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Nano Research 2024年第3期17卷 1616-1624页

作者： Hanxiao Xu Zizhuang He Yiruo Wang Xiangru Ren Panbo Liu School of Chemistry and Chemical engineering Northwestern Polytechnical UniversityXi’an 710129China

Owing to the tunable compositions and versatile functionality,the development of eco-friendly metal–phenolic coordination crystals derivatives is highly anticipated for electromagnetic wave *** this study,three kinds of magnetic hollow carbon spheres(HCSs)with macro-meso-microporous characteristics,including Fe/HCS,Co/HCS,and CoNi/HCS,are successfully fabricated via the co-operative hard template and self-assembling process,in which magnetic particles are encapsulated in carbon shell matrix after the pyrolysis of metal–polyphenol coordination crystals and further subsequent template *** the one hand,hierarchical macro-meso-micropores effectively balance the impedance gap between absorbers and air and introduce structural defects or distortion,leading to matched impedance and enhanced dipolar/defect *** the other hand,wrapped magnetic particles provide uncountable hetero-interfaces and induce ferromagnetic resonance,resulting in strengthened interfacial polarization and additional magnetic *** particular,enhanced minimum reflection loss(RL,min)and broadband effective absorption bandwidth(EAB)are achieved with only 10 wt.%filler ***,the RL,min and EAB values are-57.5 dB and 7.2 GHz for Fe/HCS,-50.0 dB and 5.8 GHz for Co/HCS,and-52.1 dB and 6.7 GHz for CoNi/HCS,***,this work provides us a modular-assembly strategy to regulate the hollow cavity of absorbers and simultaneously manipulates the chemical components of absorbers to regulate electromagnetic wave absorption performance.

关键词： hollow engineering hierarchical pores hetero-interfaces synergetic effect electromagnetic wave absorption

Effect of Texture on the Grain-Size-Dependent Functional Properties of NiTi Shape Memory Alloys and Texture Gradient Design:A Phase Field Study

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Acta Mechanica Solida Sinica 2024年第1期37卷 10-32页

作者： Bo Xu Beihai Huang Chong Wang Qingyuan Wang Failure Mechanics and engineering Disaster Prevention Key Laboratory of Sichuan ProvinceSichuan UniversityChengdu 610065China Department of Mechanical Science and engineering College of Architecture and EnvironmentSichuan UniversityChengdu 610065China Key Laboratory of Deep Underground Science and engineering Ministry of EducationSichuan UniversityChengdu 610065China

Texture is inevitably introduced during the manufacturing of most NiTi shape memory alloys(SMAs),and the textured nanocrystalline NiTi has been extensively employed in ***,the effect of texture,and the joint effect of grain size(GS)and texture on the functional properties of NiTi SMAs and the corresponding microscopic mechanisms have not been clearly understood *** this work,based on the phase field method,the effect of texture on the GS-dependent functional properties of NiTi SMAs,including super-elasticity(SE),one-way shape memory effect(OWSME),and stress-assisted two-way shape memory effect(SATWSME),is investigated,and the corresponding microscopic mechanisms are ***,the samples with discrete geometrical gradients and/or texture gradients are designed to achieve graded functional *** simulation results indicate that the dependence of functional properties on texture is due to the effect of crystallographic orientation on martensite transformation and reorientation,which can lead to different inelastic *** the designed samples with texture gradients,the stress–strain responses of sheets with various textures are different,allowing for the coordination of overall deformation of the sample by combining such sheets,with varying inelastic deformation ***,the overall response of the sample differs from that without texture gradient,leading to the achievement of graded functional *** simulation results and new findings in this work contribute to a deeper understanding of the effects of texture,GS,and their interaction on the functional properties of SMAs,and provide valuable reference for the design and development of SMA-based devices with desired functional properties.

关键词： Phase field NiTi shape memory alloy Texture Grain size Functional property Texture gradient

Nickel sulfate solution fluoride separation with hydrous zirconium oxide

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Tungsten 2024年第2期6卷 367-381页

作者： Elbert M.Nigri Ummul K.Sultana André L.A.Santos James W.Vaughan Sonia D.F.Rocha Department of Mining engineering Federal University of Minas GeraisBelo Horizonte 31270-901Brazil School of Chemical engineering University of QueenslandSt Lucia 4072Australia

Fluoride is an impurity in nickel sulfate production,which is required for electric vehicle *** zirconium oxide(HZO)was evaluated for removing fl uoride from nickel sulfate *** fluoride removal occurred at pH value 4 and optimal pH value is 4–5,considering Zr *** availability decreases with pH due to hydrogen fluoride and zirconium fluoride aqueous *** removal is initially rapid,with 50 wt.%removal in 7 min,followed by slow removal up to 68 wt.%after 72 h and follows second order rate *** removal was dominated by an ion exchange mechanism and resulting Zr–F bonds were observed using Fourier-transform infrared *** presence of nickel sulfate decreased loading capacity compared to a salt-free *** maintained adsorption capacity through five cycles of loading and regeneration.

