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Multi-dimensional Bi@C electrocatalyst for Cr3+/Cr2+ redox reaction boosting high-performance iron-chromium flow batteries

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Science China Chemistry 2025年

作者： Min Wu Mingjun Nan Shumin Liu Caihe Zhong Lin Qiao Huamin Zhang Xiangkun Ma Department of Materials Science and Engineering Dalian Maritime University division of energy Storage Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences

With the increasing demand for energy storage technology, iron-chromium flow batteries（ICFBs） have been widely concerned because of their price advantage. However, the low electrochemical activity of Cr3+/Cr2+redox couples and the side hydrogen evolution reaction limit the industrial application of ICFBs. A multi-dimensional Bi/carbon composite electrocatalyst（Bi@C）for ICFB is designed and prepared to improve the electrochemical activity of Cr3+/Cr2+redox couples. Benefiting by using the Bimetal organic framework（Bi-MOF） with solid matrix as precursors, Bi nanospheres are highly dispersed on the Bi@C electrocatalyst that effectively enhances the electrochemical activity. The special morphology of Bi@C electrocatalyst helps the transfer of electrons and ions, significantly reducing the polarization of battery. Herein, the 3D porous carbon frames accelerate mass transfer, and the 2D carbon nanobelts and carbon layer coating on 0D Bi nanospheres improve the conductivity of Bi nanospheres. Therefore, the ICFB with multi-dimensional Bi@C electrocatalyst exhibits coulombic efficiency of 98.10% and energy efficiency of 79.14% at 140 mA cm-2, which is higher than ICFBs with commercial graphite carbon electrocatalyst and with heat treatment carbon felt. This work provides a simple and economical method to fabricate a high-performance multidimensional Bi@C electrocatalyst for Cr3+/Cr2+redox couples, boosting the development of ICFBs.

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Recent Advancements in the Optimization Capacity Configuration and Coordination Operation Strategy of Wind-Solar Hybrid Storage System

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energy Engineering 2025年第1期122卷 285-306页

作者： Hongliang Hao Caifeng Wen Feifei Xue HaoQiu Ning Yang Yuwen Zhang Chaoyu Wang Edwin E.Nyakilla Department of New energy Storage Peking University Ordos Research Institute of EnergyOrdos017010China School of energy and Power Engineering Inner Mongolia University of TechnologyHohhot010080China Key Laboratory of Wind energy and Solar energy Utilization Technology Inner Mongolia University of TechnologyHohhot010051China

Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy *** paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,***/Simulink was used for simulation *** optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 ***,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations *** proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.

关键词： Electric-thermal hybrid storage modal decomposition multi-objective genetic algorithm capacity optimization allocation operation strategy

Nanoimprint lithography-assisted block copolymer self-assembly for hyperfine fabrication of magnetic patterns based on L10-FePt nanoparticles

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Science China Chemistry 2025年

作者： Jie Zhang Yi Chen Guijun Li Zelin Sun Zhengong Meng Wai-Yeung Wong Department of Applied Biology and Chemical Technology and Research Institute for Smart energy The Hong Kong Polytechnic University The Hong Kong Polytechnic University Shenzhen Research Institute division of Integrative systems and Design and Department of Electronic and Computer Engineering The Hong Kong University of Science and Technology School of Flexible Electronics (Future Technology) and Institute of Advanced Materials (IAM) Nanjing Tech University

L10-FePt-type bit-patterned media has provided a promising alternative for ultrahigh-density magnetic recording systems in the current digital era, but rapid fabrication of magnetic patterns with hyperfine bit islands is still challenging, especially with the target for miniaturization and scalable production simultaneously. Herein, Fe,Pt-containing block copolymers were utilized as single-source precursors for solution-processable patterning and subsequent generation of the demanding magnetic FePt dots by in situ pyrolysis. High-throughput nanoimprint lithography was initially employed to fabricate the predefined bit cells precisely,and then the intrinsic self-assembly of phase-separated block copolymers further drove the formation of accurate bit *** from the synergistic effect of top-down lithographic approach and bottom-up self-assembly, the customizable patterns could be achieved for large-scale mass production in targeted areas, but high-density isolated dots could also be accurately aligned along the patterned features after subsequent self-assembly. This reliable strategy would provide a good avenue to precisely construct ultrahigh-density magnetic data storage devices.

