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Stable immobilization of lithium polysulfides using three-dimensional ordered mesoporous Mn2O3 as the host material in lithium-sulfur batteries

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Carbon energy 2024年第6期6卷 99-112页

作者： Sung Joon Park Yun Jeong Choi Hyun-seung Kim Min Joo Hong Hongjun Chang Janghyuk Moon Young-Jun Kim Junyoung Mun Ki Jae Kim department of energy science Sungkyunkwan UniversitySuwonGyeonggi-doRepublic of Korea department of energy Engineering Konkuk UniversitySeoulRepublic of Korea Advanced Batteries Research Center Korea Electronic Technology InstituteSeongnamRepublic of Korea department of Future energy Engineering Sungkyunkwan UniversitySuwonRepublic of Korea department of energy Systems Engineering Chung-Ang UniversitySeoulRepublic of Korea SKKU Advanced Institute of Nanotechnology Sungkyunkwan UniversitySuwonGyeonggi-doRepublic of Korea SKKU Institute of energy science and Technology(SIEST) Sungkyunkwan UniversitySuwonRepublic of Korea School of Advanced Materials science and Engineering Sungkyunkwan UniversitySuwonRepublic of Korea

Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy ***,the dissolution of long-chain polysulfides into the electrolyte during the charge and discharge process(“shuttle effect”)results in fast capacity fading and inferior electrochemical *** this study,Mn_(2)O_(3)with an ordered mesoporous structure(OM-Mn_(2)O_(3))was designed as a cathode host for LSBs via KIT-6 hard templating,to effectively inhibit the polysulfide shuttle ***-Mn_(2)O_(3)offers numerous pores to confine sulfur and tightly anchor the dissolved polysulfides through the combined effects of strong polar-polar interactions,polysulfides,and sulfur chain *** OM-Mn_(2)O_(3)/S composite electrode delivered a discharge capacity of 561 mAh g-1 after 250 cycles at 0.5 C owing to the excellent performance of OM-Mn_(2)O_(3).Furthermore,it retained a discharge capacity of 628mA h g-1 even at a rate of 2 C,which was significantly higher than that of a pristine sulfur electrode(206mA h g-1).These findings provide a prospective strategy for designing cathode materials for high-performance LSBs.

关键词： host material lithium-sulfur battery ordered mesoporous structure shuttle effect transition-metal oxides

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Online Pareto optimal control of mean-field stochastic multi-player systems using policy iteration

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science China(Information sciences) 2024年第4期67卷 21-37页

作者： Xiushan JIANG Yanshuang WANG Dongya ZHAO Ling SHI College of New energy China University of Petroleum(East China) department of Electronic and Computer Engineering Hong Kong University of Science and Technology

In this study, the Pareto optimal strategy problem was investigated for multi-player mean-field stochastic systems governed by It? differential equations using the reinforcement learning(RL) method.A partially model-free solution for Pareto-optimal control was derived. First, by applying the convexity of cost functions, the Pareto optimal control problem was solved using a weighted-sum optimal control problem. Subsequently, using on-policy RL, we present a novel policy iteration(PI) algorithm based on the Hrepresentation technique. In particular, by alternating between the policy evaluation and policy update steps,the Pareto optimal control policy is obtained when no further improvement occurs in system performance,which eliminates directly solving complicated cross-coupled generalized algebraic Riccati equations(GAREs).Practical numerical examples are presented to demonstrate the effectiveness of the proposed algorithm.

关键词： mean-field stochastic systems Pareto optimal control policy iteration scheme $\mathcal{H}$-representation

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Effects of the inlet particle spatial distribution on the performance of a gas-solid cyclone separator

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Particuology 2024年第2期85卷 133-145页

作者： Yuge Yao Manxia Shang Xiwei Ke Zhong Huang Tuo Zhou Junfu Lyu Key Laboratory for Thermal science and Power Engineering of Ministry of Education Department of Energy and Power EngineeringTsinghua UniversityBeijing100084China

The present study was aimed at the inlet particle spatial distribution of a gas-solid separator with high solid loading and investigated its effects on cyclone performance and the inner flow *** flow fields of a cyclone with different rectangular particle flow areas on the inlet surface were numerically simulated using a four-way coupling *** simulated results indicate that reducing the inlet particle flow area and lowing the inlet particle position can effectively reduce the scattered particles inside the cyclone separator and enhance the separation *** gathering the particles to the centerline can also weaken the particle *** particles near the roof account for the swirling particle ceiling *** inlet particle spatial distribution affects the pressure drop mainly by affecting the gas tangential velocity in the cylinder ***,compared to the hori-zontal particle distribution on the inlet surface,the vertical particle distribution has greater effects on cyclone performance.

