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Dual-Ion Co-Regulation System Enabling High-Performance Electrochemical Artificial Yarn Muscles with Energy-Free Catch States

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Nano-Micro Letters 2023年第10期15卷 15-27页

作者： Ming Ren Lizhong Dong Xiaobo Wang Yuxin Li Yueran Zhao Bo Cui Guang Yang Wei Li Xiaojie Yuan Tao Zhou Panpan Xu Xiaona Wang Jiangtao Di Qingwen Li key laboratory of Multifunctional nanomaterials and Smart Systems Advanced Materials Division Suzhou Institute of Nano-Tech and Nano‑BionicsChinese Academy of SciencesSuzhou 215123People’s Republic of China School of Nano‑Technology and Nano‑Bionics University of Science and Technology of ChinaHefei 230026People’s Republic of China division of nanomaterials and jiangxi key lab of carbonene materials Jiangxi Institute of NanotechnologyNanchang 330200People’s Republic of China

Artificial yarn muscles show great potential in applications requiring low-energy consumption while maintaining high performance. However, conventional designs have been limited by weak ion-yarn muscle interactions and inefficient “rocking-chair” ion migration. To address these limitations, we present an electrochemical artificial yarn muscle design driven by a dual-ion co-regulation system. By utilizing two reaction channels, this system shortens ion migration pathways, leading to faster and more efficient actuation. During the charging/discharging process, PF_6~- ions react with carbon nanotube yarn, while Li~+ ions react with an Al foil. The intercalation reaction between PF_6~- and collapsed carbon nanotubes allows the yarn muscle to achieve an energy-free high-tension catch state. The dual-ion coordinated yarn muscles exhibit superior contractile stroke, maximum contractile rate, and maximum power densities, exceeding those of “rocking-chair” type ion migration yarn muscles. The dual-ion co-regulation system enhances the ion migration rate during actuation, resulting in improved performance. Moreover, the yarn muscles can withstand high levels of isometric stress, displaying a stress of 61 times that of skeletal muscles and 8 times that of “rocking-chair” type yarn muscles at higher frequencies. This technology holds significant potential for various applications, including prosthetics and robotics.

关键词： Artificial muscles Carbon nanotube yarns Electrochemical actuators Catch state Dual-ion co-regulation

Fast Zn^(2+)mobility enabled by sucrose modified Zn^(2+)solvation structure for dendrite-free aqueous zinc battery

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Nano Research 2023年第3期16卷 3839-3846页

作者： Yufang Cao Xiaohui Tang Linge Li Haifeng Tu Yuzhen Hu Yingying Yu Shuang Cheng Hongzhen Lin Liwen Zhang Jiangtao Di Yongyi Zhang Meinan Liu School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026China key laboratory of Multifunctional nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China division of nanomaterials and jiangxi key lab of carbonene materials Jiangxi Institute of NanotechnologyNanchang 330200China

Aqueous zinc battery has been regarded as one of the most promising energy storage systems due to its low cost and environmental benignity.However,the safety concern on Zn anodes caused by uncontrolled Zn dendrite growth in aqueous electrolyte hinders their application.Herein,sucrose with multi-hydroxyl groups has been introduced into aqueous electrolyte to modify Zn^(2+)solvation environment and create a protection layer on Zn anode,thus effectively retarding the growth of zinc dendrites.Atomistic simulations and experiments confirm that sucrose molecules can enter into the solvation sheath of Zn^(2+),and the as-formed unique solvation structure enhances the mobility of Zn^(2+).Such fast Zn^(2+)kinetics in sucrose-modified electrolyte can successfully suppress the dendrite growth.With this sucrose-modified aqueous electrolyte,Zn/Zn symmetric cells present more stable cycle performance than those using pure aqueous electrolyte;Zn/C cells also deliver an impressive higher energy density of 129.7 Wh·kg^(−1)and improved stability,suggesting a great potential application of sucrose-modified electrolytes for future Zn batteries.

关键词： solvation structure Zn^(2+)mobility dendrite suppression sucrose

High‑Temperature‑Tolerant Artificial Muscles Using Poly(p‑phenylene benzobisoxazole)Composite Yarns

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Advanced Fiber materials 2022年第5期4卷 1256-1266页

作者： Jianfeng He Ming Ren Lizhong Dong Yulian Wang Xulin Wei Bo Cui Yulong Wu Yueran Zhao Jiangtao Di Qingwen Li School of Nano‑Technology and Nano‑Bionics University of Science and Technology of China230026 HefeiChina key laboratory of Multifunctional nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano‑Tech and Nano‑BionicsChinese Academy of Sciences215123 SuzhouChina division of nanomaterials and jiangxi key lab of carbonene materials Jiangxi Institute of Nanotechnology330200 NanchangChina

