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Journal of Wuhan University of Technology(Materials Science) 2025年第1期 1-12页

作者：李宝让 DAI Jianhuan ZHANG Wei LIU Xiangchen YANG Liu School of Energy Power and Mechanical engineering North China Electric Power University School of Energy and environment Southeast University

We adopted the solution impregnation route with aluminum dihydrogen phosphate solution as liquid medium for effective surface modification on graphite *** mass ratio of graphite to Al（H2PO4）3changed from 0.5:1 to 4:1,and the impregnation time changed from 1 to *** typical composite phase change thermal storage materials doped with the as-treated graphite were fabricated using form-stable *** investigate the oxidation and anti-oxidation behavior of the impregnated graphite at high temperatures,the samples were put into a muffle furnace for a cyclic heat *** on SEM,EDS,DSC techniques,analyses on the impregnated technique suggested an optimized processing conditions of a 3 h impregnation time with the ratio of graphite:Al（H2PO4）3as 1:3 for graphite impregnation *** investigations on high-temperature phase change heat storage materials doped by the treated graphite suggested excellent oxidation resistance and thermal cycling performance.

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Turbulent Agglomeration of Microparticles in a Cylinder Wake Flow Using LES-DEM:Focusing on the Effect of the Reynolds Number

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Journal of Thermal Science 2025年第1期 34-49页

作者： WANG Shuang MU Lin LI Xue XIE Jun DONG Ming School of Energy and Power engineering Dalian University of Technology School of Optical Information and Energy engineering Wuhan Institute of Technology School of Energy and environment Shenyang Aerospace University

Turbulent agglomeration is viewed as a promising technology for enhancing fine particle removal *** better understand particle transport,agglomeration behaviors,and fluid-particle interactions,we numerically explored these phenomena under cylindrical vortex wake influence using a coupled large eddy simulation and discrete element method（LES-DEM） *** validity of the LES approach was verified by comparison with available direct numerical simulation（DNS） *** adopted the Johnson-Kendall-Roberts（JKR） contact model for particle-particle *** particle dispersion and agglomeration characteristics of particles with different diameters（dp=2-20 μm） in the laminar and transition of shear layer（TrSL） flow regimes were *** particles were concentrated at the vortex centers,while larger particles accumulated around the *** agglomeration efficiency exhibited an M-shaped profile spanwise（y-direction）.With increasing Reynolds number,the agglomeration efficiency and turbulence intensity *** particle agglomeration efficiency peaks at a certain Reynolds ***,at higher Reynolds numbers,reducing the residence time of particles in the flow field decreases the agglomeration efficiency.

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Recovery of copper from copper slag using a microbial fuel cell and characterization of its electrogenesis

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International Journal of Minerals,Metallurgy and Materials 2017年第6期24卷 621-626页

作者： Wei-ping Liu Xia-fei Yin School of Chemistry and environment engineering Jiangsu University of Technology School of environment and Civil engineering Jiangnan University

The microbial fuel cell, which can convert the chemical energy of organic matter into electricity via the catalytic action of microorganisms, is a novel environmentally friendly technology for wastewater treatment and energy generation. The electrical energy generated by the microbial fuel cell can be used as an alternative to a traditional external power source required to extract copper via electrolytic treatment. A dual-chamber microbial fuel cell(DMFC) for the treatment of copper slag sulfuric acid leach liquor was constructed. The electrogenesis performance of the DMFC and its ability to extract copper from the copper slag leachate were investigated. The results demonstrated that the maximum voltage was 540 mV when the DMFC achieved steady-state operation. The removal rate of copper ions was greater than 80.0%, and the maximum value was 92.1%. Moreover, X-ray diffraction and scanning electron microscopy were used to characterize the cathodal products. The results showed that the product deposited onto the cathode was copper and that its morphology was similar to that of the electrolytic copper powder. The DMFC can generate electricity and recover copper from copper slag simultaneously.

