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RING OPENING POLYMERIZATION OF TETRAHYDROFURAN CATALYSED BY MAGHNITE-H^+

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Chinese Journal of Polymer Science 2012年第1期30卷 56-62页

作者： Khadidja Benkenfoud Amine Harrane Mohammed Belbachir Laboratoire de chimie des Polymeres departement de chimie Faculte des SciencesUniversite d'Oran Es-SeniaBP No 1524 El M'Naouar31000 OranAlgeria

The cationic ring-opening polymerization of tetrahydrofiiran using maghnite-H~＋ is ***-H~＋,is a non-toxic solid catalyst issued from proton exchanged montmorillonite ***,also called ＂poly（butandiol） ether＂,with acetate and hydroxyl end groups was successfully *** of reaction temperature, weight ratio of initiator/monomer and reaction time on the conversion of monomer and on the molecular weight are investigated.A cationic mechanism of the reaction was *** chemistry can be considered as a suitable route for preparing poly（THF） as a soft segment for thermoplastic elastomers.

关键词： Montmorillonite Maghnite Ring opening polymerization THF

Pyrolysis of olive residue/low density polyethylene mixture：Part Ⅰ Thermogravimetric kinetics

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燃料化学学报 2008年第6期36卷 672-678页

作者： ABOULKAS A E1 HARFI K El BOUADILI A Laboratoire de Recherche sur la Reactivites des Materiaux et l Optimisation des Procedes ＂REMATOP＂ Departement de chimie Faculte des Sciences Semlalia Universite Cadi Ayyad BP 2390 40001 Marrakech Maroc departement de chimie Faculte polydisciplinaire de Beni-Mellal Universite Sultan Moulay Slimane BP 592 23000 Beni-Mellal Maroc Laboratoire de chimie Organique et Analytique Departement de chimie Faculte des Sciences et Techniques de Beni-Mellal Universite Sultan Moulay Slimane BP 523 23000 Beni-Mellal Maroc

This paper demonstrates the thermal pyrolysis of olive residue,low density polyethylene(LDPE) and olive residue/LDPE mixture in an inert atmosphere of N2 using thermogravimetric analysis(TGA).Measurements were carried out in the temperature range 300K^973K at heating rates of 2K/min,10K/min,20K/min and 50K/*** on the results obtained,three temperature regimes were selected for studying the non-isothermal kinetics of olive residue/LDPE *** first two were dominated by the olive residue pyrolysis,while the third was linked to the LDPE pyrolysis,which occurred at much higher *** between the experimental and calculated TG/DTG profiles were considered as a measurement of the extent of interactions occurring on *** maximum degradation temperatures of each component in the mixture were higher than those the individual components;thus an increase in thermal stability was *** kinetic parameters associated with thermal degradation were determined using Friedman isoconversional method.

关键词：高温分解反应低密度聚乙烯动力学 LDPE

Electronic and Optical Properties of TiS2 determined from Generalized Gradient Approximation Study

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Chinese Physics Letters 2015年第9期32卷 96-99页

作者： Hamza El-Kouch Larbi El Farh Jamal Sayah Allal Challioui Laboratoire de mecanique & energetique Departement de Physique Faculte des Sciences Universite Mohmnmed Premier Oujda Maroc Laboratoire de chimie organique macromol~culaire et produits naturels Equipe: Photochimie et Chimie Macromoleculaire Faculte des Sciences Universite Mohammed Premier Oujda. Maroc

The electronic and optical properties of TiS2 are studied of density functional theory. A linearized and augmented by using an ab-initio calculation within the frame plane wave basis set with the generalized gradient approximation as proposed by Perdew et al. is used for the energy exchange-correlation determination. The results show a metallic character of TiS2, and the plots of total and partial densities of states of TiS2 show the metallic character of the bonds and a strong hybridization between the states d of Ti and p of S below the Fermi energy. The optical properties of the material such as real and imaginary parts of dielectric constant （ε（w） = ε1（w）＋ iε2（w））, refractive index n（w）, optical reflectivity R（w）, for E / /x and E / /z are performed for the energy range of 0-.14 eV.