Today the developed yarn muscles or actuators still cannot satisfy the requirements of working in high-temperature environ-ments.Thermal resistivity is highly needed in aerospace and industrial protection applications.Herein,an artificial muscle with high-temperature tolerance is prepared using carbon nanotube(CNT)wrapped poly(p-phenylene benzobisoxazole)(PBO)composite yarns.A thermal twisting method was utilized to reorientate the stiff PBO molecular chains into a uniform and twist-stable coiled structure.The CNT/PBO composite yarn muscle generates reversible contractile strokes up to 18.9%under 5.4 MPa tension and outputs 1.3 kJ kg^(-1) energy density.In contrast to previous actuators,which are normally oper-ated at room temperatures,the CNT/PBO composite yarn muscles can work at ambient temperatures up to 300℃ with high contractile stroke and long-term stability.A bionic inchworm robot,a deployable structure,and smart textiles driven by the high-temperature-tolerant yarn muscles were demonstrated,showing the promise as a soft actuator towards high-temperature environment applications.

关键词： Artificial muscles Poly(p-phenylene benzobisoxazole) Carbon nanotube Thermal twisting High-temperature tolerance

Carbon nanotube fibers with excellent mechanical and electrical properties by structural realigning and densification

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Nano Research 2023年第11期16卷 12762-12771页

作者： Kunjie Wu Bin Wang Yutao Niu Wenjing Wang Cao Wu Tao Zhou Li Chen Xianghe Zhan Ziyao Wan Shan Wang Zhengpeng Yang Yichi Zhang Liwen Zhang Yongyi Zhang Zhenzhong Yong Muqiang Jian Qingwen Li key laboratory of Multifunctional nanomaterials and Smart Systems Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China division of nanomaterials and jiangxi key lab of carbonene materials Jiangxi Institute of NanotechnologyNanchang 330200China School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026China Henan key laboratory of materials on Deep-Earth Engineering School of Materials Science and EngineeringHenan Polytechnic UniversityJiaozuo 454003China Beijing Graphene Institute(BGI) Beijing 100095China

Floating catalysis chemical vapor deposition(FCCVD)direct spinning process is an attractive method for fabrication of carbon nanotube fibers(CNTFs).However,the intrinsic structural defects,such as entanglement of the constituent carbon nanotubes(CNTs)and inter-tube gaps within the FCCVD CNTFs,hinder the enhancement of mechanical/electrical properties and the realization of practical applications of CNTFs.Therefore,achieving a comprehensive reassembly of CNTFs with both high alignment and dense packing is particularly crucial.Herein,an efficient reinforcing strategy for FCCVD CNTFs was developed,involving chlorosulfonic acid-assisted wet stretching for CNT realigning and mechanical rolling for densification.To reveal the intrinsic relationship between the microstructure and the mechanical/electrical properties of CNTFs,the microstructure evolution of the CNTFs was characterized by cross-sectional scanning electron microscopy(SEM),wide angle X-ray scattering(WAXS),polarized Raman spectroscopy and Brunauer–Emmett–Teller(BET)analysis.The results demonstrate that this strategy can improve the CNT alignment and eliminate the inter-tube voids in the CNTFs,which will lead to the decrease of mean distance between CNTs and increase of inter-tube contact area,resulting in the enhanced inter-tube van der Waals interactions.These microstructural evolutions are beneficial to the load transfer and electron transport between CNTs,and are the main cause of the significant enhancement of mechanical and electrical properties of the CNTFs.Specifically,the tensile strength,elastic modulus and electrical conductivity of the high-performance CNTFs are 7.67 GPa,230 GPa and 4.36×10^(6)S/m,respectively.It paves the way for further applications of CNTFs in high-end functional composites.

关键词： carbon nanotube fibers mechanical property electrical property alignment packing density

The effect of NiO-Ni_(3)N interfaces in in-situ formed heterostructure ultrafine nanoparticles on enhanced polysulfide regulation in lithium-sulfur batteries

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Journal of Energy Chemistry 2022年第5期31卷 762-770页

作者： Jun Pu Zhenghua Wang Pan Xue Kaiping Zhu Jiachen Li Yagang Yao key laboratory of Functional Molecular Solids Ministry of EducationAnhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage MaterialsCollege of Chemistry and Materials ScienceAnhui Normal UniversityWuhu 241002AnhuiChina National laboratory of Solid State Microstructures College of Engineering and Applied SciencesJiangsu Key Laboratory of Artificial Functional MaterialsCollaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093JiangsuChina School of Chemical Engineering Northwest UniversityXi’an 710069ShaanxiChina division of nanomaterials and jiangxi key lab of carbonene materials Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesNanchang 330200JiangxiChina

