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Effect of a Carbon Fibre-steel Fibre-graphite Conductive Filler on the Electrothermal Properties of Cementitious Materials

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期 141-151页

作者：樊亚男 WEI Hong ZHENG Hongyong DU Hongxiu department.of architecture and Environmental Engineering Taiyuan University College of Civil Engineering Taiyuan University of Technology

Carbon fibre,steel fibre and graphite were used as conductive fillers to prepare cementitious materials with excellent electrothermal *** electrically conductive cementitious materials with different volume dosages were analysed through compressive and flexural strength,electrochemical impedance spectroscopy and temperature rise *** equivalent circuit model was established to study the electrically conductive heat generation mechanism in the electrically conductive cementitious *** results indicate that the mechanical properties of cementitious composite materials with a ternary conductive phase are better than those of pristine cementitious materials because the fibrous filler improves their mechanical ***,the incorporation of graphite in the material reduces its *** fibrous and point-like conductive phase materials into the cementitious material enhances the overall conductive pathway and considerably reduces the electrical resistance of the cementitious material,enhancing its conductive *** volume ratios of carbon fibre,steel fibre and graphite that achieve an optimal complex doping in the cementitious material were 0.35%,0.6% and 6%,*** was determined using the mutation point of each circuit element parameter as the percolation *** addition,at a certain safety voltage,there is a uniform change between the internal and surface temperatures of the conductive cementitious material,and the heating effect in this materialis is considerably better than that in the pristine cementitious material.

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Maximizing biomass utilization: An integrated strategy for coproducing multiple chemicals

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Journal of Energy Chemistry 2025年第1期100卷 180-191页

作者： Byeongchan Ahn Sua Jo Jonggeol Na J.Jay Liu Young-Ju Kim Wangyun Won department.of Chemical and Biological Engineering Korea University department.of Chemical Engineering (Integrated process) Kyung Hee University department.of Chemical Engineering and Materials Science Ewha Womans University department.of Chemical Engineering Pukyong National University Resources Engineering Plant Research department Korea Institute of Geoscience and Mineral Resources

Lignocellulosic biomass is one of the viable solutions to alleviate the global warming. However, the limited utilization of biomass majorly focused on cellulose and hemicellulose restricts the economic and environmental feasibilities. To cope with this issue, we proposed an integrated process of co-producing 1,6-hexanediol（1,6-HDO） with tetrahydrofuran and adipic acid from biomass, referred to as Strategy A. To compare the impacts of lignin upgrading and feedstock, Strategy B, which co-produces tetrahydrofuran alone, and Strategy C, which is the traditional route to produce 1,6-HDO from fossil fuels, were used. Heat networks are also designed to reduce operating costs and indirect carbon emissions due to energy consumption, saving 87% and 83% of the heat and cooling requirements, respectively, in Strategy A. The market competitiveness of Strategy A was evaluated by determining the minimum selling price through techno-economic analysis, and sustainability was thoroughly investigated by quantifying the environmental impacts through both midpoint and endpoint life-cycle assessments（LCAs）.Strategy A was found to be the most favorable both economically（USRDSCHARDOLLAR3,402/ton） and environmentally（-26.9 kg CO2eq.）. This indicates that lignin valorization is not only economically but also environmentally preferred. Finally, changes in economic and environmental feasibilities depending on economic, process, and environmental parameters were investigated using sensitivity and uncertainty analyses. The results of these analyses provide valuable insight into bio-based chemical production.

关键词： Biorefinery Carbon mitigation Climate change Global warming Lignin utilization Bioeconomy

Synthesis and Crystal Structure of 1,3-Trans-1,4-cis- 3,4-di(4-bromophenyl)-1',2',3'-trihydro-1-hydroxy- benzo[g]bicyclo[3.3]octane-2-spiro-2'-indene-1'-one

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Chinese Journal of Structural Chemistry 2006年第2期25卷 187-191页

作者： SHI Da-Qing LI Zheng-Yi SHI Chun-Ling DOU Guo-Lan department.of Chemistry Xuzhou Normal University Xuzhou Jiangsu 221116 China Key Laboratory of Biotechnology on Medical Plants of Jiangsu Province Xuzhou 221116 China

