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Efficient photocatalytic reduction of CO2 to formate by a molecular noble metal-free system

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science China Chemistry 2025年第1期 152-156页

作者： Lihua Zhang Lingjing Chen Huatian Shi Yue Wei Gui Chen Tai-Chu Lau School of Environment and Civil Engineering Research Center for Eco-environmental Engineering Dongguan University of Technology department of Chemistry and institute of Molecular Functional Materials City University of Hong Kong

Reducing CO2to carbon-neutral solar fuels can not only alleviate the energy demand but also mitigate the greenhouse *** present,developing an efficient non-noble metal photo/electrocatalytic system for converting CO2to a specific product beyond CO is still a big ***,we report a new cobalt complex bearing 2,2′-bi-1,10-phenanthroline ligand that can photocatalytically reduce CO2to formate （HCOO-）.Turnover number （TON） for HCOO-up to 677 with 99%selectivity can be achieved using organic dyes purpurin as photosensitizer and 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole （BIH） as sacrificial reductant in a CO2-saturated NMP/TEA （v/v,3:1） solution under visible light *** potential electrolysis at-1.41 V （***/Ag Cl） in the presence of 12 m M Et3NHBF4also produced HCOO-with Faradaic efficiency of 39%.Spectroscopic and electrochemical studies suggest that a[CoI-H]species is the key intermediate for CO2reduction.

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Dissecting the cell microenvironment of ovarian endometrioma through single-cell RNA sequencing

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science China Life sciences 2025年第1期 116-129页

作者： Jiangpeng Wu Siyu Xia Wenting Ye Yan Sun Jing Cai Fubing Yu Haiping Wen Xiuwei Yi Taikang Li Mingwei Chen Jiayun Chen Ge Song Chuanbin Yang Yali Song Jigang Wang department of Reproductive Medicine Dongguan Maternal and Child Health Care Hospital department of Urology and Shenzhen Clinical Research Centre for GeriatricsShenzhen People's HospitalSouthern University of Science and Technology State Key Laboratory for Quality Ensurance and Sustainable Use of Dao-di Herbs Artemisinin Research Centerand Institute of Chinese Materia MedicaChina Academy of Chinese Medical Sciences Reproductive Medicine Center Foshan Women and Children Hospital State Key Laboratory of Antiviral Drugs School of PharmacyHenan University

Ovarian endometrioma（OE）, also known as “chocolate cysts,” is a cystic mass that develops in the ovaries due to endometriosis and is a common gynecological condition characterized by the growth of endometrial tissue outside the uterus, leading to symptoms such as dysmenorrhea, pelvic pain, and infertility. However, the precise molecular and cellular mechanisms driving this pathophysiology remain largely unknown, posing challenges for diagnosis and treatment. Here, we employed integrated single-cell transcriptomic profiling of over 52,000 individual cells from endometrial tissues of OE patients and healthy donors and identified twelve major cell populations. We identified notable alterations in cell type-specific proportions and molecular signatures associated with OE. Notably, the activation of IGFBP5+macrophages with pro-inflammatory properties, NK cell exhaustion, and aberrant proliferation of IQCG+and KLF2+epithelium are key features and may be the potential mechanisms underlying the pathogenesis of OE. Collectively, our data contribute to a better understanding of OE at the single cell level and may pave the way for the development of novel therapeutic strategies.

关键词： ovary high-throughput sequencing transcriptomics gene expression analysis ligand-receptor analysis

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Spatiotemporal Pattern of social Vulnerability in Italy

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International Journal of Disaster Risk science 2018年第2期9卷 249-262页

作者： Ivan Frigerio Fabio Carnelli Marta Cabinio Mattia De Amicis Earth and Environmental sciences department University of Milano-Bicocca sociology and social research department University of Milano-Bicocca

