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Sequential alkaline-organic acid leaching process to enhance the recovery of rare earth elements from Indonesian coal fly ash

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Journal of Rare Earths 2024年第7期42卷 1366-1374,I0006页

作者： Widya Rosita Indra Perdana I Made Bendiyasa Ferian Anggara Himawan Tri Bayu Murti Petrus Agus Prasetya Isyatun Rodliyah department of Nuclear engineering and engineering Physics Faculty of EngineeringUniversitas Gadjah MadaJl Grafika No.2Yogyakarta55281Indonesia department of Chemical engineering Faculty of EngineeringUniversitas Gadjah MadaJl Grafika No.2Yogyakarta55281Indonesia department of Geological engineering Faculty of EngineeringUniversitas Gadjah MadaJl Grafika No.2Yogyakarta55281Indonesia Unconventional Geo-resources Research Group Faculty of EngineeringUniversitas Gadjah MadaJl Grafika No.2Yogyakarta55281Indonesia Center for Testing of mineral and Coal Tekmira-Directorate General of mineral and Coal-Ministry of Energy and mineral resources Jl.Jend.Sudirman No.623Wr.MuncangKec.Bandung KulonKota BandungJawa Barat40211Indonesia

In this decade,coal fly ash(CFA)is considered a potential secondary source of rare earth elements(REEs).However,most REEs in coal fly ash are encapsulated in aluminosilicate glass,making it challenging to recover them through acid *** this study,a sequential alkaline-organic acid leaching was developed for the recovery of REEs from *** effect of alkaline leaching using NaOH solution on the destructive ability of aluminosilicate glass,as well as the mineralogy and morphology changes of the resulting coal fly ash,was first ***,the effectiveness of alkaline leaching on the recovery ability of REEs through organic acid leaching was *** results show that the maximum leaching efficiency for Si and Al,which was obtained at the optimum alkaline leaching conditions,namely NaOH concentration of 10 mol/L,reaction temperature of 65℃,liquid/solid(L/S)ratio of 10 mL/g,and reaction time of 90 min,is 28%and 32%,*** digestion reaction with NaOH lixiviants also causes coal fly ash to become more porous,making it advantageous in the organic acid-leaching process at the REEs recovery *** utilization of the desilicated residue produced from the digestion process in acid leaching effectively increases the overall REEs recovery from 32.2%to 77.6%.

关键词： Rare earth elements Alkaline Organic acid Coal fly ash

Effect of Phase Separation Size on the Properties of Self-healing Elastomer

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Chinese Journal of Polymer Science 2024年第6期42卷 798-804页

作者： Jun Xu Lei Zhu Xian-Qi Feng Cong Sui Wen-Peng Zhao Shou-Ke Yan School of Chemical engineering Qingdao University of Science&TechnologyQingdao266042China College of engineering Yanching institute of TechnologyLangfang065210China Key Laboratory of Rubber-plastics Qingdao University of Science&TechnologyQingdao266042China State Key Laboratory of Chemical resource engineering Beijing University of Chemical TechnologyBeijing100029China

Regulation of phase structure has been recognized as one of the most effective ways to fabricate self-healing polymers with high mechanical *** mechanical properties of the resultant polymers are certainly affected by the size of separated phase ***,the study on this aspect is absence,because it can hardly exclude the influence of variation in monomer proportion required for tuning the separated phase ***,we report the first study on tuning the phase size through reversible addition-fragmentation chain transfer(RAFT)polymerization without changing the proportion of *** expected,the size of separated phase has been successfully mediated from 15 nm to 9 nm by tuning the molecular weight of the chain transfer *** is found that the mechanical strength and the self-healing efficiency of the resultant polymers increase simultaneously with the decrease of phase *** study on the formation kinetics of hydrogen bonds reveals that the decrease of phase size can facilitate the re-bonding rate of hydrogen bonds,even if the migration of polymer chains is restricted.

关键词： Self-healing polymers Phase separation Reversible addition-fragmentation chain transfer

A model for predicting the segregation directions of binary Geldart B particle mixtures in bubbling fluidized beds

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Particuology 2024年第7期90卷 340-349页

作者： Chenmin Liu Yuemin Zhao Yanjiao Li Yuqing Feng Chenlong Duan Chenyang Zhou Liang Dong Key Laboratory of Coal Processing and Efficient Utilization Ministry of EducationChina University of Mining and TechnologyXuzhou221116China School of Chemical engineering and technology China University of Mining and TechnologyXuzhou221116China mineral resources Business Unit CSIROClaytonVIC 3169Australia