关键词： microbial fuel cells copper slag recovery copper electrogenesis

Energy Efficiency of a Solar Green Building Using Bio-Sourced Materials for Indoor Temperature and Humidity Optimization

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Energy engineering 2025年第1期122卷 41-62页

作者： SoumiaMounir Youssef Maaloufa Abdelhamid Khabbazi ElinaMohd Husini Nurul SyalaAbdul Latip YakubuAminuDodo Rime ELHarrouni MinaAmazal Asma Souidi Malika Atigui Ahmed Aharoune National School of Architecture Agadir New Complex Ibn ZohrAgadirBP 20732Morocco EMDD CERNE2DUniversity of Mohammed V in RabatEst SaleSaleBP 227Morocco Thermodynamics and Energetics Laboratory Faculty of ScienceIbn Zohr UniversityAgadirBP 8106Morocco Faculty of Built environment University Sains Islam MalaysiaNilaiBP 71800Malaysia Architectural engineering Department Najran UniversityNajranBP 1988Saudi Arabia The Centre of Scientific and engineering Research Najran UniversityNajranBP 1988Saudi Arabia Euro-Mediterranean School of Architecture Design and UrbanismEuro-Mediterranean University of FezFezBP 51Morocco

A clean environment with low carbon emissions is the goal of research on the development of green and sustainable buildings that use bio-sourced materials in conjunction with solar energy to create more sustainable *** is particularly true in Africa,where there aren’t many studies on the *** current study suggests a 90 m^(2) model of a sustainable building in a dry climate that is movable to address the issue of housing in remote areas,ensures comfort in harsh weather conditions,uses solar renewable resources—which are plentiful in Africa—uses biosourced materials,and examines how these materials relate to temperature and humidity control while emitting minimal carbon *** order to solve the topic under consideration,the work is split into two sections:numerical and experimental *** TRNSYS and Revit,the suggested prototype building is examined numerically to examine the impact of orientation,envelope composition made of bio-sourced materials,and carbon *** a hygrothermal investigation,experiments are conducted to evaluate this prototype’s ***,an examination of the photovoltaic system’s production,consumption,and several scenarios used tomaximize battery life is included in the *** the biosourcedmaterial achieves a thermal transmittance of 0.15(W.m^(-2).K^(-1)),the results demonstrate an intriguing finding in terms of *** value satisfies the requirements of passive building,energy autonomy of the dwelling,and injection in-network with an annual value of 15,757 ***,compared to the literature,the heating needs ratio is 6.38(kWh/m^(2).an)and the cooling needs ratio is 49(kWh/m^(2).an),both of which are good *** to international norms,the inside temperature doesn’t go above 26℃,and the humidity level is within a comfortable range.

关键词： Bio-sourced materials energy sustainability green architecture built environment

Education Training Improvement of Built environment and Energy Application engineering in Line with the ABET Criteria

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Journal of Donghua University(English Edition) 2019年第6期36卷 586-593页

作者： YANG Xuebin LIU Lin LIANG Zhen SHEN Henggen College of environmental Science and engineering Donghua UniversityShanghai 201620China College of Urban Construction and Safety engineering Shanghai Institute of TechnologyShanghai 201418China

Built environment and Energy Application engineering(BEEAE),namely Heating,Ventilating,Air Conditioning and Refrigerating(HVAC&R),is one of the international accreditation *** knowledge system of professional theory and professional education in accredited engineering academic programs must meet the requirements of the relevant international engineering *** view of professional engineers and technicians training of BEEAE,the professional training programs and the knowledge system are compared and explored in line with the international certification *** study compares the items and requirements of different international certification criteria,and summarizes the experienced methods of education *** undergraduate education and training programs are then improved in accordance with the requirements from international certification *** BEEAE education training schemes should combine the knowledge system of the national professional guidance standards with the items from international certification criteria.

关键词： international accreditation criteria education training Built environment and Energy Application engineering(BEEAE) assessment and evaluation program change

Degradation analysis of nickel/metal hydride battery and its electrodes materials

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中国有色金属学会会刊：英文版 2004年第3期14卷 446-450页

作者：李丽吴锋杨凯 School of Chemical engineering and environment

The results indicate that during charge and discharge, the expansion of Ni（OH）2 crystal, pulverization of MH alloy particles and falling off from current collector are identified as the main causes for deterioration of Ni/MH batteries. Meanwhile, the contact resistance of inner battery increases due to the deterioration of the negative and positive electrode, and these changes lead to increasing battery body temperature and damaging its electrode and separator. The fibre’s expansion and hole’s diminishment of battery’s separator after degradation will affect the electrochemical performance and cycle life of Ni/MH batteries.