关键词： Hydrous zirconium oxide Nickel sulfate Fluoride Adsorption Anion exchange

Tough Polymeric Hydrogels Based on Amino Acid Derivative Mediated Dynamic Metal coordination Bonds

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Chinese Journal of Polymer Science 2024年第10期42卷 1578-1588,I0014页

作者： Meng Li Meng-Yuan Zhang Wu-Xuan Lei Zhu-Ting Lv Qing-Hua Shang Zheng Zhao Jiang-Tao Li Yi-Long Cheng engineering Research Center of Energy Storage Materials and Devices Ministry of EducationSchool of ChemistryXi’an Jiaotong UniversityXi’an710049China Polymer Materials&engineering Department School of Materials Science&engineering Chang’an UniversityXi’an710064China School of Electrical engineering Xi’an Jiaotong UniversityXi’an710049China Department of Nuclear Medicine the First Affiliated Hospital of ChinaXi’an Jiaotong UniversityXi’an710049China

Abstract The development of physically crosslinked hydrogels with excellent mechanical and sensing properties is of importance for expanding the practical applications of intelligent soft hydrogel ***,after copolymerization of hydroxyl-containing amino acid derivative N-acryloyl serine(ASer)with acrylamide(AM),we introduce Zr4+through an immersion strategy to construct metal ion-toughened non-covalent crosslinked hydrogels(with tensile strength of up to 5.73 MPa).It is found that the synergistic coordination of hydroxyl and carboxyl groups with Zr^(4+)substantially increases the crosslinking density of the hydrogels,thereby imparting markedly superior mechanical properties compared to hydroxyl-free Zr^(4+)-crosslinked hydrogels,such as N-acryloyl alanine(AAla)copolymerized with AM hydrogels(with tensile strength of 2.98 MPa)Through the adjustment of the composition of the copolymer and the density of coordination bonds,the mechanical properties of the hydrogels can be modulated over a wide ***,due to the introduction of metal ions and the dynamic nature of coordination bonds,the hydrogels also exhibit excellent sensing performance and good self-recovery properties,paving the way for the development of flexible electronic substrates with outstanding comprehensive performances.

关键词： Hydrogel Amino acid Metal coordination Mechanical performance Flexible sensor

Lattice-distorted Pt wrinkled nanoparticles for highly effective hydrogen electrocatalysis

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Nano Research 2024年第5期17卷 3819-3826页

作者： Xue Li Xiang Han Zhenrui Yang Shun Wang Yun Yang Juan Wang Jiadong Chen Zhongwei Chen Huile Jin Wenzhou Key Lab of Advanced Energy Storage and Conversion Zhejiang Province Key Lab of Leather EngineeringCollege of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Institute of New Materials and Industry Technology College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Department of Chemical engineering Waterloo Institute for NanotechnologyUniversity of WaterlooWaterlooOntario N2L 3G1Canada

Modulating Pt surfaces through the introduction of lattice distortion emerges as immensely effective strategy that enhances the kinetics of alkaline hydrogen evolution and oxidation *** this study,we fabricated lattice-distorted Pt wrinkled nanoparticles(LD-Pt WNPs)for efficient hydrogen *** LD-Pt WNPs not only outperform the Pt/C benchmark in hydrogen oxidation reaction,achieving an excellent mass-specific current of 968.5 mA·mg_(Pt)^(-1)(9 times that of Pt/C),but also demonstrate outstanding hydrogen evolution reaction activity with a small overpotential of 58.0 *** experiments and density functional theory calculations reveal that lattice defects introduce an abundance of unsaturated coordination atoms while modifying the d-band center of *** dual effect optimizes the binding strength of crucial H and OH intermediates,leading to a significant reduction in the energy barrier of the reaction bottleneck,commonly known as the Volmer *** work unveils a fresh viewpoint on projecting and developing high efficiency electrocatalysts through defect engineering.

