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Enhanced dechlorination of 2,4-dichlorophenol by recoverable Ni/Fe–Fe_3O_4 nanocomposites

Journal of environmental Sciences 2016年第10期28卷 92-101页

作者： Cancan Xu Rui Liu Lvjun Chen Jialu Tang Zhejiang Provincial Key Laboratory of water Science and Technology Department of Environment Yangtze Delta Region Institute of Tsinghua University School of environment Tsinghua University

Ni/Fe-Fe3O4 nanocomposites were synthesized for dechlorination of 2,4-dichlorophenol （2,4-DCP）. The effects of the Ni content in Ni/Fe-Fe3O4 nanocomposites, solution pH, and common dissolved ions on the dechlorination efficiency were investigated, in addition to the reusability of the nanocomposites. The results showed that increasing content of Ni in Ni/Fe-FesO4 nanocomposites, from 1 to 5 wt.%, greatly increased the dechlorination efficiency; the Ni/Fe-Fe3O4 nanocomposites had much higher dechlorination efficiency than bare Ni/Fe nanoparticles. Ni content of S wt.% and initial pH below 6.0 was found to be the optimal conditions for the catalytic dechlorination of 2,4-DCP. Both 2,4-DCP and the intermediate product 2-chlorophenol （2-CP） were completely removed, and the concentra- tion of the final product phenol was close to the theoretical phenol production from complete dechlorination of 20 mg/L of 2,4-DCP, after 3 hr reaction at initial pH value of 6.0, 3 g/L Ni/Fe-Fe3O4, S wt.% Ni content in the composite, and temperature of 22℃ 2,4-DCP dechlorination was enhanced by C1- and inhibited by NO3- and SO42-. The nanocomposites were easily separated from the solution by an applied magnetic field. When the catalyst was reused, the removal efficiency of 2,4-DCP was almost 100% for the first seven uses, and gradually decreased to 75% in cycles 8-10. Therefore, the Ni/Fe-Fe3O4 nanocomposites can be considered as a potentially effective tool for remediation of Pollution bv 2.4-DCP.

关键词： Ni/Fe-Fe3O4 nanocomposites2 4-DichlorophenolCatalytic dechlorinationRecoverableCommon dissolved ions

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Study on Headland-Bay Sandy Coast Stability in South China Coasts

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China Ocean Engineering 2011年第1期25卷 1-13页

作者：于吉涛陈子燊 department of water Resources and environment Geography and Planning SchoolSun Yat-sen University

Headland-bay beach equilibrium planform has been a crucial problem abroad to long-term sandy beach evolution and stabilization, extensively applied to forecast long-term coastal erosion evolvement and the influences of coastal engineering as well as long-term coastal management and protection. However, little concern focuses on this in China. The parabolic relationship is the most widely used empirical relationship for determining the static equilibrium shape of headland-bay beaches. This paper utilizes the relation to predict and classify 31 headland-bay beaches and concludes that these bays cannot achieve the ultimate static equilibrium planform in South China. The empirical bay equation can morphologically estimate beach stabilization state, but it is just a referential predictable means and is difficult to evaluate headland-bay shoreline movements in years and decades. By using Digital Shoreline Analysis System suggested by USGS, the rates of shoreline recession and accretion of these different headland-bay beaches are quantitatively calculated from 1990 to 2000. The conclusions of this paper include that （a） most of these 31 bays maintain relatively stable and the rates of erosion and accretion are relatively large with the impact of man-made constructions on estuarine within these bays from 1990 to 2000; （b） two bays, Haimen Bay and Hailingshan Bay, originally in the quasi-static equilibrium planform determined by the parabolic bay shape equation, have been unstable by the influence of coastal engineering; and （c） these 31 bays have different recession and accretion characters occuning in some bays and some segments. On the one hand, some bays totally exhibit accretion, but some bays show erosion on the whole. Shanwei Bay, Houmen Bay, Pinghai Bay and Yazhou Bay have the similar planforms, characterized by less accretion on the sheltering segment and bigger accretion on the transitional and tangential segments. On the other hand, different segments of some bays

关键词： Headland-bay beaches parabolic bay shape equation digital shoreline analysis system end point rate

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California Simulation of Evapotranspiration of Applied water and Agricultural Energy Use in California

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Journal of Integrative Agriculture 2013年第8期12卷 1371-1388页

作者： Morteza N Orang Richard L Snyder Shu Geng Quinn J Hart Sara Sarreshteh Matthias Falk Dylan Beaudette Scott Hayes Simon Eching California department of water Resources department of Land Air and Water ResourcesUniversity of California School of environment and Energy Shenzhen Graduate SchoolPeking University

