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Particuology 2024年第8期91卷 260-267页

作者： Tom Lang Jens Bartsch Laboratory of Solids Process engineering Department of Biochemical and Chemical EngineeringTU Dortmund University44227DortmundGermany

In comparison to the established twin-screw machines,the application of a planetary roller granulator for continuous operation of melt granulation is a promising alternative based on the unique process *** initial study focused on the material transport during processing as a key driver for the overall ***,the impact of direct process parameters on the residence time distribution was the main *** investigations are complemented in this study by considering the free processing volume,which is defined by the number of planetary spindles applied within a *** impact on the processing conditions is evaluated with respect to the process setting in terms of feed rate and rotation *** results highlight the potential of altering the underlying transport function in planetary roller melt granulation(PRMG)via the investigated direct process and equipment *** impact of the feed rate is lower in comparison,while a higher rotation speed as well as a higher free processing volume promote material ***,a normalization of the determined residence time distribution(RTD)model data was feasible with respect to the process settings and the number of applied planetary spindles in the processing *** demonstrates the key role of the free processing volume in the fundamental mechanisms of material transport and mixing during PRMG.

关键词： Continuous manufacturing Melt granulation Planetaryroller granulator Quality-by-Design Residence time Material mixing

Sustainable ammonia synthesis:An in-depth review of non-thermal plasma technologies

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Journal of Energy Chemistry 2024年第9期96卷 1-38页

作者： Vahid Shahed Gharahshiran Ying Zheng department of Chemical and biochemical engineering Thompson Engineering BuildingWestern UniversityLondonON N6A 5B9Canada

Ammonia serves both as a widely used fertilizer and environmentally friendly energy source due to its high energy density,rich hydrogen content,and emissions-free ***,it offers convenient transportation and storage as a hydrogen *** dominant method used for large-scale ammonia production is the Haber-Bosch process,which requires high temperatures and pressures and is ***,non-thermal plasma offers an eco-friendly alternative for ammonia synthesis,gaining significant *** enables ammonia production at lower temperatures and pressures using plasma *** review provides insights into the catalyst and reactor developments,which are pivotal for promoting ammonia efficiency and addressing existing *** first,the reaction kinetics and mechanisms are introduced to gain a comprehensive understanding of the reaction pathways involved in plasma-assisted ammonia ***,the enhancement of ammonia synthesis efficiency is discussed by developing and optimizing plasma reactors and effective *** effect of other feeding sources,such as water and methane,instead of hydrogen is also ***,the challenges and possible solutions are outlined to facilitate energy-saving and enhance ammonia efficiency in the future.

关键词： Nitrogen fixation Ammonia synthesis NH_(3) Non-thermal plasma Ni Ru catalyst

Biodegradability of bioplastics in different aquatic environments:A systematic review

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Journal of environmental Sciences 2024年第8期142卷 169-181页

作者： Maria Cristina Lavagnolo Valentina Poli Anna Maria Zampini Valentina Grossule department of Civil Environmental and Architectural Engineering-Laboratory of Environmental EngineeringUniversity of PadovaLungargine Rovetta 8Padova 35100Italy

Bioplastics were first introduced as environmentally friendly materials,with properties similar to those of conventional plastics.A bioplastic is defined as biodegradable if it can be decomposed into carbon dioxide under aerobic degradation,or methane and CO_(2)under anaerobic conditions,inorganic compounds,and new cellular biomass,by the action of naturally occurring *** definition however does not provide any information on the environmental conditions,timescale and extent at which decomposition processes should *** regard to the aquatic environment,recognized standards have been established to assess the ability of plastics to undergo biodegradation;however,these standards fail to provide clear targets to be met to allow labelling of a bioplastic as ***,these standards grant the user an extensive leeway in the choice of process *** these reasons,the comparison of results deriving from different studies is *** authors analysed and discussed the degree of biodegradability of a series of biodegradable bioplastics in aquatic environments(both fresh and salt water)using the results obtained in the laboratory and from on-site testing in the context of different research *** Oxygen Demand(BOD),CO_(2)evolution,surface erosion and weight loss were the main parameters used by researchers to describe the percentage of *** results showed a large variability both in weight loss and BOD,even when evaluating the same type of *** confirms the need for a reference range of values to be established with regard to parameters applied in defining the biodegradability of bioplastics.