关键词： distortion nanoparticle hydrogen evolution reaction defect engineering hydrogen oxidation reaction

Atomically dispersed calcium as solid strong base catalyst with high activity and stability

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Green Energy & Environment 2024年第10期9卷 1619-1626页

作者： Xiang-Bin Shao Zhi-Wei Xing Si-Yu Liu Ke-Xin Miao Shi-Chao Qi Song-Song Peng Xiao-Qin Liu Lin-Bing Sun State Key Laboratory of Materials-Oriented Chemical engineering Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM)College of Chemical EngineeringNanjing Tech University30 South Puzhu Road

Solid strong base catalysts are highly attractive for diverse reactions owing to their advantages of neglectable corrosion,facile separation,and environmental ***,their widespread applications are impeded by basic components aggregation and low *** this work,we fabricate single calcium atoms on graphene （denoted as Ca1/G） by use of a redox strategy for the first time,producing solid strong base catalyst with high activity and *** precursor Ca（NO3）2is first reduced to CaO at 400℃ by the support graphene,forming CaO/G with conventional basic sites,and the subsequent reduction at 850℃ results in the generation of Ca1/G with atomically dispersed *** characterizations reveal that Ca single atoms are anchored on graphene in tetra-coordination （Ca–C2–N2） where N is in situ doped from Ca（NO3）*** atomically dispersed Ca,along with their anchoring on the support,endow Ca1/G with high activity and stability toward the transesterification reaction of ethylene carbonate with *** turnover frequency value reaches 128.0 h-1on Ca1/G,which is much higher than the traditional counterpart CaO/G and various reported solid strong bases (2.9–46.2 h-1).Moreover,the activity of Ca1/G is well maintained during 5 cycles,while 60% of activity is lost for the conventional analogue CaO/G due to the leaching of Ca.

关键词： Solid strong base Single Ca atoms Heterogeneous catalysts Transesterification Reaction

Ni/Co bimetallic organic frameworks nanospheres for highperformance electrochemical energy storage

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Nano Research 2024年第6期17卷 5122-5130页

作者： Jianru Guan Minlu Liu Limin Zhu Jiamei Wang Qing Han Xiaoxia Yang Weibo Hua Lingling Xie Xiaoyu Cao School of Chemistry and Chemical engineering Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou CityHenan University of TechnologyZhengzhou 450001China School of Chemical engineering and Technology Xi’an Jiaotong UniversityXi’an 710049China School of Environmental engineering Henan University of TechnologyZhengzhou 450001China

In addition to their many well-known advantages(e.g.,ultra-high porosity,good pore size distribution,easy functionalization,and structural tolerability),metal-organic frameworks(MOFs)are a new class of advanced functional ***,their backbones are highly susceptible to deformation after exposure to acidic or alkaline *** a result of lithium-ion batteries embedding or detaching directly from MOFs,they irreversibly *** a result,they fail to maintain their electrochemical *** factors have hindered the development of MOFs as direct electrode materials,making the design of MOF materials with controlled morphology and stable dimensions a new *** this study,we adopted a versatile and effective method to synthesize a novel MOF material(NiCo-BP(BP=BTC/phen and BTC=1,3,5-benzenetricarboxylic acid))using the rigid ligands 1,10-phenanthroline and homobenzotrizoic acid,and the emergence of the Ni-O/N and Co-O/N coordination layers was observed by extended X-ray absorption fine structure(EXAFS)tests,indicating that Ni and Co were coordinated with heterocyclic N-given atoms to form a stable p-πconjugated ***,the metal-ion is attached to the carboxylic acid ligand on the other side,making the metal-organic skeleton complete and *** nanosphere structure of NiCo-BP(~400 nm)allows for full exposure and utilisation of the active sites,especially the Ni,Co,and phenanthroline units,and exhibit impressively high specific capacity and cycling *** a high current density of 1.0 A·g^(−1),a high discharge specific capacity of 631.6 mAh·g^(−1)was obtained after 1000 *** co-participation of two organic ligands in the coordination is in accordance with the theory of soft and hard acids and bases,which contributes to the ability of the material to maintain a high capacity in cycling as well as its cyclic stability.

关键词： lithium-ion batteries metal organic frame electrochemical energy storage dual ligand hard-soft-acid-base

Antibacterial and antioxidant bifunctional hydrogel based on hyaluronic acid complex MoS_(2)-dithiothreitol nanozyme for treatment of infected wounds

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Regenerative Biomaterials 2024年第4期3卷 98-110页

作者： Yongping Lu Weiqi Kang Yue Yu Ling Liang Jinrong Li Haiying Lu Ping Shi Mingfang He Yuemin Wang Jianshu Li Xingyu Chen Guangyuan Central Hospital Guangyuan 628000P.R.China State Key Laboratory of Polymer Materials engineering College of Polymer Science and EngineeringSichuan UniversityChengdu 610065P.R.China Institute of Biomedical engineering College of MedicineSouthwest Jiaotong UniversityChengdu 610031P.R.China

