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Ionic liquid-trimetallic electrocatalytic system for C–O bond cleavage in lignin model compounds and lignin under ambient conditions

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Nano Research 2024年第4期17卷 2420-2428页

作者： Guangyong Liu Yumiao Lu JunFeng Lu Yanlei Wang Shijing Liang Hongyan He Lilong Jiang National engineering Research Center of Chemical Fertilizer Catalyst Fuzhou UniversityFuzhou 350002China CAS Key Laboratory of Green Process and engineering State Key Laboratory of Multiphase Complex SystemsBeijing Key Laboratory of Ionic Liquids Clean ProcessInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China Longzihu New Energy Laboratory Zhengzhou Institute of Emerging Industrial TechnologyZhengzhou 450000China

Electrocatalytic depolymerization of lignin into value-added chemicals offers a promising technique to make biorefining ***,we report a robust trimetallic PdNiBi electrocatalyst for reductive C–O bond cleavage of different lignin model dimers and oxidized lignin under mild *** reduction reaction proceeds with complete substrate conversion and excellent yields toward monomers of phenols(80%–99%)and acetophenones(75%–96%)in the presence of an ionic liquid electrolyte with operational *** experimental investigations together with density functional theory(DFT)calculations reveal that the outstanding performance of the catalyst results from the synergistic effect of the metal elements,which facilitates the easier formation of a key Cαradical intermediate and the facile desorption of the as-formed products at the *** results open up new opportunities for lignin valorization through the green electrocatalytic approach.

关键词： electrocatalytic depolymerization lignin Ionic liquids density functional theory(DFT)calculation

Dynamics of Advantageous Mutant Spread in Spatial Death-Birth and Birth-Death Moran Models

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Communications on Applied Mathematics and Computation 2024年第1期6卷 576-604页

作者： Jasmine Foo Einar Bjarki Gunnarsson Kevin Leder David Sivakoff School of Mathematics University of MinnesotaTwin CitiesMN55455USA Department of industrial and systems engineering University of MinnesotaTwin CitiesMN55455USA Departments of Statistics and Mathematics The Ohio State UniversityColumbusOH43210USA

The spread of an advantageous mutation through a population is of fundamental interest in population genetics. While the classical Moran model is formulated for a well-mixed population, it has long been recognized that in real-world applications, the population usually has an explicit spatial structure which can significantly influence the dynamics. In the context of cancer initiation in epithelial tissue, several recent works have analyzed the dynamics of advantageous mutant spread on integer lattices, using the biased voter model from particle systems theory. In this spatial version of the Moran model, individuals first reproduce according to their fitness and then replace a neighboring individual. From a biological standpoint, the opposite dynamics, where individuals first die and are then replaced by a neighboring individual according to its fitness, are equally relevant. Here, we investigate this death-birth analogue of the biased voter model. We construct the process mathematically, derive the associated dual process, establish bounds on the survival probability of a single mutant, and prove that the process has an asymptotic shape. We also briefly discuss alternative birth-death and death-birth dynamics, depending on how the mutant fitness advantage affects the dynamics. We show that birth-death and death-birth formulations of the biased voter model are equivalent when fitness affects the former event of each update of the model, whereas the birth-death model is fundamentally different from the death-birth model when fitness affects the latter event.

关键词： Spatial death-birth models Spatial birth-death models Spatial evolutionary models Spatial cancer models Evolutionary graph theory Stochastic processes Biased voter model Dual process Fixation probability Shape theorem

Recent progress on Sn_(3)O_(4)nanomaterials for photocatalytic applications

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International Journal of Minerals,Metallurgy and Materials 2024年第2期31卷 231-244页

作者： Xin Yu Congcong Li Jian Zhang Lili Zhao Jinbo Pang Longhua Ding Institute for Advanced Interdisciplinary Research(iAIR) School of Chemistry and Chemical EngineeringUniversity of JinanJinan 250022China School of Sino-German engineering Shanghai Technical Institute of Electronics and InformationShanghai 201411China division of systems and Synthetic Biology Department of Life SciencesChalmers University of Technology41296 GöteborgSweden

Tin(IV)oxide(Sn_(3)O_(4))is layered tin and exhibits mixed valence *** has emerged as a highly promising visible-light pho-tocatalyst,attracting considerable *** comprehensive review is aimed at providing a detailed overview of the latest advance-ments in research,applications,advantages,and challenges associated with Sn_(3)O_(4)photocatalytic *** fundamental con-cepts and principles of Sn_(3)O_(4)are ***_(3)O_(4)possesses a unique crystal structure and optoelectronic properties that allow it to ab-sorb visible light efficiently and generate photoexcited charge carriers that drive photocatalytic ***,strategies for the control and improved performance of Sn_(3)O_(4)photocatalytic nanomaterials are *** control,ion doping,and hetero-structure construction are widely employed in the optimization of the photocatalytic performance of Sn_(3)O_(4)*** effective imple-mentation of these strategies improves the photocatalytic activity and stability of Sn_(3)O_(4)***,the review explores the diverse applications of Sn_(3)O_(4)photocatalytic nanomaterials in various fields,such as photocatalytic degradation,photocatalytic hydro-gen production,photocatalytic reduction of carbon dioxide,solar cells,photocatalytic sterilization,and optoelectronic *** discus-sion focuses on the potential of Sn_(3)O_(4)-based nanomaterials in these applications,highlighting their unique attributes and ***,the review provides an outlook on the future development directions in the field and offers guidance for the exploration and de-velopment of novel and efficient Sn_(3)O_(4)-based *** the identification of emerging research areas and potential avenues for improvement,this review aims to stimulate further advancements in Sn_(3)O_(4)-based photocatalysis and facilitate the translation of this promising technology into practical applications.