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Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao Wu Xiaoling Liu Biao Meng Tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Activation energy

A stochastic approach for integrating market and technical uncertainties in economic evaluations of petroleum development

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Petroleum Science 2009年第3期6卷 319-326页

作者： Changhyup Park Joe M. Kang Taewoong Ahn BK21 Research division for energy Resources Seoul National University division of energy systems Engineering Seoul National University

The paper presents a stochastic and economic analysis for petroleum development under uncertain market and technical environments. Mean-reversion with jumps for price forecasting is used to consider market uncertainty, while various scenarios for the reservoir properties and cost are employed to consider technical uncertainty. Monte Carlo simulation is carried out to obtain the feasible range of net present values and internal rates of return. The influence of stochastic parameters is examined through correlation coefficients. The stochastic approach yields more reliable evaluation and effectively investigates the characteristics of development. The integration of uncertainties and contractual terms results in an irregular tendency in the future cash flow and reveals that a larger reserve does not guarantee a greater profit. The reserve and the well rate affect the economic values whereas the parameters for price prediction don＇t. The research confirms the necessity of qualifying uncertainties for realistic decision-making at the initial stage of development.

关键词： Uncertainty petroleum development decision-making stochastic approach mean reversion with jumps

Iterative static modeling of channelized reservoirs using history-matched facies probability data and rejection of training image

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Petroleum Science 2019年第1期16卷 127-147页

作者： Kyungbook Lee Sungil Kim Jonggeun Choe Baehyun Min Hyun Suk Lee Petroleum and Marine Research division Korea Institute of Geoscience and Mineral Resources Department of Climate and energy systems Engineering Division of Sustainable Systems Engineering Ewha Womans University Department of energy systems Engineering Seoul National University

Most inverse reservoir modeling techniques require many forward simulations, and the posterior models cannot preserve geological features of prior models. This study proposes an iterative static modeling approach that utilizes dynamic data for rejecting an unsuitable training image(TI) among a set of TI candidates and for synthesizing history-matched pseudo-soft data. The proposed method is applied to two cases of channelized reservoirs, which have uncertainty in channel geometry such as direction, amplitude, and width. Distance-based clustering is applied to the initial models in total to select the qualified models efficiently. The mean of the qualified models is employed as a history-matched facies probability map in the next iteration of static models. Also, the most plausible TI is determined among TI candidates by rejecting other TIs during the iteration. The posterior models of the proposed method outperform updated models of ensemble Kalman filter(EnKF) and ensemble smoother(ES) because they describe the true facies connectivity with bimodal distribution and predict oil and water production with a reasonable range of uncertainty. In terms of simulation time, it requires 30 times of forward simulation in history matching, while the EnKF and ES need 9000 times and 200 times, respectively.

关键词： History-matched facies probability map Training image rejection Iterative static modeling Channelized reservoirs Multiple-point statistics History matching

Influence of tribofilm on superlubricity of highly-hydrogenated amorphous carbon films in inert gaseous environments

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Science China(Technological Sciences) 2016年第12期59卷 1795-1803页

作者： LIU ShuWei ZHANG ChenHui OSMAN Eryilmaz CHEN XinChun MA TianBao HU YanZhong LUO JianBin ALI Erdemir State Key Laboratory of Tribology Tsinghua University energy systems division Argonne National Laboratory