Evaluation of social vulnerability(SV) against natural hazards remains a big challenge for disaster risk reduction. Spatiotemporal analysis of SV is important for successful implementation of prevision and prevention measures for risk mitigation. This study examined the spatiotemporal pattern of SV in Italy, and also analyzed socioeconomic factors that may influence how the Italian population reacts to catastrophic natural events. We identified 16 indicators that quantify SV and collected data for the census years 1991, 2001, and 2011. We created a social vulnerability index(SVI) for each year by using principal component analysis outputs and an additive *** spatial data analysis, including global and local autocorrelations, was used to understand the spatial patterns of social vulnerability across the country. Specifically, univariate local Moran's index was performed for the SVI of each of the three most recent census years in order to detect changes in spatial clustering during the whole study period. The original contribution of this Italy case study was to use a bivariate spatial correlation to describe the spatiotemporal correlation between the threes annual SV indices. The temporal analysis shows that the percentage of municipalities with medium social vulnerability in Italy increased from 1991 to 2011 and those with very high social vulnerability decreased. Spatial analysis provided evidence of clusters that maintained significant high values of social vulnerability throughout the studyperiods. The SVI of many areas in the center and the south of the peninsula remained stable, and the people living there have continued to be potentially vulnerable to natural hazards.

关键词： Bivariate Moran’s index Cluster analysis Italy Natural hazards social vulnerability

Thermospheric neutral wind studies over the equatorial region:A review

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Earth and Planetary Physics 2025年第1期9卷 81-100页

作者： Siti Syazwani Nasuha Idahwati Sarudin Nurul Shazana Abdul Hamid Ahmad Fairuz Omar School of Physics Universiti Sains Malaysia11800 USMPulau PinangMalaysia department of Applied Physics Faculty of Science and TechnologyUniversiti Kebangsaan Malaysia43600 UKM BangiSelangorMalaysia Space science Centre(ANGKASA) Institute of Climate ChangesUniversiti Kebangsaan Malaysia43600 UKM BangiSelangorMalaysia

Thermospheric neutral winds(TNWs)refer to the neutral gases in the thermosphere circulating as tides,which play a crucial role in the dynamics of the thermosphere-ionosphere system(TIS).Global geospace neutral winds,particularly over the magnetic equator,have been a subject of study for several ***,despite the known importance of neutral winds,a comprehensive understanding and characterization of the winds is still *** ground-based and satellite missions have provided valuable information on the contribution of neutral winds to the global atmospheric ***,efforts in the global monitoring of neutral winds are still lacking,and the drivers behind the behavior of TNWs as well as their influence on the TIS remain *** address these knowledge gaps in the global circulation of TNWs,it is crucial to develop a deep understanding of the neutral wind characteristics over different *** low-latitude equatorial region in particular has been observed to exert complex influences on TNWs because of the unique effects of the Earth’s magnetic field at the dip *** neutral winds over this region will provide valuable insights into the unique dynamics and processes that occur in this region,thereby enhancing our understanding of their role in the overall dynamics of the ***,through empirical observations,an improved ability to accurately model and predict the behavior of this region can be *** review article addresses challenges in understanding equatorial winds by reviewing historical measurements,current missions,and the interactions of ionospheric and thermospheric phenomena,emphasizing the need for comprehensive measurements to improve global atmospheric dynamics and weather forecasting.

关键词： thermospheric neutral wind thermosphere-ionosphere system dip equator equatorial region

Population and Environment:Necessary Transition Initiatives for Developing Countries

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Chinese Journal of Population,Resources and Environment 2009年第3期7卷 83-88页

作者： Shah Md.Atiqul Haq department of sociology Social Science BuildingShah Jalal University of Science & Technology

Now environment is an important topic in academic *** researches focus on the negative outcomes of nature which are being continually created by human and much attention has been paid to how the environment is protected through integrated research,movement and *** few studies are concentrated on population and environment and are to find out the interconnectivity and underlying mechanism that have an effect on people's preferring additional children and perception to *** researchers claim that population growth is a great problem for environment but they do not provide the indepth integrated knowledge and mechanism that influence fertility trend and environmental *** is very crucial to develop practical and concrete initiatives to confirm a transition to reduce population growth and redirect the perception on population and environment.

关键词： environmental quality family planning reproductivebehavior transition initiative

Inaugural Message from Editors-in-Chief

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Journal of social Computing 2020年第1期1卷 I0001-I0004页

作者： James Evans Xiaoming Fu Jar-Der Luo Faculty Director of Computational social science Knowledge Lab at the University of Chicago and the Santa Fe Institute the University of Gottingen Germany department of sociology Tsinghua University Tsinghua social Network research Center

On behalf of the Editorial Board,it is our privilege to present the first issue of the Journal of social Computing,affectionately shortened *** computing concerns the intersection of social behavior and computational *** focused on recreating human social conventions and contexts through software and technology,we propose its expansion to the full interface between social interaction and computation.

