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Clean energy 2024年第2期8卷 8-26页

作者： Amirhossein Mirabadi Saeid Minaei Younes Noorollahi Morteza Almasi department of Agricultural systems Science and Research BranchIslamic Azad UniversityTehranIran Biosystems Engineering department Faculty of AgricultureTarbiat Modares UniversityTehranIran energy Modelling and Sustainable energy System(METSAP)research Lab. Faculty of New Sciences and TechnologiesUniversity of TehranIran

This paper presents a comprehensive model for selecting optimal sites for geothermal heated greenhouses in the agricultural *** research involves two main components:assessing the geothermal energy resource using geological,geochemical and geophysical indicators;and developing a siting model based on fuzzy logic that considers technical,environmental and socio-economic fac*** study focuses on East Azerbaijan province in Iran-a cold *** results indicate that~3.24%of the total area of the province is suitable for constructing geothermal greenhouses,resulting in potential savings of~148000 and 745978 m3 of natural gas in areas with high and very high suitability,respectively.

关键词： geothermal energy site selection GIS fuzzy logic resource assessment

Vertical plane depth-resolved surface potential and carrier separation characteristics in flexible CZTSSe solar cells with over 12% efficiency

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Carbon energy 2024年第3期6卷 36-52页

作者： Dae-Ho Son Ha Kyung Park Dae-Hwan Kim Jin-Kyu Kang Shi-Joon Sung Dae-Kue Hwang Jaebaek Lee Dong-Hwan Jeon Yunae Cho William Jo Taeseon Lee JunHo Kim Sang-Hoon Nam Kee-Jeong Yang Division of energy Technology DGISTDaeguRepublic of Korea research Center for Thin Film Solar Cells DGISTDaeguRepublic of Korea department of physics Ewha Womans UniversitySeoulRepublic of Korea department of physics Incheon National UniversityIncheonRepublic of Korea department of Mechanical Engineering Massachusetts Institute of TechnologyCambridgeMassachusettsUSA

Cu2ZnSn(S,Se)4(CZTSSe)solar cells have resource distribution and economic *** main cause of their low efficiency is carrier loss resulting from recombination of photo-generated electron and *** overcome this,it is important to understand their electron-hole behavior *** determine the carrier separation characteristics,we measured the surface potential and the local current in terms of the absorber *** elemental variation in the intragrains(IGs)and at the grain boundaries(GBs)caused a band edge shift and bandgap(Eg)*** the absorber surface and subsurface,an upward Ec and Ev band bending structure was observed at the GBs,and the carrier separation was *** the absorber center,both upward Ec and Ev and downward Ec-upward Ev band bending structures were observed at the GBs,and the carrier separation was *** improve the carrier separation and suppress carrier recombination,an upward Ec and Ev band bending structure at the GBs is desirable.

关键词： carrier separation CZTSSe flexible solar cell local current surface potential

Tuning hot carrier transfer dynamics by perovskite surface modification

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Chinese Chemical Letters 2024年第10期35卷 457-460页

作者： Chenghao Ge Peng Wang Pei Yuan Tai Wu Rongjun Zhao Rong Huang Lin Xie Yong Hua School of Materials and energy Yunnan UniversityKunming 650091China department of physics Center for Optoelectronics Engineering ResearchYunnan UniversityKunming 650091China

Understanding the role of perovskite surface passivators in hot carriers transfer dynamics is important to develop highly efficient perovskite solar cells(PSCs).In this work,we have designed and synthesized a naphthalimide-based organic small molecule(NCN)for perovskite surface defect *** reveal that the introduction of NCN not only reduces the density of perovskite defect-state,but also promotes hot carriers(HCs)cooling in perovskite through the transient absorption spectroscopy *** HCs cooling permits HCs transfer from perovskite layer into NCN layer,thus resulting in the decreased charge-carrier recombination in NCN-treated *** expected,the power conversion efficiency(PCE)of PSCs with NCN is enhanced to 22.02%from 19.95%for the control *** findings are relevant for developing highly efficient PSCs.

