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Journal of Earth science 2024年第1期35卷 131-143页

作者： Dan Wang Youpu Dong Zhipeng Xi Dongyue Zhang Jiaxin Duan Huayu Yu Liang Yu Faculty of land resource Engineering Kunming University of Science and TechnologyKunming 650093China

The Gengma-Lancang-Menghai seismic belt,the southernmost part of the North-South seismic belt,is controlled by four active faults:the Nantinghe fault(NTHF),the Sanjianshan fault(SJSF),the Hanmuba-Lancang fault(HMB-LCF),and the Heihe fault(HHF),from northwest to ***,the tectonic activity of the faults in the Gengma-Lancang-Menghai seismic belt has not been fully studied *** the present work,we conducted tectonic geomorphic indices to analyze the relative tectonic activity along the faults in the seismic belt based on the digital elevation *** interpreted asymmetric factor,index of drainage basin shape,hypsometric integral,normalized streamlength gradient,valley floor-to-width to height ratio,and longitudinal profiles to show that the relative tectonic activity is higher in the north and lower in the south,and is strong in the region from Shanjia to Huimin in the center of the seismic belt.

关键词： Gengma-Lancang-Menghai seismic belt southeastern Tibetan Plateau geomorphic indices longitudinal profile

Review of the research on the development and utilization of clay-type lithium resources

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Particuology 2024年第4期87卷 46-53页

作者： Ruiqi Xie Zhihui Zhao Xiong Tong Xian Xie Qiang Song Peiqiang Fan Faculty of land resource Engineering Kunming University of Science and TechnologyKunming650093China Yunnan Engineering Research Center for Metal Tailings resource Utilization Kunming650093China

Since the demands for lithium have been in explosive growth recently and several great clay lithium resources were founded in China,the development and utilization of clay-type lithium resources become a hot *** order to provide a guidance for the concentration and extracting lithium of clay-type lithium resources,this review systematically summarized the main types and characteristics of clay-type lithium resources and the research status of lithium extraction from clay lithium ***,the flotation research status of the main mineral of clay lithium ore was also ***,we discussed the difficulties in the development and utilization of clay-type lithium ore and put forward the subsequent research *** paper can provide a guidance for the con-centration and extracting lithium of clay-type lithium resources in the future.

关键词： Clay lithium Clay mineral flotation Lithium extraction Leaching

Thermodynamic theory of flotation for a complex multiphase solid -liquid system and high-entropy flotation

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International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1177-1197页

作者： Shuming Wen State Key Laboratory of Complex Nonferrous Metal resources Clean Utilization Faculty of Land Resource EngineeringKunming University of Science and TechnologyKunming 650093China

The flotation of complex solid–liquid multiphase systems involve interactions among multiple components,the core problem facing flotation ***,the combined use of multicomponent flotation reagents to improve mineral flotation has become an important issue in studies on the efficient use of refractory mineral ***,studying the flotation of complex solid–liquid systems is extremely difficult,and no systematic theory has been developed to *** addition,the physical mechanism associated with combining reagents to improve the flotation effect has not been unified,which limits the development of flotation theory and the progress of flotation *** this study,we applied theoretical thermodynamics to a solid–liquid flotation system and used changes in the entropy and Gibbs free energy of the reagents adsorbed on the mineral surface to establish thermodynamic equilibrium equations that de-scribe interactions among various material components while also introducing adsorption equilibrium constants for the flotation reagents adsorbed on the mineral *** homogenization effect on the mineral surface in pulp solution was determined using the chemical potentials of the material components of the various mineral surfaces required to maintain *** flotation effect can be improved through synergy among multicomponent flotation reagents;its physical essence is the thermodynamic law that as the number of compon-ents of flotation reagents on the mineral surface increases,the surface adsorption entropy change increases,and the Gibbs free energy change of adsorption *** to the results obtained using flotation thermodynamics theory,we established high-entropy flotation theory and a technical method in which increasing the types of flotation reagents adsorbed on the mineral surface,increasing the adsorption entropy change of the flotation reagents,decreasing the Gibbs free energy change,and improving the adsorption efficiency

关键词： multicomponent flotation reagent adsorption entropy change equations of thermodynamic equilibrium adsorption equilibri-um constant high-entropy flotation

