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Interfacial engineering of the layered oxide cathode materials for sodium-ion battery

Nano Research 2024年第3期17卷 1441-1464页

作者： Quanqing Zhao Ruru Wang Ming Gao Faheem KButt Jianfeng Jia Haishun Wu Youqi Zhu Key Laboratory of Magnetic Molecules and Magnetic Information materials of Ministry of Education School of Chemistry and Materials ScienceShanxi Normal UniversityTaiyuan 030032China Metals and Chemistry Research Institute China Academy of Railway Sciences Corporation LimitedBeijing 100081China Department of Physics Division of Science and TechnologyUniversity of EducationLahore 54770Pakistan Research Center of materials Science Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green ApplicationsBeijing Institute of TechnologyBeijing 100081China

The layered metal oxides are reviewed as the hopeful cathode materials for high-performance sodium-ion batteries(SIBs)due to their large theoretical capacity,favorable two-dimensional(2D)ion diffusion channel,and simple manipuility.However,their cycling stability,rate capability,and thermal stability are still significantly concerned and highlighted before further practical application.The chemical,mechanical and electrochemical stability of the cathode–electrolyte interfaces upon cycling is of great significance.Herein,the unique structural and electrochemical properties of the layered oxide cathode materials for SIB are reviewed.The mechanism of bulk/surface degradation induced by oxygen evolution,phase transition,microcrack,and electrolyte decomposition is thoroughly understood.Furthermore,the interfacial engineering to construct stable interface through various effective methods is fully discussed.The future outlook and challenges for interfacial engineering in this filed are also summarized.This review should shed light on the rational design and construct of robust interface for applications of superior layered oxide cathodes in SIB and may suggest future research directions.

关键词： interfacial engineering sodium-ion battery layered oxide electrolyte interface

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High cerium content(Nd-Pr-Ce)_(2)Fe_(14)B melt-spun ribbons with high coercivity

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Journal of Rare Earths 2024年第4期42卷 690-695页

作者： Yujiang Zhong Junming Wang Zikai Yuan Ruijin Liu Minggang Zhu Zhe Liu Xin Chen Wei Li Zhaohui Guo division of functional materials Central Iron and Steel Research InstituteBeijing100081China Ningbo Jinji Strong Magnetic Material Co. Ltd.Ningbo315172China Jiangxi Jiangwu Rare Metal New Material Co. Ltd.Nanchang330013China

The effects of wheel speeds on the magnetic properties and microstructures of[(Nd,Pr)_(1-x)Ce_(x)]-Fe-B meltspun ribbons were investigated.Compared to melt-spun ribbons with low cerium(Ce)content(x=0.2),amorphous formation can be suppressed at high wheel speed in the ribbons with a relatively high Ce content(x=0.8),and with the increase of the wheel speed,the magnetic properties of the ribbons with high Ce content raise continuously.At high wheel speed,the coercivity mechanism of melt-spun ribbons is mainly pinning field,and the high wheel speed introduces a large number of defects into the matrix as pinning sites.Furthermore,ribbons with high Ce content form a fine and uniform grain structure,so the grain boundary area enlarges,which further hinders the movement of domain walls.The combined effects of the above factors enable ribbons with high Ce content to have excellent magnetic properties(Hcj=0.977 T,Mr=64 m^(2) A/kg)at the wheel speed of 35 m/s.

关键词： Wheel speed Cecontent Microstructure Magnetic properties Rare earths

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Solid-state impedance spectroscopy studies of dielectric properties and relaxation processes in Na_(2)O–V_(2)O_(5)–Nb_(2)O_(5)–P_(2)O_(5) glass

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International Journal of Minerals,Metallurgy and materials 2024年第1期31卷 186-196页

作者： Sara Marijan Luka Pavic division of materials Chemistry Ruđer Boskovic InstituteBijenicka 54HR-10000 ZagrebCroatia

