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Assessment of soil total phosphorus storage in a complex topography along China's southeast coast based on multiple mapping scales

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Pedosphere 2024年第1期34卷 236-251页

作者： Zhongxing CHEN Jing LI Kai HUANG Miaomiao WEN Qianlai ZHUANG Licheng LIU Peng ZHU Zhenong JIN Shihe XING Liming ZHANG Fujian Provincial Key Laboratory of Soil Environmental health and Regulation College of Resources and EnvironmentFujian Agriculture and Forestry UniversityFuzhou 350002China State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China Guangxi Zhuang Autonomous Region Plant protection Station Nanjing 530022China department of Earth Atmosphericand Planetary SciencesPurdue UniversityWest Lafayette IN47907US department of Bioproducts and Biosystems Engineering University of Minnesota-Twin CitiesSaint Paul MN 55108USA department of Geography The University of Hong KongHong Kong 999077China

Soil phosphorus (P) plays a vital role in both ecological and agricultural ecosystems, where total P (TP) in soil serves as a crucial indicator of soil fertility and quality. Most of the studies covered in the literature employ a single or narrow range of soil databases, which largely overlooks the impact of utilizing multiple mapping scales in estimating soil TP, especially in hilly topographies. In this study, Fujian Province, a subtropical hilly region along China’s southeast coast covered by a complex topographic environment, was taken as a case study. The influence of the mapping scale on soil TP storage (TPS)estimation was analyzed using six digital soil databases that were derived from 3 082 unique soil profiles at different mapping scales, i.e., 1:50 000 (S5),1:200 000 (S20), 1:500 000 (S50), 1:1 000 000 (S100), 1:4 000 000 (S400), and 1:10 000 000 (S1000). The regional TPS in the surface soil (0–20 cm) based on the S5, S20, S50, S100, S400, and S1000 soil maps was 20.72, 22.17, 23.06, 23.05, 22.04, and 23.48 Tg, respectively, and the corresponding TPS at0–100 cm soil depth was 80.98, 80.71, 85.00, 84.03, 82.96, and 86.72 Tg, respectively. By comparing soil TPS in the S20 to S1000 maps to that in the S5map, the relative deviations were 6.37%–13.32%for 0–20 cm and 0.33%–7.09%for 0–100 cm. Moreover, since the S20 map had the lowest relative deviation among different mapping scales as compared to S5, it could provide additional soil information and a richer soil environment than other smaller mapping scales. Our results also revealed that many uncertainties in soil TPS estimation originated from the lack of detailed soil information, i.e., representation and spatial variations among different soil types. From the time and labor perspectives, our work provides useful guidelines to identify the appropriate mapping scale for estimating regional soil TPS in areas like Fujian Province in subtropical China or other places with similar complex topographies. Moreover,

关键词： agricultural management appropriate mapping scale digitized conventional soil map estimation uncertainty subtropical hilly region

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Analysis of the Teaching of Ancient Chinese History in the Heritage Conservation Technology Major

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Journal of Contemporary Educational Research 2024年第5期8卷 53-58页

作者： Ying Wang department of Cultural Relics protection Technology Beijing Landscape Architecture SchoolBeijing 102488China

Ancient Chinese history is an important part of the curriculum of the Heritage Conservation Technology *** can better understand the history of cultural relics and improve their humanistic literacy,which will help them in restoring cultural *** present,there are numerous challenges in teaching ancient Chinese history in the Heritage Conservation Technology *** challenges necessitate the development of effective teaching reform *** paper outlines these challenges and explores effective teaching reform strategies to provide a reference for educators.