关键词： Message computing behalf

Reproducible research Publication Workflow:A Canonical Workflow Framework and FAIR Digital Object Approach to Quality research Output

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Data Intelligence 2022年第2期4卷 306-319页

作者： Limor Peer Claudia Biniossek Dirk Betz Thu-Mai Christian Institution for social and Policy Studies Yale UniversityConnecticut 06520USA Center for empirical research in Economics and Behavioral sciences(CEREB) University of ErfurtThuringen 99089Germany Odum institute for research in social science University of North Carolina SystemNorth Carolina 27514-3916USA

In this paper we present the Reproducible research Publication Workflow(RRPW)as an example of how generic canonical workflows can be applied to a specific *** RRPW includes essential steps between submission and final publication of the manuscript and the research artefacts(i.e.,data,code,etc.)that underlie the scholarly claims in the manuscript.A key aspect of the RRPW is the inclusion of artefact review and metadata creation as part of the publication *** paper discusses a formalized technical structure around a set of canonical steps which helps codify and standardize the process for researchers,curators,and *** proposed application of canonical workflows can help achieve the goals of improved transparency and reproducibility,increase FAIR compliance of all research artefacts at all steps,and facilitate better exchange of annotated and machine-readable metadata.

关键词： FAIR research output FAIR Digital Objects Reproducible research research compendium Compendium publication workflow Data quality review

Tourism versus nature conservation: reconciliation of common interests and objectives——an analysis through Picos de Europa National Park

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Journal of Mountain science 2018年第11期15卷 2505-2516页

作者： LóPEZ Iván PARDO Mercedes department of Psychology and sociology University of Zaragoza department of social Analysis University Carlos Ⅲ of Madrid

Nature tourism and particularly tourism in national parks have acquired significant importance in contemporary societies. Post-Fordist consumers have reevaluated the meanings of ‘nature' and ‘natural spaces' and now avoid standardization to seek singularity. Tourism in national parks is a consequence of this tendency and has both positive and negative aspects. The purpose of this sociological research is to describe the most relevant conflicts in the Picos de Europa National Park(Spain) involving the park's conservation, local economic development,and tourism. Seven in-depth interviews and three focus groups were addressed to key local *** this research were identified three chief areas of existing or potential inter-related conflicts and the main actors interacting with them. The first is on population, particularly, the negative consequences of depopulations on the local socio-economic development and the environment. A second source of conflicts identified is caused by the difficult conciliation between commercial exploitation and conservation of the protected natural area. More precisely, this specific form of tourism positively contributes to the economy of local communities whilst problems can arise for the conservation goals of National Parks. Thirdly, in this research is also analyzed the institutional governance and the inter and intra-governmental conflicts as well as with the Park's management body. These findings provide important information for the improved management of tourism and conflicting interests in natural parks.

关键词： National parks Environmental conservation Nature tourism Mountain traditional economy Picos de Europa Spain

Comparative analysis of empirical and deep learning models for ionospheric sporadic E layer prediction

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Earth and Planetary Physics 2025年第1期9卷 10-19页

作者： BingKun Yu PengHao Tian XiangHui Xue Christopher JScott HaiLun Ye JianFei Wu Wen Yi TingDi Chen XianKang Dou institute of Deep Space sciences Deep Space Exploration LaboratoryHefei 230088China CAS Key Laboratory of Geospace Environment School of Earth and Space SciencesUniversity of Science and Technology of ChinaHefei 230026China Hefei National Laboratory University of Science and Technology of ChinaHefei 230088China department of Meteorology University of ReadingReading RG66BBUK

Sporadic E(Es)layers in the ionosphere are characterized by intense plasma irregularities in the E region at altitudes of 90-130 *** they can significantly influence radio communications and navigation systems,accurate forecasting of Es layers is crucial for ensuring the precision and dependability of navigation satellite *** this study,we present Es predictions made by an empirical model and by a deep learning model,and analyze their differences comprehensively by comparing the model predictions to satellite RO measurements and ground-based ionosonde *** deep learning model exhibited significantly better performance,as indicated by its high coefficient of correlation(r=0.87)with RO observations and predictions,than did the empirical model(r=0.53).This study highlights the importance of integrating artificial intelligence technology into ionosphere modelling generally,and into predicting Es layer occurrences and characteristics,in particular.

关键词： ionospheric sporadic E layer radio occultation ionosondes numerical model deep learning model artificial intelligence