Uplift of the central part of the Jinsha River， southeastern Tibetan Plateau: Evidence from apatite fission track dating and bedrock channel longitudinal profiles

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Journal of Earth science 2024年

作者： Yangyang Ren Youpu Dong Wenchang Li Faculty of land resource Engineering Kunming University of science and Technology

The initial timing of uplift at the southeastern margin of the Tibetan Plateau (SMTP) remain under debate， with estimates ranging from the Eocene， to the Oligocene. The Jinsha River was formed before the Miocene， therefore， it is likely to record the uplift information of the Tibetan Plateau， which is important for understanding the tectonic uplift of the SMTP. Here， we collected granite samples from the Yangla area in the middle part of the Jinsha River， and analyzed the uplift characteristics of the Cenozoic in the middle part of the Jinsha River by using the apatite fission tracks and the river longitudinal profiles. We show shat the uplift time of the first phase is about 25–20 Ma， and the uplift time of the second phase is about 5 Ma; From the channel profile， seven tributaries of the Jinsha Rivers also have developed two phase of knickpoints. The tributaries consist of three sections with distinct geomorphological parameters， each separated by knickpoints. We argue that large-scale uplift occurred in the Late Cenozoic on the SMTP， with different locations having different uplift times， and the interior may have undergone significant uplift in the Early Oligocene， but significant uplift of the SMTP occurred by the Late Oligocene to Early Miocene. The Jinsha River flowing from the interior of the plateau have developed multiple knick points during the uplift process， recording information of the uplift of the Tibetan Plateau.

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Coupling Coordination Analysis of Cropland Intensification and Agroecosystem Services:Evidence from Loess Plateau in Shaanxi Province,China

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Chinese Geographical science 2024年第3期34卷 401-419页

作者： FU Shaowu FU Mengyu QIU Menglong Center for land resource Research in Northwest China Shaanxi Normal UniversityXi’an 710119China

One of the greatest challenges in the agroecosystem is to improve cropland intensification while preserving agroecosystem *** many studies have investigated the effect of cropland intensification on agroecosystem service,the interactive coupling and coordination among these factors remain largely *** view of this,this study performed a case study of the Loess Plateau in Shaanxi Province,China and constructed comprehensive evaluation models to quantify the cropland intensification and agroecosystem service in this *** analysis and the coupling coordination degree model were used to evaluate the interactive relationship between cropland intensification and agroecosystem service,and statistical analysis and spatial autocorrelation were used to analyze the spatial characteristics and potential mechanism of the coupling *** show that both the cropland intensification and agroecosystem service in the study area were relatively low yet gradually increased from 2000 to *** service lag was identified as the dominant unbalanced development *** the supply capacity of agroecosystem services plays a key role in the balanced development of cropland in the Loess *** coupling coordination degree between cropland intensification and agroecosystem service ranges from basic coordination to serious ***,cropland intensification practices in the area should be optimized to enhance this coordination *** upward trend was also observed in the coupling coordination degree from2000 to *** withdrawal of marginal cropland in the Grain for Green program is one of the most important reasons for this trend,especially for the northern *** 83.6%of the high-high clusters are concentrated in the southern region of the Loess Plateau,whereas 70.5%of the low-low clusters are distributed in the northern *** clustering characteristics are mainly attributed to the environmental

关键词： cropland intensification agroecosystem services balance analysis coupling coordination degree Loess Plateau,China

Preparation and interface state of phosphate tailing-based geopolymers

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Journal of Central South University 2024年第6期31卷 1900-1914页

作者： ZHANG Shou-xun XIE Xian XIE Rui-qi TONG Xiong WU Yu-yao LI Jia-wen LI Yue Faculty of land resource Engineering Kunming University of Science and TechnologyKunming 650093China National&Regional Engineering Research Center for Green Comprehensive Utilization of Gangue resources from Metal Mine Kunming 650093China

