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The Response of Carbonate System to Watershed Urbanization Process in a Semi-Arid River

Journal of Ocean University of China 2024年第4期23卷 991-1002页

作者： LI Yunxiao DANG Jiajia HUANG Xiao YANG Hong WANG Xiao LI Lina BAI Jie CHEN Xi Department of environmental science College of Resource and EnvironmentShanxi Agricultural UniversityTaigu 030801China Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China Department of Geography and environmental science University of ReadingWhiteknightsReading RG66ABUK Marine Agriculture Research Center Tobacco Research InstituteChinese Academy of Agricultural SciencesQingdao 266101China 5 Key Laboratory of Marine environmental science and Ecology Ministry of EducationCollege of Environmental Science and EngineeringOcean University of ChinaQingdao 266100China

Different from rivers in humid areas,the variability of riverine CO_(2) system in arid areas is heavily impacted by anthropogenic disturbance with the increasing urbanization and water *** this study,the water chemistry and the controls of carbonate system in an urbanized river(the Fenhe River)on the semi-arid Loess Plateau were *** water chemistry of the river water showed that the high dissolved inorganic carbon(DIC)concentration(about 37 mg L^(-1))in the upstream with a karst land type was mainly sourced from carbonate weathering involved by H_(2)CO_(3) and H_(2)SO_(4),resulting in an oversaturated partial pressure of CO_(2)(pCO_(2))(about 800μatm).In comparison,damming resulted in the widespread appearance of non-free flowing river segments,and aquatic photosynthesis dominated the DIC and pCO_(2) spatiality demonstrated by the enriched stable isotope of DIC(δ^(13)CDIC).Especially in the mid-downstream flowing through major cities in warm and low-runoff August,some river segments even acted as an atmospheric CO_(2) *** noteworthy is wastewater input leading to a sudden increase in DIC(>55 mg L^(-1))and pCO_(2)(>4500μatm)in the downstream of Taiyuan City,and in cold November the increased DIC even extended to the outlet of the *** results highlight the effects of aquatic production induced by damming and urban sewage input on riverine CO_(2) system in semi-arid areas,and reducing sewage discharge may mitigate CO_(2) emission from the rivers.

关键词： dissolved inorganic carbon stable carbon isotope carbonate weathering aquatic photosynthesis sewage input the Fenhe River

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CO_(2)methanation boosted by support-size-dependent strong metal-support interaction and B-O-Ti component

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Green Energy & Environment 2024年第2期9卷 321-332页

作者： Shaoyu Yuan Yushan Yang Zhangyi Xiong Peijing Guo Sufang Sun Zejiang Li Jianlong Du Yongjun Gao College of Chemistry and environmental science Hebei UniversityNo.180Wusidong RoadBaoding071002HebeiChina

Strong metal-support interaction(SMSI)has a great impact on the activity and selectivity of heterogeneous catalysts,which was usually adjusted by changing reduction temperature or processing catalyst in different ***,few researches concentrate on modulating SMSI through regulating the structure of the ***,we show how changing the surface environment of the anatase TiO_(2)(B–TiO_(2))can be used to modulate the *** moderate TiOx overlayer makes the Ni metal highly dispersed on the high specific surface area of support,resulting in a substantially enhanced CO_(2)methanation ***,a novel phenomenon was observed that boron dopants promote the for-mation of the B–O–Ti interface site,enhancing the catalytic performance of CO_(2)*** calculations confirm that the B–O–Ti structure facilitates the activation of CO_(2)and further hydrogenation to methane.

关键词： CO_(2)Methanation B-doped TiO_(2) SMSI Size-dependent

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Visible light-driven oxidation of non-native substrate by laccase attached on Ru-based metal-organic frameworks

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Journal of environmental sciences 2024年第3期137卷 741-753页

作者： Wenguang Huang Wentao Zhang Guantongyi Chen Yun Chen Jun Ma Dawei Huang Qinzheng Zhaoc Bingdang Wu State environmental Protection Key Laboratory of environmental Pollution Health Risk Assessment South China Institute of Environmental SciencesMinistry of Ecology and Environment of PRCGuangzhou 510655China Tsinghua Shenzhen International Graduate School Tsinghua UniversityShenzhen 518055China School of environmental science and Engineering Suzhou University of Science and TechnologySuzhou 215002China Key Laboratory of Suzhou Sponge City Technology Suzhou 215002China