The California Simulation of Evapotranspiration of Applied water （CaI-SIMETAW） model is a new tool developed by the California department of water Resources and the University of California, Davis to perform daily soil water balance and determine crop evapotranspiration （ETo）, evapotranspiration of applied water （ETaw）, and applied water （AW） for use in California water resources planning. ETaw is a seasonal estimate of the water needed to irrigate a crop assuming 100% irrigation efficiency. The model accounts for soils, crop coefficients, rooting depths, seepage, etc. that influence crop water balance. It provides spatial soil and climate information and it uses historical crop and land-use category information to provide seasonal water balance estimates by combinations of detailed analysis unit and county （DAU/County） over Califomia. The result is a large data base of ETc and ETaw that will be used to update information in the new California water Plan （CWP）. The application uses the daily climate data, i.e., maximum （Tx） and minimum （Tn） temperature and precipitation （Pcp）, which were derived from monthly USDA-NRCS PRISM data （PRISM Group 2011） and daily US National Climate Data Center （NCDC） climate station data to cover California on a 4 kmx4 km change grid spacing. The application uses daily weather data to determine reference evapotranspiration （ETo）, using the Hargreaves-Samani （HS） equation （Hargreaves and Samani 1982, 1985）. Because the HS equation is based on temperature only, ETo from the HS equation were compared with CIMIS ETo at the same locations using available CIMIS data to determine correction factors to estimate CIMIS ETo from the HS ETo to account for spatial climate differences. CaI-SIMETAW also employs near real-time reference evapotranspiration （ETo） information from Spatial CIMIS, which is a model that combines weather station data and remote sensing to provide a grid of ETo information. A second database containing the available soil water

关键词： soil water balance crop water requirements weather generator water resource planning crop coefficient energy use

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Insights on the solubilization products after combined alkaline and ultrasonic pre-treatment of sewage sludge

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Journal of environmental Sciences 2015年第3期27卷 97-105页

作者： Xinbo Tian Chong Wang Antoine Prandota Trzcinski Leonard Lin Wun Jern Ng Advanced environmental Biotechnology Centre Nanyang Environment and Water Research Institute Nanyang Technological University School of Civil and environmental Engineering Nanyang Technological University Public Utilities Board Water Reclamation (Plants) Department Nanyang environment and water Research Institute Nanyang Technological University

This work provides insights on the solubilization products after a simultaneous combination of alkaline and ultrasonic （ALK ＋ ULS） pre-treatment of sewage sludge. Soluble chemical oxygen demand （SCOD） increased from 1200 to 11,000 mg/L after such treatment. Organics with molecular weight around 5.6 kDa were solubilized because of the synergistic effect of ultrasound and alkali. Organics with molecular weight larger than 300 kDa increased from 7.8% to 60%, 16% and 42.3% after ULS, ALK and ALK ＋ ULS treatment, respectively. Excitation emission matrix fluorescence spectroscopy analysis identified soluble microbial product-like and humic acid-like matters as the main solubilization products. Sludge anaerobic biodegradability was significantly enhanced with the simultaneous application of ALK ＋ ULS pre-treatment. ALK ＋ ULS pre-treatment resulted in 37.8% biodegradability increase compared to the untreated sludge. This value was higher compared to the biodegradability increase induced by individual ALK pre-treatment （5.7%） or individual ULS pre-treatment （20.7%） under the same conditions applied.

关键词： Ultrasound AlkaliSewage sludge Molecular weight Excitation emission matrix (EEM) Anaerobic biodegradability

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Impact of industrial wastewater disposal on surface water bodies in Mostord area, North Greater Cairo

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Journal of environmental Sciences 2001年第4期13卷 485-490页

作者： M.F.Abdel Sabour 1, F.H.Rabie 2, T.Mostafa 3, S.A.Hassan 4 (1 Soil and water Pollution Unit, Nuclear Research Center, Egypt. 2 Soil department, Faculty of Agricultural, Ain Shams University, Egypt 3 Soils, water and environment Research Instit Soil and water Pollution Unit Nuclear Research Center 埃及 Ain Shams University 埃及 Soils Water and Environment Research Institute ARC 埃及 Soils Water and Environment Research InstituteARC 埃及

