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Advancing respirable coal mine dust source apportionment:a preliminary laboratory exploration of optical microscopy as a novel monitoring tool

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International Journal of Coal Science & Technology 2024年第2期11卷 222-233页

作者： Nestor Santa Emily Sarver department of Mining and minerals engineering Virginia TechBlacksburgVA 24061USA

Exposure to respirable coal mine dust(RCMD)can cause chronic and debilitating lung ***-time monitoring capabilities are sought which can enable a better understanding of dust components and *** many underground mines,RCMD includes three primary components which can be loosely associated with three major dust sources:coal dust from the coal seam itself,silicates from the surrounding rock strata,and carbonates from the inert‘rock dust’products that are applied to mitigate explosion hazards.A monitor which can reliably partition RCMD between these three components could thus allow source *** tracking silicates,specifically,could be valuable since the most serious health risks are typically associated with this component-particularly if abundant in crystalline *** a monitoring concept based on field microscopy,and following up on prior research using polarized light,the aim of the current study was to build and test a model to classify respirable-sized particles as either coal,silicates,or *** model development,composite dust samples were generated in the laboratory by successively depositing dust from high-purity materials onto a sticky transparent substrate,and imaging after each deposition event such that the identity of each particle was known a *** testing followed a similar approach,except that real geologic materials were used as the source for each dust *** showed that the model had an overall accuracy of 86.5%,indicating that a field-microscopy based moni-tor could support RCMD source apportionment and silicates tracking in some coal mines.

关键词： Polarized light microscopy Image processing Dust monitoring Respirable silica Coal mining

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Experimental Study on Heat Storage Properties Comparison of Paraffin/Metal Foams Phase Change Material Composites

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Journal of Thermal Science 2024年第2期33卷 469-478页

作者： Waqar AHMED Abid HUSSAIN Hanzla SHAHID Imran ALI Hafiz Muhammad ALI department of Mechanical engineering University of Engineering and TechnologyTaxila47080Pakistan department of Mechanical engineering Institute of Space TechnologyIslamabadPakistan department of Mechanical Mechatronics and Manufacturing EngineeringUniversity of Engineering and Technology LahoreFaisalabad CampusPunjabPakistan Mechanical engineering department King Fahd University of Petroleum and MineralsDhahran31261Saudi Arabia Interdisciplinary Research Center for Renewable Energy and Power Systems(IRC-REPS) King Fahd University of Petroleum and MineralsDhahran31261Saudi Arabia

Heat storage properties of phase change materials(PCMs) are essential characteristics that perform a key role in thermal heat energy storage *** thermal properties of PCMs can be improved by developing metal foam/PCM *** addition of metal foam in PCMs has a significant effect on the thermal characteristics of *** this paper,the heat storage properties of two different metal foam/PCM composites were experimentally *** behavior of paraffin in metal foam(copper and iron-nickel)/paraffin composites concerning pure paraffin at a constant heat flux of 1000 W/m^(2) in three directions simultaneously(x,y,and z) was *** was infiltrated into copper and iron-nickel foams to develop composite materials which resulted in enhancing the thermal conductivity of the paraffin.A comparative analysis is made on the heat storage properties of paraffin in copper and iron-nickel foams/paraffin *** temperature distribution during the phase transition process is experimentally *** comparison indicates that temperature uniformity in copper foam/paraffin composite is better than in iron-nickel foam/paraffin composite and pure paraffin at the same heat *** results show that at heat flux of 1000 W/m^(2),the heat storage time for copper foam/paraffin composite is 20.63% of that of iron-nickel foam/paraffin composite.

关键词： heat storage capacity paraffin/metal foam composite temperature uniformity heat storage rate phase transition process

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The viscous strip approach to simplify the calculation of the surface acoustic wave generated streaming

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Applied Mathematics and Mechanics(English Edition) 2024年第4期45卷 711-724页

作者： F.JAZINI DORCHEH M.GHASSEMI fuel Cells and Nano Systems(FCNS)Laboratory Department of Mechanical EngineeringK.N.Toosi University of TechnologyTehran 19697Iran

In recent decades,the importance of surface acoustic waves,as a biocompatible tool to integrate with microfluidics,has been proven in various medical and biological *** numerical modeling of acoustic streaming caused by surface acoustic waves in microchannels requires the effect of viscosity to be considered in the equations which complicates the *** this paper,it is shown that the major contribution of viscosity and the horizontal component of actuation is concentrated in a narrow region alongside the actuation *** the inviscid equations are considerably easier to solve,a division into the viscous and inviscid domains would alleviate the computational load *** particles'traces calculated by this approximation are excellently alongside their counterparts from the completely viscous *** is also shown that the optimum thickness for the viscous strip is about 9-fold the acoustic boundary layer thickness for various flow patterns and amplitudes of actuation.