关键词： Ancient Chinese history Heritage Conservation Technology Teaching reform

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Eu-MOF-Based Fluorescent Ratiometric Sensor by Detecting 3,4,5-Trihydroxybenzoic for Fingerprint Visualization on Porous Objects

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Photonic Sensors 2024年第1期14卷 85-98页

作者： Muwen LIANG Yabin ZHAO Yaping LUO Bin DU Wei HU Bing LIU Xihui MU Zhaoyang TONG department of Investigation People's Public Security University of ChinaBejing 100038China State Key Laboratory of NBC protection for Civilian Beijing 102205China

Latent fingerprints(LFPs)at the crime scene are served as important clues to locate the trajectory of criminal behavior and portray the characteristics of the ***,visualizing LFPs is of considerable *** this work,the europium metal-organic framework(Eu-MOF)sensor was successfully constructed for sensitive detection of gallic acid(3,4,5-trihydroxybenzoic acid,GA)and visualization of the sweat *** boric-acid-modified Eu-MOF was prepared by using the simple one-pot solvothermal method using Eu as the metal i ion center and 3,5-dicarboxybenzeneboronic acid(BBDC)as the organic *** sensor showed desirable photoluminescent performance through the chelating of BBDC with Eu3+.The sensor exhibited the satisfactory linear relationship to GA in the range of 1 nM to 20 nM with a low detection limit of 0.34 nM under the optimized *** prepared sensor with ideal selectivity to GA was successfully applied for visualizing LFPs on porous substrates with the high contrast and superior *** the good performance of the sensor,all fingerprint images obtained from 1200 samples presented clear friction ridges and met the identification ***,the sensor had less impact on the subsequent deoxyribonucleic acid(DNA)detection,displaying a promising perspective for applications in extracting physical evidence of site investigation.

关键词： Europium metal-organic framework(Eu-MOF) photoluminescence 3,4,5-trihydroxybenzoic latent fingerprints(LFPs)development

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Syntheses and properties of associative acrylamide copolymers containing short hydrophobic chains used in a friction reducer for slick-water fracturing

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Petroleum Science 2024年第3期21卷 1889-1901页

作者： Ya-Xing Dai Xian-Li Zhang Si-Yuan Liu Feng-Run-Ze Zhang Yi-Xi Zhang Yu-Tong Sang Jing-Xi Zheng Zhao-Sheng Liu Peng Zhang College of Chemistry and Chemical Engineering Chongqing University of Science and TechnologyChongqing401331China College of Ecology and Environment Chongqing Resources and Environmental Protection of UniversityChongqing401331China China China Property Project department of Dezhou Mining Property Service CenterShengli Oilfield Company of SinopecDezhou253000ShandongChina

Two allyldimethylalkyl quaternary ammonium salt(AQAS)monomers,N,N-dimethylallylphenylpropylammonium bromide(AQAS1)and N,N-dimethylallylnonylammonium bromide(AQAS2),were synthesized and used to prepare modified polyacrylamide *** new drag reducers were synthesized from acrylamide(AM),sodium acrylate(Na AA)and a cationic modified monomer(AQAS1 or AQAS2)via aqueous solution polymerization,and the copolymers were named P(AM/Na AA/AQAS1)and P(AM/Na AA/AQAS2),*** structures of the drag reduction agents were confirmed by IR and1H NMR *** molecular weight(Mw)of P(AM/Na AA/AQAS1)was 1.79×10^(6)g/*** the copolymer concentration was 1000 mg/L and the flow rate was 45 L/min,in fresh water the highest drag reduction rate was 75.8%,in 10,000 mg/L Na Cl solution the drag reduction rate decreased to 72.9%.The molecular weight of P(AM/Na AA/AQAS2)was 3.17×10^(6)g/*** the copolymer concentration was500 mg/L and the flow rate was 45 L/min,the drag reduction rate reached 75.2%,and in 10,000 mg/L Na Cl solution the drag reduction rate was 73.3%,decreased by approximately 1.9%.The drag reduction rate for partially hydrolyzed polyacrylamide(HPAM)was also investigated,and the results showed that the drag reduction rates for 500 and 1000 mg/L HPAM solutions were merely 43.2%and 49.0%in brine,*** with HPAM,both of the above copolymers presented better drag reduction capacities.

