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Co/CoO heterojunction rich in oxygen vacancies introduced by O2 plasma embedded in mesoporous walls of carbon nanoboxes covered with carbon nanotubes for rechargeable zinc-air battery

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Carbon energy 2024年第7期6卷 14-25页

作者： Leijun Ye Weiheng Chen Zhong-Jie Jiang Zhongqing Jiang Key Laboratory of Optical Field Manipulation of Zhejiang Province Department of PhysicsZhejiang Sci-Tech UniversityHangzhouChina department of Mechanical Engineering Ningbo University of TechnologyNingboChina Guangzhou Key Laboratory for Surface Chemistry of energy Materials Guangdong Engineering and Technology Research Center for Surface Chemistry of Energy MaterialsCollege of Environment and EnergySouth China University of TechnologyGuangzhouChina

Herein,Co/CoO heterojunction nanoparticles(NPs)rich in oxygen vacancies embedded in mesoporous walls of nitrogen-doped hollow carbon nanoboxes coupled with nitrogen-doped carbon nanotubes(P-Co/CoOV@NHCNB@NCNT)are well designed through zeolite-imidazole framework(ZIF-67)carbonization,chemical vapor deposition,and O_(2) plasma *** a result,the threedimensional NHCNBs coupled with NCNTs and unique heterojunction with rich oxygen vacancies reduce the charge transport resistance and accelerate the catalytic reaction rate of the P-Co/CoOV@NHCNB@NCNT,and they display exceedingly good electrocatalytic performance for oxygen reduction reaction(ORR,halfwave potential[EORR,1/2=0.855 V *** hydrogen electrode])and oxygen evolution reaction(OER,overpotential(η_(OER,10)=377mV@10mA cm^(−2)),which exceeds that of the commercial Pt/C+RuO_(2) and most of the formerly reported ***,both the aqueous and flexible foldable all-solid-state rechargeable zinc-air batteries(ZABs)assembled with the P-Co/CoOV@NHCNB@NCNT catalyst reveal a large maximum power density and outstanding long-term cycling ***-principles density functional theory calculations show that the formation of heterojunctions and oxygen vacancies enhances conductivity,reduces reaction energy barriers,and accelerates reaction kinetics *** work opens up a new avenue for the facile construction of highly active,structurally stable,and cost-effective bifunctional catalysts for ZABs.

关键词： heterojunction oxygen evolution/reduction reaction oxygen vacancies rechargeable zinc–air battery three‐dimensional nitrogen‐doped hollow carbon nanoboxes

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A weakly-solvated ether-based electrolyte for fast-charging graphite anode

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Chinese Chemical Letters 2024年第8期35卷 526-532页

作者： Xiao Zhu Yanbing Mo Jiawei Chen Gaopan Liu Yonggang Wang Xiaoli Dong department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New EnergyiChEM(Collaborative Innovation Center of Chemistry for Energy Materials)Fudan UniversityShanghai 200433China

Weakly-solvated electrolytes(WSEs)utilizing solvents with weak coordination ability offer advantages for low-potential graphite anode owing to their facile desolvation process and anions-derived inorganic-rich solid electrolyte interphase(SEI)***,these electrolytes face challenges in achieving a balance between the weak solvation affinity and high ionic conductivity,as well as between rigid inorganic-rich SEI and flexible SEI for long-term ***,we introduce 1,3-dioxolane(DOL)and lithium bis(trifluoromethanesulfonyl)-imide(LiTFSI)as functional additives into a WSE based on nonpolar cyclic ether(1,4-dioxane).The well-formulated WSE not only preserves the weakly solvated features and anion-dominated solvation sheath,but also utilizes DOL to contribute organic species for stabilizing the SEI *** from these merits,the optimized electrolyte enables graphite anode with excellent fast-charging performance(210 mAh/g at 5 C)and outstanding cycling stability(600 cycles with a capacity retention of 82.0%at room temperature and 400 cycles with a capacity retention of 80.4%at high temper-ature).Furthermore,the fabricated LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)||graphite full cells demonstrate stable operation for 140 cycles with high capacity retention of 80.3%.This work highlights the potential of tailoring solvation sheath and interphase properties in WSEs for advanced electrolyte design in graphite-based lithium-ion batteries.