关键词： surface acoustic wave microfluidics numerical simulation particle tracing acoustic streaming

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Analysis on carbon emission reduction intensity of fuel cell vehicles from a life-cycle perspective

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Frontiers in Energy 2024年第1期18卷 16-27页

作者： Ziyuan TENG Chao TAN Peiyuan LIU Minfang HAN fuel Cell and Energy Storage Center Department of Energy and Power EngineeringState Key Laboratory of Control and Simulation of Power Systems and Generation EquipmentTsinghua UniversityBeijing 100084China

The hydrogen fuel cell vehicle is rapidly developing in China for carbon reduction and *** paper evaluated the life-cycle cost and carbon emission of hydrogen energy via lots of field surveys,including hydrogen production and packing in chlor-alkali plants,transport by tube trailers,storage and refueling in hydrogen refueling stations(HRSs),and application for use in two different *** also conducted a comparative study for battery electric vehicles(BEVs)and internal combustion engine vehicles(ICEVs).The result indicates that hydrogen fuel cell vehicle(FCV)has the best environmental performance but the highest energy ***,a sufficient hydrogen supply can significantly reduce the carbon intensity and FCV energy cost of the current *** carbon emission for FCV application has the potential to decrease by 73.1%in City A and 43.8%in City *** only takes 11.0%–20.1%of the BEV emission and 8.2%–9.8%of the ICEV *** cost of FCV driving can be reduced by 39.1%in City *** improvement can be obtained with an economical and“greener”hydrogen production pathway.

关键词： hydrogen energy life-cycle assessment(LCA) fuel cell vehicle carbon emission energy cost

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Implications of electrode modifications in aqueous organic redox flow batteries

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Journal of Energy Chemistry 2024年第8期95卷 499-510,I0011页

作者： Zahid Manzoor Bhat Mohammad Furquan Muhammad Aurang Zeb Gul Sial Umair Alam Atif Saeed Alzahrani Mohammad Qamar Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management(IRC-HTCM) King Fahd University of Petroleum&Minerals(KFUPM)Dhahran 31261Saudi Arabia department of Materials Science and engineering King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia Interdisciplinary Research Center for Sustainable Energy Systems(IRC-SES) King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia

Aqueous organic redox flow batteries(RFBs)exhibit favorable characteristics,such as tunability,multielectron transfer capability,and stability of the redox active molecules utilized as anolytes and catholytes,making them very viable contenders for large-scale grid storage *** attention has been paid on the development of efficient redox-active molecules and their performance optimization through chemical substitutions at various places on the backbone as part of the pursuit for high-performance *** the fact that electrodes are vital to optimal performance,they have not garnered significant *** research has been conducted on the effects of electrode modifications to improve the performance of *** primary emphasis has been given on the impact of electrode engineering to augment the efficiency of aqueous organic *** overview of electron transfer at the electrode-electrolyte interface is *** implications of electrode modification on the performance of redox flow batteries,with a particular focus on the anodic and cathodic half-cells separately,are then *** each section,significant discrepancies surrounding the effects of electrode engineering are thoroughly examined and ***,we have presented a comprehensive assessment along with our perspectives on the future trajectory.

关键词： Redox flow batteries Electrode modification Organic redox molecules Outer sphere and inner sphere

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A Novel Layered Double Hydroxide and Dodecyl Alcohol Assisted PCM Composite with High Latent Heat Storage Capacity and Thermal Conductivity

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Journal of Thermal Science 2024年第2期33卷 537-547页

作者： AL-AHMED Amir SARI Ahmet KHAN Firoz AL-RASHEIDI Masoud Hekimoğlu Gökhan AFZAAL Mohammad A.ALSULAMI Ahmed DAFALLA Hatim SALHI Billel A.ALSULAIMAN Fahad Interdisciplinary Research Center for Renewable Energy and Power Systems(IRC-REPS) King Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia department of Metallurgical and Material engineering Karadeniz Technical UniversityTrabzon61080Turkey Maths and Natural Sciences Division Higher Colleges of TechnologyP.O.Box 7947SharjahUnited Arab Emirates department of Mechanical engineering King Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia Core Research Facilities King Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia Interdisciplinary Research Center for Membranes and Water Security King Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia

Dodecyl alcohol(DDA) is a promising solid-liquid phase change material(PCM) due to its favorable latent heat storage(LHS) ***,the leakage issue of PCM in a melted state during the heating period and low thermal conductivity restricts its utilization potential in thermal energy storage(TES) *** the same context,the present work aims to overcome the leakage issue and improve the thermal conductivity of the *** this in mind,a novel leak-proof layered double hydroxide(LDH)/DDA composite PCM is proposed through a solution-based impregnation *** leak-proof impregnation ratio of the DDA impregnated within the cavities of the synthesized Al/Fe-LDH was determined to be 60%.Detailed morphological,physicochemical,and thermal properties of the fabricated composite were studied by scanning electron microscopy(SEM),Fourier transforms infrared(FTIR) spectroscopy,X-ray diffraction(XRD)spectroscopy,differential scanning calorimetry(DSC),thermalgravimetric analysis(TGA),and thermal cycling *** results show that the LDH/DDA composite has a suitable phase change temperature(about 20℃) for passive solar thermal management of building *** composite PCM showed high LHS enthalpy(about136 J/g),good thermal stability,and cycling LHS *** also showed nearly 152% higher thermal conductivity compared to that of pure DDA,ultimately reducing the melting and solidification time of the pure DDA by 44.9% and 45.5%,respectively.

关键词： dodecyl alcohol layered double hydroxide composite PCM thermal conductivity thermal energy storage(TES)

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Effects of dust controls on respirable coal mine dust composition and particle sizes:case studies on auxiliary scrubbers and canopy air curtain

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International Journal of Coal Science & Technology 2024年第3期11卷 86-101页

作者： F.Animah C.Keles W.R.Reed E.Sarver department of Mining and minerals engineering Virginia Polytechnic Institute&State UniversityBlacksburgVAUSA National Institute of Occupational Safety and Health(NIOSH) PittsburghPAUSA

Control of dust in underground coal mines is critical for mitigating both safety and health *** decades,the National Institute of Occupational Safety and Health(NIOSH)has led research to evaluate the effectiveness of various dust control technologies in coal *** studies have included the evaluation of auxiliary scrubbers to reduce respirable dust downstream of active mining and the use of canopy air curtains(CACs)to reduce respirable dust in key operator *** detailed dust characterization was not a focus of such studies,this is a growing area of *** preserved filter samples from three previous NIOSH studies,the current work aims to explore the effect of two different scrubbers(one wet and one dry)and a roof bolter CAC on respirable dust composition and particle size *** this,the preserved filter samples were analyzed by thermogravimetric analysis and/or scanning electron microscopy with energy dispersive *** indicate that dust composition was not appreciably affected by either scrubber or the ***,the wet scrubber and CAC appeared to decrease the overall particle size *** an effect of the dry scrubber was not consistently observed,but this is probably related to the particular sampling location downstream of the scrubber which allowed for significant mixing of the scrubber exhaust and other return *** from the insights gained with respect to the three specific dust control case studies revisited here,this work demonstrates the value of preserved dust samples for follow-up investigation more broadly.

关键词： Respirable dust Dust control SEM–EDX Scrubber Canopy air curtain Silica

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The utilization of spent palm cooking oil for formulating oil-based drilling muds with excellent H_(2)S scavenging capability

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Petroleum Research 2024年第2期9卷 280-288页

作者： Sagheer A.Onaizi department of Chemical engineering and Interdisciplinary Research Center for Hydrogen and Energy StorageKing Fahd University of Petroleum&Minerals31261DhahranSaudi Arabia

In this study,a spent palm cooking oil-based mud with an excellent H_(2)S scavenging capability induced by the inclusion of a small quantity of potassium permanganate is formulated and tested for the first *** mud formulation,containing the spent palm oil as the continuous phase and water as the dispersed phase,respectively,was stabilized by Span 80 and rhamnolipid biosurfactant as primary and secondary emulsifiers,respectively,while hydrophobic zinc nanoparticles(NPs)were used as weighting *** results showed that H_(2)S scavenging capacity at the breakthrough time reached 182.4 g H_(2)S/barrel mud,which increased to 417.9 g H_(2)S/barrel mud at the saturation time,demonstrating the effective H_(2)S scavenging performance of the formulated *** spent palm oil-based mud(SPOBM)also showed a good flow behavior that could be well fitted using the Herschel-Bulkley and Casson *** effect of temperature on the apparent viscosity of the SPOBM has been investigated,and the fitting of the viscosity-temperature data provided an estimate of the activation energy as 23.53 kJ/*** findings reported in this article reveal the feasibility of transforming the spent/waste cooking oils into a valuable commodity for formulating greener drilling fluids with acceptable rheology and excellent H_(2)S scavenging performance.