Solid-state impedance spectroscopy(SS-IS)was used to investigate the influence of structural modifications resulting from the addition of Nb2O5 on the dielectric properties and relaxation processes in the quaternary mixed glass former(MGF)system 35Na_(2)O–10V_(2)O_(5)–(55-x)P_(2)O_(5)–xNb_(2)O_(5)(x=0–40,mol%).The dielectric parameters,including the dielectric strength and dielectric loss,are determined from the frequency and temperature-dependent complex permittivity data,revealing a significant dependence on the Nb2O5 content.The transition from a predominantly phosphate glass network(x<10,region I)to a mixed niobate–phosphate glass net-work(10≤x≤20,region II)leads to an increase in the dielectric parameters,which correlates with the observed trend in the direct-cur-rent(DC)conductivity.In the predominantly niobate network(x≥25,region III),the highly polarizable nature of Nb5+ions leads to a fur-ther increase in the dielectric permittivity and dielectric strength.This is particularly evident in Nb-40 glass-ceramic,which contains Na_(13)Nb_(35)O_(94) crystalline phase with a tungsten bronze structure and exhibits the highest dielectric permittivity of 61.81 and the lowest loss factor of 0.032 at 303 K and 10 kHz.The relaxation studies,analyzed through modulus formalism and complex impedance data,show that DC conductivity and relaxation processes are governed by the same mechanism,attributed to ionic conductivity.In contrast to glasses with a single peak in frequency dependence of imaginary part of electrical modulus,M″(ω),Nb-40 glass-ceramic exhibits two distinct contributions with similar relaxation times.The high-frequency peak indicates bulk ionic conductivity,while the additional low-fre-quency peak is associated with the grain boundary effect,confirmed by the electrical equivalent circuit(EEC)modelling.The scaling characteristics of permittivity and conductivity spectra,along with the electrical modulus,validate time-temperature superposition and demonstrate a strong correlation with composition and modific

关键词： phosphate glasses glass-ceramics impedance spectroscopy dielectric properties relaxation processes permittivity scaling conductivity scaling modulus formalism

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Effect of grain boundary diffusion of terbium on mode of mechanical fracture of sintered NdFeB magnets

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Journal of Rare Earths 2024年第4期42卷 696-704页

作者： Zexin Lu Tinghui Wang Jianjun Jiang Bizhang Zheng Lijing Yang Xingqi He Anli Lin Shengzhi Dong Zhenlun Song CAS Key Laboratory of Magnetic materials and Devices Zhejiang Province Key Laboratory of Magnetic Materials and Application TechnologyNingbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo315201China Faculty of Mechanical Engineering and Mechanics Ningbo UniversityNingbo315211China Ningbo Xinqi Precision Magnetism Steel Co. Ltd..Ningbo315156China Center for Advanced Measurement Science National Institute of MetrologyBeijing102200China division of functional materials Central Iron&Steel Research InstituteBeijing100081China

Grain boundary diffusion process(GBDP)is a widely used method of increasing the coercivity of sintered NdFeB magnets.In this study,the effects of the GBDP on the bending strength and microhardness of sintered NdFeB magnets and the fracture mode were investigated.Results show that the bending strength of magnets is reduced by pickling and heat treatment and greatly recove rs after heavy rare earth element(Tb)grain boundary diffusion.The pickling and the heat treatment cause a slight decrease in microhardness.Compared with the recovery of the bending strength,the hardness decreases after the GBDP.The fracture mode of bended magnets changes from intergranular to transgranular.This study helps in further improving the mechanical and magnetic properties of sintered NdFeB magnets.

关键词： Sintered NdFeB magnets Grain boundary diffusionprocess Bending strength Heavy rare earth element Coercivity

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A Magnetic-Multiplier-Enabled Hybrid Generator with Frequency division Operation and High Energy Utilization Efficiency

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Research 2024年第1期2023卷 561-570页

作者： Jie Chen Kangjie Wu Shaokun Gong Jianchao Wang Ke Wang Hengyu Guo College of Physics and Electronic Engineering Chongqing Key Laboratory Photo-electric Functional MaterialsChongqing Normal UniversityChongqing 401331China State Key Laboratory of Mechanical Transmission College of Mechanical and Vehicle EngineeringChongqing UniversityChongqing 400044China School of Physics Chongqing UniversityChongqing 400044China

The hybrid electromagnetic-triboelectric generator(HETG)is a prevalent device for mechanical energy harvesting.However,the energy utilization efficiency of the electromagnetic generator(EMG)is inferior to that of the triboelectric nanogenerator(TENG)at low driving frequencies,which limits the overall efficacy of the HETG.To tackle this issue,a layered hybrid generator consisting of a rotating disk TENG,a magnetic multiplier,and a coil panel is proposed.The magnetic multiplier not only forms the EMG part with its high-speed rotor and the coil panel but also facilitates the EMG to operate at a higher frequency than the TENG through frequency division operation.The systematic parameter optimization of the hybrid generator reveals that the energy utilization efficiency of EMG can be elevated to that of rotating disk TENG.Incorporating a power management circuit,the HETG assumes the responsibility for monitoring the water quality and fishing conditions by collecting low-frequency mechanical energy.The magneticmultiplier-enabled hybrid generator demonstrated in this work offers a universal frequency division approach to improve the overall outputs of any hybrid generator that collects rotational energy,expanding its practical applications in diverse multifunctional self-powered systems.