关键词： Perovskite solar cells Interface passivation Hot carrier Charge recombination Stability Naphthalimide

Techno-economic analysis of green hydrogen production by a floating solar photovoltaic system for industrial decarbonization

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Clean energy 2024年第4期8卷 1-14页

作者： Rahma Muthia Anastasia Segari Putri Pramudya Mochamad Rafly Maulana Widodo Wahyu Purwanto department of Chemical Engineering Faculty of EngineeringUniversitas IndonesiaDepok16424Indonesia Sustainable energy systems and Policy research Cluster Universitas IndonesiaDepok16424Indonesia Master Program in energy systems Engineering Faculty of EngineeringUniversitas IndonesiaDepok16424Indonesia

This study proposes a conceptual design of green hydrogen production via proton exchange membrane electrolysis powered by a floating solar photovoltaic *** system contributes to industrial decarbonization in which hydrogen blending with natural gas is proposed as an approach to smooth the energy *** proposed design addresses the challenge of supplying a continuous flow-rate of green hydrogen,which is typically demanded by industrial end *** study particularly considers a realistic area required for the installation of a floating solar photovoltaic *** enable the green hydrogen production of 7.5 million standard cubic feet per day,the required structure includes the floating solar photovoltaic system and Li-ion batteries with the nominal capacities of 518.4 megawatts and 780.8 *** is equivalent to the requirement for 1524765 photovoltaic modules and 3718 Li-ion *** assessment confirms the technical viability of the proposed concept of green hydrogen production,transportation and *** the present commercialization is hindered by economics due to a high green hydrogen production cost of USD 26.95 per kg,this green hydrogen pathway is expected to be competitive with grey hydrogen produced via coal gasification and via natural gas steam reforming by 2043 and 2047,respectively.

关键词： floating solar photovoltaics gas blending green hydrogen industrial decarbonization lithium-ion battery photon exchange membrane electrolysis

Hydrogen Spillover Effect in Electrocatalysis:Delving into the Mysteries of the Atomic Migration

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energy & Environmental Materials 2024年第5期7卷 185-209页

作者： Ashish Gaur Jatin Sharma HyukSu Han department of energy Science Sungkyunkwan University Institute of Nano Science and Technology department of energy Sungkyunkwan University

Hydrogen spillover effect has recently garnered a lot of attention in the field of electrocatalytic hydrogen evolution reactions. A new avenue for understanding the dynamic behavior of atomic migration in which hydrogen atoms moving on a catalyst surface was opened up by the setup of the word"hydrogen spillover."However, there is currently a dearth of thorough knowledge regarding the hydrogen spillover effect. Currently, the advancement of sophisticated characterization procedures offers progressively useful information to enhance our grasp of the hydrogen spillover effect. The understanding of material fabrication for hydrogen spillover effect has erupted. Considering these factors, we made an effort to review most of the articles published on the hydrogen spillover effect and carefully analyzed the aspect of material fabrication. All of our attention has been directed toward the molecular pathway that leads to improve hydrogen evolution reactions performance. In addition, we have attempted to elucidate the spillover paths through the utilization of DFT calculations. Furthermore, we provide some preliminary research suggestions and highlight the opportunities and obstacles that are still to be confronted in this study area.

关键词： electrocatalysis hydrogen evolution reaction hydrogen spillover effect interfacial atomic migration metal–support interaction

The circuitry landscape of perovskite solar cells:An in-depth analysis

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Journal of energy Chemistry 2024年第7期94卷 393-413页

作者： Siddhi Vinayak Pandey Daniel Prochowicz Apurba Mahapatra Saravanan Pandiaraj Abdullah N.Alodhayb Seckin Akin Pankaj Yadav department of Solar energy School of Energy TechnologyPandit Deendayal Energy UniversityGandhinagar 382007GujaratIndia department of Physical Chemistry Polish Academy of SciencesKasprzaka 44/5201-224 WarsawPoland department of Self-Development Skills King Saud UniversityRiyadh 11451Saudi Arabia department of physics and Astronomy College of ScienceKing Saud UniversityP.O.Box 2455Riyadh 11451Saudi Arabia department of Metallurgical and Materials Engineering Necmettin Erbakan University42060 KonyaTurkey department of physics School of Energy TechnologyPandit Deendayal Energy UniversityGandhinagar 382007GujaratIndia