Light-induced electron transfer can broaden the substrate range of ***,the efficiency of photo-enzyme coupling is limited by the poor combination of photosensitizer or photocatalyst with ***,we prepared the nano-photocatalyst MIL-125-NH_(2)@Ru(bpy)by in site embedding ruthenium pyridine-diimine complex[Ru(bpy)_(3)^(2+)into metal organic frameworks MIL-125-NH_(2)and associated it with multicopper oxidase(MCO)*** to[Ru(bpy)_(3)]^(2+),the coupling efficiency of MIL-125-NH_(2)@Ru(bpy)_(3)for enzymatic oxygen reduction increased by 35.7%.A series of characterizations confirmed that the amino group of laccase formed chemical bonds with the surface defects or hydrophobic groups of MIL-125-NH_(2)@Ru(bpy)_(3).Consequently,the tight binding accelerated the quenching process and electron transfer between laccase and the immobilized ruthenium pyridine-diimine *** work would open an avenue for the synthesis of MOFs photocatalyst towards photo-enzyme coupling.

关键词： Laccase Light-driven biocatalysis Ruthenium photocatalyst Metal-organic frameworks Enzyme immobilization

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Light-responsive Self-Immolative L-glutamic Acid-based Polyester Nanoparticles for Controlled Drug Release via Passerini Three-Component Polymerization

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Chinese Journal of Polymer science 2024年第5期42卷 570-578,I0005页

作者： Xiao-Fei Sun Xu Zhang Shu-Ping Song Ya-Qun Yao Yan Zhang Cheng-Liang Wang Jing-Jiang Sun Qing-Fu Wang Key Laboratory of Rubber-plastics Ministry of EducationSchool of Polymer Science and EngineeringQingdao University of Science and TechnologyQingdao266042China Qingdao Research Academy of environmental science Qingdao266012China

L-glutamic acid(LA)is a bio-based,non-toxic,environmentally friendly material derived from *** present study reports the application of Passerini three-component polymerization(P-3CP)for the straightforward preparation of LA-based light-responsive polyesters(PLTDs)under mild *** with molar masses up to 8500 g/mol and high yields exceeding 90%are *** chemical structures and light-responsive self-immolative behavior of PLTDs are comprehensively characterized by employing ultraviolet-visible(UV-Vis)spectroscopy,size exclusion chromatography(SEC),nuclear magnetic resonance(NMR)spectroscopy,and liquid chromatography mass spectrometry(LC-MS).Meanwhile,monodisperse PLTD-based doxorubicin-loaded nanoparticles(PLTD-DOX-NP)(size=193 nm,PDI=0.018)are formulated by nanoprecipitation *** light-induced depolymerization,the PLTD-DOX-NP undergoes rapid decomposition,resulting in a burst release of 80%cargo within 13 ***,according to biological toxicity tests,the PLTD-NP possesses adequate biosafety,both before and after ***,the incorporation of P-3CP with biorenewable LA-based monomer adheres to the principles of green chemistry,significantly simplifying the synthetic pathway of light-responsive polymers.

关键词： L-glutamic acid Passerini three-component polymerization Light-responsive Polyester Nanoparticles

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Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation

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Chinese Chemical Letters 2024年第4期35卷 199-203页

作者： Yinyin Xu Yuanyuan Li Jingbo Feng Chen Wang Yan Zhang Yukun Wang Xiuwen Cheng Key Laboratory for environmental Pollution Prediction and Control College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China Key Laboratory of Pollutant Chemistry and environmental Treatment College of Chemistry and Environmental ScienceYili Normal UniversityYining 835000China

A novel N, O modified Mn_(3)O_(4)@porous carbon catalyst(NOC-Mn_(3)O_(4)) was prepared by direct carbonization using the manganese-metal organic framework(Mn-MOF) and covalent organic framework(COF) as precursors to activate peroxymonosulfate(PMS) for the degradation of bisphenol A(BPA) and rhodamine B(Rh B). Benefiting from the N and O co-doping of COF, larger specific surface area, faster electron transfer and Mn cycling, the optimum 1NOC-Mn_(3)O_(4)could significantly improve the degradation performance of BPA and Rh B(92.1% and 96.9% within 30 min) as compared to C-Mn_(3)O_(4)without COF doping. In addition, 1NOC-Mn_(3)O_(4) showed good reusability and strong anti-interference ability. Radical quenching experiments, X-ray photoelectron spectroscopy(XPS), Electron paramagnetic resonance spectrometer(EPR) and electrochemical tests showed that the 1NOC-Mn_(3)O_(4)/PMS system degraded BPA and Rh B by both radical and non-radical pathways. Moreover, the possible degradation pathways of BPA and Rh B were proposed by liquid chromatography-mass spectrometry(LC-MS). Except for that, the toxicity of BPA, Rh B and their intermediates were evaluated. This study opens up a new prospect for the design of COF-doped PMS catalysts.

