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Atmospheric chemistry of 2-nitrobenzaldehyde:Initiated by photo-excitation,OH-oxidation,and small TiO_(2) clusters adsorption catalysis

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Journal of environmental Sciences 2024年第5期139卷 123-137页

作者： Feng-Yang Bai Xiang-Huan Liu Ting-Ting Meng Zhou Yu Yi-Chen Wang Shuang Ni Zhen Zhao institute of Catalysis for energy and environment College of Chemistry and Chemical EngineeringShenyang Normal UniversityShenyang 110034China

The fate of 2-nitrobenzaldehyde(2-NBA)is of interest in atmospheric chemistry as it is a semi-volatile organic compound with high *** study presents a quantum chemical study of the gas-phase reactions of 2-NBA photo-excitation and OH-oxidation in the absence and presence of small TiO_(2) *** further understand the unknown photolysis mechanism,the photo-reaction pathways of ground singlet state and the lying excited triplet state of 2-NBA were investigated including the initial and subsequent reactions of proton transfer,direct CO,NO_(2),and HCO elimination routes in the presence of O_(2) and ***,the OH-mediated degradation of 2-NBA proceeded via five H-extraction and six OH-addition channels by indirect mechanism,which follows a succession of reaction steps initiated by the formation of weakly stable intermediate *** H-extraction from the-CHO group was the dominant pathway with a negative activation energy of-1.22 kcal/*** calculated rate coefficients at 200–600 K were close to the experimental data in literature within 308-352 K,and the kinetic negative temperature independence was found in both experimental literature and computational ***,2-NBA was favored to be captured onto small TiO_(2) clusters via six adsorption configurations formed via various combination of three types of bonds of Ti…O,Ti…C,and O…H between the molecularly adsorbed 2-NBA and TiO_(2) *** indicted that the chemisorptions of aldehyde oxygen have largest *** results suggested adsorption conformations have a respectable impact on the catalysis *** study is significant for understanding the atmospheric chemistry of 2-nitrobenzaldehyde.

关键词： 2-nitrobenzaldehyde OH radical oxidation Rate coefficient Photolysis mechanism Adsorption catalysis

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Microwave-assisted pyrolysis of plastics for aviation oil production:energy and economic analyses

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Frontiers of Chemical Science and engineering 2024年第7期18卷 141-153页

作者： Sichen Fan Yifan Liu Yaning Zhang Wenke Zhao Chunbao Xu School of energy Science and engineering Harbin Institute of TechnologyHarbin 150001China School of energy and environment City University of Hong KongHong Kong SARChina

Microwave-assisted pyrolysis is an effective method for recycling plastic wastes into oils that can be used for aviation fuels. In this study, energy and economic analyses of aviation oil production from microwave-assisted pyrolysis of polystyrene were performed. The total energy efficiency, recovered energy efficiency, unitary cost, unitary energy economic cost, relative cost difference, and energy economic factor were detailed. And the effects of microwave power, pyrolysis temperature, microwave absorbent loading, and microwave absorbent type on these parameters were covered. It was found that pyrolysis temperature has the most significant effect on the unitary cost and unitary energy economic cost of aviation oil, and-microwave absorbent type has a significant influence on energy economic factor during the whole microwave-assisted pyrolysis process. The optimum reaction conditions at the tonnage system for pyrolysis of 1 t polystyrene were microwave power of 650 W, pyrolysis temperature of 460 °C, and silicon carbide (microwave absorbent) at a loading of 2 t (twice than feedstock loading). At these optimal conditions, the total energy efficiency, recovered energy efficiency, unitary cost, unitary energy economic cost, relative cost difference, and energy economic factor were 62.78%, 96.51%, 3.21 × 10^(4) yuan·t^(-1), 779 yuan·GJ^(-1), 1.49, and 71.02%, respectively.