The extensive research and development in perovskite solar cells (PSCs) have rekindled the hopes of converting solar energy into *** elusive understanding of underlying mechanisms is required for the development of efficient *** the years,Impedance Spectroscopy (IS) characterization,along with complementary techniques,has proven to be an effective way to understand and analyze the charge transport and recombination at interface and bulk of *** IS of PSCs have been analyzed,interpreted,and improvised continuously,revealing intricate details about the ***,there is a lack of centralized source of these details,which make it tougher to account for the generalized approach to understand the device *** present work is focused on compiling the research done on various PSC device architectures via IS to construct a comprehensive foundation of information on impedance plots,equivalent circuits,and associated processes.

关键词： Impedance Spectroscopy Perovskite solar cells Equivalent Circuits

Simulation Study on Constraining Gravitational Wave Propagation Speed by Gravitational Wave and Gamma-ray Burst Joint Observation on Binary Neutron Star Mergers

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research in Astronomy and Astrophysics 2024年第8期24卷 42-51页

作者： Jin-Hui Rao Shu-Xu Yi Lian Tao Qing-Wen Tang department of physics School of Physics and Materials ScienceNanchang UniversityNanchang 330031China Institute of High energy physics Chinese Academy of SciencesBeijing 100049China

Theories of modified gravity suggest that the propagation speed of gravitational waves(GW)v_gmay deviate from the speed of light c.A constraint can be placed on the difference between c and v_gwith a simple method that uses the arrival time delay between GW and electromagnetic wave simultaneously emitted from a burst *** simulated the joint observation of GW and short gamma-ray burst signals from binary neutron star merger events in different observation campaigns,involving advanced LIGO(aLIGO)in design sensitivity and Einstein Telescope(ET)joint-detected with Fermi/*** a result,the relative precision of constraint on v_gcan reach~10~(-17)(aLIGO)and~10^(-18)(ET),which are one and two orders of magnitude better than that from GW170817,*** continue to obtain the bound of graviton mass m_g≤7.1(3.2)×10~(-20)eV with aLIGO(ET).Applying the Standard-Model Extension test framework,the constraint on v_gallows us to study the Lorentz violation in the nondispersive,nonbirefringent limit of the gravitational *** obtain the constraints of the dimensionless isotropic coefficients S_(00)^(4)at mass dimension d=4,which are-1×10^(-15)

关键词： gravitational waves-(stars)gamma-ray burst general-stars neutron

REMnO3（RE=Pr,Nd,Sm,Eu,Gd） perovskite as efficient catalysts for oxygen reduction reaction

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Journal of Rare Earths 2024年第11期42卷 2078-2087页

作者： Rakesh Ranjan Mahalik Siba Soren Ipsha Hota A.K.Debnath K.P.Muthe Purnendu Parhi department of Chemistry Ravenshaw University Technical physics Division Bhabha Atomic Research Centre

Rare earth metal based perovskite emerges as important catalytic material for energy production and *** ABO3type materials are now the focus of research in the field of oxygen reduction and evolution ***,in this work we evaluated the oxygen reduction properties of the synthesized one-dimensional REMnO3（RE=Pr,Nd,Sm,Eu and Gd）.The one-dimensional REMnO3prepared by the hydrothermal synthesis route results in pure phase perovskite on *** perovskite was characte rized with X-ray diffraction,Fourier transform-infrared（FT-IR）,field emission-scanning electron microscopy（FE-SEM）,transmission electron microscopy（TEM） and X-ray photoelectron spectroscopy（XPS）.The oxygen reduction reaction activities were investigated with the help of electrochemical workstation that consists of three-electrode system immersed in 0.1 mol/L KOH electrolyte solution saturated with *** Koutechy-Levich plot obtained from rotating ring disk electrode shows all the prepared catalysts follow 4e-processes during oxygen *** effect of "A" site cation variation in REMnO3 on oxygen reduction reaction is ***3showed better onset potential for oxygen reduction reaction among the prepared rare earth ***3having high RE:Mn ratio（A-site rich co mpositions） promotes oxygen reduction reaction（ORR） *** the perovs kites showed good oxygen reduction property with high stability and methanol tolerance.