The studied area (Shoubra El Khima, Bahteem and Mostorod) lies in the industrial area north of Greater Cairo. The area suffers from several environmental problems such as sewage and disposal of pollutants from the surrounding factories into the surface water pathways in the area. water samples were collected seasonally from different waterways found in the area, domestic and or industrial liquid wastes from 12 discharge tubes of different factories (as a point source of pollution). Chemical characteristics of different water samples and its heavy metals content were determined using ion coupled plasma technique (ICP). Results indicate that industrial and domestic wastewater samples contain several toxic levels of tested heavy metals (Cd, Co, Pb and Ni) which have a serious impact on surface waterways in the area. Shebin El Qanater collector drain samples exhibited the highest levels of Cd, Co, Pb and Ni compared to other tested water bodies. Mostorod collector drain samples showed the highest levels of Zn and Cu. Industrial effluent samples collected from Cairo Company for Fabric industry had the highest amounts of total Zn Cu, Cd, Co and Pb, while Delta steel company discharges the highest amounts of total Fe and Mn. Al Ahleya Plastic Company discharges the highest amounts of total Ni. Generally, it is necessary to impose the environmental laws and its regulation regarding the industrial wastewater treatments and disposals to minimize the risk of the adverse effects of these pollutants.

关键词： industrial wastewater disposal north Greater Cairo Egypt

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Impact of ozone assisted ultrasonication pre-treatment on anaerobic digestibility of sewage sludge

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Journal of environmental Sciences 2015年第7期27卷 29-38页

作者： Xinbo Tian Antoine Prandota Trzcinski Li Leonard Lin Wun Jern Ng Advanced environmental Biotechnology Centre Nanyang Environment and Water Research Institute Nanyang Technological University School of Civil and environmental Engineering Nanyang Technological University Public Utilities Board Water Reclamation (Plants) Department Nanyang environment and water Research Institute Nanyang Technological University

Impact of ultrasonication（ULS） and ultrasonication-ozonation（ULS-Ozone） pre-treatment on the anaerobic digestibility of sewage sludge was investigated with semi-continuous anaerobic reactors at solid retention time（SRT） of 10 and 20 days. The control, ULS and ULS-Ozone reactors produced 256, 309 and 348 m L biogas/g CODfedand the volatile solid（VS） removals were 35.6%, 38.3% and 42.1%, respectively at SRT of 10 days. At SRT of20 days, the biogas yields reached 313, 337 and 393 m L biogas/g CODfedand the VS removal rates were 37.3%, 40.9% and 45.3% in the control, ULS and ULS-Ozone reactors, ***-Ozone pre-treatment increased the residual organic amount in the digested *** soluble residual organics were found to contain macromolecules with molecular weights（MW） larger than 500 k Da and smaller polymeric products with MW around 19.4and 7.7 k Da. These compounds were further characterized to be humic acid-like substances with fluorescent spectroscopy analysis.

关键词： Sewage sludge Ultrasound Ozone Pre-treatment Molecular weight Anaerobic digestion

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Photooxidation of Furfural with Phthalocyanine-sensitized TiO_2 Particle Under Xenon Lamp

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Chemical Research in Chinese Universities 2007年第2期23卷 154-158页

作者： KANG Chun-li LU Yu GUO Ping ZHANG Fan YU Hong-bing LIN Xue-yu department of environment Science College of environment and Resources Jilin University Changchun 130021 China department of Hydrology and water Resource College of Environment and Resources Jilin University Changchun 130021 China

Copper phthalocyanine was selected as the photosensitizer to sensitize TiO2 in this experiment with furfural as the target pollutant. The composite catalysts（TiO2/CuPC） obtained showed a great activity under a xenon lamp. By experiments, the optimal preparation conditions of the composite catalysts were set as follows ： the CuPC loading mass fraction was 1.5%, the mass fraction of acetylacetone was 0. 3% , and the stirring time was 10 h. UV-Vis diffuse reflectance spectra, XRD, and BET were used to characterize the properties of the composite catalysts, which showed that after loading CuPC on TiO2, the composite catalyst retained the same crystal structure as pure TiO2 and the wavelength range of its absorption spectrum was broadened to 600-700 nm while its surface area was smaller than that of the pure TiO2. Under the optimal conditions, 20 mg/L furfural solution was degraded by nearly 90% and TOC by about 70%. When the catalyst was reused 6 times, the activity of the catalyst was still retained by about 75%.