The title compound C35H30Br2O3 （C32H24Br2O2·CH3COCH3） has been synthesized by the dimerization of 2-（4＇-bromobenzal）-1-indenone induced by low-valent titanium reagent, and characterized by elemental analysis, IR,^1H NMR and X-ray single-crystal diffraction. The crystal belongs to triclinic, space group P1^- with a = 10.273（7）, b = 11.036（7）, c = 13.944（9） ,A°, a = 73.972（9）, β =76.577（10）,γ= 88.871（10）°, V = 1476.3（17）A°^3, Mr = 658.41, Z = 2, Dr = 1.481 g/cm^3, μ（MoKa） = 2.780 mm^-1, F（000） = 668, the final R = 0.0452 and wR = 0.0975. X-ray analysis reveals that the two cyclopentane rings spiro-fused each other adopt envelope conformations, while the other cyclopentane ring （C（1）--C（2）-C（7）-C（9）） is coplanar. In addition, there is a classical intermolecular hydrogen bond O（1）-H（1）...O（2） connecting the adjacent molecules into dimers.

关键词： benzo[g]bicyclo[3.3]octane-2-spiro-2'-indene-1'-one synthesis crystal structure,low-valent titanium

Status and prospects for symmetric organic redox flow batteries

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Journal of Energy Chemistry 2025年第1期100卷 125-143页

作者： Md Al Raihan C.Adam Dyker department.of Chemistry University of New Brunswick

As environmental concerns from fossil fuel consumption intensify, large-scale energy storage becomes imperative for the integration of renewable sources like wind, hydro, and solar with the electrical *** flow batteries, particularly those employing organic molecules, are positioned as a key technology for this purpose. This review explores the growing field of symmetric organic redox flow batteries(ORFBs) within this context. Unlike traditional asymmetric designs based on unique active materials for each electrode, symmetric ORFBs involve a single bipolar species for both electrodes. This review highlights the benefits of a symmetric design, and categorizes five distinct classes of organic bipolar molecules used in both aqueous and non-aqueous solvents. By providing a comprehensive overview of their cell cycling and performance characteristics, the strengths and weaknesses of the diverse categories of bipolar molecules are highlighted for both solvent systems, as are opportunities for future development. This should guide new research directions and advance the development of practical symmetric ORFBs.

关键词： Redox flow battery Symmetric battery Organic battery Aqueous electrolyte Non-aqueous electrolyte

Topology optimization of supporting structure for seismic response reduction of an arch

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Science China(Technological Sciences) 2016年第6期59卷 852-861页

作者： MIYAZU Yuji OHSAKI Makoto TSUDA Seita department.of architecture Hiroshima University department.of architecture and Architectural Engineering Kyoto University department.of Design and Technology Okayama Prefectural University

A flexible supporting structure that reduces seismic response of an arch is proposed. Topology and cross-sectional areas of the supporting structure modeled as a truss structure are optimized through two steps of static and dynamic optimization problems. In the first step, a flexible supporting structure that has diagonal displacement at the top under horizontal load is obtained by solving static optimization problems. Then, in the second step, the cross-sectional area of the flexible member is optimized to minimize the seismic response acceleration of the arch evaluated by the complete quadratic combination(CQC) method. Time-history seismic response analysis is carried out to show that the response in the normal direction of the roof successfully decreases due to flexibility of the supporting structure; in addition, installing passive energy dissipation devices into the flexible supporting structure is very effective in reducing the tangential response of the arch.

关键词： topology optimization arch supporting structure truss nonlinear programming problem CQC method

Study on constructive system of green cave dwelling in Loess Plateau—Interpretation with the “regional gene” theory

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2007年第11期8卷 1754-1761页

作者： WANG Zhu WEI Qin HE Yong department.of architecture Zhejiang University Hangzhou 310058 China department.of architecture Shanghai University Shanghai 200444 China

This article reveals the inherent evolution adjusting mechanism of regional architecture by means of considering the concept and method of "regional gene" as the research approach of regional architecture construction system, and in the mean- while establishes the "gene database" of regional architecture and optimum technology, on the basis of the principle of sustainable development and scientific evaluation system. In addition, this article chooses the planning of model villages of cave dwellings in Loess Plateau and the construction of ecological cave dwellings for case study to prove the feasibility of the research approach.