关键词： generator rotating assume

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Modeling asymmetric fracture mechanics of Mg alloy wire in drawing process

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Journal of Magnesium and Alloys 2024年第5期12卷 2057-2069页

作者： Sunghoon Choi Jongwon Shin Joung Sik Suh Dongchoul Kim Department of Mechanical Engineering Sogang University Advanced Metals division Korea Institute of Materials Science

In this study, a numerical analysis was conducted on the ductile fracture of a 2-mm diameter Mg-1Zn-0.5Mn-0.5Sr-0.1Ca alloy wire during drawing. The hexagonally close-packed crystal structure of Mg alloys causes asymmetric fracture behavior, especially in the compression region. The aim of this study is to develop a comprehensive damage model for Mg alloy wire that accurately predicts ductile fracture, with a focus on the compression region. A novel experimental method was introduced to measure the ductile fracture of Mg alloy wires under different stress states. The wire drawing process was simulated using the Generalized Incremental Stress-State dependent damage(GISSMO)Model and the Semi-Analytical Model for Polymers(SAMP) model. The damage model's prediction and the experimental results were found to be in excellent agreement, especially in determining crack initiation. Computational analysis established a safe zone diagram for die angle and reduction ratio, and experimental validation confirmed the feasibility of this approach. The proposed damage model can provide a practical and reliable analysis for optimizing the drawing process of Mg alloy wire.

关键词： Mg alloy Wire drawing Finite element method Damage model Safe zone diagram

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Proton‑Prompted Ligand Exchange to Achieve High‑Efficiency CsPbI_(3) Quantum Dot Light‑Emitting Diodes

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Nano-Micro Letters 2024年第6期16卷 53-62页

作者： Yanming Li Ming Deng Xuanyu Zhang Lei Qian Chaoyu Xiang Laboratory of Advanced Nano‑Optoelectronic materials and Devices Qianwan Institute of CNITECHNingbo 315300People’s Republic of China division of functional materials and Nanodevices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201People’s Republic of China Zhejiang Provincial Engineering Research Center of Energy Optoelectronic materials and Devices Ningbo Institute of Materials Technology&EngineeringChinese Academy of SciencesNingbo 315201People’s Republic of China Faculty of Electrical Engineering and Computer Science Ningbo UniversityNingbo 315211ZhejiangPeople’s Republic of China University of Nottingham Ningbo China Ningbo 315100People’s Republic of China

CsPbI_(3)perovskite quantum dots(QDs)are ideal materials for the next generation of red light-emitting diodes.However,the low phase stability of CsPbI_(3)QDs and long-chain insulating capping ligands hinder the improvement of device performance.Traditional in-situ ligand replacement and ligand exchange after synthesis were often difficult to control.Here,we proposed a new ligand exchange strategy using a proton-prompted insitu exchange of short 5-aminopentanoic acid ligands with long-chain oleic acid and oleylamine ligands to obtain stable small-size CsPbI_(3)QDs.This exchange strategy maintained the size and morphology of CsPbI_(3)QDs and improved the optical properties and the conductivity of CsPbI_(3)QDs films.As a result,high-efficiency red QD-based light-emitting diodes with an emission wavelength of 645 nm demonstrated a record maximum external quantum efficiency of 24.45%and an operational half-life of 10.79 h.

关键词： CsPbI_(3) perovskite quantum dots Light-emitting diodes Ligand exchange Proton-prompted in-situ exchange

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Design and fabrication of Nd-Fe-B magnet with excellent thermal stability

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Journal of Rare Earths 2024年第5期42卷 980-986,I0006页

作者： Rui Han Shengzhi Dong Dong Li Dongmin Zhang Hongsheng Chen Jiyuan Xu George CHadjipanayis Zhuolin Li Ying Zhang Wei Li division of functional materials Research Central Iron and Steel Research InstituteBeijing100081China Department of Physics and Astronomy Sharp Lab University of DelawareNewarkDE19716USA Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing100190China

A novel Nd-Fe-B type permanent magnet with excellent thermal stability was designed by Co replacing Fe in the main phase and the grain boundary phase.The remanence and coercivity temperature coefficient reach 0.058%/℃and 0.465%/℃in the te mperature range from 25 to 100℃,which are much lower than those of commercial Nd-Fe-B magnet.An enhanced Curie temperature is obtained for the novel magnet due to the Co substitution,which significantly improves the operating temperature.The microstructure result reveals that an amorphous phase exists in the intergranular grains which is probably responsible for the deterioration of intrinsic coercivity.This work can provide a reference for the design and optimization of components of sintered Nd-Fe-B magnets with excellent thermal stability.