关键词： Weakly-solvated solvent Bisalt ether-based electrolyte Graphite anode NCM||graphite battery Interfacial optimization

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Effects of surface morphology on tribological properties of Arapaima gigas scales

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Friction 2024年第7期12卷 1469-1482页

作者： Shuaijun ZHANG Pengpeng BAI Xiangli WEN Chengwei WEN Hui CAO Wanyou YANG Yu TIAN State Key Laboratory of Tribology in Advanced equipment Department of Mechanical EngineeringTsinghua UniversityBeijing 100084China Key Laboratory of Bionic Engineering(Ministry of Education China)Jilin UniversityChangchun 130022China

The remarkable mechanical adaptability of arapaima(Arapaima gigas)scales has made them an important subject of ***,no research has been conducted into their tribological properties,which are crucial for the protectability and flexibility of *** this study,by combining morphological characterizations,friction experiments,and theoretical analyses,the relationship between the surface morphology and tribological properties of arapaima scales is *** results indicate that arapaima scales exhibit varying surface morphologies in different *** specifically,the exposed regions of scales feature grooves and a circulus,whereas the covered regions exhibit *** specific surface morphology of arapaima scales produces varying tribological properties across different regions and sliding *** unique tribological properties of arapaima scales influence the forces received from predator attacks and neighboring scales,directly influencing the arapaima’s protective *** study provides new insights into the mechanisms of natural flexible dermal armors,and it has potential applications in personal protective systems.

关键词： arapaima scales surface morphology tribological properties protectability

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Unlock the full potential of carbon cloth-based scaffolds towards magnesium metal storage via regulation on magnesiophilicity and surface geometric structure

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Journal of energy Chemistry 2024年第3期90卷 423-434,I0010页

作者： Jing Liu Min Wang Zhonghua Zhang Jinlei Zhang Yitao He Zhenfang Zhou Guicun Li College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina department of Pharmacy Jining Medical UniversityRizhao 276826ShandongChina department of energy and Power Engineering School of Energy and EnvironmentAnhui University of TechnologyMa’anshan 243000AnhuiChina

The development of rechargeable magnesium(Mg) batteries is of practical significance to upgrade the electric energy storage devices due to exceptional capacity and abundant resources of Mg-metal ***,the reversible Mg electrochemistry suffers from unsatisfied rate capability and lifespan,mainly caused by non-uniform distribution of *** this work,a fresh design concept of threedimensional carbon cloths scaffolds is proposed to overcome the uncontrollable Mg growth via homogenizing electric field and improving magnesiophilicity.A microscopic smooth and nitrogen-containing defective carbonaceous layer is constructed through a facile pyrolysis of ZIF8 on carbon *** revealed by finite element simulation and DFT calculation results,the smooth surface endows with uniform electric field distribution and simultaneously the nitrogen-doping species enable good magnesiophilicity of *** fine and uniform Mg nucleus as well as the inner electrodeposit behavior are also *** a result,an exceptional cycle life of 500 cycles at 4.0 mA cm^(-2) and 4.0 mA h cm^(-2) is firstly realized to our best ***,the functional scaffolds can be cycled for over 2200 h at 2.0 mA cm^(-2) under a normalized capacity of 5.0 mA h cm^(-2),far exceeding previous *** work offers an effective approach to enable the full potential of carbon cloths-based scaffolds towards metal storage for next generation battery applications.

关键词： Magnesium metal anodes Electrodeposition Heterogeneous nucleation

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Cutting edge preparation of microdrills by shear thickening polishing for improved hole quality in electronic PCBs

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Frontiers of Mechanical Engineering 2024年第2期19卷 99-107页

作者： Jiahuan WANG Mingfeng KE Jiepei LIAO Yu ZHOU Saurav GOEL Jaya VERMA Xu WANG Weigang GUO Julong YUAN Binghai LYU College of Mechanical Engineering Zhejiang University of TechnologyHangzhou 310000China Ultra-precision Machining Center Key Laboratory of Special Purpose Equipment and Advanced Manufacturing TechnologyZhejiang University of TechnologyHangzhou 310000China School of Engineering London South Bank UniversityLondon SE10AAUK Shenzhen Jinzhou Precision Technology Corporation Shenzhen 518116China department of Mechanical Engineering University of Petroleum and Energy StudiesDehradun 248007India Special equipment Institute Hangzhou Vocational&Technical CollegeHangzhou 310018China

Printed circuit boards(PCBs)are representative composite materials,and their high-quality drilling machining remains a persistent challenge in the *** finishing of the cutting edge of a microdrill is crucial to drill performance in machining fine-quality holes with a prolonged tool *** miniature size involving submicron scale geometric dimensions,a complex flute shape,and low fracture toughness makes the cutting edge of microdrills susceptible to breakage and has been the primary limiting factor in edge preparation for *** this study,a newly developed cutting edge preparation method for microdrills was tested experimentally on electronic printed circuit *** proposed method,namely,shear thickening polishing,limited the cutting edge burrs and chipping on the cutting edge,and this in turn transformed the cutting edge’s radius from being sharp to ***,the edge–edge radius could be regulated by adjusting the processing *** drilling experiments were conducted to investigate the influence of different cutting edge radii on wear,hole position accuracy,nail head value,and hole wall *** proposed approach showed 20%enhancement in hole position accuracy,33%reduction in the nail head value,and 19%reduction in hole wall roughness compared with the original ***,a threshold is needed;without it,excessive shear thickening polishing will result in a blunt edge,which may accelerate the wear of the *** was identified as the primary factor that reduced hole *** study indicates that in printed circuit board machining,microdrills should effectively eliminate grinding defects and maintain the sharpness of the cutting edge as much as possible to obtain excellent drilling ***,shear thickening polishing is a promising method for cutting edge preparation of *** research and optimization can lead to additional improvements in microdrill performance and contribute to the conti