In gas fluidization processes involving different types of particles,the mixing or segregation behavior of the solid mixture is crucial to the overall outcome of the *** study develops a model to predict the segregation directions of binary mixtures of Geldart B particles with density and size differences in bubbling fluidized *** proposed model was established by combining the particle segregation model,a previous particle segregation model,with a derived bed voidage equation of the bubbling fluidization based on the two-phase *** model was then analyzed with different function graphs of the model equations under various *** results indicated that an increase in gas velocity or volume fraction of larger particles would strengthen size segregation,causing the larger and less dense components to *** validate the model,42 sets of data collected from 6 independent literature sources were compared with the predictions of the *** the gas velocities were below 3.2 times the minimum gas velocity,the predictions were consistent with experimental *** study has shed new light on the mechanisms of particle segregation in binary fluidized systems and provides a theoretical foundation for designing and manipulating gas-solid fluidized reactors.

关键词： Particle segregation Binary mixture Bubbling fluidization Geldart B particles Two-phase theory

Low-temperature NH_(3)-SCR performance of a novel Chlorella@Mn composite denitrification catalyst

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Journal of Environmental Sciences 2024年第3期137卷 271-286页

作者： Hengheng Liu Fengyu Gao Songjin Ko Ning Luo Xiaolong Tang Erhong Duan Honghong Yi Yuansong Zhou School of Energy and Environmental engineering University of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory of resource-oriented Treatment of Industrial Pollutants Beijing 100083China School of Environmental Science and engineering University of Science and Technology HebeiHebei 050018China department of Chemistry Pyongyang University of ArchitecturePyongyangDemocratic People’s Republic of Korea

The synthesis process of conventional Mn-based denitrification catalysts is relatively complex and *** this paper,a resource application of chlorella was proposed,and a Chlorella@Mn composite denitrification catalyst was innovatively synthesized by electrostatic *** Chlorella@Mn composite denitrification catalyst prepared under the optimal conditions(0.54 g/L Mn^(2+)concentration,20 million chlorellas/mL concentration,450℃ calcination temperature)exhibited a well-developed pore structure and large specific surface area(122 m^(2)/g).Compared with MnOx alone,the Chlorella@Mn composite catalyst achieved superior performance,with~100%NH_(3)selective catalytic reduction(NH_(3)-SCR)denitrification activity at 100-225℃.The results of NH_(3)temperature-programmed desorption(NH_(3)-TPD)and H_(2)temperature-programmed reduction(H_(2)-TPR)showed that the catalyst had strong acid sites and good redox *** potential testing showed that the electronegativity of the chlorella cell surface could be used to enrich with Mn^(2+).X-ray photoelectron spectroscopy(XPS)confirmed that Chlorella@Mn had a high content of Mn^(3+)and surface chemisorbed ***-situ diffuse refectance infrared Fourier transform spectroscopy(in-situ DRIFTS)experimental results showed that both Langmuir-Hinshelwood(L-H)and Eley-Rideal(E-R)mechanisms play a role in the denitrification process on the surface of the Chlorella@Mn catalyst,where the main intermediate nitrate species is monodentate *** presence of SO_(2)promoted the generation and strengthening of Bronsted acid sites,but also generated more sulfate species on the surface,thereby reducing the denitrification activity of the Chlorella@Mn *** Chlorella@Mn composite catalyst had the characteristics of short preparation time,simple process and low cost,making it promising for industrial application.

关键词： Chlorella@Mn catalyst NH_(3)-SCR Poisoning resistance Reaction mechanism Infuence of SO_(2)

Chain Elongation Using Native Soil Inocula:Exceptional n-Caproate Biosynthesis Performance and Microbial Mechanisms

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engineering 2024年第8期39卷 262-272页

作者： Lin Deng Yang Lv Tian Lan Qing-Lian Wu Wei-Tong Ren Hua-Zhe Wang Bing-Jie Ni Wan-Qian Guo State Key Laboratory of Urban Water resource and the Environment Harbin Institute of TechnologyHarbin 150090China Centre for technology in Water and Wastewater&School of Civil and Environmental engineering University of Technology SydneySydneyNSW 2007Australia