关键词： Gas-solid cyclone Inlet particle spatial distribution Four-way coupling Separation efficiency Scattered particle

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Demonstration of a small‐scale power generator using supercritical CO_(2)

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Carbon energy 2024年第4期6卷 269-290页

作者： Ligeng Li Hua Tian Xin Lin Xianyu Zeng Yurong Wang Weilin Zhuge Lingfeng Shi Xuan Wang Xingyu Liang Gequn Shu State Key Laboratory of Engines Tianjin UniversityTianjinChina department of Thermal science and energy Engineering University of Science and Technology of ChinaHefeiChina State Key Laboratory of Automotive Safety and energy Tsinghua UniversityBeijingChina

The supercritical CO_(2)(sCO_(2))power cycle could improve efficiencies for a wide range of thermal power *** sCO_(2)turbine generator plays an important role in the sCO_(2)power cycle by directly converting thermal energy into mechanical work and electric *** operation of the generator encounters challenges,including high temperature,high pressure,high rotational speed,and other engineering problems,such as *** studies of sCO_(2)turbines are insufficient because of the significant difficulties in turbine manufacturing and system *** most experimental investigations that primarily focus on 100 kW‐or MW‐scale power generation systems,we consider,for the first time,a small‐scale power generator using sCO_(2).A partial admission axial turbine was designed and manufactured with a rated rotational speed of 40,000 rpm,and a CO_(2)transcritical power cycle test loop was constructed to validate the performance of our manufactured generator.A resistant gas was proposed in the constructed turbine expander to solve the leakage *** dynamic and steady performances were *** results indicated that a peak electric power of 11.55 kW was achieved at 29,369 *** maximum total efficiency of the turbo‐generator was 58.98%,which was affected by both the turbine rotational speed and pressure ratio,according to the proposed performance map.

关键词： generator performance map power generation supercritical CO_(2) turbine

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Characterization and Analysis of Inconel 718 Alloy Ground at Different Speeds

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Chinese Journal of Mechanical Engineering 2024年第2期37卷 137-149页

作者： Hao Liu Huili Han Qinghong Jiang Minglin He Bi Zhang department of Mechanical and energy Engineering Southern University of Science and TechnologyShenzhen 518055China department of Mechanical Engineering Hong Kong Polytechnic UniversityHong KongChina

Inconel 718(IN718)alloy is widely applied to fabricate high temperature resistant or corrosion resistant parts due to its excellent mechanical ***,the machining of IN718 alloy is difficult as it may cause serious tool wear and poor surface quality(SQ)of the *** this work,grinding experiments on IN718 alloy at different speeds were conducted by using a CBN grinding *** relationship between grinding speed,SQ and subsurface damage(SSD)was well *** increasing grinding speed,surface roughness decreased,and SQ was greatly ***,the microhardness of the grinding surface declined as the grinding speed *** SSD depth was almost unchanged when the grinding speed was lower than 15 m/s,then it decreased with higher grinding *** was attributed to the mechanical-thermal synergistic effect in the grinding *** results indicated that increasing grinding speed can effectively improve the SQ and reduce the SSD of IN718 *** conclusion in the work may also provide insight into processing other hard-to-machining materials.