关键词： Electrocatalytic activity Oxygen reduction reaction (ORR) Perovskite Rare earths REMnO3 SmMnO3

Experimental and computational optimization of Prussian blue analogues as high-performance cathodes for sodium-ion batteries:A review

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Journal of energy Chemistry 2024年第6期93卷 627-662,I0015页

作者： Gwangeon Oh Junghoon Kim Shivam Kansara Hyokyeong Kang Hun-Gi Jung Yang-Kook Sun Jang-Yeon Hwang department of energy Engineering Hanyang UniversitySeoul 04763Republic of Korea energy Storage research Center Clean Energy Research DivisionKorea Institute of Science and TechnologySeoul 02792Republic of Korea department of energy Science Sungkyunkwan UniversitySuwon 16419Republic of Korea KIST-SKKU Carbon-Neutral research Center Sungkyunkwan UniversitySuwon 16419Republic of Korea department of Battery Engineering Hanyang UniversitySeoul 04763Republic of Korea

In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte *** integrated experimental data and density functional theory(DFT)in sodium-ion battery(SIB)research to refine the atomic arrangements and crystal lattices and introduce substitutions and *** changes affect the lattice stability,intercalation,electronic and ionic conductivities,and electrochemical *** unraveled the intricate structure-electrochemical behavior relationship by combining experimental data with computational models,including first-principles *** holistic approach identified techniques for optimizing PB and Prussian blue analog(PBA)structu ral properties for *** also discuss the tuning of electrolytes by systematically adjusting their composition,concentration,and additives using a combination of molecular dynamics(MD)simulations and DFT *** review offers a comprehensive assessment of strategies for enhancing the electrochemical properties of PB and PBAs through structural engineering and electrolyte modifications,combining experimental insights with advanced computational simulations,and paving the way for next-generation energy storage systems.

关键词： Prussian blue analogs(PBAs) Sodium ion batteries(SIBs) Structural engineering Electrolyte modifications Experiments Density functional theory(DFT)

Efficient processed carbon Soot@MoS2 hybrid Bi-functional electrode for dye-sensitized solar cell and asymmetric supercapacitor devices

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Nano Materials Science 2024年第4期6卷 484-494页

作者： B.Arjun Kumar Gopal Ramalingam Salah Addin Burhan Al Omari Zhumabay Bakenov Sambasivam Sangaraju Sangarapani Sudhakar Quantum Material research Lab (QMRL) Department of Nanoscience and TechnologyAlagappa University department of Mechanical and Aerospace Engineering United Arab Emirates University department of Chemical and Materials Engineering Nazarbayev University National Water and energy Center United Arab Emirates University department of physics Alagappa University

A feasible approach to rectify the world's energy demand using sustainable development of adequate energy generation and storage technologies in a single *** this respect,we made a holistic approach with a bifunctional electrode material to perform effectively in energy generation and storage ***2nanosheets were produced by the eco-friendly method and reduced graphene oxide is used to prepared by carbon soot which is derived from castor *** prepared soot and rGO were combined with MoS2nanosheets using a simple sonication *** as-prepared sample was introduced in the supercapacitor and DSSC *** combination MoS2@rGO provides an enhanced conversion efficiency of 11.81%and the reproducibility of DSSC is also ***,MoS2@rGO is used to fabricate an asymmetric supercapacitor to investigate its real-time *** device produced the maximum power density （1666.6 mW/kg） and energy density （25.69 mWh/Kg） at 1 A/*** asymmetric supercapacitor device holds a cyclic stability of 81.4%for 5000 cycles and it powered up an LED device for 4 min.

关键词： Carbon soot Solar cells Supercapacitors MoS 2 DSSC