The long-term storage of phosphate tailings will occupy a large amount of land,pollute soil and groundwater,thus,it is crucial to achieve the harmless disposal of phosphate *** this study,high-performance geopolymers with compressive strength of 38.8 MPa were prepared by using phosphate tailings as the main raw material,fly ash as the active silicon-aluminum material,and water glass as the alkaline *** solid content of phosphate tailings and fly ash was 60% and 40%,respectively,and the water-cement ratio was *** results of XRD,FTIR,SEM-EDS and XPS show that the reactivity of phosphate tailings with alkaline activator is weak,and the silicon-aluminum material can react with alkaline activator to form zeolite and gel,and encapsulate/cover the phosphate tailings to form a dense phosphate tailings-based *** the formation of geopolymers,part of the aluminum-oxygen tetrahedron replaced the silicon-oxygen tetrahedron,causing the polycondensation reaction between geopolymers and increasing the strength of *** leaching toxicity test results show that the geopolymer has a good solid sealing effect on heavy metal *** preparation of geopolymer from phosphate tailings is an important way to alleviate the storage pressure and realize the resource utilization of phosphate tailings.

关键词： phosphate tailing geopolymer interface state toxicity leaching

Advances in depressants for flotation separation of Cu–Fe sulfide minerals at low alkalinity:A critical review

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International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 1-17页

作者： Qicheng Feng Wenhang Yang Maohan Chang Shuming Wen Dianwen Liu Guang Han State Key Laboratory of Complex Nonferrous Metal resources Clean Utilization Faculty of Land Resource EngineeringKunming University of Science and TechnologyKunming 650093China Yunnan Key Laboratory of Green Separation and Enrichment of Strategic Mineral resources Kunming University of Science and TechnologyKunming 650093China

The flotation separation of Cu–Fe sulfide minerals at low alkalinity can be achieved using selective *** the flotation system of Cu–Fe sulfide minerals,depressants usually preferentially interact with the pyrite surface to render the mineral surface hydrophilic and hinder the adsorption of the *** review summarizes the advances in depressants for the flotation separation of Cu–Fe sulfide minerals at low *** advances include use of inorganic depressants (oxidants and sulfur–oxygen compounds),natural polysaccharides (starch,dextrin,konjac glucomannan,and galactomannan),modified polymers (carboxymethyl cellulose,polyacrylamide,lignosulfonate,and tricarboxylate sodium starch),organic acids (polyglutamic acid,sodium humate,tannic acid,pyrogallic acid,salicylic acid,and lactic acid),sodium dimethyl dithiocarbamate,and *** potential application of specific inorganic and organic depressants in the flotation separation of Cu–Fe sulfide minerals at low alkalinity is *** advances in the use of organic depressants with respect to the flotation separation of Cu–Fe sulfide minerals are comprehensively ***,the depression performances and mechanisms of different types of organic depressants on mineral surfaces are ***,several perspectives on depressants vis-à-vis flotation separation of Cu–Fe sulfide minerals at low alkalinity are proposed.

关键词： Cu–Fe sulfide minerals flotation separation selective depressants depression mechanism

Retrospective and prospective review of the generalized nonlinear strength theory for geomaterials

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International Journal of Minerals,Metallurgy and Materials 2024年第8期31卷 1767-1787页

作者： Shunchuan Wu Jiaxin Wang Shihuai Zhang Shigui Huang Lei Xia Qianping Zhao Faculty of land resource Engineering Kunming University of Science and TechnologyKunming 650093China Key Laboratory of Geohazard Forecast and Geoecological Restoration in Plateau Mountainous Area MNRKunming 650093China Yunnan Key Laboratory of Geohazard Forecast and Geoecological Restoration in Plateau Mountainous Area Kunming 650093China School of Earth and Space sciences University of Science and Technology of ChinaHefei 230026China School of Civil and resource Engineering University of Science and Technology BeijingBeijing 100083China

Strength theory is the basic theory for calculating and designing the strength of engineering materials in civil,hydraulic,mechanical,aerospace,military,and other engineering ***,the comprehensive study of the generalized nonlinear strength theory(GNST)of geomaterials has significance for the construction of engineering rock *** paper reviews the GNST of geomaterials to demonstrate the research status of nonlinear strength characteristics of geomaterials under complex stress ***,it systematically summarizes the research progress of GNST(classical and empirical criteria).Then,the latest research the authors conducted over the past five years on the GNST is introduced,and a generalized three-dimensional(3D)nonlinear Hoek‒Brown(HB)criterion(NGHB criterion)is proposed for practical *** criterion can be degenerated into the existing three modified HB criteria and has a better prediction *** strength prediction errors for six rocks and two in-situ rock masses are 2.0724%-3.5091%and 1.0144%-3.2321%,***,the development and outlook of the GNST are expounded,and a new topic about the building strength index of rock mass and determining the strength of in-situ engineering rock mass is *** summarization of the GNST provides theoretical traceability and optimization for constructing in-situ engineering rock mass strength.