关键词： Ni/MH电池电极材料退化蓄电池分离器

Laser assisted phase transformation of carbon-based transition metal oxide electrode for high-performance supercapacitor application

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Science China Chemistry 2025年

作者： Mingzhen Xiu Jianghong Zhang Yu Lu Xun Cao Kang Huang Siyu Zhu Bowei Zhang Yu Liang Chunwang Zhao Junsheng Wu Yizhong Huang School of Materials Science and engineering Nanyang Technological University Energy Research Institute Interdisciplinary Graduate Programme Nanyang Technological University Institute of Sustainability for Chemicals Energy and Environment Agency for Science Technology and ResearchSingapore Institute of Advanced Materials and Technology University of Science and Technology Beijing School of Materials Science and Technology Shenyang University of Chemical Technology School of Materials Science and Hydrogen Energy Foshan University

Transitional metal oxides have a wide range of applications due to their superior *** enhanced performance of metal oxide relies on their desirable oxidation states,which is challenging to achieve and requires complex *** study demonstrates a facile strategy enabling rapid phase transformation of transition metal *** approach involves synthesis of a tetragonal Mn3O4/carbon cloth composite using the liquid plasma discharge deposition （LPDD） technique,followed by laser irradiation with the presence of ethylene glycol under an N2gas *** resulting face-centered cubic MnO/carbon cloth electrode exhibits an excellent capacitance of 1,125 F g-1at 2 A g-1,with remarkable capacitance retention of 95%after10,000 *** approach can be extended to other transition metals including Co,Cu,Cr,Fe,Ni,and *** simulations reveal the significance of ethylene glycol and the underlying mechanism associated with the phase transformation of transition metal *** present study offers a powerful technique for the phase transformation of transition metal oxide which can guide the development of new electrode materials with enhanced electrochemical properties for high-performance energy storage applications.

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Alternative Strategy for Development of Dielectric Calcium Copper Titanate‑Based Electrolytes for Low‑Temperature Solid Oxide Fuel Cells

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Nano-Micro Letters 2025年第1期17卷 310-332页

作者： Sajid Rauf Muhammad Bilal Hanif Zuhra Tayyab Matej Veis MAKYousaf Shah Naveed Mushtaq Dmitry Medvedev Yibin Tian Chen Xia Martin Motola Bin Zhu College of Mechatronics and Control engineering Shenzhen UniversityShenzhen 518060People’s Republic of China Department of Inorganic Chemistry Faculty of Natural SciencesComenius University BratislavaIlkovicova684215 BratislavaSlovakia Energy Storage Joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing 210096People’s Republic of China Hydrogen Energy Laboratory Ural Federal University620002 EkaterinburgRussia Laboratory of Electrochemical Devices Based on Solid Oxide Proton Electrolytes Institute of High Temperature Electrochemistry620066 EkaterinburgRussia School of Microelectronics Hubei UniversityWuhan 430062People’s Republic of China

The development of low-temperature solid oxide fuel cells(LT-SOFCs)is of significant importance for realizing the widespread application of *** has stimulated a substantial materials research effort in developing high oxide-ion conductivity in the electrolyte layer of *** this context,for the first time,a dielectric material,CaCu_(3)Ti_(4)O_(12)(CCTO)is designed for LT-SOFCs electrolyte application in this *** individual CCTO and its heterostructure materials with a p-type Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ)(NCAL)semiconductor are evaluated as alternative electrolytes in LT-SOFC at 450–550℃.The single cell with the individual CCTO electrolyte exhibits a power output of approximately 263 mW cm^(-2) and an open-circuit voltage(OCV)of 0.95 V at 550℃,while the cell with the CCTO–NCAL heterostructure electrolyte capably delivers an improved power output of approximately 605 mW cm^(-2) along with a higher OCV over 1.0 V,which indicates the introduction of high hole-conducting NCAL into the CCTO could enhance the cell performance rather than inducing any potential short-circuiting *** is found that these promising outcomes are due to the interplay of the dielectric material,its structure,and overall properties that led to improve electrochemical mechanism in CCTO–***,density functional theory calculations provide the detailed information about the electronic and structural properties of the CCTO and NCAL and their heterostructure CCTO–*** study thus provides a new approach for developing new advanced electrolytes for LT-SOFCs.