关键词： Ti ab Electronic and Optical Properties of TiS2 determined from Generalized Gradient Approximation Study

Synthesis of Some New 1,4-Dihydropyridine derivatives through a Facile One-pot Hantzsch Condensation Catalyzed by Triethylamine

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Chinese Journal of Chemistry 2012年第3期30卷 733-737页

作者： Ghalem, Wassima Boulcina, Raouf debache, Abdelmadjid Laboratoire de Synthese des Molecules d＇Interet Biologique Departement de ChimieFaculte des Sciences Exactes Universite Mentouri de Constantine 25000 Constantine Algerie

A facile and efficient synthesis of new 1,4-dihydropyridine derivatives was reported via Hantzsch three-com- ponent condensation reaction of aldehydes or formylphenylboronic acids, ethyl acetoacetate, and ammonium acetate in the presence of a catalytic amount of triethylamine under solvent-free conditions. The method described here of- fers several advantages including high yields, short reaction times, and simple work-up procedure.

关键词： 1,4-dihydropyridine triethylamine formylphenylboronic acid Hantzsch reaction solvent-flee condi-tion

Kinetic degradation of amoxicillin by using the electro-Fenton process in the presence of a graphite rods from used batteries

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Chinese Journal of Chemical Engineering 2021年第4期34卷 183-190页

作者： Hakima Kadji Idris Yahiaoui Zehira Garti Abdeltif Amrane Farida Aissani-Benissad Laboratoire de Genie de l'Environnement(LGE) Faculte de TechnologieUniversite de Bejaia06000 BejaiaAlgeria Ecole Nationale Superieure de chimie de Rennes Universite RenneslCNRSUMR 622611 allee de BeaulieuCS 50837France

This study reports the removal of amoxicillin(AMX)in aqueous media using the electroFenton process in the presence of a graphite cathode recovered from used *** impact of the relevant parameters on the electroFenton process,namely the applied current intensity,the temperature,the initial concentration of AMX and the initial concentration of ferrous ions were *** results showed that the optimal values were:I=600 mA,T=25℃,[AMX]_(0)=0.082 mmol·L^( 1) and[Fe^(2+)]=1 mmol·L^(1),leading to 95%degradation and 74%*** model parameters of AMX mineralization were determined using nonlinear methods,showing that it follows a pseudosecondorder *** Energy consumption(EC)calculated under the optimal values was found to be 0.79 kWhg 1,which was of the same order of magnitude of those reported in other findings;while it is noteworthy that the electrodes used in our study are of a lower cost.

关键词： Wastewater Amoxicillin Electro-Fenton Pharmaceuticals Solid waste recovery Kinetic modelling

Exploration of strong-field double ionization of C_(3)H_(6) with the structures of propene and cyclopropane in intense laser fields

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Chinese Physics B 2018年第3期27卷 225-230页

作者： Qing-Yun Xu Yan-Rong Tian Hui-Zhong Lu Jun Zhang Tong-Tong Xu Hong-Dan Zhang Xue-Shen Liu Jing Guo Institute of Atomic and Molecular Physics Jilin UniversityChangchun 130012China Laboratoire de chimie The oiique Faculte des SciencesUniversite de SherbrookeSherbrooke J1K 2R 1Canad

By using classical ensemble method,we investigate the double ionization of C_(3)H_(6) molecule with different structures(propene and cyclopropane)in intense laser *** numerical results show that the non-sequential double ionization occurs in propene molecule rather than cyclopropane molecule in 1200 nm laser *** further explain this interesting phenomenon,the momentum distribution of double ionized electrons is presented and the result presents the"finger-like"structure at about 30 TW/cm^(2) of propene molecule,and this structure is more obvious than that in cyclopropane *** above phenomena are also demonstrated by analysing the energy distributions of double-ionized electrons versus ***,we also investigated the angular distribution at the end of pulse,which is different between propene and cyclopropane.