Inhibiting the “shuttle effect” of soluble polysulfides and improving reaction kinetics are the key factors necessary for further exploration of high-performance Li-S batteries. Herein, an effective interface engineering strategy is reported, wherein nitriding of an Ni-based precursor is controlled to enhance Li-S cell regulation. The resulting in-situ formed NiO-Ni_(3)N heterostructure interface not only has a stronger polysulfide adsorption effect than that of monomeric NiO or Ni_(3)N but also has a faster Li ion diffusion ability than a simple physical mixture. More importantly, this approach couples the respective advantages of NiO and Ni_(3)N to reduce polarization and facilitate electron transfer during polysulfide reactions and synergistically catalyze polysulfide conversion. In addition, ultrafine nanoparticles are thought to effectively improve the use of additive materials. In summary, Li-S batteries based on this NiO-Ni_(3)N heterostructure have the features of long cycle stability, rapid charging-discharging, and good performance under high sulfur loading.

关键词： NiO-Ni_(3)N heterostructure Interface effect Ultrafine nanoparticles Li-S batteries Polysulfides

Hollow Gradient-Structured Iron-Anchored Carbon Nanospheres for Enhanced Electromagnetic Wave Absorption

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Nano-Micro Letters 2023年第1期15卷 144-160页

作者： Cao Wu Jing Wang Xiaohang Zhang Lixing Kang Xun Cao Yongyi Zhang Yutao Niu Yingying Yu Huili Fu Zongjie Shen Kunjie Wu Zhenzhong Yong Jingyun Zou Bin Wang Zhou Chen Zhengpeng Yang Qingwen Li key laboratory of Multifunctional nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123JiangsuPeople’s Republic of China School of Science Nanchang Institute of TechnologyNanchang 330099JiangxiPeople’s Republic of China division of nanomaterials and jiangxi key lab of carbonene materials Jiangxi Institute of NanotechnologyNanchang 330200JiangxiPeople’s Republic of China School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026AnhuiPeople’s Republic of China School of materials Science and Engineering Nanyang Technological University50 Nanyang AvenueSingapore 639798Singapore Jiangsu key laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application School of Physical Science and TechnologySuzhou University of Science and TechnologySuzhou 215009People’s Republic of China School of Mechanical and Power Engineering Nanjing Tech UniversityNanjing 211800People’s Republic of China Henan key laboratory of materials On Deep-Earth Engineering School of Materials Science and EngineeringHenan Polytechnic UniversityJiaozuo 454003People’s Republic of China College of Safety Science and Engineering Xi’an University of Science and TechnologyXi’an 710054People’s Republic of China

In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which can effectively adjust the thermodynamic and kinetic reactions of iron ions during the solvothermal process.As a result,Fe nanoparticles can be gradually decreased from the inner side to the surface across the hollow carbon shell.The results reveal that it offers an outstanding reflection loss value in combination with broadband wave absorption and flexible adjustment ability,which is superior to other relative graded distribution structures and satisfied with the requirements of lightweight equipment.In addition,this work elucidates the intrinsic microwave regulation mechanism of the multiscale hybrid electromagnetic wave absorber.The excellent impedance matching and moderate dielectric parameters are exhibited to be the dominative factors for the promotion of microwave absorption performance of the optimized materials.This strategy to prepare gradient-distributed microwave absorbing materials initiates a new way for designing and fabricating wave absorber with excellent impedance matching property in practical applications.

关键词： Gradient structures Carbon nanospheres Electromagnetic wave absorption Impedance matching

ZnS nanolayer coated hollow carbon spheres with enhanced rate and cycling performance for Li-S batteries

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Science China(Technological Sciences) 2022年第2期65卷 272-281页

作者： MENG FanCheng XU Bin LONG Tao CHENG Sheng LI Yong ZHANG YongYi LIU JieHua School of materials Science and Engineering Engineering Research Centre of High-Performance Copper Alloy Materials and ProcessingMinistry of EducationHefei University of TechnologyHefei 230009China division of nanomaterials and jiangxi key lab of carbonene materials Suzhou Institute of Nano-Tech and Nano-BionicsNanchangChinese Academy of SciencesNanchang 330200China Instrumental Analysis Centre Hefei University of TechnologyHefei 230009China School of Instrument Science and Opto-electronics Engineering Hefei University of TechnologyHefei 230009China key laboratory of Multifunctional nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026China