关键词： Surface integrity Grinding speed IN718 alloy Precision machining CBN grinding wheel

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Prediction of Ground State Configurations and Electrochemical Properties of Li_(3)InCl_(6) Doped with F, Br, and Ga

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Chinese Physics Letters 2024年第5期41卷 171-176页

作者：鲁征宇陈乐添胡绪陈素雅张旭周震 department of Materials science and Engineering Nankai UniversityTianjin 300350China Interdisciplinary Research Center for Sustainable energy science and Engineering School of Chemical EngineeringZhengzhou UniversityZhengzhou 450001China

Compared with conventional solid-state electrolytes, halide solid-state electrolytes have several advantages such as a wider electrochemical window, better compatibility with oxide cathode materials, improved air stability,and easier preparation conditions making them conductive to industrial production. We concentrate on a typical halide solid-state electrolyte, Li_(3)InCl_(6), predict the most stable structure after doping with Br, F, and Ga by using the Alloy Theoretic Automated Toolkit based on first-principles calculations, and verify the accuracy of the prediction model. To investigate the potential of three equivalently doped ground state configurations of Li_(3)InCl_(6) as solid-state electrolytes for all-solid-state lithium-ion batteries, their specific properties such as crystal structure,band gap, convex packing energy, electrochemical stability window, and lithium-ion conductivity are computationally analyzed using first-principles calculations. After a comprehensive evaluation, it is determined that the F-doped ground state configuration Li_(3)InCl_(2.5)F_(3.5) exhibits better thermal stability, wider electrochemical stability window, and better lithium ion conductivity(1.80 m S·cm^(-1) at room temperature). Therefore, Li_(3)InCl_(2.5)F_(3.5) has the potential to be used in the field of all-solid-state lithium-ion batteries as a new type of halide electrolyte.

关键词： lithium stability electrolyte

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Enhanced termination of zinc and cadmium ions from wastewater employing plain and chitosan-modified mxenes: synthesis, characterization,and adsorption performance

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Green Chemical Engineering 2024年第03期5卷 339-347页

作者： Njood R.Azeez Suhaib S.Salih Mohammed Kadhom Harith N.Mohammed Tushar K.Ghosh department of Chemical Engineering College of Engineering University of Tikrit department of Environmental science College of Energy and Environmental Science Al-Karkh University of Science department of Nuclear science & Engineering Institute University of Missouri-Columbia

Zinc and cadmium pollutants cause a significant environmental effect that cannot be ignored. Due to their considerable amount in an aqueous environment, industries are seeking suitable adsorbents that are environmentally friendly and inexpensive for removing metals from wastewater before disposing of them in surface waters. This research employed original MXene(MX) and chitosan-modified MXene(CSMX) to extract zinc(Zn(Ⅱ)) and cadmium(Cd(Ⅱ)) metal ions from water-based solutions. The composite material produced was analyzed using techniques such as X-ray Diffraction(XRD), Scanning Electron Microscopy(SEM), Fourier Transform Infrared Spectroscopy(FTIR), and Brunauer-Emmett-Teller(BET). The effects of contact duration, p H of the solution, and initial concentration of metal ions on the adsorption process of Zn(Ⅱ) and Cd(Ⅱ) onto both MX and CSMX composites were investigated. MX and prepared CSMX composite presented a high adsorption capacity for both studied heavy metals, which were 91.55 and 73.82 mg/g for Zn(Ⅱ) and Cd(Ⅱ) onto MX, 106.84 and 93.07 mg/g for Cd(Ⅱ) and Zn(Ⅱ) onto CSMX composite, respectively. Furthermore, the maximum competitive adsorption capacities for Zn(Ⅱ) onto MX and CSMX composites are 77.29 and 93.47 mg/g, and for are Cd(Ⅱ)60.30 and 79.66 mg/g, respectively. Hence, the removal capacities for both single and competitive metal ions were superior to CSMX composite. However, the adsorption capacities after five successive regeneration sequences were only dropped by 13.2% for Zn(Ⅱ) and 17.4% for Cd(Ⅱ) onto the CSMX composite compared to the first cycle. These results confirm that both metals could be efficiently terminated from wastewater, which makes the prepared CSMX composite a favorable candidate adsorbent in practical applications.