关键词： energy analysis economic analysis microwave-assisted pyrolysis polystyrene aviation oil

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Hard carbon for sodium storage:Mechanism and performance optimization

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Nano Research 2024年第7期17卷 6038-6057页

作者： Yongxin Wang Meng Li Yu Zhang Naiqing Zhang State Key Laboratory of Urban Water Resource and environment School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001China School of energy Science and engineering Harbin Institute of TechnologyHarbin 150001China

Due to the shortage of lithium resource reserves and the pressure of rising prices,sodium-ion batteries have regained the attention of the public,and shown great potential for application in the fields of grid energy storage and low-speed vehicles to achieve the purpose of complementing lithium-ion batteries,so it is imperative to promote the commercial application of sodiumion *** sodium-ion battery anode materials,hard carbon is the material most likely to be used ***,there is still much work to be done before its *** review provides a comprehensive overview of the current research status from the following three ***,the microstructure and sodium storage active sites of hard carbon are ***,the mechanism of sodium storage in hard carbon is investigated,which can be broadly categorized into four model,“insertion–filling”,“adsorption–insertion”,“adsorption–filling”,and“multistage”.Finally,from the perspective of improving the electrochemical performance of hard carbon,the performance improvement strategies proposed in recent years are *** with the performance of hard carbon commercial products of some enterprises,the future development goal of hard carbon is prospected,hoping that all sectors of society can work hard for this common goal.

关键词： sodium-ion battery hard carbon mechanism performance optimization

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Regulating solid electrolyte interphase film on fluorinedoped hard carbon anode for sodium-ion battery

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Carbon energy 2024年第6期6卷 200-215页

作者： Cuiyun Yang Wentao Zhong Yuqiao Liu Qiang Deng Qian Cheng Xiaozhao Liu Chenghao Yang Guangzhou Key Laboratory for Surface Chemistry of energy Materials New Energy Research InstituteSchool of Environment and EnergySouth China University of TechnologyGuangzhouChina

For the performance optimization strategies of hard carbon,heteroatom doping is an effective way to enhance the intrinsic transfer properties of sodium ions and electrons for accelerating the reaction ***,the previous work focuses mainly on the intrinsic physicochemical property changes of the material,but little attention has been paid to the resulting interfacial regulation of the electrode surface,namely the formation of solid electrolyte interphase(SEI)*** this work,element F,which has the highest electronegativity,was chosen as the doping source to,more effectively,tune the electronic structure of the hard *** effect of F-doping on the physicochemical properties of hard carbon was not only systematically analyzed but also investigated with spectroscopy,optics,and in situ characterization techniques to further verify that appropriate F-doping plays a positive role in constructing a homogenous and inorganic-rich SEI *** experimentally demonstrated link between the electronic structure of the electrode and the SEI film properties can reframe the doping optimization strategy as well as provide a new idea for the design of electrode materials with low reduction kinetics to the *** a result,the optimized sample with the appropriate F-doping content exhibits the best electrochemical performance with high capacity(434.53 mA h g^(-1)at 20mA g^(-1))and excellent rate capability(141 mAh g^(-1)at 400 mA g^(-1)).

关键词： F-doping hard carbon reduction kinetics sodium-ion batteries solid electrolyte interphase film

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Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination:A mini review

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Chinese Chemical Letters 2024年第5期35卷 77-84页

作者： Xiao-Hong Yi Chong-Chen Wang Beijing Key Laboratory of Functional Materials for Building Structure and environment Remediation School of Environment and Energy EngineeringBeijing University of Civil Engineering and ArchitectureBeijing 100044China

Water pollution caused by global population growth,urban expansion and industrialization development is one of the urgent issues that need to be addressed in the 21st *** to now,it was challenging for metal-organic frameworks(MOFs)to be used in the actual water treatment due to that the powder MOFs suffered from difficult reuse,poor water stability and easy *** is an effective strategy to immobilize MOFs powder onto porous sponge foam carriers for accomplishing large flux,facile recycling,easy processing water treatment *** this review article,the fabrication approaches and applications of different MOFs/sponge composites were highlighted,in which the fluorescence detection of pollutants,adsorption and separation of pollutants,catalytic reduction and oxidation of pollutants were ***,the future challenges and opportunities of MOF/sponge for water treatment are proposed,aiming to provide in-depth guidance for the future design and manufacture of the immobilized MOFs onto sponge foams.