关键词： Peroxymonosulfate Covalent organic framework Mn-metal organic framework Organic pollutant Degradation

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Recovering rare earths,lithium and fluorine from rare earth molten salt electrolytic slag using sub-molten salt method

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Journal of Rare Earths 2024年第9期42卷 1774-1781,I0005页

作者： Delong Yang Mingming Yu Yusufujiang Mubula Weiquan Yuan Zheyu Huang Bo Lin Guangjun Mei Tingsheng Qiu School of Resources and environmental Engineering Jiangxi University of Science and TechnologyGanzhou341000China Jiangxi Key Laboratory of Mining Engineering Jiangxi University of Science and TechnologyGanzhou341000China School of Resources and environmental Engineering Wuhan University of TechnologyWuhan430070China Gannan Institute of science and Technology Ganzhou341000China

Viewing the problem of high ene rgy consumption in the process of recovering rare earths from rare earth molten salt electrolysis slag,an environmentally friendly and low carbon process by sub-molten salt decomposition was *** thermodynamic analysis of sub-molten salt reaction indicates that the recovery of rare earths from the slag using sub-molten salt medium is thermodynamically *** this process,the rare earth fluoride and lithium in the slag are almost transformed into rare earth hydroxide,sodium fluoride and lithium hydroxide,fluorine and lithium are transferred into the washing solution,and the rare earths in the residues can be leached into solution by acid *** the optimum reaction conditions of reaction temperature 200℃,reaction time 3 h,NaOH initial concentration 80%,NaOH-Slag mass ratio 3:1,the leaching efficiency of rare earths,fluorine and lithium can reach to 99.05%,98.23% and 99.22%.After evaporation,the fluorine and lithium in the washing solution can be obtained in the forms of sodium fluoride and lithium fluoride,the recovery efficiency reach 95.5%and 92.8%,*** RE oxides(99.53%) can be obtained from the leaching solution after precipitation and roasting.

关键词： Rare earth electrolysis slag Sub-molten salt Green extraction Fluorine Lithium Recovery

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Three-dimensional numerical analysis of plant-soil hydraulic interactions on pore water pressure of vegetated slope under different rainfall patterns

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第9期16卷 3696-3706页

作者： Haowen Guo Charles Wang Wai Ng Qi Zhang Department of Civil and environmental Engineering The Hong Kong University of Science and TechnologyHong KongChina

Understanding the pore water pressure distribution in unsaturated soil is crucial in predicting shallow landslides triggered by rainfall,mainly when dealing with different temporal patterns of rainfall ***,the hydrological response of vegetated slopes,especially three-dimensional(3D)slopes covered with shrubs,under different rainfall patterns remains unclear and requires further *** address this issue,this study adopts a novel 3D numerical model for simulating hydraulic interactions between the root system of the shrub and the surrounding *** series of numerical parametric studies are conducted to investigate the influences of slope inclination,rainfall pattern and rainfall *** rainfall patterns(advanced,bimodal,delayed,and uniform)and two rainfall durations(4-h intense and 168-h mild rainfall)are considered to study the hydrological response of the *** computed results show that 17%higher transpiration-induced suction is found for a steeper slope,which remains even after a short,intense rainfall with a 100-year return *** extreme rainfalls with advanced(PA),bimodal(PB)and uniform(PU)rainfall patterns need to be considered for the short rainfall duration(4 h),while the delayed(PD)and uniform(PU)rainfall patterns are highly recommended for long rainfall durations(168 h).The presence of plants can improve slope stability markedly under extreme rainfall with a short duration(4 h).For the long duration(168 h),the benefit of the plant in preserving pore-water pressure(PWP)and slope stability may not be sufficient.

