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Electrochemical reduction of carbon dioxide to produce formic acid coupled with oxidative conversion of biomass

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Journal of Energy chemistry 2024年第5期92卷 705-729页

作者： Xi Liu Yifan Wang Zhiwei Dai Daihong Gao Xuebing Zhao Key Laboratory of industrial Biocatalysis Ministry of EducationTsinghua UniversityBeijing 100084China Institute of Applied chemistry Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

Electrochemical reduction of CO_(2)(CO_(2)RR)has become a research hot spot in recent years in the context of carbon *** is one of the most promising products obtained by electrochemical reduction of CO_(2) due to its high energy value as estimated by market price per energy unit and wide application in chemical *** is the most abundant renewable resource in the natural *** biomass oxidative conversion with CO_(2)RR driven by renewable electricity would well achieve carbon *** this work,we comprehensively reviewed the current research progress on CO_(2)RR to produce HCOOH and coupled system for conversion of biomass and its derivatives to produce value-added ***-and Bi-based electrocatalysts are discussed for CO_(2)RR with regards to the structure of the catalyst and reaction ***-oxidation reactions of biomass derived sugars,alcohols,furan aldehydes and even polymeric components of lignocellulose were reviewed as alternatives to replace oxygen evolution reaction(OER)in the conventional electrolysis *** was recommended that to further improve the efficiency of the coupled system,future work should be focused on the development of more efficient and stable catalysts,careful design of the electrolytic cells for improving the mass transfer and development of environment-friendly processes for recovering the formed formate and biomass oxidation products.

关键词： Electrochemical reduction of CO_(2) Formic acid Oxidative conversion of biomass Lignocellulose Coupled system

Alternative synthetic route for the heterometallic CO-releasing [Sb@Rh12（CO）27]3- icosahedral carbonyl cluster and synthesis of its new unsaturated [Sb@Rh12（CO）24]4- and dimeric [{Sb@Rh12Sb（CO）25}2Rh（CO）2PPh3]7- derivatives

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Progress in Natural Science:Materials International 2016年第5期26卷 461-466页

作者： Cristina Femoni Iacopo Ciabatti Maria Carmela Iapalucci Silvia Ruggieri Stefano Zacchini department of industrial chemistry “toso montanari” University of Bologna

The hetero-metallic [Sb@Rh12（CO）27]3-cluster has been known as for over three decades thanks to Vidal and co-workers, and represents the first example of an E-centered（E=heteroatom） icosahedral rhodium carbonyl cluster. However, its synthesis required high temperature（140–160 °C） and elevated CO pressure（400 atm）.Applying the redox condensation method for cluster preparation, we herein report a new synthetic, high-yield route for preparing [Sb@Rh12（CO）27]3-under much milder conditions of temperature and pressure. Notably,when the same synthesis was carried out under N2instead of CO atmosphere, the new isostructural but unsaturated derivative [Sb@Rh12（CO）24]4-was obtained, for which we report the full X-ray structural characterization. This species represents one of the few examples of an icosahedral cluster disobeying the electron-counting Wade-Mingos rules, possessing less than the expected 170 cluster valence electrons（CVEs）.Judging from IR monitoring, the two species can be obtained one from the other by switching between N2and CO atmosphere, making [Sb@Rh12（CO）27]3-a spontaneous CO-releasing molecule. Finally, the study of the chemical reactivity of [Sb@Rh12（CO）27]3-with PPh3allowed us to obtain the new [{Sb@Rh12Sb（CO）25}2Rh（CO）2PPh3]7-dimeric compound, for which we herein report the full X-ray structural and31P NMR analyses.

关键词： Carbonyl cluster Rhodium Antimony Crystal structure Synthesis

Effect of Humidity on Formaldehyde Oxidation over Ce_(0.8)Zr_(0.2)O_(y)Catalyst

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Journal of Wuhan University of Technology(Materials Science) 2024年第5期39卷 1108-1115页

作者： TANG Ruijiu YANG Zonglin LIU Xiang JIA Lijuan WANG Fang DUAN Kaijiao LIU Tiancheng College of chemistry and Environment Yunnan Minzu UniversityTechnology Innovation Team of Green Purification Technology for Industrial Waste GasEducation Department of YunnanKey Laboratory of Environmental Functional Materials of Yunnan Province Education DepartmentKunming 650504China