关键词： Shale gas Slick water Drag reducer Modified monomer Copolymerization

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Functional assessment of cadherin as a shared mechanism for cross/dual resistance to Cry1Ac and Cry2Ab in Helicoverpa zea

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Journal of Integrative Agriculture 2024年第5期23卷 1604-1617页

作者： Jizhen Wei Min Zhang Pin Li Zhongyuan Deng Xinming Yin Shiheng An Xianchun Li State Key Laboratory of Wheat and Maize Crop Science/College of Plant protection Henan Agricultural UniversityZhengzhou 450046China department of Entomology and BIO5 Institute University of ArizonaTucsonAZ 85721USA School of Agricultural Sciences Zhengzhou UniversityZhengzhou 450001China

Helicoverpa zea is a major target pest of pyramided transgenic crops expressing Cry1,Cry2 and/or Vip3Aa proteins from Bacillus thuringiensis(Bt)in the United ***-selected Cry1Ac/Cry2Ab cross resistance and fieldevolved practical dual resistance of *** to these two toxins have been widely *** the widespread Cry1Ac/Cy2Ab dual resistance of *** has resulted from the selection of one shared or two independent resistance mechanisms by pyramided Bt crops remains *** is a well-confirmed receptor of Cry1Ac and a suggested receptor of Cry2Ab in at least three Lepidopteran *** test whether cadherin may serve as one shared mechanism for the cross and dual resistance of *** to Cry1Ac and Cry2Ab,we cloned *** cadherin(HzCadherin)cDNA and studied its functional roles in the mode of action of Cry1Ac and Cry2Ab by gain-and lossof-function *** expression of HzCadherin in *** midgut,*** fat body and Sf9 cells made all three of these cell lines more susceptible to activated Cry1Ac but not activated Cry2Ab,whereas silencing HzCadherin of *** midgut and fat body cells significantly reduced the susceptibility to Cry1Ac but not ***,suppressing HzCadherin with siRNA made *** larvae resistant to *** results clearly demonstrate that HzCadherin is not a receptor for Cry2Ab,and thus it is unlikely to serve as one shared mechanism for the cross and dual resistance of *** to Cry1Ac and Cry2Ab.

关键词： Bt crops cadherin Cry toxin receptor resistance mechanism

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Nano/Micro-Structural Supramolecular Biopolymers: Innovative Networks with the Boundless Potential in Sustainable Agriculture

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Nano-Micro Letters 2024年第8期16卷 79-101页

作者： Roohallah Saberi Riseh Mohadeseh Hassanisaadi Masoumeh Vatankhah Rajender S.Varma Vijay Kumar Thakur department of Plant protection Faculty of AgricultureVali-e-Asr University of RafsanjanImam Khomeini SquareRafsanjan ***Iran Centre of Excellence for Research in Sustainable Chemistry Department of ChemistryFederal University of São CarlosSão CarlosSP 13565‑905Brazil Biorefining and Advanced Materials Research Center Scotland’s Rural Collage(SRUC)Edinburgh EH93JGUK

Sustainable agriculture plays a crucial role in meeting the growing global demand for food while minimizing adverse environmental impacts from the overuse of synthetic pesticides and conventional *** this context,renewable biopolymers being more sustainable offer a viable solution to improve agricultural sustainability and ***/micro-structural supramolecular biopolymers are among these innovative biopolymers that are much sought after for their unique *** biomaterials have complex hierarchical structures,great stability,adjustable mechanical strength,stimuli-responsiveness,and self-healing *** molecules may be added to their flexible structure,for enabling novel agricultural *** overview scrutinizes how nano/micro-structural supramolecular biopolymers may radically alter farming practices and solve lingering problems in agricultural sector namely improve agricultural production,soil health,and resource *** bioactive ingredient released from biopolymers allows the tailored administration of agrochemicals,bioactive agents,and biostimulators as they enhance nutrient absorption,moisture retention,and root ***/micro-structural supramolecular biopolymers may protect crops by appending antimicrobials and biosensing entities while their eco-friendliness supports sustainable *** their potential,further studies are warranted to understand and optimize their usage in agricultural *** effort seeks to bridge the knowledge gap by investigating their applications,challenges,and future prospects in the agricultural *** experimental investigations and theoretical modeling,this overview aims to provide valuable insights into the practical implementation and optimization of supramolecular biopolymers in sustainable agriculture,ultimately contributing to the development of innovative and eco-friendly solutions to enhance agricultural productivity while minimizing envir

关键词： Supramolecular Biopolymers Sustainable agriculture Nanotechnology

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A self-cleaning window for high-efficiency photodegradation of indoor formaldehyde

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Chinese Chemical Letters 2024年第9期35卷 340-345页