关键词： Root-soil interactions Rainfall patterns Slope stability Three-dimensional(3D)

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The relationship between indoor air quality(IAQ)and perceived air quality(PAQ)-a review and case analysis of Chinese residential environment

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Energy and Built Environment 2024年第2期5卷 230-243页

作者： Jingjing Pei Meinan Qu Luyao Sun Xueyong Wang Yihui Yin Tianjin Key Laboratory of Indoor Air environmental Quality Control School of Environmental Science and EngineeringTianjin UniversityTianjin 300072China

Due to the majority of time people spent indoors,indoor air quality is not only critical to people’s health,comfort,but can also significantly influence occupants perception on indoor *** quality is closely related to many factors including thermal parameters,pollutant concentrations,and ventilation ***,the current building indoor air quality evaluation method is based the objective measurement of indoor parameters,without considering occupants’subjective *** paper is aimed at summarizing a profound review on the PAQ evaluation *** among various PAQ evaluating methods with advantages,similarities and differences were *** of literatures about indoor air quality in Chinese residential buildings field is also summarized,and discussion on the subjective influence of temperature and relative humidity,venti-lation performance,volatile organic compounds(VOCs)concentration,and particulate matters on perceived air quality is carried out.

关键词： Perceived air quality Temperature and relative humidity Volatile organic compound Ventilation Particulate matter

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Direct generation of Zn metal using laser-induced ZnS to eradicate carbon emissions from electrolysis Zn production

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Frontiers of environmental science & Engineering 2024年第1期18卷 83-95页

作者： Ying Chen Ning Duan Linhua Jiang Fuyuan Xu Guangbin Zhu Yao Wang Yong Liu Wen Cheng Yanli Xu State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China School of environmental science and Engineering Tianjin UniversityTianjin 300350China School of Materials science and Engineering Anhui University of Science&TechnologyHuainan 232001China

In response to the goal of net-zero emissions proposed by Intergovernmental Panel on Climate Change, Chinese government has pledged that carbon emissions will peak by 2030, and achieve carbon neutrality by 2060. However, the high carbon energy structure of traditional industries has aggravated environmental problems, such as greenhouse effect and air pollution. The goal of carbon neutrality will be difficult to achieve without the development of disruptive theories and technologies. The electrolytic zinc industry requires high-temperature roasting at ~1000 ℃, generating large amounts of greenhouse gases and SO_(2). High concentrations of sulfuric acid (200 g/L) are subsequently used for electrolysis, and each ton of zinc produced generates 50 kg of anode slime with lead content of up to 16%, as well as 0.35 m3 of wastewater containing zinc and lead. To solve these problems, an optical metallurgy method is proposed in this study. The proposed method uses laser-induced photoreduction to decompose ZnS and reduce metal ions to metal. Results indicate that Zn0 and S8 can be detected on the surface of ZnS at a specific wavelength and laser fluence. The generation mechanism of Zn0 is such that laser induces an electronic transition that breaks ionic bond in ZnS, resulting in its decomposition and photoreduction to Zn0 under an inert argon gas atmosphere. This method does not reduce other metals in the mineral since it does not use high-temperature roasting, providing a new way of producing high-purity metal without greenhouse gas emissions and heavy metal pollution caused by traditional zinc electrolysis.

关键词： Laser metallurgy ZnS Photochemical reduction Zinc

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Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water

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Chinese Chemical Letters 2024年第9期35卷 326-330页

作者： Jinjie Lu Qikai Liu Yuting Zhang Yi Zhou Yanbo Zhou State environmental Protection Key Laboratory of environmental Risk Assessment and Control on Chemical Process East China University of Science and TechnologyShanghai 200237China

Microbial contamination in water has emerged as a critical concern and thus developing biocide materials for controlling microbial contamination is *** all pathogenic bacteria in water is difficult when using traditional water treatment ***,these bacteria can easily reproduce during pipeline *** this work,a facile and effective chitosan derivative biocide denoted as PCC was developed by grafting with quaternary phosphonium salt(QPS).PCC became positively charged with a wide range of p H and demonstrated antibacterial activity up to 95%and 100%against Escherichia coli and Staphylococcus aureus as model pathogens,*** grafting of QPS may disrupt the cell membrane and lead to bacterial inactivation,as demonstrated by the scanning electron microscopy image and the concentration of intracellular substance *** assay results indicate that PCC achieved good biocompatibility with negligible in vitro *** findings introduce a promising approach for bacterial decontamination due to its low cytotoxicity and high biocidal activity.

关键词： Chitosan Quaternary phosphonium salt Antibacterial performance Antibacterial mechanism Morphology change

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