In the preparation of a series of Ce_(0.8)Zr_(0.2)O_(y)catalysts catalyzing the removal of formaldehyde,BET,H2-TPR,IR,SEM,XPS,and XRD were used to characterize the catalyst,and the influence of humidity on the catalyst activity was studied by adjusting the humidity during the *** experimental results showed that the formaldehyde removal rate increased with the increase of *** the humidity was higher than 50%,the formaldehyde removal rate decreased by 3%over that when the humidity was 50%.The characterization results showed that humidity facilitated the activation of oxygen and the formation of hydroxyl groups,which both promoted the formation and oxidative decomposition of intermediates and prevented the deposition of intermediates that clogged the pores,allowing more formaldehyde to be adsorbed and oxidized,which increased the activity of the *** provides new mechanistic evidence for the oxidation of formaldehyde and helps in the development of relatively low-cost materials for formaldehyde purification.

关键词： formaldehyde humidity Ce_(0.8)Zr_(0.2)O_(y) catalytic oxidation

Evaluating innovation ecosystem resiliency using agent-based modeling and systems dynamics

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Journal of Safety Science and Resilience 2024年第2期5卷 204-221页

作者： Soheila Abdi Mehdi Yazdani Esmaeil Najafi department of industrial Engineering Science and Research BranchIslamic Azad UniversityTehranIran department of industrial Engineering Qazvin BranchIslamic Azad UniversityQazvinIran

Evaluating the resilience of the innovation ecosystem to maintain its performance,in the sense of resistance to disruption and recovery after it,has recently received more *** studies have been conducted to model different ecosystems and evaluate their ***,modeling the innovation ecosystem from a holistic perspective and performing a quantitative assessment of its resilience have received less *** paper models the innovation ecosystem holistically and evaluates its resilience index using a quantitative approach through five main *** the first step,a case study related to the innovation ecosystem of Iran's Ministry of Energy,called the Power Innovation Ecosystem,is modeled by combining system dynamics and agent-based *** validating the model in the second step,the disruption of the loss of experts is investigated in the third step,and all possible actions to recover each actor are *** the fourth step,the performance of the ecosystem is simulated before and after the disruption using the data gathered in the previous ***,resilience is calculated in two different ways in the fifth *** improvement solutions are also suggested when considering that the resilience index of the innovation ecosystem is at a medium *** research may assist policymakers in observing the resilience level of the innovation ecosystem based on the proposed *** applying strategic changes to this model,they can determine the effects of their policies and make the most appropriate decisions to increase the resilience of the innovation ecosystem.

关键词： Resilience index innovation ecosystem System dynamics Agent-based modeling

Predicting grain size-dependent superplastic properties in friction stir processed ZK30 magnesium alloy with machine learning methods

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Journal of Magnesium and Alloys 2024年第5期12卷 1931-1943页

作者： Farid Bahari-Sambran Fernando Carreno C.M.Cepeda-Jiménez Alberto Orozco-Caballero Physical Metallurgy department CENIM-CSICAv.Gregorio del Amo 828040 MadridSpain department of Mechanical Engineering Chemistry and Industrial DesignPolytechnic University of MadridRonda de Valencia 328012MadridSpain

The aim of this work is to predict,for the first time,the high temperature flow stress dependency with the grain size and the underlaid deformation mechanism using two machine learning models,random forest(RF)and artificial neural network(ANN).With that purpose,a ZK30 magnesium alloy was friction stir processed(FSP)using three different severe conditions to obtain fine grain microstructures(with average grain sizes between 2 and 3μm)prone to extensive superplastic *** three friction stir processed samples clearly deformed by grain boundary sliding(GBS)deformation mechanism at high *** maximum elongations to failure,well over 400% at high strain rate of 10^(-2)s^(-1),were reached at 400℃ in the material with coarsest grain size of 2.8μm,and at 300℃ for the finest grain size of 2μ***,the superplastic response decreased at 350℃ and 400℃ due to thermal instabilities and grain coarsening,which makes it difficult to assess the operative deformation mechanism at such *** work highlights that the machine learning models considered,especially the ANN model with higher accuracy in predicting flow stress values,allow determining adequately the superplastic creep behavior including other possible grain size scenarios.