This study demonstrates the feasibility and effectiveness of utilizing native soils as a resource for inocula to produce n-caproate through the chain elongation(CE)platform,offering new insights into anaerobic soil *** results reveal that all five of the tested soil types exhibit CE activity when supplied with high concentrations of ethanol and acetate,highlighting the suitability of soil as an ideal source for n-caproate *** with anaerobic sludge and pit mud,the native soil CE system exhibited higher selectivity(60.53%),specificity(82.32%),carbon distribution(60.00%),electron transfer efficiency(165.00%),and conductivity(0.59 ms∙cm^(-1)).Kinetic analysis further confirmed the superiority of soil in terms of a shorter lag time and higher yield.A microbial community analysis indicated a positive correlation between the relative abundances of Pseudomonas,Azotobacter,and Clostridium and n-caproate ***,metagenomics analysis revealed a higher abundance of functional genes in key microbial species,providing direct insights into the pathways involved in n-caproate formation,including in situ CO_(2)utilization,ethanol oxidation,fatty acid biosynthesis(FAB),and reverse beta-oxidation(RBO).The numerous functions in FAB and RBO are primarily associated with Pseudomonas,Clostridium,Rhodococcus,Stenotrophomonas,and Geobacter,suggesting that these genera may play roles that are involved or associated with the CE ***,this innovative inoculation strategy offers an efficient microbial source for n-caproate production,underscoring the importance of considering CE activity in anaerobic soil microbial ecology and holding potential for significant economic and environmental benefits through soil consortia exploration.

关键词： Soil Chain elongation n-caproate Reverse beta-oxidation Fatty acid biosynthesis Metagenomics

Multimodal Machine Learning Guides Low Carbon Aeration Strategies in Urban Wastewater Treatment

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engineering 2024年第5期36卷 51-62页

作者： Hong-Cheng Wang Yu-Qi Wang Xu Wang Wan-Xin Yin Ting-Chao Yu Chen-Hao Xue Ai-Jie Wang State Key Laboratory of Urban Water resource and Environment School of Civil and Environmental EngineeringHarbin Institute of Technology(Shenzhen)Shenzhen 518055China Key Laboratory of Drinking Water Safety and Distribution technology of Zhejiang Province College of Civil Engineering and ArchitectureZhejiang UniversityHangzhou 310058China

The potential for reducing greenhouse gas(GHG)emissions and energy consumption in wastewater treatment can be realized through intelligent control,with machine learning(ML)and multimodality emerging as a promising ***,we introduce an ML technique based on multimodal strategies,focusing specifically on intelligent aeration control in wastewater treatment plants(WWTPs).The generalization of the multimodal strategy is demonstrated on eight ML *** results demonstrate that this multimodal strategy significantly enhances model indicators for ML in environmental science and the efficiency of aeration control,exhibiting exceptional performance and *** random forest with visual models achieves the highest accuracy in forecasting aeration quantity in multimodal models,with a mean absolute percentage error of 4.4%and a coefficient of determination of *** testing in a full-scale plant reveals that the multimodal model can reduce operation costs by 19.8%compared to traditional fuzzy control *** potential application of these strategies in critical water science domains is *** foster accessibility and promote widespread adoption,the multimodal ML models are freely available on GitHub,thereby eliminating technical barriers and encouraging the application of artificial intelligence in urban wastewater treatment.

关键词： Wastewater treatment Multimodal machine learning Deep learning Aeration control Interpretable machine learning

Experimental study on the dynamic response of a 3-D wedge under asymmetric impact

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Journal of Hydrodynamics 2024年第2期36卷 263-274页

作者： Saeed Hosseinzadeh Kristjan Tabri Maritime engineering Research Group School of EngineeringUniversity of SouthamptonSouthamptonUK department of Civil engineering and Architecture Tallinn University of TechnologyTallinnEstonia Marine technology Competence Center Tallinn University of TechnologyKuressaareEstonia

Water entry problems represent complex multiphase flows involving air,water,and structure interaction,occurring rapidly in rough seas,and potentially effecting structural integrity of floating *** paper experimentally investigates asymmetric slamming loads acting on a 3-D elastic wedge *** specimen,featuring two different bottom plates(stiffened and unstiffened),each 4 mm thick,aims to assess the effect of structural stiffness on dynamic *** experiments are conducted at different drop heights of 25 cm and 50 cm and varying heel angles from 5°to 25°.The paper describes the experimental conditions,including wedge geometry,material properties,and the test *** study explores the influence of heel angle on impact acceleration,revealing an increase in peak acceleration with a higher inclination angle,particularly in the vertical ***,the hydrodynamic pressure resulting from asymmetric slamming is *** pressure results analyzed and compared at different locations along the length of the *** experimental findings indicate that,despite the leeward side(stiffened)experiencing a smaller hydrodynamic load,the heel angle significantly affects pressure results on the windward side(unstiffened),leading to a more pronounced dynamic *** time history of pressure results emphasizes the effect of elastic vibrations,particularly noticeable on the unstiffened bottom *** study contributes to a deeper understanding of asymmetric slamming on aluminum structures,facilitating the enhancement of mathematical models and the validation of numerical simulations.

