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Pedosphere 2024年第3期34卷 631-640页

作者： Rochelle Joie SARACANLAO Hannah VAN RYCKEL Mieke VERBEECK Maarten EVERAERT Erik SMOLDERS Division of soil and water Management Department of Earth and Environmental ScienceKU LeuvenKasteelpark Arenberg 20Heverlee B-3001(Belgium) soil Service of Belgium.Willem De Croylaan 48 Leuven 3001(Belgium)

Iron(Fe)minerals are commonly used to remove phosphorus(P)from waste streams,producing P-loaded Fe(Ⅲ)oxides or Fe(Ⅱ)phosphate minerals(e.g.,vivianite).These minerals may be used as fertilizers to enhance P circularity if solubilized in soil.Here,we tested the P fertilizer value of recycled Fe phosphates(FePs)in a pot trial and in an incubation experiment,hypothesizing that P release from FePs is possible under Fe(Ⅲ)-reducing conditions.First,a pot trial was set up with rice(Oryza sativa)in all combinations of soil flooding or not,three P-deficient soils(acid,neutral,and calcareous),and six FePs(three Fe(Ⅲ)Ps and three Fe(Ⅱ)Ps)referenced to triple superphosphate(TSP)or zero amendments.Shoot P uptake responded to TSP application in all treatments but only marginally to FePs.The redox potential did not decrease to-200 mV by flooding for a brief period(13 d)during the pot trial.A longer incubation experiment(60 d)was performed,including a treatment of glutamate addition to stimulate reductive conditions,and P availability was assessed with CaCl_(2)extraction of soils.Glutamate addition and/or longer incubation lowered soil redox potential tosoil and in the neutral soil amended with Fe(Ⅲ)P-sludge.It can be concluded that prolonged soil flooding and organic matter addition can enhance the P fertilizer efficiency of FePs.Additionally,application of FeP in powder form may enhance P availability.

关键词： agronomic efficiency circular economy P-loaded Fe(Ⅲ)oxides paddy soil vivianite redox

Annual growth of Fagus orientalis is limited by spring drought conditions in Iran’s Golestan Province

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Journal of Forestry Research 2024年第1期35卷 128-142页

作者： Khalil Ghorbani Jahangir Mohammadi Laleh Rezaei Ghaleh department of water Engineering Faculty of Water and Soil EngineeringGorgan University of Agricultural Sciences and Natural ResourcesGorganIran department of Forestry Gorgan University of Agricultural Sciences and Natural ResourcesGorganIran department of water Engineering Faculty of AgricultureUrmia UniversityUrmiaIran

Due to the lack of a uniform and accurate defi-nition of‘drought’,several indicators have been introduced based on different variables and methods,and the efficiency of each of these is determined according to their relationship with drought.The relationship between two drought indices,SPI(standardized precipitation index)and SPEI(standard-ized precipitation-evapotranspiration index)in different sea-sons was investigated using annual rings of 15 tree samples to determine the effect of drought on the growth of oriental beech(Fagus orientalis Lipsky)in the Hyrcanian forests of northern Iran.The different evapotranspiration calcula-tion methods were evaluated on SPEI efficiency based on Hargreaves-Samani,Thornthwaite,and Penman-Monteith methods using the step-by-step M5 decision tree regression method.The results show that SPEI based on the Penman-Monteith in a three-month time scale(spring)had similar temporal changes and a better relationship with annual tree rings(R^(2)=0.81)at a 0.05 significant level.Abrupt change and a decreasing trend in the time series of annual tree rings are similar to the variation in the SPEI based on the Penman-Monteith method.Factors affecting evapotranspiration,temperature,wind speed,and sunshine hours(used in the Penman-Monteith method),increased but precipitation decreased.Using non-linear modeling methods,SPEI based on Penman-Monteith best illustrated climate changes affecting tree growth.