关键词： C_(3)H_(6)molecule non-sequential double ionization momentum distribution

Titanate Nanorods Modified with Nanocrystalline ZnS Particles and Their Photocatalytic Activity on Pollutant Removal

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Journal of Materials Science & Technology 2016年第11期32卷 1122-1128页

作者： G.Naudin T.Entradas B.Barrocas O.C.Monteiro faculte de chimie Universite Pierre et Marie Curie (UPMC) Batiment F 3e etage 4 placeJussieu 75005 Paris France Centro de Quimica e Bioquimica Faculdade de Ciencias Universidade de Lisboa 1749-016 Lisboa Portugal

Aiming to produce materials with enhanced photocatalytic properties, the synthesis of new crystalline nanocomposites by combining titanate nanorods（TNR） with ZnS nanocrystallites is described in this *** TNR modification was accomplished by an in situ nucleation and growth process of ZnS *** diethyldithiocarbamate was used as the metal chalcogenide precursor. The prepared materials were structural, morphological and optical characterized by X-ray diffraction, transmission electron microscopy and high resolution transmission electron microscopy, energy dispersive spectroscopy and powder diffuse reflectance spectra. Crystalline Zn S nanoparticles were obtained as a homogeneous and continuous layer, covering completely the TNR surface. The application of these new nanocomposite materials on photocatalytic degradation of pollutants was investigated. First, the evaluation of hydroxyl radical formation, using the terephthalic acid as probe, was studied. Afterwards, the adsorption and photodegradation of safranine-T, used here as a model pollutant molecule, was investigated. The obtained data indicate that the prepared nanocomposites have potential to be used as photocatalysts for organic pollutant *** best removal results（97% removal） were obtained using the 0.01 Zn S/HTNR sample as catalyst（0.2 g/L; 10 ppm safranin-T solution） with a combination of a low dye adsorption（20%） and a high dye photocatalytic degradation（77%）.

关键词： Nanocomposite materials Surface modification Photocatalysis Adsorption ability Optical properties

Photoresponse and H2 gas sensing properties of highly oriented Al and Al/Sb doped ZnO thin films

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Progress in Natural Science:Materials International 2013年第6期23卷 519-523页

作者： Hannane Benelmadjat Boubekeur Boudine Aissa Keffous Noureddine Gabouze Laboratoire de Physico-chimie des Semi-Conducteurs Departement de PhysiqueFaculte des Sciences ExactesUniversite Mentouri-Route Ain Elbey Laboratoire de Cristallographie Departement de PhysiqueFaculte des Sciences ExactesUniversite Mentouri-Route Ain Elbey Silicon Technology development Unit

ZnO:Al and ZnO:Al/Sb thin films have been prepared and *** thin films were deposited on Si substrates by the sol-gel *** structural,optical and electrical properties of ZnO films have been investigated by spectrophotometry,ellipsometry,X-ray diffraction and current-voltage *** is found that the films exhibit wurtzite structure with a highly c-axis orientation perpendicular to the surface of the substrate,a high reflectivity in the infrared region and a response to ***,it has been found that Si/（ZnO:Al/Sb）/Al photodiode is promising in photoconduction device while Si/（ZnO:Al）/Al can be used as gas sensor responding to the low H2concentrations.

关键词： Zinc oxide Co-doping Thin films Gas sensing Photoresponse

Oxidation of propane over ammonium-transition metal mixed keggin phosphomolybdate salts

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Journal of Natural Gas Chemistry 2010年第1期19卷 54-60页

作者： T. Mazari C. Roch. Marchal S. Hocine N. Salhi C. Rabia Laboratoire de chimie du Gaz Naturel Faculte' de Chimie Universite' des Sciences et de la Technologie Houari Boumedie`ne USTHB BP32 El-Alia Bab-Ezzouar Alger Alge'rie ILV-UMR 8180 CNRS Universite' de Versailles -St Quentin-en-Yvelines Ba?timent Lavoisier 45 avenue des Etats-Unis 78035 Versailles Cedex France

Mixed ammonium-transition metal salts with formula of （NH4）xMyHzPMo12O40 （M = Ni^2＋, Co^2＋ or Fe ^3＋） denoted as MPMo12 have been investigated for the oxidation of propane, with molecular oxygen, at temperature range between 380 ℃ and 420 ℃ after in-situ pre-treatment performed at two heating rate of 5 or 9℃/min. They were characterized by BET method, XRD, UV-Vis and IR techniques. The catalysts were found to be active in the propane oxidation and selective to propene or acrolein, in particular for samples pre-treated with the heating rate of 9℃/min. FePMo12 was found to be a more active catalyst for propene （17.2% yield） with minimal over deep oxidation （0.3% yield in COx）.

关键词： phosphomolybdate ammonium keggin propane oxidation propene acrolein