关键词： Flexible fluid structure interactions(FFSI) experimental study asymmetric impact hydrodynamic pressure slamming loads

The Geology, Fluid Inclusions, and O-S Isotopes of the Mibei Gold Deposit, Hunan Province, Southern China

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Acta Geologica Sinica(English Edition) 2024年第4期98卷 992-1006页

作者： XUE Wenhao LIANG Yayun LI Xiaofeng LI Mingyi XIE Wenbo PENG Xue XIA Rui HE Hongsheng XIAO Jincheng School of Civil and resource engineering University of Science and Technology BeijingBeijing 100083China Geophysical and Geochemical Survey Institute of Hunan Changsha 410116China New Geological Energy Exploration and Development engineering technology Research Center of Hunan Changsha 410116China State Key Laboratory of Geological Processes and mineral resources China University of Geosciences(Beijing)Beijing 100083China Comprehensive Survey Command Center for Natural resources China Geological SurveyBeijing 100055China

The Mibei gold deposit,located in the southwestern part of the Xuefengshan uplift zone,the middle section of the Jiangnan orogenic belt in southern China,has estimated gold resources of approximately seven *** deposit is primarily a quartz vein-type gold deposit,with ore bodies occurring mainly within Neoproterozoic *** main metallic minerals in the ore are pyrite,chalcopyrite,and *** this study,the petrography and microthermometry of ore-forming fluid inclusions,oxygen isotopes of gold-bearing quartz,and sulfur isotopes of goldbearing sulfides and arsenopyrite were *** types of fluid inclusions were identified:type Ⅰa three-phase inclusions comprising vapor and two phases of liquids(V_(CO_(2))+L_(CO_(2))+L_(H2O)),type Ⅰb two-phase liquids(L_(CO_(2))+L_(H2O)),typeⅡ two-phase vapor-rich inclusions(V/V+L> 50%),and type Ⅲ pure liquid *** Ⅰ inclusions were heated uniformly to the liquid phase,type Ⅱ inclusions were heated uniformly to the gas phase,and type Ⅲ inclusions were heated without *** general,the temperature range of homogenization to liquid phase of fluid inclusions in the Mibei gold deposit is 204-227℃.The salinity of the inclusion ranges from 4.6 to 12.2 wt% NaCl *** δ~(18)O_(SMOW) of gold-bearing quartz varies from 16.9‰ to 17.5‰.The δ~(18)O_(H2O) of gold-bearing quartz are varied from 6.5‰ to 7.5‰.The δ~(34)S values of gold-bearing pyrite range from 1.7‰ to 6.8‰.The δ~(34)S values of gold-bearing arsenopy rite range from 5.6%o to 5.9‰.Theδ~(34)S values of pyrite from wall rocks slate range from 6.4‰ to 11.6‰.This evidence implies that the ore-forming fluids of the Mibei gold deposit originated from magmatic-hydrothermal processes,mixing with minor S from the surrounding *** with the evolution of the Jiangnan orogenic belt,due to the magmatic and tectonic activities of the Xuefengshan uplift during the Caledonian period,the fault seal mechanism controlled the ore-forming p

关键词： ore-forming fluid ore genesis Mibei gold deposit Xuefengshan uplift zone Jiangnan orogenic belt

Ferric ion-triggered surface oxidation of galena for efficient chalcopyrite-galena separation

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International Journal of minerals,Metallurgy and Materials 2024年第2期31卷 261-267页

作者： Qiancheng Zhang Limin Zhang Feng Jiang Honghu Tang Li Wang Wei Sun School of minerals Processing and Bioengineering Central South UniversityChangsha 410083China engineering Research Center of Ministry of Education for Carbon Emission Reduction in Metal resource Exploitation and Utilization Changsha 410083China School of resource and Environment Hunan University of Technology and BusinessChangsha 410083China

The efficient separation of chalcopyrite(CuFeS2)and galena(PbS)is essential for optimal resource ***,find-ing a selective depressant that is environmentally friendly and cost effective remains a *** various techniques,such as mi-croflotation tests,Fourier transform infrared spectroscopy,scanning electron microscopy(SEM)observation,X-ray photoelectron spec-troscopy(XPS),and Raman spectroscopy measurements,this study explored the use of ferric ions(Fe^(3+))as a selective depressant for *** results of flotation tests revealed the impressive selective inhibition capabilities of Fe^(3+)when used *** analysis showed that Fe^(3+)significantly reduced the adsorption of isopropyl ethyl thionocarbamate(IPETC)on the galena surface while having a minimal impact on *** analysis using SEM,XPS,and Raman spectra revealed that Fe^(3+)can oxidize lead sulfide to form compact lead sulfate nanoparticles on the galena surface,effectively depressing IPETC adsorption and increasing surface *** findings provide a promising solution for the efficient and environmentally responsible separation of chalcopyrite and galena.

关键词： galena chalcopyrite ferric ions flotation separation surface oxidation