关键词： Climate change Drought index Hyrcanian forests SPEI'Annual growth rings Fagus orientalis

Runoff and Infiltration responses of revegetated slopes to clipping management on the northern Loess Plateau

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International soil and water Conservation Research 2024年第1期12卷 171-183页

作者： Qilin He Binbin Li Fengbao Zhang Nan Shen Mingyi Yang The Research Center of soil and water Conservation and Ecological Environment Chinese Academy of Sciences and Ministry of EducationYanglingShaanxi712100China Institute of soil and water Conservation Chinese Academy of Sciences and Ministry of Water ResourcesYanglingShaanxi712100China Institute of soil and water Conservation Northwest A&F UniversityYanglingShaanxi712100China water and soil Conservation Monitoring Center of Ministry of water Resources Beijing100053China University of Chinese Academy of sciences Beijing100049China

Large-scale vegetation restoration can reduce local watershed water yield,limit vegetation establishment and subsequent growth,and influence regional ecosystem functions.Clipping management by reducing aboveground parts of grassland was gradually recommended and adopted in Grain-for-Green project management to offset these additional issues.Thus,scientific evaluation of the effectiveness of clipping management on infiltration and runoff processes is necessary for maintaining the stability of the surface water system and the sustainability of vegetation restoration in semi-arid regions.A field simulated rainfall experiment was conducted with four managed clipping grasslands(mainly bunge needlegrass and Stipa grandis),including no clipping,light clipping,heavy clipping,and complete clipping under three slope gradients(10,20,and 30°)and three rainfall intensities(60,90,and 120 mm/h)to explore the mechanism of runoff and infiltration responses to clipping using structural equation modeling and variation partitioning based on an SCS-CN model.The results showed the runoff coefficient of the light clipping,heavy clipping,and complete clipping plots were 1.33,2.22,and 4.22 times that of the no clipping plot.The light clipping,heavy clipping,and complete clipping plots decreased the infiltration coefficients by 0%,5%,and 26%relative to the no clipping plot.Rainfall intensity dominated runoff and infiltration amounts,and clipping intensity's total effect was stronger than slope gradient.Clipping intensity and slope gradient were more influential on runoff with increasing rainfall intensity.The mutual inhibition effect was between clipping intensity and slope gradient on runoff.In order to maintain the sustainability of restoration,a 25-50%vegetation coverage after clipping maximizes the benefits of increasing runoff and maintaining enough soil water supply that prevents possible soil drought.We propose that future vegetation restoration policies should evaluate the appropriate clipping intensity;meanwhile,local physiograph

关键词： Runoff Infiltration Grassland clipping management SCS-CN model Structural equation model Variation partitioning

Long-term fertilizer nitrogen management—soil health conundrum

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Pedosphere 2024年第1期34卷 23-25页

作者： BIJAY-SINGH department of soil science Punjab Agricultural UniversityLudhiana 141004India

The mental model that fertilizer nitrogen (N) acts as a replacement for N mineralized from soil organic matter (SOM) needs to be revisited. soil organic matter, the storehouse of N in soil, is one of the most important indicators of soil health. It supplies more N to crop plants than the current-year fertilizer N even when applied at high rates. Limited research shows that the application of fertilizer N above the optimum levels on a long-term basis deteriorates soil health by mineralizing SOM and depleting the soil N pool. Because soil N includes portions of fertilizer N applied in several previous years, year after year application of fertilizer N below the optimum levels will also lead to a gradual decline in soil N pool or soil health. To sustain high crop yield levels, fertilizer N needs to be applied on a long-term basis neither above nor below the optimum levels to ensure that soil health in terms of sustaining supply of soil N is maintained, if not enhanced.

关键词： soil soil optimum

Promotion effects of salt-alkali on ammonia volatilization in a coastal soil

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Pedosphere 2024年第1期34卷 191-199页

作者： Zhenqi SHI Dongli SHE Yongchun PAN Yongqiu XIA College of Agricultural science and Engineering Hohai UniversityNanjing 210098China Jiangsu Province Engineering Research Center for Agricultural soil-water Efficient Utilization Carbon Sequestration and Emission ReductionNanjing 210098China Key Laboratory of soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China