关键词： microdrill shear thickening polishing cutting edge preparation electronic printed circuit boards hole quality

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Characterization and Analysis of Inconel 718 Alloy Ground at Different Speeds

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Chinese Journal of Mechanical Engineering 2024年第2期37卷 137-149页

作者： Hao Liu Huili Han Qinghong Jiang Minglin He Bi Zhang department of Mechanical and energy Engineering Southern University of Science and TechnologyShenzhen 518055China department of Mechanical Engineering Hong Kong Polytechnic UniversityHong KongChina

Inconel 718(IN718)alloy is widely applied to fabricate high temperature resistant or corrosion resistant parts due to its excellent mechanical ***,the machining of IN718 alloy is difficult as it may cause serious tool wear and poor surface quality(SQ)of the *** this work,grinding experiments on IN718 alloy at different speeds were conducted by using a CBN grinding *** relationship between grinding speed,SQ and subsurface damage(SSD)was well *** increasing grinding speed,surface roughness decreased,and SQ was greatly ***,the microhardness of the grinding surface declined as the grinding speed *** SSD depth was almost unchanged when the grinding speed was lower than 15 m/s,then it decreased with higher grinding *** was attributed to the mechanical-thermal synergistic effect in the grinding *** results indicated that increasing grinding speed can effectively improve the SQ and reduce the SSD of IN718 *** conclusion in the work may also provide insight into processing other hard-to-machining materials.

关键词： Surface integrity Grinding speed IN718 alloy Precision machining CBN grinding wheel

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Effect of boundary conditions on shakedown analysis of heterogeneous materials

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Applied Mathematics and Mechanics(English Edition) 2024年第1期45卷 39-68页

作者： Xiuchen GONG Yinghao NIE Gengdong CHENG Kai LI State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentInternational Research Center for Computational MechanicsDepartment of Engineering MechanicsDalian University of TechnologyDalian 116023Liaoning ProvinceChina

The determination of the ultimate load-bearing capacity of structures made of elastoplastic heterogeneous materials under varying loads is of great importance for engineering analysis and design. Therefore, it is necessary to accurately predict the shakedown domains of these materials. The static shakedown theorem, also known as Melan's theorem, is a fundamental method used to predict the shakedown domains of structures and materials. Within this method, a key aspect lies in the construction and application of an appropriate self-equilibrium stress field(SSF). In the structural shakedown analysis, the SSF is typically constructed by governing equations that satisfy no external force(NEF) boundary conditions. However, we discover that directly applying these governing equations is not suitable for the shakedown analysis of heterogeneous materials. Researchers must consider the requirements imposed by the Hill-Mandel condition for boundary conditions and the physical significance of representative volume elements(RVEs). This paper addresses this issue and demonstrates that the sizes of SSFs vary under different boundary conditions, such as uniform displacement boundary conditions(DBCs), uniform traction boundary conditions(TBCs), and periodic boundary conditions(PBCs). As a result, significant discrepancies arise in the predicted shakedown domain sizes of heterogeneous materials. Built on the demonstrated relationship between SSFs under different boundary conditions, this study explores the conservative relationships among different shakedown domains, and provides proof of the relationship between the elastic limit(EL) factors and the shakedown loading factors under the loading domain of two load vertices. By utilizing numerical examples, we highlight the conservatism present in certain results reported in the existing literature. Among the investigated boundary conditions, the obtained shakedown domain is the most conservative under ***, utilizing PBCs to

关键词： heterogeneous material self-equilibrium stress field(SSF) shakedown analysis effect of boundary conditions

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Nonlinear Impact Damage Evolution of Charpy Type and Analysis of Its Key Influencing Factors

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Chinese Journal of Mechanical Engineering 2024年第1期37卷 254-264页

作者： Jianfeng Mao Qian Xu Jiadong Yang Chi Cao Dasheng Wang Fengping Zhong Mingya Chen Institute of Process equipment and Control Engineering Zhejiang University of TechnologyHangzhou 310032China Taizhou Key Laboratory of Advanced Manufacturing Technology Taizhou InstituteZhejiang University of TechnologyTaizhou 318014China State Key Laboratory of Nuclear Power Safety Monitoring Technology and equipment Shenzhen 518172China Zhejiang Academy of Special equipment Science Hangzhou 310020China Suzhou Nuclear Power Research Institute Suzhou 215004China