关键词： Metal-organic frameworks Sponge foam Water decontamination Adsorption Catalysis

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Experimental Investigation of the Operating Characteristics of a Pulsating Heat Pipe with Ultra-Pure Water and Micro Encapsulated Phase Change Material Suspension

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Journal of Thermal Science 2024年第2期33卷 457-468页

作者： SHI Weixiu SU Xiaoyang CHEN Hongdi PAN Lisheng Beijing engineering Research Center of Sustainable energy and Buildings Beijing University of Civil Engineering and ArchitectureBeijing100044China School of environment and energy engineering Beijing University of Civil Engineering and ArchitectureBeijing100044China State Key Laboratory of High Temperature Gas Dynamics Institute of MechanicsChinese Academy of SciencesBeijing100190China

The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated phase change material(MEPCM) suspension,a heat transfer performance experimental facility of the PHP was *** heat transfer characteristic with MEPCM suspension of different mass concentrations(0.5% and 1.0%) and ultra-pure water were compared *** was found that when the PHP uses MEPCM suspension as its working fluid,operating stability is impoverished under lower heating power and the operating stability is better under higher heating *** the inclination angle of 90°,the temperature at heating side decreases compared to ultra-pure water and the temperature at heating side decreases with the raising of MEPCM suspension mass *** heat transfer characteristic of the PHP is positively correlated with the inclination angle and the 90° is *** unfavorable effect of the inclination angle decreases with heating power *** the inclination angle is 90°,the PHP with MEPCM suspension at 1.0% of mass concentration has the lowest thermal transfer resistance and followed by ultra-pure water and MEPCM suspension at 0.5% of mass concentration has the highest thermal transfer *** the inclination angles are 60° and30°,the effect of gravity on the flow direction is reduced to 86.6% and 50% of that on the inclination angle of 90°,respectively,and the promoting effect of gravity on the working fluid is further weakened as the inclination angle further *** to the high viscosity of MEPCM suspension,the PHP with ultra-pure water has the lowest heat transfer *** the inclination angles is 60°,the thermal resistance with MEPCM suspension at0.5% of the mass concentration is lower than that at 1.0% at the heating power below 230 *** thermal resistance of MEPCM suspension tends to be simila

关键词： pulsating heat pipe(PHP) micro encapsulated phase change material(MEPCM) heat transfer characteristic inclination angle

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A fully distributed robust optimal control approach for air-conditioning systems considering uncertainties of communication link in IoT-enabled building automation systems

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energy and Built environment 2024年第3期5卷 446-454页

作者： Wenzhuo Li Rui Tang Shengwei Wang institute for environmental Design and engineering The BartlettUniversity College LondonUK Department of Building environment and energy engineering The Hong Kong Polytechnic UniversityKowloonHong Kong Research institute for Smart energy The Hong Kong Polytechnic UniversityKowloonHong Kong

Internet of Things(IoT)technologies are increasingly implemented in buildings as the cost-effective smart sens-ing infrastructure of building automation systems(BASs).They are also dispersed computing resources for novel distributed optimal control ***,wireless communication networks are critical to fulfill these tasks with the performance influenced by inherent uncertainties in networks,e.g.,unpredictable occurrence of link *** and hierarchical distributed approaches are vulnerable against link failure,while the robustness of fully distributed approaches depends on the algorithms *** study therefore proposes a fully distributed robust optimal control approach for air-conditioning systems considering uncertainties of com-munication link in IoT-enabled *** distributed algorithm is adopted that agents know their out-neighbors *** directly coordinate with the connected neighbors for global *** are conducted to test and validate the proposed approach by comparing with existing approaches,i.e.,the centralized,the hierarchical distributed and the fully distributed *** show that different approaches are vulnerable against to uncertainties of communication link to different *** proposed approach always guarantees the optimal control performance under normal conditions and conditions with link failures,verifying its high *** also has low computation complexity and high optimization efficiency,thus applicable on IoT-enabled BASs.

关键词： Multi-agent system Edge computing Air-conditioning system Internet of Things(IoT) Communication link failure

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Unique electromagnetic wave absorber for three-dimensional framework engineering with copious heterostructures

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Journal of Materials Science & Technology 2024年第3期170卷 129-139页

作者： Liyuan Yu Qianqian Zhu Zhiqiang Guo Yuhang Cheng Zirui Jia Guanglei Wu institute of Materials for energy and environment State Key Laboratory of Bio-fibers and Eco-textilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China College of Chemistry and Chemical engineering Qingdao UniversityQingdao 266071China

In order to obtain high-performance electromagnetic wave absorbers,the adjustment of structure and components is *** on the above requirements,this system forms a three-dimensional frame structure consisting of MXene and transition metal oxides(TMOs)through efficient electrostatic *** three-dimensional network structure has rich heterojunction structures,which can cause a large amount of interface polarization and conduction losses in incident electromagnetic *** structures cause multiple reflections and scattering of electromagnetic waves,which is also an important reason for further increasing electromagnetic wave *** the doping ratio is 1:1,the system has the best impedance matching,the maximum effective absorption bandwidth(EAB max)can reach 5.12 GHz at 1.7 mm,and the minimum reflection loss(RL_(min))is-50.30 dB at 1.8 *** provides a reference for the subsequent formation of 2D-MXene materials into 3D materials.