关键词： Thermal stability Remanence temperature coefficient Operating temperature Atomic substitution Rare earths

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Microfluidic bubble-generator enables digital light processing 3D printing of porous structures

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Aggregate 2024年第1期5卷 280-291页

作者： Philipp Weber Ling Cai Francisco Javier Aguilar Rojas Carlos Ezio Garciamendez-Mijares Maria Celeste Tirelli Francesco Nalin Jakub Jaroszewicz Wojciech Swi eszkowski Marco Costantini Yu Shrike Zhang division of Engineering in Medicine Department of MedicineBrigham and Women’s HospitalHarvard Medical SchoolCambridgeMassachusettsUSA Institute of Physical Chemistry—Polish Academy of Sciences KasprzakaPoland Biomaterials Group Materials Design DivisionFaculty of Materials Science and EngineeringWarsaw University of TechnologyWoloskaPoland

Three-dimensional(3D)printing is an emerging technique that has shown promising success in engineering human tissues in recent years.Further development of vatphotopolymerization printing modalities has significantly enhanced the complexity level for 3D printing of various functional structures and components.Similarly,the development of microfluidic chip systems is an emerging research sector with promising medical applications.This work demonstrates the coupling of a digital light processing(DLP)printing procedure with a microfluidic chip system to produce size-tunable,3D-printable porosities with narrow pore size distributions within a gelatin methacryloyl(GelMA)hydrogel matrix.It is found that the generation of size-tunable gas bubbles trapped within an aqueous GelMA hydrogel-precursor can be controlled with high precision.Furthermore,the porosities are printed in two-dimensional(2D)as well as in 3D using the DLP printer.In addition,the cytocompatibility of the printed porous scaffolds is investigated using fibroblasts,where high cell viabilities as well as cell proliferation,spreading,and migration are confirmed.It is anticipated that the strategy is widely applicable in a range of application areas such as tissue engineering and regenerative medicine,among others.

关键词： 3D printing biofabrication bubble digital light processing microfluidics porous

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A multifunctional nanoaggregate-based system for detection of rheumatoid arthritis via Optoacoustic/NIR-Ⅱ fluorescent imaging and therapy via inhibiting JAK-STAT/NF-κB/NLRP3 pathways

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Aggregate 2024年第1期5卷 353-366页

作者： Junjie Chen Longqi Chen Zunpan She Fang Zeng Shuizhu Wu Biomedical division State Key Laboratory of Luminescent Materials and DevicesGuangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesCollege of Materials Science and EngineeringSouth China University of TechnologyGuangzhouChina

Rheumatoid arthritis(RA)is a debilitating autoimmune disease that causes chronic pain and serious complications,presenting a significant challenge to treat.Promising approaches for treating RA involve signaling pathways modulation and targeted therapy.To this end,a multifunctional nanosystem,TPC-U@HAT,has been designed for RA therapy,featuring multitargeting,dual-stimuli response,and on-demand drug release capabilities.TPC-U@HAT is composed of a probe/prodrug TPC,a JAK1 kinase inhibitor upadacitinib,and the drug carrier HAT.TPC is composed of an aggregation-induced emission(AIE)-active NIR-II chromophore TPY and an NF-κB/NLRP3 inhibitor caffeic acid phenethyl ester(CAPE),connected via boronic ester bond which serves as the reactive-oxygen-species-responsive linker.The carrier,HAT,is created by grafting bone-targeting alendronate and hydrophobic tocopheryl succinate onto hyaluronic acid chains,which can encapsulate TPC and upadacitinib to form TPC-U@HAT.Upon intravenous injection into mice,TPC-U@HAT accumulates at inflamed lesions of RA through both active and passive targeting,and the overexpressed hyaluronidase and H_(2)O_(2) therein cleave the hyaluronic acid polymer chains and boronate bonds,respectively.This generates an AIE-active chromophore for detection and therapeutic evaluation of RA via both optoacoustic imaging and NIR-II fluorescent imaging and concomitantly releases CAPE and upadacitinib to exert efficacious therapy by inhibiting NF-κB/NLRP3 and JAK-STAT pathways.

关键词： aggregation-induced emission dual-stimuli response multispectral optoacoustic tomography imaging multitargeting NIR-II fluorescence imaging rheumatoid arthritis

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