作者： Changzhu Huang Wei Dai Shimao Deng Yixin Tian Xiaolin Liu Jia Lin Hong Chen department of Physics Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric PowerShanghai University of Electric PowerShanghai 200090China Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution ControlGuangdong Provincial Key Laboratory of Soil and Groundwater Pollution ControlSchool of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China Eastern Institute for Advanced Study Eastern Institute of TechnologyNingbo 315200China

Formaldehyde(HCHO)as an indoor air pollutant released by new furniture and decorative materials is of great *** a self-cleaning device to remove HCHO is an ideal way to improve indoor air *** this study,a self-cleaning window with a multilayered structure constructed from fluorinedoped tin oxide/bismuth tungstate/resorcinol-formaldehyde resin(FTO/Bi_(2)WO_(6)/RF)has been fabricated,which is capable of degrading HCHO in natural indoor *** as-fabricated device could utilize the natural room light and promote the generation and transfer of the photocatalytic carriers in Bi_(2)WO_(6),which subsequently delivers a good catalytic oxygen reduction efficiency in RF to produce hydrogen peroxide(H_(2)O_(2)).The as-synthesized H_(2)O_(2)could further split into hydroxyl radicals(•OH),then oxide the HCHO molecules in the *** present study demonstrates a novel and efficient strategy to fabricate a transparent multifunctional window for self-cleaning indoor gaseous pollutants,the concept is of great importance to be expanded in a broad range of indoor furniture for in-house air pollution control.

关键词： Bismuth tungstate Resorcinol-formaldehyde Photocatalysis Hydrogen peroxide HCHO degradation

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Prevalence of Gender-Based Violence among Sex Workers in Bangui, Central African Republic (CAR)

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Advances in Sexual Medicine 2024年第2期14卷 13-20页

作者： D. Mossoro-Kpinde Hermione S. C. Diemer Henri R. Tende Nzengou Richard S. Siki Francis J. D. D. Tekpa Bertrand Ministry of Labor Employment Social Protection and Vocational Training Bangui Central African Republic department of Public health Faculty of Health Sciences University of Bangui Bangui Central African Republic Community of the Tree of Life Bangui Central African Republic Traumatology department The Central African Republic RCA Community Hospital Bangui Central African Republic

Background: Violence against women has become an international public health and human rights issue in recent decades. The violence suffered by sex workers is of little interest for research, yet it constitutes a major health and safety problem. We propose to assess the extent of the phenomenon of gender-based violence (GBV) among sex workers (SWs) in the city of Bangui in the CAR. Methodology: This is a descriptive cross-sectional epidemiological study covering the period from July to October 2021 carried out among SWs in Bangui, the capital of the CAR. Given that the SWs association had only 159 members in Bangui, an exhaustive sampling was retained. Were included in the study, any SW present during the data collection period and having given their written consent. The parameters studied were socio-demographic characteristics: age, sex, residence, level of education, marital status, and characteristics linked to violence: the notion of violence during their professional activity, the type of violence, the declaration and the declaration if necessary, the response and management of this violence. The data collected was analyzed using Epi info version 7 software. Results: Of the 159 SWs that counted the association, 108 had been included. The average age was 27.0 years with extremes of 14 and 46 years. The age groups of 25 to 34 years were the most represented (43.5%). Fifty-six SWs (51.9%) had reached the secondary level. Unemployed SWs were in the majority at 74.1%;Sixty-six (66) SWs in our sample (61.1%) had already been victims of violence during the exercise of their activity Sexual violence was the most represented (28.5%) followed by verbal violence (22.4%). Sixty-eight (62.9%) wanted to stop the professional activity of SWs and 93.1% would accept another income-generating activity in place of sex work. Conclusion: It is necessary to supervise SWs and protect them within the framework of respect for human rights, rather than criminalizing them and the exploit

关键词： Female Sex Workers Gender-Based Violence Central African Republic

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Parkland trees on smallholder farms ameliorate soil physical-chemical properties in the semi-arid area of Tigray,Ethiopia

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Journal of Arid Land 2024年第1期16卷 1-13页