关键词： MXene Three-dimensional frame Heterojunction structure Conduction loss Electromagnetic wave absorption

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Experimental Investigation on Solution Regeneration Performance and Coefficients in Full-Open System for Heat and Water Recovery of Flue Gas

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Journal of Thermal Science 2024年第3期33卷 1094-1108页

作者： WEI Hongyang HUANG Shifang MA Yuxin CHEN Bo SUN Li ZHANG Xiaosong School of energy and environment Southeast UniversityNanjing210096China MOE engineering Research Center for Building energy Equipment&environment Southeast UniversityNanjing210096China Jiangsu Frontier Electric Technology Co. LtdNanjing211106China

The recovery of heat and water from low-grade flue gas is of considerable importance for energy conservation and environmental *** the full-open absorption heat pump shows promise as a means of achieving heat and water recovery,the lack of research on heat and mass transfer performance of open-type solution evaporation regeneration represents a significant impediment to its design and *** paper experimentally investigates the regeneration performance of an open-type spaying tower equipped with ceramic structured *** different regeneration modes are proposed,namely ambient air receiver mode and flue gas receiver mode,to utilize air or low-grade flue gas as a driving *** impact of different input parameters on the regeneration characteristics,including heat transfer capacity,water removal rate,thermal efficiency,and humidity effectiveness,are *** findings indicate that the enhancement of regeneration can be achieved through the increase of solution flow rate,solution temperature,and flue gas flow rate in both regeneration ***,high solution concentration and flue gas humidity ratio can weaken water removal rates and reduce thermal *** the regeneration of CaCl_(2)-H_(2)O with a concentration of55%,flue gas around 200℃with a humidity ratio below 44 g/kg can successfully drive the solution regeneration *** the solution concentration or flue gas humidity ratio continues to rise,additional energy is necessary for ***,the coupled heat and mass transfer coefficients are fitted,which can contribute to the design and optimization of the open-type regenerator.

关键词： heat and water recovery solution regeneration flue gas regeneration performance coefficient

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Study on the fast elimination of smoke particle based on electro-acoustic coupling agglomeration technology

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Particuology 2024年第5期88卷 1-10页

作者： Jie Feng Mingfeng Lu Kaige Wang Kun Luo Mingzhou Yu Guangxue Zhang Jiangrong Xu Shuping Pan Hailin Gu The institute for energy engineering China Jiliang UniversityHangzhou310018China State Key Laboratory of Clean energy Utilization Zhejiang UniversityHangzhou310027China Qingshanhu energy Research Center Zhejiang UniversityHangzhou310017China Zhejiang Ecological environment Monitoring Center Hangzhou310012China

Fire smoke,which consists large amounts of fine particles,is considered as the fatal factor in *** this study,a fast smoke particle elimination method based on electro-acoustic coupling agglomeration technology is ***,the experimental results show that the electro-acoustic coupling agglomeration has higher smoke elimination efficiency compared to *** smoke transmission is much less than 80%after 30s of single acoustic or electric field action,while the coupled field reaches 90%.Then,the effects of acoustic frequency,sound pressure level and voltage on the smoke elimination characteristics are *** is found that the optimal acoustic frequency is *** as the sound pressure level and voltage increase,the elimination efficiency first increases and then tends to stabilize,the critical values of the sound pressure level and voltage are 135 dB and *** indicates that there is an optimal combination of the three ***,through the theoretical analysis of particle movement and the micro-morphology of agglomerates,the particle agglomeration mechanism under the electro-acoustic coupling is *** study provides a new idea for the fast elimination of fire smoke particle.

关键词： Smoke particle Agglomeration Electro-acoustic coupling Smoke elimination

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