Coastal ecosystems are highly susceptible to salt-related problems due to their formation process and geographical location. As such ecosystems are the most accessible land resources on Earth, clarifying and quantifying the effects of salt-alkali conditions on N concentration and ammonia(NH_(3)) volatilization are pivotal for promoting coastal agricultural productivity. The challenge in establishing this effect is to determine how salt-alkali conditions impact NH_(3) volatilization through direct or indirect interactions. An incubation experiment using a coastal soil from a paddy farmland, combined with the structural equation modeling(SEM) method, was conducted to reveal the net effects of salt-alkali on NH_(3) volatilization and the role of environmental and microbial factors in mutual interaction networks. The specific experimental design consisted of four salt treatments(S1, S2, S3, and S4: 1‰, 3‰, 8‰, and 15‰ NaCl by mass of soil, respectively), four alkaline treatments(A1, A2, A3, and A4: 0.5‰, 1‰, 3‰, and 8‰ NaHCO_(3)by mass of soil, respectively) and a control without NaCl or NaHCO_(3) addition(CK), and each treatment had three urea concentrations(N1, N2, and N3: 0.05, 0.10, and 0.15 g N kg^(-1) soil,respectively) and three replicates. At the N1, N2, and N3 levels, NH_(3)volatilization increased by 9.31%–34.98%, 3.07%–26.92%, and 2.99%–43.61% as the NaCl concentration increased from 1‰ to 15‰, respectively, compared with CK. With an increase in the NaHCO_(3)concentration from 0.5‰ to 8‰, NH_(3) volatilization increased by 8.36%–56.46%, 5.49%–30.10%, and 30.72%–73.18% at the N1, N2, and N3 levels, respectively, compared with CK. According to the SEM method, salinity and alkalinity had positive direct effects on NH_(3)volatilization, with standardized path coefficients of 0.40 and 0.19, respectively.Considering the total effects(net positive and negative effects) in the SEM results, alkalinity had a greater influence than salinity(total standardized coefficient0.104 > 0.086). Nitrogen concentrations in the

关键词： alkalinity coastal ecosystem NH_(3)emission N-transforming microbe salinity structural equation modeling

soil type and wetting intensity control the enhancement extent of N_(2)O efflux in soil with drought and rewetting cycles

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International soil and water Conservation Research 2024年第1期12卷 137-144页

作者： Panpan Jiao Lei Yang Zhongwu Li Peng Zheng Xiaodong Nie School of Geographical sciences Hunan Normal UniversityChangsha 410081China State Key Laboratory of soil Erosion and Dryland Farming on the Loess Plateau The Research Center of Soil and Water Conservation and Ecological EnvironmentChinese Academy of Sciences and Ministry of EducationYangling 712100China Institute of soil and water Conservation Chinese Academy of Sciences and Ministry of Water ResourcesYangling 712100China University of Chinese Academy of sciences Beijing 100049China Key Laboratory of soil Environment and Pollution Remediation Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China

Climate change alters the intensity and frequency of drought and rewetting(D/W)events;however,the influence patterns of D/W on soil N_(2)O efflux in the water-limited area were not fully understood.Therefore,the impacts of D/W cycles varying in different extent of rewetting and frequency to N_(2)O efflux in two kinds of soil on the Loess Plateau were investigated.The incubation conditions consisted of 1)D/W treatments with four 7-day cycles from 10%water holding capacity(WHC)to 60%WHC or 90%WHC,2)constant moisture of 60%WHC and 90%WHC.The pulse of N_(2)O efflux rate under 10-60%WHC treatment was higher than that under 10-90%WHC treatment in calcic cambisols,while opposite trend was observed in earth-cumuli-orthic anthrosols.Meanwhile,the pulse of N_(2)O efflux rate decreased as cycle number increased for different wetting intensities and soil types.The direct N_(2)O efflux under 10-60%WHC and 10-90%WHC treatments were 5.49 and 1.89μg N_(2)O-N g^(-1)soil in calcic cambisols,with those being 1.92 and 10.85μg N_(2)O-N g^(-1)soil in earth-cumuli-orthic anthrosols,respectively.The N loss in earth-cumuli-orthic anthrosols was approximately 5.74 times greater than that in calcic cambisols under 10-90%WHC treatment,whereas the N loss under 10-60%WHC treatment was about 2.86 times greater in calcic cambisols than that in earth-cumuli-orthic anthrosols.This study suggested that extreme rainfall events can enhance the N_(2)O efflux and N loss in agricultural soils on the Loess Plateau in terms of soil type and wetting intensity,which should not be ignored in the N fertilizer management.