关键词： Biodegradation Bioplastic Plastic Natural environment Plastic waste

Significant enhancement in local thermal conductivity of erythritol at interface with nanoparticles due to their interaction

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Nano Research 2024年第8期17卷 7726-7736页

作者： Ning Cao Yanhui Feng Kening Yan Zihan Liu Jiawei Wan Lin Qiu School of Energy and environmental engineering University of Science and Technology BeijingBeijing 100083China State Key Laboratory of biochemical engineering Key Laboratory of Biopharmaceutical Preparation and DeliveryInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

When nano-fillers are used to enhance the thermal conductivity of organic phase change materials(PCMs),the naturally formed interface is considered to hinder thermal transport of the composite ***,the effect of the interface on the thermal properties of surrounding PCM has not been fully *** this paper,three composite PCMs(Ery@SiC,Ery@SiO_(2) and Ery@Si_(3)N_(4))were prepared by melt-blending *** local thermal conductivity and reduced Young’s modulus(E^(*))of the erythritol at the interface and far away from the interface in the composite PCMs were simultaneously measured by scanning thermal microscopy(SThM).The results revealed significant enhancement in local thermal conductivity of erythritol at the interface and its obvious positive correlation with E^(*).For different composite PCMs,molecular dynamics(MD)simulations suggested that the increase in intrinsic thermal conductivity and E^(*)of erythritol is attributed to the increase in interaction energy between erythritol and nanoparticles,as more erythritol phonon vibrations transform from localized mode to delocalized mode and erythritol has a higher density at the *** findings will provide new ideas for the design of PCM for energy storage.

关键词： scanning thermal microscopy phase change materials thermal conductivity reduced Young’s modulus interaction energy phonon participation ratio

Aggregation-regulated bioreduction process of graphene oxide by Shewanella bacteria

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Chinese Journal of Chemical engineering 2024年第5期69卷 56-62页

作者： Kaixin Han Yibo Zeng Yinghua Lu Ping Zeng Liang Shen department of Chemical and biochemical engineering College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Pen-Tung Sah Institute of Micro-Nano Science and Technology Xiamen UniversityXiamen 361005China Chinese Research Academy of environmental Sciences Beijing 100012China

The bioreduction of graphene oxide(GO)using environmentally functional bacteria such as Shewanella represents a green approach to produce reduced graphene oxide(rGO).This process differs from the chemical reduction that involves instantaneous molecular *** bioreduction,the contact of bacterial cells and GO is considered the rate-limiting *** reveal how the bacteria-GO integration regulates rGO production,the comparative experiments of GO and three Shewanella strains were carried ***-transform infrared spectroscopy,X-ray photoelectron spectroscopy,Raman spectroscopy,and atomic force microscopy were used to characterize the reduction degree and the aggregation *** results showed that a spontaneous aggregation of GO and Shewanella into the condensed entity occurred within 36 h.A positive linear correlation was established,linking three indexes of the aggregation potential,the bacterial reduction ability,and the reduction degree(ID/IG)comprehensively.

关键词： Graphene oxide Reduced graphene oxide Bioreduction Aggregation Shewanella

Assessment of the implementation status of best available techniques for cleaner production in the textile industry

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Frontiers of environmental Science & engineering 2024年第8期18卷 133-148页

作者： Mehmet Eren Yaman Emrah Ozturk Ulku Yetis Mehmet Kitis department of environmental engineering Suleyman Demirel UniversityIsparta 32260Turkey department of environmental Protection Technologies Isparta University of Applied SciencesIsparta 32200Turkey department of environmental engineering Middle East Technical UniversityAnkara 06800Turkey

The draft Integrated Pollution Prevention and Control(IPPC)regulation mandates compliance with best available techniques(BATs)for textile manufacturers.A study in Turkish textile facilities,covering 56 units across four sub-sectors,assessed the status of 488 BATs through on-site visits and *** aim was to gauge the sector’s adherence to *** findings revealed that 37% of surveyed BATs were fully implemented,rising to 88% when considering potential future *** suggests a strong industry inclination toward adopting BATs for cleaner production and *** study highlighted significant BAT-related investments in the textile sector,driven by environmental concerns,regulations,customer demands,resource efficiency,competition,and cost-benefit ***,the study results also indicated that there is still much work to do for the implementation of some *** was found that 60 BATs had lower implementation ratios(IR:0%-43%).Lower IR values for these BATs are mainly due to factors like specificity,high costs,long payback periods,operational difficulties,limited expertise,space constraints,customer requirements,quality concerns,operational issues,and sector-specific *** study recommends similar assessments in other European industrial sectors to evaluate compliance with mandatory BATs outlined in the Industrial Emissions *** insights from this study on the Turkish textile sector can serve as a valuable guide for future evaluations.