关键词： LT-SOFCs Dielectric CaCu_(3)Ti_(4)O_(12) Semiconductor Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ) Ionic conductivity Heterostructure electrolyte

Effects of yttrium under lead stress on growth and physiological characteristics of Microcystis aeruginosa

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Journal of Rare Earths 2016年第7期34卷 747-756页

作者：武阳王应军杜金戈王章鸿吴清莲 Department of environmental engineering College of Environment Sichuan Agricultural University Department of environmental engineering School of Energy and Environment Southeast University

Yttrium is a main kind of rare earth elements （REEs） with wide applications in modem industry and farming. Lead has been considered to be one of the most important heavy metal pollutants due to its environmental persistence and tendency. In order to clarify the effects of REEs on cyanobacteria in case of suffering heavy metal pollutants, we investigated the effect of different concentrations of yttrium ion （y3＋） on the common blue-green microalgae Microcystis aeruginosa, grown under conditions of lead ion （Pb2＋） stress. Growth and physiological status were tested involving several important enzyme of antioxidant defense system （superoxide dismutase （SOD）, peroxidase （POD）, catalase （CAT）, malondiadehyde （MDA）, chlorophyll a （Chl-a）, soluble sugar and Microcystin-LR （MC-LR） in cultured experiments. Results indicated that growth ofM. aeruginosa was stimulated when treated less than 0.50 mg/L y3-and 0.20 mg/L is the optimum concentration. With the increasing content of Chl-a and activity of SOD, POD, CAT at the 12th day at relatively low concentration of y3＋ treatment （〈0.20 mg/L）, enhancement of photosynthesis and the improvement of eliminating active oxygen on M. aeruginosa were observed. On the contrast, soluble sugar content on algae reduced as the treatment of initial y3＋ concentration was in the range of 0.00-0.50 mg/L. Besides, there was a significant accumulation in both contents of MDA and MC-LR exposed from 1.00 to 5.00 mg/L y3＋, indicating that the ruin of antioxidant defense system and further aggravation to the existence of algal cell may be due to MC-LR releasing. M. aeruginosa might suffer a more positive physiological impact for exposure of relatively low y3＋ concentration against Pb2＋ stress harm, which provided a far-reaching significance on blue-green algae research.

关键词： yttrium lead MC-LR rare earth elements Microcystis aeruginosa

Application of rare-earth element Y in refining impure copper

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International Journal of Minerals,Metallurgy and Materials 2015年第5期22卷 453-459页

作者： Hai-hong Li Xue-qin Sun Shang-zhou Zhang Qin-yi Zhao Guang-zhen Wang School of environment and Materials engineering Yantai University

The effects of rare-earth element Y in refining impure copper were investigated in this paper. The composition, microstructures, and corrosion resistance properties of impure copper before and after refinement with Y were investigated using direct-reading spectrometry, inductively coupled plasma atomic emission spectrometry, optical microscopy, scanning electron microscopy, and potentiodynamic polariza- tion measurements. The results show that the concentrations of impurities S, As, Sb, Bi, A1, Cd, and Se are remarkably decreased. Adding an appropriate amount of Y refines the microstructure and enhances the corrosion resistance properties of impure copper in HC1 solution via a purification effect. The formation enthalpies of compounds formed between Y and various impurity elements were calculated on the basis of Miedema＇s theory. The thermodynamic mechanisms of the refinement of impure copper by Y were also discussed.

关键词： copper refining yttrium addition impurities removal microstructure corrosion resistance