关键词： Drought/rewetting cycles N_(2)O efflux Wetting intensity Microbial biomass N Dissolved organic N Loess plateau

A review of integrated surface-subsurface numerical hydrological models

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science China Earth sciences 2024年第5期67卷 1459-1479页

作者： Lele SHU Hao CHEN Xianhong MENG Yan CHANG Litang HU Wenke WANG Longcang SHU Xuan YU Christopher DUFFY Yingying YAO Donghai ZHENG Key Laboratory of Cryospheric science and Frozen soil Engineering Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China College of water sciences Beijing Normal UniversityBeijing 100038China School of water and Environment Chang’an UniversityXi’an 710064China College of Hydrology and water Resources Hohai UniversityNanjing 210098China State Key Laboratory of soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China department of Civil and Environmental Engineering Pennsylvania State UniversityState CollegePA 16801USA department of Earth and Environmental science School of Human Settlements and Civil EngineeringXi’an Jiaotong UniversityXi’an 710049China Institute of Tibetan Plateau Research Chinese Academy of SciencesBeijing 100101China

Hydrological modeling,leveraging mathematical formulations to represent the hydrological cycle,is a pivotal tool in representing the spatiotemporal dynamics and distribution patterns inherent in hydrology.These models serve a dual purpose:they validate theoretical robustness and applicability via observational data and project future trends,thereby bridging the understanding and prediction of natural processes.In rapid advancements in computational methodologies and the continuous evolution of observational and experimental techniques,the development of numerical hydrological models based on physicallybased surface-subsurface process coupling have accelerated.Anchored in micro-scale conservation principles and physical equations,these models employ numerical techniques to integrate surface and subsurface hydrodynamics,thus replicating the macro-scale hydrological responses of watersheds.Numerical hydrological models have emerged as a leading and predominant trend in hydrological modeling due to their explicit representation of physical processes,heightened by their spatiotemporal resolution and reliance on interdisciplinary integration.This article focuses on the theoretical foundation of surface-subsurface numerical hydrological models.It includes a comparative and analytical discussion of leading numerical hydrological models,encompassing model architecture,numerical solution strategies,spatial representation,and coupling algorithms.Additionally,this paper contrasts these models with traditional hydrological models,thereby delineating the relative merits,drawbacks,and future directions of numerical hydrological modeling.

关键词： Numerical Hydrological Models Surface-Subsurface Process Coupling Numerical Methods Hydrological Modeling

Mass transfer characteristics of chiral pharmaceuticals on membrane used for polar organic chemical integrative sampler

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Journal of Environmental sciences 2024年第2期136卷 670-681页

作者： Liyang Wang Ruixia Liu Youya Zhou Peng Yuan Xiaoling Liu Hongjie Gao College of water science Beijing Normal UniversityBeijing 100018China State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental ScienceBeijing 100012China Technical Centre for soil Agriculture and Rural Ecology and EnvironmentMinistry of Ecology and EnvironmentBeijing 100012China

Passive sampling technology has good application prospects for monitoring trace pollutants in aquatic environments.Further research on the sampling mechanism of this technology is essential to improve the measurement accuracy and extend the application scope of this approach.In this study,adsorption and permeation experiments were performed to investigate the sorption and mass transfer properties of five chiral pharmaceuticals at the enantiomeric level on polyethersulfone(PES)and polytetrafluoroethylene(PTFE)membranes used in a polar organic chemical integrative sampler.Batch adsorption experiments showed that the PES membrane had an adsorption phenomenon for most selected pollutants and an insignificant sorption behavior was observed for all selected pharmaceuticals on the PTFE membrane except for R(S)-fluoxetine.The diffusion coefficients of selected pharmaceuticals onto the PTFE membrane were approximately one order of magnitude higher than those onto the PES membrane.The permeation experiment indicated that under different hydraulic conditions,the change of the relative pollutant concentration through the PTFE membrane for the composite pollutant system was more obvious than that for the single pollutant system,and mass transfer hysteresis exists for both contaminant systems through PES membranes.Using the first-order equation or 3-component model to estimate the overall mass transfer coefficients,the results showed that the overall mass transfer coefficient values of pollutants in the composite pollutant system onto both membranes were higher than those in the single pollutant system.This parameter was mainly influenced by the synergistic effects of the multi-analyte interaction and diminished water boundary layers during the mass transfer process.