关键词： Best available techniques(BAT) Cleaner production Green Deal Integrated Pollution Prevention and Control(IPPC) Textile sector

Enhanced termination of zinc and cadmium ions from wastewater employing plain and chitosan-modified mxenes: synthesis, characterization,and adsorption performance

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Green Chemical engineering 2024年第3期5卷 339-347页

作者： Njood R.Azeez Suhaib S.Salih Mohammed Kadhom Harith N.Mohammed Tushar K.Ghosh department of Chemical engineering College of Engineering University of Tikrit department of environmental Science College of Energy and Environmental Science Al-Karkh University of Science department of Nuclear Science & engineering Institute University of Missouri-Columbia

Zinc and cadmium pollutants cause a significant environmental effect that cannot be ignored. Due to their considerable amount in an aqueous environment, industries are seeking suitable adsorbents that are environmentally friendly and inexpensive for removing metals from wastewater before disposing of them in surface waters. This research employed original MXene(MX) and chitosan-modified MXene(CSMX) to extract zinc(Zn(Ⅱ)) and cadmium(Cd(Ⅱ)) metal ions from water-based solutions. The composite material produced was analyzed using techniques such as X-ray Diffraction(XRD), Scanning Electron Microscopy(SEM), Fourier Transform Infrared Spectroscopy(FTIR), and Brunauer-Emmett-Teller(BET). The effects of contact duration, p H of the solution, and initial concentration of metal ions on the adsorption process of Zn(Ⅱ) and Cd(Ⅱ) onto both MX and CSMX composites were investigated. MX and prepared CSMX composite presented a high adsorption capacity for both studied heavy metals, which were 91.55 and 73.82 mg/g for Zn(Ⅱ) and Cd(Ⅱ) onto MX, 106.84 and 93.07 mg/g for Cd(Ⅱ) and Zn(Ⅱ) onto CSMX composite, respectively. Furthermore, the maximum competitive adsorption capacities for Zn(Ⅱ) onto MX and CSMX composites are 77.29 and 93.47 mg/g, and for are Cd(Ⅱ)60.30 and 79.66 mg/g, respectively. Hence, the removal capacities for both single and competitive metal ions were superior to CSMX composite. However, the adsorption capacities after five successive regeneration sequences were only dropped by 13.2% for Zn(Ⅱ) and 17.4% for Cd(Ⅱ) onto the CSMX composite compared to the first cycle. These results confirm that both metals could be efficiently terminated from wastewater, which makes the prepared CSMX composite a favorable candidate adsorbent in practical applications.

关键词： Adsorption Chitosan MXene Zn(II) Cd(II) Wastewater

Surface engineering with ionic polymers on membranes for boron removal

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Frontiers of Chemical Science and engineering 2024年第5期18卷 61-69页

作者： Xiting Zhang Chenyi Fang J Paul Chen Sui Zhang department of Chemical and Biomolecular engineering National University of SingaporeSingapore 117576Singapore department of Civil and environmental engineering National University of SingaporeSingapore 119260Singapore College of Chemistry and environmental engineering Shenzhen UniversityShenzhen 518060China

Removal of boric acid from seawater and wastewater using reverse osmosis membrane technologies is imperative and yet remains inadequately addressed by current commercial *** research efforts performed post-modification of reverse osmosis membranes to enhance boron rejection,which is usually accompanied by substantial sacrifice in water *** study delves into the surface engineering of low-pressure reverse osmosis membranes,aiming to elevate boron removal efficiency while maintaining optimal salt rejection and water *** were modified by the self-polymerization and co-deposition of dopamine and polystyrene sulfonate at varying ratios and *** surfaces became smoother and more hydrophilic after *** optimum membrane exhibited a water permeability of 9.2±0.1 L·m^(-2)·h^(-1)·bar^(-1),NaCl rejection of 95.8%±0.3%,and boron rejection of 49.7%±0.1% and 99.6%±0.3% at neutral and alkaline pH,*** water permeability is reduced by less than 15%,while the boron rejection is 3.7 times higher compared to the blank *** research provides a promising avenue for enhancing boron removal in reverse osmosis membranes and addressing water quality concerns in the desalination process.