关键词： Adsorption Chitosan MXene Zn(II) Cd(II) Wastewater

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Modelling the formation and dissolution behavior of alumina agglomerate in the cryolite

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Particuology 2024年第3期86卷 211-222页

作者： Jiaqi Wang Mao Li Benjun Cheng Hesong Li School of energy science and Engineering Central South UniversityChangsha410083China

The presence of alumina agglomerates seriously affects the current efficiency of the aluminum electrolysis *** the dynamic dissolution process of agglomerates is essential to improve the current efficiency of aluminum electrolysis.A mathematical model is proposed to describe the different phenomena from the formation until complete dissolution of *** permeation and solidification processes of cryolite,a semi-analytical mathematical model is developed to formulate the formation,melting and dissolution processes of agglomerates,and the time duration for each stage is *** and heat mass transfer of agglomerates are explored based on the packing theory and mechanism of heat mass transfer in wet porous *** approach is applied to investigate the main factors affecting the dissolution stages and porosity of *** results show that the superheat has a great influence on the formation and melting stage,the diameter of agglomerates can reach 14.93 mm for 200 particles *** density decreases with the increase of agglomerated particle number,which varies in the range of 2.27-2.28 g/cm^(3).The average dissolution rate of agglomerates is about 1.83×10^(-5)-2.95×10^(-5) kg/s within the range of alumina concentration in this study.

关键词： Mathematical model Alumina agglomerate Porous media Packing theory Heatand mass transfer

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Corrosion evaluation and resistance study of alloys in chloride salts for concentrating solar power plants

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Rare Metals 2024年第3期43卷 1222-1233页

作者： Dong-Mei Han Yong Shuai Bachirou Guene Lougou Bo-Xi Geng Xi-Bo He Tian-Tian Yan Jia-Meng Song School of energy science and Engineering Harbin Institute of TechnologyHarbin150001China

Thermal energy storage(TES)systems based on molten salt are widely used in concentrating solar power(CSP)*** investigation of the corrosion behavior of alloy materials in molten salt is crucial for the correct selection of alloy materials and the design of TES *** this study,the corrosion behavior of 304,310S,316,and In625 alloys in molten chloride salts(27 mol%NaCl-22 mol%KCl-51 mol%MgCl,)was *** evolution of mass loss of the alloy samples with corrosion time and temperature and the analysis of the experimental results by scanning electron microscopy(SEM),energy dispersive spectrometer(EDS),and X-ray diffraction(XRD)revealed the corrosion mechanism of the alloy samples in molten chloride *** main factors affecting the corrosion of the alloy samples were further *** was found that the loose multi-layer corrosion was formed on the surface of the corroded alloy samples with the increase in corrosion ***,the experimental *** that Mo played a positive role in improving the corrosion resistance of the alloy samples because the presence of Mo could inhibit the outward diffusion of alloying element *** work enriches the molten salt corrosion database and provides a reference for the selection of alloy materials for TES systems with potential application in CSP plants.

关键词： Thermal energy storage Molten chloride salt Alloy materials Corrosion mechanism Corrosion resistance

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Effects of Number of Bleed Holes on Shock-Wave/Boundary-Layer Interactions in a Transonic Compressor Stator

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Journal of Thermal science 2024年第2期33卷 611-624页

作者： LI Bai ZHOU Xun LUO Lei DU Wei School of energy science and Engineering Harbin Institute of TechnologyHarbin150001China

An extensive numerical investigation is conducted to characterize the flow separation control in a transonic compressor cascade with a porous *** bleed holes are arranged on the suction surface in a single row,two staggered rows and three staggered *** each bleed scheme,five bleed pressure ratios are examined at an inlet Mach number of *** results indicate that the aerodynamic performance of the cascade is significantly improved by the porous *** the single-row scheme,the maximum reduction in total pressure losses is 57%.For the two-staggered-row and three-staggered-row schemes,there is an optimal bleed pressure ratio of 1.0,and the maximum reductions in total pressure loss are 68% and 75%,*** low loss in the cascade is due to the well-controlled boundary *** new local supersonic region created by the bleed hole is the key reason for the improved boundary *** vortex induced by side bleeding provides another mechanism for delaying flow *** the bleed holes could create multiple local supersonic regions,which reduce the range of the adverse pressure gradient that the boundary layer needs to *** is the reason why cascades with more bleed holes perform better.

关键词： transonic compressor stator shock wave/boundary layer interaction porous bleed number of bleed holes

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