关键词： rock mechanics rock mass strength strength theory failure criterion Hoek-Brown criterion intermediate principal stress deviatoric plane smoothness and convexity

Sliding behaviors of the trapezoidal roof rock block under a lateral dynamic disturbance

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第3期16卷 741-760页

作者： Feng Dai Wancheng Zhu Min Ren Shunchuan Wu Leilei Niu Faculty of land resources Engineering Kunming University of Science and TechnologyKunming650093China Center for Rock Instability and Seismicity Research Department of Mining EngineeringSchool of Resource and Civil EngineeringNortheastern UniversityShenyang110819China

The surrounding rock of underground space is always affected by external dynamic disturbance from the side position,such as blasting vibration from a stope at the same level or seismic waves from adjacent strata.A series of laboratory tests,numerical simulations and theoretical analyses were carried out in this study to disclose the sliding mechanism of roof rock blocks under lateral ***,the experiments on trapezoidal key block under various clamping loads and disturbance were conducted,followed by numerical simulations using the fast Lagrangian analysis of continua(FLAC3D).Then,based on the conventional wave propagation model and the classical shear-slip constitutive model,a theoretical model was proposed to capture the relative displacement between blocks and the sliding displacement of the key *** results indicate that the sliding displacement of the key block increased linearly with the disturbance energy and decreased exponentially with the clamping load when the key block was disturbed to slide(without instability).Meanwhile,when the key block was disturbed to fall,two types of instability process may appear as immediate type or delayed *** addition,the propagation of stress waves in the block system exhibited obvious low-velocity and lowfrequency characteristics,resulting in the friction reduction effect appearing at the contact interface,which is the essential reason for the sliding of rock *** results can be applied to practical underground engineering and provide valuable guidance for the early detection and prevention of rockfalling disasters.

关键词： Lateral dynamic disturbance Trapezoidal rock block system Low-velocity and low-frequency wave Friction reduction effect Instability mode

Mechanistic insights into stepwise activation of malachite for enhancing surface reactivity and flotation performance

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International Journal of Minerals,Metallurgy and Materials 2024年第10期31卷 2159-2172页

作者： Qicheng Feng Wanming Lu Han Wang Qian Zhang State Key Laboratory of Complex Nonferrous Metal resources Clean Utilization Faculty of Land Resource EngineeringKunming University of Science and TechnologyKunming 650093China Yunnan Key Laboratory of Green Separation and Enrichment of Strategic Mineral resources Kunming University of Science and TechnologyKunming 650093China

Malachite is a common copper oxide mineral that is often enriched using the sulfidization-xanthate flotation ***,the direct sulfidization method cannot yield copper concentrate ***,a new sulfidization flotation process was developed to promote the efficient recovery of *** this study,Cu^(2+)was used as an activator to interact with the sample surface and increase its reaction sites,thereby strengthening the mineral sulfidization process and *** to single copper ion activation,the flota-tion effect of malachite significantly increased after stepwise Cu^(2+)*** potential,X-ray photoelectron spectroscopy(XPS),time-of-flight secondary ion mass spectroscopy(ToF-SIMS),scanning electron microscopy and energy dispersive spectrometry(SEM-EDS),and atomic force microscopy(AFM)analysis results indicated that the adsorption of S species was significantly enhanced on the mineral surface due to the increase in active Cu sites after Cu^(2+)stepwise ***,the proportion of active Cu-S spe-cies also increased,further improving the reaction between the sample surface and subsequent ***-transform infrared spec-troscopy(FT-IR)and contact angle tests implied that the xanthate species were easily and stably adsorbed onto the mineral surface after Cu^(2+)stepwise activation,thereby improving the hydrophobicity of the mineral ***,the copper sites on the malachite sur-face after Cu^(2+)stepwise activation promote the reactivity of the mineral surface and enhance sulfidization flotation of malachite.

关键词： malachite copper ions stepwise activation flotation mechanism enhanced sulfidization