关键词： Sorption phenomenon Permeation behavior Mass transfer properties Modeling calculation Chiral pharmaceuticals PES and PTFE membrane

Global patterns of soil phosphatase responses to nitrogen and phosphorus fertilization

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Pedosphere 2024年第1期34卷 200-210页

作者： Xiaomei GOU Yongqing REN Xin QIN Xiaorong WEI Jingjing WANG State Key Laboratory of soil Erosion and Dryland Farming on the Loess Plateau the Research Center of Soil and Water Conservation and Ecological EnvironmentChinese Academy of Sciences and Ministry of EducationYangling 712100China Institute of soil and water Conservation Chinese Academy of Sciences and Ministry of Water ResourcesYangling 712100China River and Lake Management Office Shaanxi Provincial Department of Water ResourcesXi'an 710004China College of Natural Resources and Environment Northwest A&F UniversityYangling 712100China University of Chinese Academy of sciences Beijing 100049China CAS Center for Excellence in Quaternary science and Global Change Xi'an 710061China

Hydrolysis of organic phosphorus(P) by soil phosphatases is an important process of P cycling in terrestrial ecosystems, significantly affected by nitrogen(N) and/or P fertilization. However, how soil acid phosphatase(ACP) and alkaline phosphatase(ALP) activities respond to N and/or P fertilization and how these responses vary with climatic regions, ecosystem types, and fertilization management remain unclear. This knowledge gap hinders our ability to assess P cycling and availability from a global perspective. We performed a meta-analysis to evaluate the global patterns of soil ACP and ALP activities in response to N and/or P addition. We also examined how climatic regions(arctic to tropical), ecosystem types(cropland, grassland, and forest), and fertilization management(experiment duration and fertilizer type and application rate) affected changes in soil phosphatases after fertilization. It was shown that N fertilizer resulted in 10.1% ± 2.9% increase in soil ACP activity but a minimal effect on soil ALP activity. In contrast, P fertilizer resulted in 7.7% ± 2.6% decrease in soil ACP activity but a small increase in soil ALP activity. The responses of soil ACP and ALP activities to N and/or P fertilization were largely consistent across climatic regions but varied with ecosystem types and fertilization management, and the effects of ecosystem types and fertilization management were enzyme-dependent. Random forest analysis identified climate(mean annual precipitation and temperature) and change in soil pH as the key factors explaining variations in soil ACP and ALP activities. Therefore, N input and ecosystem types should be explicitly disentangled when assessing terrestrial P cycling.

关键词： acid phosphatase alkaline phosphatase ecosystem type fertilization management meta-analysis phosphorus cycling phosphorus limitation

Global black soil distribution

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Frontiers of Agricultural science and Engineering 2024年第2期11卷 271-281页

作者： Yuxin TONG Marcos E.ANGELINI Yusuf YIGINI Isabel LUOTTO Global soil Partnership Land and Water Division Food and Agriculture Organization of the United Nations

Black soils, characterized by their thick, dark horizons enriched with organic matter, epitomize highly fertile soils. However, their fertility precipitates intense land use, engendering challenges such as soil erosion, nutrient depletion, pollution, compaction, salinization, and acidification. Notably, these soils are significant contributors to global greenhouse gas emissions, primarily due to substantial losses in soil organic carbon. Despite these challenges, black soils are pivotal for global food production. This paper delineates the implementation of digital soil mapping for the global cartography of black soils and human interference on these soils. Predominantly distributed in Eastern Europe, Central and Eastern Asia, and North and South America, black soils cover an approximate area of 725 Mha, with the Russian Federation,Kazakhstan, and China collectively have over half of this area. Agriculturally,these soils underpin significant proportions of global crop yields, producing 66% of sunflower, 30% of wheat, and 26% of potato outputs. The organic carbon content in the upper 30 cm of these soils is estimated at 56 Gt.Sustainable management of black soils is imperative for ensuring food security and addressing climate change on a global scale.

关键词： Black soils distribution map food security soil organic carbon