作者： Selam LJALEM Emiru BIRHANE Kassa TEKA Daniel H BERHE department of Land Resources Management and Environmental protection College of Dryland Agriculture and Natural ResourcesMekelle UniversityMekelle 231Ethiopia Institute of Climate and Society Mekelle UniversityMekelle 231Ethiopia Faculty of Environmental Sciences and Natural Resource Management Norwegian University of Life Sciences(NMBU)Ås 1432Norway department of Natural Resources Management Adigrat UniversityAdigrat 50Ethiopia

Proposed agroforestry options should begin with the species that farmers are most familiar with,which would be the native multipurpose trees that have evolved under smallholder farms and socioeconomic *** African birch(Anogeissus leiocarpa(DC.)Guill.&Perr.)and pink jacaranda(Stereospermum kunthianum Cham.)trees are the dominant species in the agroforestry parkland system in the drylands of Tigray,*** farmers highly value these trees for their multifunctional uses including timber,firewood,charcoal,medicine,*** trees also could improve soil ***,the amount of soil physical and chemical properties enhanced by the two species must be determined to maintain the sustainable conservation of the species in the parklands and to scale up to similar agroecological ***,we selected twelve isolated trees,six from each species that had similar dendrometric characteristics and were growing in similar environmental *** divided the canopy cover of each tree into three radial distances:mid-canopy,canopy edge,and canopy gap(control).At each distance,we took soil samples from three different *** collected 216 soil samples(half disturbed and the other half undisturbed)from each canopy position and soil *** density(BD),soil moisture content(SMC),soil organic carbon(SOC),total nitrogen(TN),available phosphorus(AP),available potassium(AK),p H,electrical conductivity(EC),and cation exchange capacity(CEC)were *** revealed that soil physical and chemical properties significantly improved except for soil texture and EC under both species,CEC under ***,and soil p H under ***,all the studied soils were improved under both species canopy as compared with canopy ***,TN,AP,and AK under canopy of these trees were respectively 24.1%,11.1%,55.0%,and 9.3% higher than those soils under *** two parkland agroforestry species significantly enhanced soil fertility near the canopy of top

关键词： agroforestry bulk density carbon stock dispersed tree soil texture tree canopy

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Synthesis and Characterization of Novel Schiff Base for Enhanced Dye-Sensitized Solar Cell Photo-Response Mechanism

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Crystal Structure Theory and Applications 2024年第2期12卷 11-20页

作者： Raphael Shadai Oguike Hanatu Akanagn Omolara Oni Corrosion protection and Materials Science Laboratory Chemistry Department Abubakar Tafawa Balewa University Bauchi Nigeria

The efficient photo-response mechanism is one of the key factors in the commercialization of dye-sensitized solar cells in a bid to satisfy renewable energy demands. Progress in green technology has put solar energy on the front burner as a provider of clean and affordable energy for a sustainable society. We report the synthesis of a novel Schiff base with optical transparency in the visible and near IR region of the solar spectrum that can find application in the DSSCs photo-response mechanism. The synthesized crystal exhibited features that could handle some of the shortcomings of dye-sensitized solar cells which include wide band solar spectrum absorption and capability for swift charge transfer within the photoelectrodes. The synthesized Schiff base was characterized using x-ray diffractometer, UV/Visible spectrometer, Frontier transmission infrared spectrometer and conductometer. XRD data revealed the grown crystal to have an average crystallite size of 2.08 nm with average microstrain value of about 269.43. The FT-IR recorded transmission wave ѵ (CO) at 1207.7 cm−1 while dominant wave occurred at ѵ1654.9 and ѵ1592.3 cm−1 relating to ѵ (CN) stretching and ѵ (NH) bending respectively were observed. The IR spectrum revealed the bonding species and a probable molecular structure of 2,6-bis(benzyloxy)pyridine. The UV/Visible spectra convoluted to maximum peak within the near IR region suggesting that 2,6-bis(benzyloxy)pyridine can absorb both the visible and near IR region while its electrical conductivity was determined to be 4.58 µS/cm. The obtained result of the present study revealed promising characteristics of a photosensitizer that can find application in the photo-response mechanism of DSSCs.

关键词： Dye-Sensitized Solar Cell Schiff Base Photosensitizer Optical Transparency Benzil Pyridine

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