关键词： photocatalysis Sn_(3)O_(4)nanomaterials building heterostructures antibacterial therapy water splitting

Development of a Novel Noise Reduction Algorithm for Smart Checkout RFID System in Retail Stores

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Computers, Materials & Continua 2024年第7期80卷 1277-1304页

作者： Shazielya Shamsul Mohammed A.H.Ali Salwa Hanim Abdul-Rashid Atef M.Ghaleb Fahad M.Alqahtani Department of Mechanical engineering Faculty of EngineeringUniversiti MalayaKuala Lumpur50603Malaysia Centre for Sustainable and Smart Manufacturing(CSSM) Faculty of EngineeringUniversiti MalayaKuala Lumpur50603Malaysia Department of industrial engineering College of EngineeringAlfaisal UniversityRiyadh11533Saudi Arabia Department of industrial engineering College of EngineeringKing Saud UniversityP.O.Box 800Riyadh11421Saudi Arabia

This paper presents a smart checkout system designed to mitigate the issues of noise and errors present in the existing barcode and RFID-based systems used at retail stores’checkout *** is achieved by integrating a novel AI algorithm,called Improved Laser Simulator Logic(ILSL)into the RFID *** enhanced RFID system was able to improve the accuracy of item identification,reduce noise interference,and streamline the overall checkout *** potential of the systemfor noise detection and elimination was initially investigated through a simulation study usingMATLAB and ILSL ***,it was deployed in a small-scale environment to validate its real-world *** show that RFID with the proposed new algorithm ILSL and AI basket is capable of accurately detecting the related itemswhile eliminating noise originating fromunrelated objects,achieving an accuracy rate of 88%.

关键词： Smart checkout system RFID technology improved laser simulator logic(ILSL) reduce noise checkout process

On convergence of covariance matrix of empirical Bayes hyper-parameter estimator

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Control Theory and Technology 2024年第2期22卷 149-162页

作者： Yue Ju Biqiang Mu Tianshi Chen School of Data Science and Shenzhen Research Institute of Big Data The Chinese University of Hong KongShenzhenShenzhen518172GuangdongChina division of Decision and Control systems School of Electrical Engineering and Computer ScienceKTH Royal Institute of Technology10044StockholmSweden Key Laboratory of systems and Control Institute of Systems ScienceAcademy of Mathematics and System ScienceChinese Academy of SciencesBeijing100190China

Regularized system identification has become the research frontier of system identification in the past *** related core subject is to study the convergence properties of various hyper-parameter estimators as the sample size goes to *** this paper,we consider one commonly used hyper-parameter estimator,the empirical Bayes(EB).Its convergence in distribution has been studied,and the explicit expression of the covariance matrix of its limiting distribution has been ***,what we are truly interested in are factors contained in the covariance matrix of the EB hyper-parameter estimator,and then,the convergence of its covariance matrix to that of its limiting distribution is *** general,the convergence in distribution of a sequence of random variables does not necessarily guarantee the convergence of its covariance ***,the derivation of such convergence is a necessary complement to our theoretical analysis about factors that influence the convergence properties of the EB hyper-parameter *** this paper,we consider the regularized finite impulse response(FIR)model estimation with deterministic inputs,and show that the covariance matrix of the EB hyper-parameter estimator converges to that of its limiting ***,we run numerical simulations to demonstrate the efficacy of ourtheoretical results.

关键词： Regularized system identification Hyper-parameter estimator Empirical Bayes Convergence of covariance matrix

When mRNA meets gene editing

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Nano Research 2024年第8期17卷 7337-7356页

作者： Weijie Li Chen Wang Yuan Lu Key Laboratory of industrial Biocatalysis Ministry of EducationDepartment of Chemical EngineeringTsinghua UniversityBeijing 100084China Department of Chemical engineering Tsinghua UniversityBeijing 100084China

The critical challenge of gene therapy lies in delivering gene editing *** with DNA,while RNA is less stable and more accessible to degrade,it comes with the benefit of lower off-target effects since permanent insertion is not *** review focuses on mRNA-based delivery of gene editing agents,highlighting novel mRNA delivery *** provide context,a comparison is made between three main gene editing agents:programmable nucleases,base editors,and prime *** potential of Cas\pi and transposons is also discussed in this ***,a summary of four main barriers to mRNAbased in vivo delivery is ***,this review detailedly introduced different delivery systems,both viral(lentivirus)and non-viral vectors(genome editing via oviductal nucleic acids delivery,lipid nanoparticles,polymer-based nanoparticles,viruslike-particles,extracellular vesicles,and migrasome).Each delivery strategy is assessed by comparing its advantages and disadvantages to offer a comprehensive and objective overview of the delivery ***,we emphasized the vital role of the protein corona as a critical regulator for ***,we concluded the challenges of mRNA-based gene editing strategies(RNA stability,targeting,potential immunogenicity,cytotoxicity,heterogeneity,and rational design).The purpose of this review is to guide further research and provide a comprehensive analysis of mRNA-based in vivo delivery of gene editing agents in this promising field.