关键词： Regional architecture construction system Regional gene Primordial cave dwellings Green cave dwelling Sus tainable development

Recent TCP(Tidal Current Power) projects in Korea

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Science China(Technological Sciences) 2010年第1期53卷 57-61页

作者： Chul Hee JO Kang Hee LEE Yu Ho RHO School of Engineering Inha University253Yonghyun-DongNam-GuIncheon 402-751Republic of Korea Graduate School Department.of Naval Architecture & Ocean EngineeringInha University253Yonghyun-DongNam-GuIncheon 402-751Republic of Korea

Having strong current on the west coast with up to 10 m tidal range in Korea,there are many suitable and applicable locations for TCP(Tidal Current Power) application in *** only the west coast,but also the south west regions having narrow channels between islands creating fast ocean stream are suitable for *** first TCP application in Korea is 1 MW helical VAT(Vertical Axis Turbine) device installed in Wooldolmog area in *** first HAT(Horizontal Axis Turbine) TCP device of 25 KW was developed and installed in cooling water weir of Samchonpo power plant in ***,a 100 kW prototype HAT TCP device is being planned to be installed in Daebang strait in *** big project would be Inchon TCP farm of 200 MW on the west coast in *** consortium of 5 members was formed in April,*** site will be the largest TCP site in the *** paper describes recent TCP projects in Korea with background and environmental conditions of the projects.

关键词： TCP(Tidal Current Power) ocean energy renewable energy clean energy HAT(Horizontal Axis Turbine) VAT(Vertical Axis Turbine)

On the nonlinear transformation of breaking and non-breaking waves induced by a weakly submerged shelf

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Journal of Hydrodynamics 2018年第4期30卷 592-604页

作者： Giorgio Contento Guido Lupieri Thomas Puzzer department.of Engineering and architecture University of Trieste

The interaction of regular quasi-monochromatic waves with a weakly submerged rectangular shelf is studied by means of CFD simulations. The fundamental incident wave frequency is kept constant for the full set of simulated cases, while the incident wave amplitude is made increase progressively, so that the interaction with the shelf is dominated by almost inviscid non-linear flow for the smallest and by breaking for the highest incident waves. A parameter identification（PI） procedure is used to adapt a reduced model to the highly resolved time-space matrix of wave elevations obtained from the numerical simulations, on the weather and lee side respectively. In particular the wave number and the frequency of the component waves in the reduced model are left uncoupled, thus computed by the PI independently. The comparison of simulated data with experiments generally shows a very good agreement. Free/locked, incident/reflected, first/higher order wave components are quantified accurately by the PI and the energy transfer to super-harmonics is clearly evidenced. Moreover the results of the PI show clearly a very large increase in the phase speed of the higher order free waves on the lee side of the shelf, with increasing deviation from the linear behavior with increasing incident wave amplitude.

关键词： Nonlinear wave transformation submerged shelf wave breaking coupled space-time domain analysis reduced model parameter identification

DeepRadiation:An intelligent augmented reality platform for predicting urban energy performance just through 360 panoramic streetscape images utilizing various deep learning models

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Building Simulation 2023年第3期16卷 499-510页

作者： Ali Nakhaee Arefe Paydar department.of architecture Architecture SchoolCollege of Fine ArtsUniversity of TehranTehran ***Iran

Urban energy simulation is critical for understanding and managing energy performance in *** this research,we design a novel framework called DeepRadiation,to enable automatic urban environmental performance *** incorporating deep learning strategies,DeepRadiation predicts solar radiation on an urban scale using just panoramic streetscape images without any 3D modeling and *** York City was chosen as the case study for this *** is comprised of three different deep learning models organized into two *** first stage,named DeepRadiation modeling,serves as the framework's *** this stage,solar radiation analysis was performed using a Pix2Pix model,a type of conditional generative adversarial networks(GANs).After extracting GIS data and performing energy simulation analysis to prepare the dataset,the Pix2Pix model was trained on 10000 paired panoramic depth images of streetscapes with only building blocks and related panoramic images of streetscapes with only solar radiation *** GAN generator evaluation measures named qualitative evaluation and quantitative evaluation were used to validate the trained Pix2Pix *** demonstrated high levels of accuracy(qualitative evaluation:93%,quantitative evaluation:89%).DeepRadiation application as the DeepRadiation's sescond stage is the framework's *** this stage,two convolutional neural network(CNN)models(DeepLabv3 and MiDaS)were used to perform computer vision tasks on panoramic streetscape images,such as semantic segmentation and depth *** DeepRadiation application stage allows urban designers,architects,and urban policymakers to use the DeepRadiation framework and experience the final output via augmented reality.

关键词： automating urban energy simulation solar radiation analysis deep learning Pix2Pix computer vision augmented reality