Wound repair is a complex physiological process that often leads to bacterial infections,which significantly threaten human ***,developing wound-healing materials that promote healing and prevent bacterial infections is *** this study,the coordination interaction between sulfhydryl groups on dithiothreitol(DTT)and MoS_(2)nanosheets is investigated to synthesize a MoS_(2)-DTT nanozyme with photothermal properties and an improved free-radical scavenging ***-bond-modified hyaluronic acid is used as a monomer and is cross-linked with a PF127-DA *** is prepared in coordination with MoS_(2)-DTT as the functional *** hydrogel exhibits antioxidant and antibacterial properties,attributed to the catalytic activity of catalase-like enzymes and photothermal *** the near-infrared(NIR),it exhibits potent antibacterial effects against gram-positive(Staphylococcus aureus)and gram-negative bacteria(Escherichia coli),achieving bactericidal rates of 99.76%and 99.42%,***,the hydrogel exhibits remarkable reactive oxygen species scavenging and antioxidant capabilities,effectively countering oxidative stress in L929 ***,in an animal model,wounds treated with the PHMoD(2.0)and NIR laser heal the fastest,sealing completely within 10 *** results indicate the unique biocompatibility and bifunctionality of the PHMoD,which make it a promising material for wound-healing applications.

关键词： hydrogel wound repair antibacterial antioxidant nanozyme photothermal therapy

Nitrogen⁃doped 3D graphene⁃carbon nanotube network for efficient lithium storage

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无机化学学报 2024年第10期40卷 1840-1849页

作者： XIE Jie XU Hongnan LIAO Jianfeng CHEN Ruoyu SUN Lin JIN Zhong School of Materials Science and engineering Changzhou UniversityChangzhouJiangsu 213164China Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province School of Chemistry and Chemical EngineeringYancheng Institute of TechnologyYanchengJiangsu 224051China Key Laboratory of Mesoscopic Chemistry Ministry of EducationState Key Laboratory of Coordination ChemistrySchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China

A 3D nitrogen⁃doped graphene/multi⁃walled carbon nanotube(CS⁃GO⁃NCNT)crosslinked network mate⁃rial was successfully synthesized utilizing chitosan and melamine as carbon and nitrogen sources,concomitant with the incorporation of multi⁃wall carbon nanotubes and employing freeze drying *** material amalgamates the merits of 1D/2D hybrid carbon materials,wherein 1D carbon nanotubes confer robustness and expedited elec⁃tron transport pathways,while 2D graphene sheets facilitate rapid ion ***,the introduction of nitrogen heteroatoms serves to furnish additional active sites for lithium *** served as an anode material for lithium⁃ion batteries,the CS⁃GO⁃NCNT electrode delivered a reversible capacity surpassing 500 mAh·g^(-1),mark⁃edly outperforming commercial graphite *** after 300 cycles at a high current density of 1 A·g^(-1),it remained a reversible capacity of up to 268 mAh·g^(-1).

关键词： graphene carbon nanotube hybrid material anode lithium⁃ion battery

A Simplified Method for the Stress Analysis of Underground Transfer Structures Crossing Multiple Subway Tunnels

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Computer Modeling in engineering & Sciences 2024年第6期139卷 2893-2915页

作者： Shen Yan Dajiang Geng Ning Dai Mingjian Long Zhicheng Bai College of Civil engineering Tongji UniversityShanghai200092China China Construction 4th engineering Bureau 6th Corp. Ltd.Shanghai201199China Department of Civil and Architecture engineering Hubei Polytechnic UniversityHuangshi435003China

According to the design specifications,the construction of extended piles involves traversing the tunnel’s upper region and extending to the underlying rock *** address this challenge,a subterranean transfer structure spanning multiple subway tunnels was *** on the function of piles in the transfer structure as springs with axial and bending stiffness,and taking into account the force balance and deformation coordination conditions of beams and plates within the transfer structure,we established a simplified mechanical model that incorporates soil stratification by combining it with the Winkler elastic foundation beam *** resolved established simplifiedmechanicalmodel employed finite difference technology and the Newton-Simpsonmethod,elucidating the mechanical mechanism of the transfer *** research findings suggest that the load carried by the upper structural columns can be transferred to the pile foundation beneath the beams through the transfer structure,subsequently reaching the deep soil layer and ensuring minimal impact on adjacent *** established simplified analysis method can be used for stress analysis of the transfer structure,concurrently considering soil stratification,pile foundation behavior,and plate *** pile length,pile section size,and beam section size within the transfer structure should account for the characteristics of the upper load,ensuring an even distribution of the beam bending moment.

关键词： Crossing tunnels transfer structure force mechanism simplify analysis layered soil mass