关键词： gene editing mRNA delivery viral vectors non-viral vectors CRISPR

A novel low-cost visual ear tag based identification system for precision beef cattle livestock farming

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Information Processing in Agriculture 2024年第1期11卷 117-126页

作者： Andrea Pretto Gianpaolo Savio Flaviana Gottardo Francesca Uccheddu Gianmaria Concheri Department of Civil Environmental and Architectural EngineeringUniversity of PaduaItaly Department of Animal Medicine Production and HealthUniversity of PadovaItaly Department of industrial engineering University of PadovaItaly

The precision livestock farming(PLF)has the objective to maximize each animal's performance while reducing the environmental impact and maintaining the quality and safety of meat *** the PLF techniques,the personalised management of each individual animal based on sensors systems,represents a viable *** is worth noting that the implementation of an effective PLF approach can be still expensive,especially for small and medium-sized farms;for this reason,to guarantee the sustainability of a customized livestock management system and encourage its use,plug and play and cost-effective systems are *** this context,we present a novel low-cost method for identifying beef cattle and recognizing their basic activities by a single surveillance *** leveraging the current state-of-the-art methods for real-time object detection,(i.e.,YOLOv3)cattle's face areas,we propose a novel mechanism able to detect the ear tag as well as the water ingestion state when the cattle is close to the *** cow IDs are read by an Optical Character Recognition(OCR)algorithm for which,an ad hoc error correction algorithm is here presented to avoid numbers misreading and correctly match the IDs to only actually present *** to the detection of the tag position,the OCR algorithm can be applied only to a specific region of interest reducing the computational cost and the time *** times for the areas are outputted as cattle activity recognition *** results demonstrate the effectiveness of our proposed method,showing a mAP@0.50 of 89%.

关键词： Precision livestock farming Deep learning Cattlei dentification Low-cost sensors Computer vision

Multi-carrier Tb/s silicon photonic coherent receiver

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Science China(Information Sciences) 2024年第1期67卷 284-291页

作者： Zhen WANG Xingfeng LI Jingchi LI Jian SHEN Yong ZHANG Yikai SU State Key Lab of Advanced Optical Communication systems and Networks Department of Electronic EngineeringShanghai Jiao Tong University

We propose a silicon polarization-diversity coherent receiver for wavelength-multiplexing transmission without using the large-footprint arrayed waveguide grating(AWG).We have integrated our proposed coherent receiver on the silicon-on-insulator(SOI) platform for high-capacity *** the proposed coherent receiver,high-frequency photocurrent signals from other wavelengths are suppressed by electrical low-pass ***,the signal-signal beat interference(SSBI) generated from each wavelength is eliminated by the balanced *** two features lend to the proposed coherent receiver being free of the mm-scale *** have demonstrated our proposed coherent receiver to detect a 1.12-Tb/s wavelength-division-multiplexed and polarization-division-multiplexed 16-ary quadrature amplitude modulation(PDM-16-QAM) *** compact footprint of the silicon chip promises small-form-factor receivers for future ultra-high-capacity coherent communication systems that require a high integration level and low fabrication cost.

关键词： silicon photonics optical receivers coherent communication wavelength-division-multiplexing(WDM) polarization-division-multiplexing(PDM)

On extended state Kalman filter-based identification algorithm for aerodynamic parameters

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Control Theory and Technology 2024年第2期22卷 235-243页

作者： Wenyan Bai Ruizhe Jia Peng Yu Wenchao Xue Beijing Aerospace Automatic Control Institute Beijing100854China School of Automation and Electrical engineering University of Science and Technology BeijingBeijing100083China Key Laboratory of Knowledge Automation for industrial Processes Ministry of EducationBeijing100083China Key Laboratory of systems and Control Institute of Systems ScienceAcademy of Mathematics and Systems ScienceChinese Academy of SciencesBeijing100190China

In this paper, the problem of time-varying aerodynamic parameters identification under measurement noises is studied. By analyzing the key aerodynamic parameters that affect the aircraft control system, a system model with extended states for identifying equivalent aerodynamic parameters is established, and error parameters are extended to the system state, avoiding the difficulty caused by the unknown dynamic in the system. Furthermore, an identification algorithm based on extended state Kalman filter is designed, and it is proved that the algorithm has quasi-consistency, thus, the estimation error can be evaluated in real time. Finally, the simulation results under typical flight scenarios show that the designed algorithm can accurately identify aerodynamic parameters, and has desired convergence speed and convergence precision.

关键词： Aerodynamic parameters Parameter identification Extended state Kalman filter