关键词： Machine learning Artificial intelligence Magnesium alloys Superplasticity Friction stir processing Grain coarsening

Analysis of Supply Chain Sustainability Drivers in the Oil and Gas Industry under Covid-19 Pandemic

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Journal of Systems Science and Systems Engineering 2024年第2期33卷 131-161页

作者： Sujan Piya department of industrial Engineering and Engineering Management University of SharjahSharjahUnited Arab Emirates

The supply chain of many industries,including Oil and Gas,was significantly affected by the disruption caused by the Covid ***,in turn,had a knock-on effect on other industries around the *** the impact of the disruption posed a major challenge for the *** study contributes to the existing literature by identifying and analyzing the most significant drivers that affected the sustainability of the Oil and Gas supply chain during the Covid *** drivers were identified based on an extensive literature review and a survey conducted with experts working in the Oil and Gas ***-criteria decision-making methodologies were used to analyze these *** analysis from the fuzzy analytical hierarchy process found that the most important drivers for the sustainability of the Oil and gas supply chain during the pandemic were"Risk management capacity","Government regulation"and"Health and safety of employees".On the other hand,the driver"Community Pressure"was found to be of the least ***,the study integrated the results of the fuzzy analytical hierarchy process with the fuzzy technique for order of preference by similarity to ideal solution to calculate the supply chain sustainability index.A case example was demonstrated to rank the industries based on such *** study can support the governmental institutions in benchmarking the Oil and Gas industry based on its sustainability ***,the outcomes of the study will help industrial decision makers prioritize the drivers the company should focus and devise strategies based on the priority to improve the sustainability of their supply chain during severe *** will be crucial as the World health organization has cautioned that the world may encounter another pandemic in the near future.

关键词： Supply chain sustainability drivers Oil and gas supply chain Fuzzy analytical hierarchy process Fuzzy technique for order of preference by similarity to ideal solution Covid-19

Lithium-Metal Free Sulfur Battery Based on Waste Biomass Anode and Nano-Sized Li_(2)S Cathode

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Energy & Environmental Materials 2024年第2期7卷 39-47页

作者： Pejman Salimi Eleonora Venezia Somayeh Taghavi Sebastiano Tieuli Lorenzo Carbone Mirko Prato Michela Signoretto Jianfeng Qiu Remo Proietti Zaccaria Istituto Italiano di Tecnologia via Morego 30Genoa 16163Italy department of chemistry and industrial chemistry University of Genovavia Dodecaneso 311-16146Genoa Italy CATMAT Lab Department of Molecular Sciences and NanosystemsCa'Foscari University Venice and INSTM ConsortiumRU of VeniceVia Torino 15530172Venezia Mestre Italy department of Physics Shaoxing UniversityShaoxing 312000China

The realization of a stable lithium-metal free(LiMF)sulfur battery based on amorphous carbon anode and lithium sulfide(Li_(2)S)cathode is here *** particular,a biomass waste originating full-cell combining a carbonized brewer's spent grain(CBSG)biochar anode with a Li_(2)S-graphene composite cathode(Li_(2)S70Gr30)is *** design is particularly attractive for applying a cost-effective,high performance,environment friendly,and safe anode material,as an alternative to standard graphite and metallic lithium in emerging battery *** anodic and cathodic materials are characterized in terms of structure,morphology and composition through X-ray diffraction,scanning and transmission electron microscopy,X-ray photoelectron and Raman ***,an electrochemical characterization comprising galvanostatic cycling,rate capability and cyclic voltammetry tests were carried out both in half-cell and full-cell *** systematic investigation reveals that unlike graphite,the biochar electrode displays good compatibility with the electrolyte typically employed in sulfur *** CBSG/Li_(2)S70Gr30 full-cell demonstrates an initial charge and discharge capacities of 726 and 537 mAh g^(-1),respectively,at 0.05C with a coulombic efficiency of 74%.Moreover,it discloses a reversible capacity of 330 mAh g^(-1)(0.1 C)after over 300 *** on these achievements,the CBSG/Li_(2)S70Gr30 battery system can be considered as a promising energy storage solution for electric vehicles(EVs),especially when taking into account its easy scalability to an industrial level.