The current research of Charpy impact mainly focuses on obtaining the ductile brittle transition temperature of materials by *** with experiments,numerical simulation can study many problems with harsh ***,there are still few studies on the influence of geometric factors such as side *** this paper,the geometry of standard Charpy impact test is *** with different widths and side grooves are *** finite element model of Charpy impact was established by ABAQUS *** test results and simulation results to verify each *** effects of sample width,side groove depth and side groove bottom fillet on the impact fracture resistance of the sample were *** results show that the specimen width is positively correlated with the impact toughness of the *** side groove greatly reduces the impact toughness of the material;the toughness of side groove decreases with the increase of depth;the fracture toughness of side groove decreases with the increase of fillet at the bottom of side *** proportion of toughness energy to impact energy of samples was *** results show that the toughness energy accounts for about 70%of the impact energy of the sample,which has little to do with the geometric characteristics of the *** study presents a reliable method for studying Charpy impact *** influence of geometric parameters is obtained,which provides a reference method for the study of impact toughness of high toughness materials.

关键词： Johnson-Cook model Impact toughness Charpy impact

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Exceptional catalytic effect of novel rGO-supported Ni-Nb nanocomposite on the hydrogen storage properties of MgH_(2)

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Journal of Materials Science & Technology 2024年第5期172卷 83-93页

作者： Samuel Guemou Liuting Zhang Shuai Li Yiqun Jiang Tao Zhong Zichuan Lu Ren Zhou Fuying Wu Qian Li School of energy and Power Instrumental Analysis CenterJiangsu University of Science and TechnologyZhenjiang 212003China National Engineering Research Center for Magnesium Alloys&National Key Laboratory of Advanced Casting Technologies&College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing Institute of New energy Storage Materials and equipment Chongqing 401135China Max Planck Institute for Iron Research Düsseldorf 40237Germany

The design of an excellent active catalyst to improve the sluggish kinetic and thermodynamic properties of magnesium hydride(MgH_(2))remains a great challenge to achieve its practical *** this study,a novel Ni-Nb/rGO nanocomposite catalyst was successfully prepared by one-spot hydrothermal and sub-sequent calcination *** novel Ni-Nb/rGO nanocomposite exhibits an exceptional catalytic effect on improving MgH_(2) sorption ***,the onset desorption temperature of MgH_(2)+10 wt%Ni-Nb/rGO composite is reduced to 198℃,much lower than that of undoped MgH_(2)(330℃).In-terestingly,the composite can release 5.0,5.9,and 6.0 wt%H_(2) within 10 min at 245,260,and 275℃,***,the dehydrogenated MgH_(2)+10 wt%Ni-Nb/rGO composite starts to absorb hydrogen even at room temperature with approximate 2.75 wt%H_(2) uptake at 75℃under 3 MPa H_(2) pressure within 30 min and exhibits excellent stability by maintaining 6.0 wt%hydrogen content after 20 cycles at 300℃.Chou’s model suggests that the de/hydrogenation kinetics of Ni-Nb/rGO-modified MgH_(2) switches from surface penetration model to diffusion model at lower ***,the ac-tivation energies(E a)for the de/hydrogenation of MgH_(2)+10 wt%Ni-Nb/rGO are reduced to 57.8 kJ/mol and 33.9 kJ/mol,which are significantly lower than those of undoped MgH_(2).The work demonstrates that the addition of a novel ternary Ni-Nb/rGO catalyst is an effective strategy to not only boost the sorption kinetics of MgH_(2) but also maintain its cycling property.

关键词： Hydrogen storage materials Magnesium hydride Ni-Nb/rGO Kinetic analysis Catalytic mechanism

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Navigating the safe operation of high-voltage cathodes:Challenges and strategies

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Nano Research 2024年第10期17卷 8694-8705页

作者： Yue Sun Changjian Zuo Yi-Chun Lu Electrochemical energy and Interfaces Laboratory Department of Mechanical and Automation EngineeringThe Chinese University of Hong KongHong Kong 999077China

Lithium-ion batteries play a crucial role in storing energy for renewable sources and electric vehicles,yet face challenges related to insufficient energy *** the working-voltage of cathodes is promising to boost the energy density of batteries by increasing both the output voltage and capacity of cathode,which however could compromise life cycle and *** review provides a comprehensive summary of essential factors governing pathways of cathode-induced thermal runaway,including electrolyte decomposition,phase transitions,and crosstalk-induced *** and electrolyte modifications aimed at mitigating parasitic reactions and preventing crosstalk were also *** review concludes with insights into the future application of these strategies,providing a comprehensive perspective on the realization of high-energy and safe batteries.

关键词： battery safety high-voltage cathode lithium-ion battery thermal runaway

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