive dynamic programming(ADP) technique based on the internal model principle(IMP). The proposed method, termed as IMP-ADP, does not require complete state feedback-merely the measurement of input and output data. More specifically, based on the IMP, the output control problem can first be converted into a stabilization problem. We then design an observer to reproduce the full state of the system by measuring the inputs and outputs. Moreover, this technique includes both a policy iteration algorithm and a value iteration algorithm to determine the optimal feedback gain without using a dynamic system model. It is important that with this concept one does not need to solve the regulator equation. Finally, this control method was tested on an inverter system of grid-connected LCLs to demonstrate that the proposed method provides the desired performance in terms of both tracking and disturbance rejection.

关键词： Adaptive dynamic programming(ADP) internal model principle(IMP) output feedback problem policy iteration(PI) value iteration(VI)