关键词： biochars ether-based electrolytes lithium sulfide lithium-metal free batteries superior cycling stability

Tribological behavior of shape-specific microplate-enriched synovial fluids on a linear two-axis tribometer

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Friction 2024年第3期12卷 539-553页

作者： Agnese FRAGASSI Antonietta GRECO Martina DI FRANCESCO Luca CESERACCIU Aiman ABU AMMAR Israel DVIR Thomas Lee MOORE Haytam KASEM Paolo DECUZZI Laboratory of Nanotechnology for Precision Medicine Fondazione Istituto Italiano di TecnologiaGenova 16163Italy department of chemistry and industrial chemistry University of GenovaGenoa 16146Italy Materials Characterization Facility Istituto Italiano di TecnologiaGenova 16163Italy department of Pharmaceutical Engineering Azrieli College of Engineering JerusalemJerusalem 9103501Israel department of Mechanical Engineering Azrieli College of Engineering JerusalemJerusalem 9103501Israel

Nano-and micro-particles are being increasingly used to tune interfacial frictional properties in diverse applications,from friction modifiers in industrial lubrication to enhanced biological fluids in human osteoarthritic ***,we assessed the tribological properties of a simulated synovial fluid enriched with non-spherical,poly lactic-co-glycolic acid(PLGA)microparticles(μPL)that have been previously demonstrated for the pharmacological management of osteoarthritis(OA).Three different μPL configurations were fabricated presenting a 20μm×20μm square base and a thickness of 5μm(thin,5H μPL),10μm(10H μPL),and 20μm(cubical,20H μPL).After extensive morphological and physicochemical characterizations,the apparent Young’s modulus of the μPL was quantified under compressive loading returning an average value of~6 kPa,independently of the particle ***,using a linear two-axis tribometer,the static(μ_(s))and dynamic(μ_(d))friction coefficients of the μPL-enriched simulated synovial fluid were determined in terms of particle configuration and concentration,varying from 0(fluid only)to 6×10^(5) μPL/*** particle morphology had a modest influence on friction,possibly because the μPL were fully squeezed between two mating surfaces by a 5.8 N normal load realizing boundary-like lubrication ***,friction was observed to depend on the dimensionless parameterW,defined as the ratio between the total volume of the μPL enriching the simulated synovial fluid and the volume of the fluid *** coefficients of friction were documented to grow withWreaching a plateau of μ_(s)~0.4 and μ_(d)~0.15,already at Ω~2×10^(-3).Future investigations will have to systematically analyze the effect of sliding velocity,normal load,and rigidity of the mating surfaces to elucidate in full the tribological behavior of μPL in the context of osteoarthritis.

关键词： osteoarthritis microparticles tribology synovial fluid pin on plate

Porous garnet as filler of solid polymer electrolytes to enhance the performance of solid-state lithium batteries

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Nano Research 2024年第4期17卷 2663-2670页

作者： Yang Zhang Lei Zhang Peng Guo Chaoyan Zhang Xiaochuan Ren Zhen Jiang Jianjun Song Chuan Shi College of Physics Qingdao UniversityQingdao 266071China industrial Research Institute of Nonwovens and Technical Textiles College of Textiles and ClothingQingdao UniversityQingdao 266071China department of chemistry University of PennsylvaniaPhiladelphiaPA 19104USA

In order to enhance the ionic conductivity of solid polymer electrolytes(SPEs)and their structural rigidity against lithium dendrite during lithium-ion battery(LIB)cycling,we propose porous garnet Li6.4La3Zr2Al0.2O12(LLZO),as the filler to *** porous LLZO with interlinked grains was synthesized via a resol-assisted cationic coordinative co-assembly *** porous structure of LLZO with high specific surface area facilitates the interaction between polymer and filler and provides sufficient entrance for Li^(+)migration into the LLZO ***,the interconnection of LLZO grains forms continuous inorganic pathways for fast Li^(+)migration,which avoid the multiple diffusion for Li^(+)in *** a result,the SPEs with porous LLZO(SPE-PL)show a high ionic conductive of 0.73 mS·cm^(-1) at 30℃ and lithium-ion transference number of *** porous LLZO with uniformly dispersed pores also acts as an ion distributor to regulate ionic *** lithium-symmetrical batteries assembled with SPE-PL show a highly stable Li plating/stripping cycling for nearly 3000 h at 0.1 mA·cm^(-2).The corresponding Li/LiFePO_(4) batteries also exhibit excellent cyclic performance with capacity retention of 75%after nearly 500 *** work brings new insights into the design of conductive fillers and the optimization of SPEs.

关键词： solid polymer electrolytes lithium metal battery porous conductive filler solid state battery