In this study,we mainly focus on the structural morphology and inter-atomic bonding state of tribofilms resulting from a highly-hydrogenated amorphous carbon(a-C:H) film in order to ascertain the underlying mechanisms for its superlubric behavior(i.e.,less than 0.01 friction coefficient).Specifically,we achieved superlubricity(i.e.,friction coefficients of down to 0.003) with this film in dry nitrogen and argon atmospheres especially when the tribo-pair is made of an a-C:H coated Si disk sliding against an a-C:H coated steel ball,while the a-C:H coated disk against uncoated ball does not provide *** also found that the state of superlubricity is more stable in argon than in nitrogen and the formation of a smooth and uniformly-thick carbonaceous tribofilm appears to be one of the key factors for the realization of such ***,the interfacial morphology of sliding test pairs and the atomic-scale bond structure of the carbon-based tribofilms also play an important role in the observed superlubric behavior of a-C:H *** Raman spectroscopy and high resolution transmission electron microscopy,we have compared the structural differences of the tribofilms produced on bare and a-C:H coated steel *** the a-C:H coated ball as mating material which provided superlow friction in argon,structural morphology of the tribofilm was similar or comparable to that of the original a-C:H coating;while for the bare steel ball,the sp^2-bonded C fraction in the tribofilm increased and a fingerprint-like nanocrystalline structure was detected by high resolution transmission electron microscopy(HRTEM).We also calculated the shear stresses for different tribofilms,and established a relationship between the magnitude of the shear stresses and the extent of sp^3-sp^2 phase transformation.

关键词： diamond-like carbon(DLC) films superlubricty tribofilm high resolution transmission electron microscopy(HRTEM) phase transformation

Investigation of drying characteristics of low rank coal of bubbling fluidization through experiment using lab scale

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Science China(Technological Sciences) 2011年第7期54卷 1680-1683页

作者： DoMan JEON TaeJin KANG HyungTaek KIM SiHyun LEE SangDo KIM division of energy systems Research Ajou University Korea Institute of energy Research DaeJeon Republic of Korea

Lignite is a low rank coal which is evenly distributed throughout the world and accounts for 45% of the total coal reserves. As it has a higher moisture content, its moisture content must be reduced in order to utilize it in power plant. In the present work, experiments on lignite has been done using a lab scale fluidized-bed reactor. Drying lignite through fluidized-bed reactor has a higher drying rate because there is good contact between particles and gas in the fluidized-bed reactor. Fluidized-bed drying can use air of 1.5 times of the minimum fluidizing velocity performance at bubbling fluidized-bed. Experiments have been performed on coal particle sizes of 0.3-1 mm, 1-1.18 mm and 1.18-2.8 mm, with operating temperatures being 100℃, 125℃ and 150℃, respectively. It is found that fluidization has a higher drying rate due to the heat transfer rate through air velocity. Hence, moisture content in lignite can be dried to a desired value with a time interval of 10 rain. The experiment through fluidized-bed reactor is expected to be useful for saving money and time.

关键词： low rank coal moisture content minimum fluidizing velocity bubbling fluidized-bed

Optical enhancement effects of plasmonic nanostructures on organic photovoltaic cells

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Chinese Chemical Letters 2015年第4期26卷 419-425页

作者： Hui Joon Park L.Jay Guo division of energy systems Research Ajou University Department of Electrical Engineering and Computer Science University of Michigan

In this article, the optical enhancement effects of plasmonic nanostructures on OPV cells were reviewed as an effective way to resolve the mismatch problems between the short exciton diffusion length in organic semiconductors （around 10 nm） and the large thickness required to fully absorb sunlight （e.g. hundreds of nanometers）. Especially, the performances of OPVs with plasmonic nanoparticles in photoactive and buffer layers and with periodic nanostructures were investigated. Furthermore, nanoimprint lithography-based nanofabrication processes that can easily control the dimension and uniformity of structures for large-area and uniform I^lasmonic nanostructures were demonstrated.

关键词： Organic photovoltaicPlasmonic nanostructureNanoparticleNanogratingNanoimprint lithography