关键词： TiO2 CuPC Phthalocyanine-photosensitizer Furfural Photooxidation

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Catalyst–Support Interaction in Polyaniline‑Supported Ni_(3)Fe Oxide to Boost Oxygen Evolution Activities for Rechargeable Zn‑Air Batteries

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Nano-Micro Letters 2025年第1期17卷 176-190页

作者： Xiaohong Zou Qian Lu Mingcong Tang Jie Wu Kouer Zhang Wenzhi Li Yunxia Hu Xiaomin Xu Xiao Zhang Zongping Shao Liang An department of Mechanical Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Jiangsu Key Laboratory of Atmospheric environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and TechnologyNanjing University of Information Science and TechnologyNanjing 210044People’s Republic of China department of Chemistry The Chinese University of Hong KongMa Lin BuildingShatinHong Kong SAR 999077People’s Republic of China WA School of Mines:Minerals Energy and Chemical Engineering(WASM‑MECE)Curtin UniversityPerthWA 6102Australia Research Institute for Advanced Manufacturing The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China

Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe *** is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe *** the excellent activity and stability,rechargeable Zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.

关键词： Catalyst-support interaction Supported catalysts Heterointerface Oxygen evolution reaction Zn-air batteries

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Comparison and Optimization of Mid-low Temperature Cogeneration Systems for Flue Gas in Iron and Steel Plants

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Journal of Iron and Steel Research International 2013年第11期20卷 33-40页

作者： ZHANG Li-hua WU Li-jun ZHANG Xiao-hong JU Gui-dong Thermal and environmental Engineering Institute Tongji University Resources and environment department Shandong Water Polytechnic

Three generation systems, namely, steam Rankine cycle （SRC）, organic Rankine cycle （ORC）, and steam-organic combined Rankine cycle （S-ORC）, were simulated using the Engineering Equation Solver fEES） to efficiently utilize flue gas emissions from 200 to 450 ℃ in iron and steel plants. Based on the simulation results for thermal efficiency, exergy efficiency, and power generation, the performances of the three power generation systems were compared and analyzed. To further utilize waste heat from the turbine exhaust steam of the ORC system, cas- cade （）RC （CORC） was designed for heat sources above 300 ℃. Based on a comprehensive performance comparison, the application of the ORC using R141b is preferable for 200 to 300 ℃ flue gas. For 300 to 450 ℃ flue gas, CORC is an alternative technology to improve the efficiency and quality of waste heat utilization. For flue gas above 450 ℃, S-ORC can achieve higher efficiency and power generation than conventional SRC, with a relatively small negative pressure and high dryness of the turbine outlet steam. Hence, S-ORC can be considered as a substitute for SRC.

关键词： mid-low temperature flue gas Rankine cycle thermal energy recovery generation system

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A COUPLED MODEL OF HYDRODYNAMICS AND water QUALITY FOR YUQIAO RESERVOIR IN HAIHE RIVER BASIN

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Journal of Hydrodynamics 2008年第5期20卷 574-582页

作者： LIU Xiao-bo PENG Wen-qi HE Guo-jian LIU Jing-ling WANG Yu-chun School of environment Beijing Normal University Beijing 100875 China department of water environment China Institute of Water Resources and Hydropower Research Beijing100038 China department of Hydraulic Engineering State Key Laboratory of Hydroscience and Engineering TsinghuaUniversity Beijing 100084 China

In order to simulate the characteristics of hydrodynamic field and mass transport processes in the Yuqiao Reservoir （YQR）, a 2-D coupled model of hydrodynamics and water quality was developed, and the water-quality related state variables in this model included CODMn, TN and TP. The hydrodynamic model was driven by employing observed winds and daily measured flow data to simulate the seasonal water cycle of the reservoir. The simulation of the mass transport and transformation processes of CODMn, TN and TP was based on the unsteady diffusion equations, driven by observed meteorological forcing and external loadings, with the fluxes form the bottom of reservoir and the plant photosynthesis and respiration as internal sources and sinks. A finite volume method and Alternating Direction Implicit （ADI） scheme were used to solve these equations. The model was calibrated and verified by using the data observed from YQR in two different years. The results showed that in YQR, the wind-driven current was an important style of lake current, while the concentration of water quality item was decreasing from east to west because of the external pollutant loadings. There was a good agreement between the simulated and measured values, with the minimal calculation error percent of 0.1% and 2.6% and the mean error percent of 44.0% and 51.2% for TN and TP separately. The simulation also showed that, in YQR, the convection was the main process in estuaries of inflow river, and diffusion and biochemical processes dominate in center of reservoir. So it was necessary to build a pre-pond to reduce the external loadings into the reservoir.

关键词： model simulation Yuqiao Reservoir (YQR) wind driven current water quality

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