Conductive carbon structure has been considered as a promising sulfur-hosting material as the cathode of lithium-sulfur batteries.However, the issue of polysulfide shuttling requires an additional component to help restrict and convert sulfur substances.Herein, in this work, hollow and porous carbon nanospheres(HCS) are synthesized by a template method and a high-temperature carbonization treatment. A thin layer of ZnS coating is then deposited on the HCS-based sulfur(ZnS@HCS/S) cathode with controlled thickness, and the overall electrochemical properties are systematically evaluated. Results show that with 30 nm-thick ZnS coating, the cathode reveals an improved capacity of 1411 m A h g^(-1), and higher capacities from 0.2 to 3 C rate compared with bare HCS/S cathode. Moreover, the ZnS coating also enhances the cycling stability of ZnS@HCS/S cathode over 280 cycles at 0.5 C, with only 0.2% capacity decay per cycle. This work demonstrates potential applications for high-performance lithiumsulfur batteries.

关键词： lithium-sulfur battery ZnS nanolayer hollow carbon sphere rate performance cycling stability

FeCo alloy catalysts promoting polysulfide conversion for advanced lithium-sulfur batteries

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Journal of Energy Chemistry 2020年第10期29卷 339-347页

作者： Hongyi Li Linfeng Fei Rong Zhang Shenglan Yu Yongyi Zhang Longlong Shu Yong Li Yu Wang School of materials Science and Engineering Nanchang UniversityNanchang 330031JiangxiChina division of nanomaterials and jiangxi key lab of carbonene materials Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesNanchang 330200JiangxiChina College of Chemistry Biology and Material ScienceEast China University of TechnologyNanchang 330013JiangxiChina

Lithium sulfur batteries(LSBs)draw extensive interest because of the ultra-high capacity and low material cost.However,the sluggish lithium polysulfides(LIPSs)conversion processes are detrimental to cycle stability and rate capability,inhibiting the commercial application of LSBs.Here we present the well-designed Fe Co alloy catalysts anchored on porous carbon(FeCo-C)as sulfur host to improve the electrochemical performance by accelerating the conversion reactions.The FeCo alloy demonstrates high catalytic effect and strong adsorption capability of LIPSs,in which potential polarization can be greatly decreased and"shuttle effects"can be largely avoided.As a result,the obtained S/Fe Co-C composites show an initial specific capacity of 791.9 m Ah g^-1 at a large current density of 2 C and maintain 502.5 mAh g^-1 even after 500 cycles.Moreover,720 m Ah g^-1(corresponding to 70%retention)can be achieved after 100 cycles at 0.2 C with a high sulfur content of 80 wt%,enabling high sulfur utilization.This work not only provides a new insight to investigate the conversion kinetics of Li PSs,but also opens up a new avenue for advanced lithium sulfur batteries.

关键词： Lithium sulfur batteries FeCo alloys Catalysts Adsorption Porous carbon

High-loading Co-doped NiO nanosheets on carbon-welded carbon nanotube framework enabling rapid charge kinetic for enhanced supercapacitor performance

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Journal of Energy Chemistry 2020年第11期29卷 240-247页

作者： Hao Xu Yufang Cao Yong Li Pei Cao Dandan Liu Yongyi Zhang Qing wen Li School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026AnhuiChina key laboratory of Multifunctional nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123JiangsuChina division of nanomaterials and jiangxi key lab of carbonene materials Suzhou Institute of Nano-Tech and Nano-BionicsNanchangChinese Academy of SciencesNanchang 330200JiangxiChina School of materials Science and Engineering Nanchang UniversityNanchang 330031JiangxiChina

Developing high power and energy supercapacitors(SCs)is a long-pursued goal for the application in transportation and energy storage station.Herein,a rationally-designed Co-doped nickel oxide nanosheets@carbon-welded carbon nanotube foam(Co-doped NiO@WCNTF)as freestanding electrode is successfully prepared for high power and energy SCs.The WCNTF framework with high specific surface area provides three dimensional highly conductive network for fast charge transport and ensures high loading of active materials(9.2 mg/cm2).Moreover,porous Co-doped NiO nanosheets uniformly anchored on the WCNTF framework enable rapid charge kinetics due to the high intrinsic conductivity of Co-doped Ni O nanosheets and their good contact with conductive WCNTF substrate.As a result,the unique integrated electrode with 3D architecture exhibits an ultrahigh specific capacitance of 11.45 F/cm2 at 5 mA/cm2,outstanding rate capability(11.45 F/cm2 at 5 mA/cm2 and a capacitance retention of 86.2%at 30 mA/cm2)and good cycling stability,suggesting great potential for high performance supercapacitor.

关键词： Carbon nanotube foam Pseudocapacitors Co-doped NiO nanosheets Freestanding electrode