关键词： Hydrogen sulfide(H_(2)S) Oil-based mud(OBM)drilling fluids Spent palm oil H_(2)S scavengers Rheology

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Advanced electrocatalysts with unusual active sites for electrochemical water splitting

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InfoMat 2024年第1期6卷 65-82页

作者： Hainan Sun Xiaomin Xu Hyunseung Kim Zongping Shao WooChul Jung department of Materials Science and engineering Korea Advanced Institute of Science and Technology(KAIST)DaejeonRepublic of Korea WA School of Mines:minerals Energy and Chemical engineering(WASM-MECE) Curtin UniversityPerthWestern AustraliaAustralia

Electrochemical water splitting represents a promising technology for green hydrogen *** design advanced electrocatalysts,it is crucial to identify their active sites and interpret the relationship between their structures and *** extensively studied as electrocatalysts include noble-metal-based(e.g.,Ru,Ir,and Pt)and non-noble-metal-based(e.g.,3d transition metals)***,advancements in characterization techniques and theoretical calculations have revealed novel and unusual active *** present review highlights the latest achievements in the discovery and identification of various unconventional active sites for electrochemical water splitting,with a focus on state-of-the-art strategies for determining true active sites and establishing structure–activity ***,we discuss the remaining challenges and future perspectives for the development of next-generation electrocatalysts with unusual active *** presenting a fresh perspective on the unconventional reaction sites involved in electrochemical water splitting,this review aims to provide valuable guidance for the future study of electrocatalysts in industrial applications.

关键词： electrochemical water splitting hydrogen evolution reaction oxygen evolution reaction structure–activity relationship unusual active sites

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Boosting the catalytic activity toward oxygen reduction via a heterostructure of porous iron oxide-decorated 2D NiO/NG nanosheets

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Journal of Energy Chemistry 2024年第6期93卷 669-681,I0016页

作者： Kakali Maiti Matthew T.Curnan Hyung Jun Kim Kyeounghak Kim Jeong Woo Han department of Chemical engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbuk 37673Republic of Korea department of Materials Science and engineering Research Institute of Advanced MaterialsSeoul National UniversitySeoul 08826Republic of Korea department of Chemical engineering Clean-Energy Research InstituteHanyang UniversitySeoul 04763Republic of Korea CSIR-Institute of minerals and Materials Technology RRL CampusAcharya ViharBhubaneswarOdisha 751013India

As a noble metal substitute,two-dimensional(2D)hierarchical nano-frame structures have attracted great interest as candidate catalysts due to their remarkable advantages-high intrinsic activity,high electron mobility,and straightforward surface ***,they may replace Pt-based catalysts in oxygen reduction reaction(ORR)***,a simple method is developed to design hierarchical nano-frame structures assembled via 2D NiO and N-doped graphene(NG)*** procedure can yield nanostructures that satisfy the criteria correlated with improved electrocatalytic performance,such as large surface area,numerous undercoordinated atoms,and high defect ***,porous NG nanosheet architectures,featuring NiO nanosheets densely coordinated with accessible holey Fe_(2)O_(3) moieties,can enhance mesoporosity and balance *** improvements can facilitate charge transport and expose formerly inaccessible reaction sites,maximizing active site density *** functional theory(DFT)calculations reveal favored O_(2) adsorption and dissociation on Fe_(2)O_(3) hybrid structures when supported by 2D NiO and NG nanomaterials,given 2D materials donated charge to Fe_(2)O_(3) active *** systematic studies reveal that synergistic contributions are responsible for enriching the catalytic activity of Fe_(2)O_(3)@NiO/NG in alkaline media-encompassing internal voids and pores,unique hierarchical support structures,and concentrated N-dopant and bimetallic atomic ***,this work expands the toolbox for designing and synthesizing highly efficient 2D/2D shelled functional nanomaterials with transition metals,endeavoring to benefit energy conversion and related ORR applications.

关键词： N-doped graphene Holey Fe_(2)O_(3)nanocrystals NiO nanosheets High catalytic performance ORR

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