关键词： membrane low-pressure reverse osmosis boron surface engineering

Evaluation of the coefficient of lateral stress at rest of granular materials under repetitive loading conditions

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Journal of Rock Mechanics and Geotechnical engineering 2024年第5期16卷 1709-1721页

作者： Heerym Han Hyunwook Choo Junghee Park department of Civil and environmental engineering Hanyang UniversitySeoul04763South Korea department of Civil and environmental engineering Incheon National UniversityIncheon22012South Korea

Although the internal stress state of soils can be affected by repetitive loading,there are few studies evaluating the lateral stress(or K_(0))of soils under repetitive *** study investigates the changes in K_(0) and directional shear wave velocity(V_(s))in samples of two granular materials with different particle shapes during repetitive loading.A modified oedometer cell equipped with bender elements and a diaphragm transducer was developed to measure the variations in the lateral stress and the shear wave velocity,under repetitive loading on the loading and unloading *** study produced the following results:(1)Repetitive loading on the loading path resulted in an increase in the K_(0) of test samples as a function of cyclic loading number(i),and(2)Repetitive loading on the unloading path resulted in a decrease in K_(0) according to *** shear wave velocity ratio(i.e.V_(s)(HH)/V_(s)(VH),where the first and second letters in parentheses corresponds to the directions of wave propagation and particle motion,respectively,and V and H corresponds to the vertical and horizontal directions,respectively)according to i supports the experimental observations of this ***,when the tested material was in lightly over-consolidated state,there was an increase in K_(0) during repetitive loading,indicating that it was the initial K_(0),rather than the loading path,which is responsible for the change in K_(0).The power model can capture the variation in the K_(0) of samples according to ***,the K_(0)=1 line acts as the boundary between the increase and decrease in K_(0) under repetitive loading.

关键词： Coefficient of lateral stress at rest Repetitive loading Granular materials Shear wave velocity Stiffness anisotropy

Antibiotic ciprofloxacin removal from aqueous solutions by electrochemically activated persulfate process:Optimization,degradation pathways,and toxicology assessment

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Journal of environmental Sciences 2024年第9期143卷 85-98页

作者： Elif Yakamercan Ahmet Aygün Halis Simsek environmental engineering department Bursa Technical UniversityBursaTurkey Agricultural and Biological engineering department Purdue UniversityWest LafayetteINUSA

Ciprofloxacin(CIP)is a commonly used antibiotic in the fluoroquinolone group and is widely used in medical and veterinary medicine disciplines to treat bacterial *** CIP is discharged into the sewage system,it cannot be removed by a conventional wastewater treatment plant because of its recalcitrant *** this study,boron-doped diamond anode and persulfate were used to degrade CIP in an aquatic solution by creating an electrochemically activated persulfate(EAP)*** added to the system as a coactivator and the process was called EAP+*** effects of independent variables,including pH,Fe^(2+),persulfate concentration,and electrolysis time on the systemwere optimized using the response surface *** results showed that the EAP+Fe process removed 94%of CIP under the following optimum conditions:A pH of 3,persulfate/Fe^(2+)concentration of 0.4 mmol/L,initial CIP concentration 30 mg/L,and electrolysis time of 12.64 *** removal efficiency was increased from 65.10%to 94.35%by adding Fe^(2+)as a transition *** degradation products,7 pathways,and 78 intermediates of CIP were studied,and three of those intermediates(m/z 298,498,and 505)were *** toxicological analysis based on toxicity estimation software results indicated that some degradation products of CIP were toxic to targeted animals,including fathead minnow,Daphnia magna,Tetrahymena pyriformis,and *** optimumoperation costswere similar in EAP and EAP+Fe processes,approximately 0.54€/m^(3).

关键词： Ciprofloxacin Response surface methodology Electrochemically activated persulfate Electrooxidation