检索结果-南通市图书馆

Nano-Micro Letters 2025年第2期17卷 169-186页

作者： Bitgaram Kim Myeong‑Chang Sung Gwang‑Hee Lee Byoungjoon Hwang Sojung Seo Ji‑Hun Seo Dong‑Wan Kim department of Materials Science and engineering Korea University145 Anam‑RoSeongbuk‑GuSeoul 02841Republic of Korea School of civil Environmental and Architectural EngineeringKorea University145 Anam‑RoSeongbuk‑GuSeoul 02841Republic of Korea Materials Science and chemical engineering Center Institute for Advanced Engineering(IAE)Yongin 17180Republic of Korea

A critical challenge hindering the practical application of lithium–oxygen batteries(LOBs)is the inevitable problems associated with liquid electrolytes,such as evaporation and safety *** study addresses these problems by proposing a modified polyrotaxane(mPR)-based solid polymer electrolyte(SPE)design that simultaneously mitigates solvent-related problems and improves ***-SPE exhibits high ion conductivity(2.8×10^(−3)S cm^(−1)at 25℃)through aligned ion conduction pathways and provides electrode protection ability through hydrophobic chain *** this mPR-SPE into solid-state LOBs resulted in stable potentials over 300 *** situ Raman spectroscopy reveals the presence of an LiO_(2)intermediate alongside Li_(2)O_(2)during oxygen *** situ X-ray diffraction confirm the ability of the SPE to hinder the permeation of oxygen and moisture,as demonstrated by the air permeability *** present study suggests that maintaining a low residual solvent while achieving high ionic conductivity is crucial for restricting the sub-reactions of solid-state LOBs.

关键词： Solid polymer electrolyte Lithium-oxygen batteries Polyrotaxane ion conductivity Hydrophobic chain

Effects of particle composition and environmental parameters on catalytic hydrodechlorination of trichloroethylene by nanoscale bimetallic Ni-Fe

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2014年第5期26卷 1162-1170页

作者： Jianjun Wei Yajing Qian Wenjuan Liu Lutao Wang Yijie Ge Jianghao Zhang Jiang Yu Xingmao Ma department of environmental Science and engineering Beijing University of Chemical Technology department of civil and environmental engineering Southern Illinois University Carbondale

Catalytic nickel was successfully incorporated into nanoscale iron to enhance its dechlorination efficiency for trichloroethylene （TCE）, one of the most commonly detected chlorinated organic compounds in groundwater. Ethane was the predominant product. The greatest dechlorination efficiency was achieved at 22 molar percent of nickel. This nanoscale Ni-Fe is poorly ordered and inhomogeneous; iron dissolution occurred whereas nickel was relatively stable during the 24-hr reaction. The morphological characterization provided significant new insights on the mechanism of catalytic hydrodcchlorination by bimetallic nanoparticles. TCE degradation and ethane production rates were greatly affected by environmental parameters such as solution pH, temperature and common groundwater ions. Both rate constants decreased and then increased over the pH range of 6.5 to 8.0, with the minimum value occurring at pH 7.5. TCE degradation rate constant showed an increasing trend over the temperature range of 10 to 25℃. However, ethane production rate constant increased and then decreased over the range, with the maximum value occurring at 20℃, Most salts in the solution appeared to enhance the reaction in the first half hour but overall they displayed an inhibitory effect. Combined ions showed a similar effect as individual salts.

关键词： nanoscale Ni-Fe trichloroethylene hydrodechlorination catalytic dechlorination composition environmental parameters

Influence of random heterogeneity of shear wave velocity on sliding mass response and seismic deformations of earth slopes

在线全文

学校读者我要写书评

暂无评论

Earthquake engineering and engineering Vibration 2020年第2期19卷 269-287页

作者： Pourya Kazemi Esfeh Bahram Nadi Nicholas Fantuzzi department of civil ChemicalEnvironmentaland Materials EngineeringUniversity of BolognaItaly department of civil engineering Azad University of NajafabadIran

Soil shear wave velocity has been recognized as a governing parameter in the assessment of the seismic response of *** spatial variability of soil shear wave velocity can influence the seismic response of sliding mass and seismic ***,most analyses of sliding mass response have been carried out by deterministic *** paper stochastically investigates the effect of random heterogeneity of shear wave velocity of soil on the dynamic response of sliding mass using the correlation matrix decomposition method and Monte Carlo simulation(MCS).The software FLAC 7.0 along with a Matlab code has been utilized for this *** influence of statistical parameters on the seismic response of sliding mass and seismic displacements in earth slopes with different inclinations and stiffnesses subject to various earthquake shakings was *** results indicated that,in general,the random heterogeneity of soil shear modulus can have a notable impact on the sliding mass response and that neglecting this phenomenon could lead to underestimation of sliding deformations.

关键词： random heterogeneity random fields Monte Carlo simulation sliding mass response seismic deformations

Acute and chronic toxicity of nickel to nitrifiers at different temperatures

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2019年第8期31卷 169-178页

作者： Xiaoguang Liu Mohammad M.I.Chowdhury Masuduz Zaman Mingu Kim George Nakhla department of civil and environmental engineering University of Western Ontario department of chemical and Biochemical engineering University of Western Ontario

This study investigated the acute nickel toxicity on nitrification of low ammonia synthetic wastewater at 10, 23, and 35°C. The nickel inhibition half-velocity constants(K_(I,Ni)) for ammonia oxidizing bacteria(AOB) and nitrite oxidizing bacteria(NOB) based on Ni/MLSS ratio at 10, 23, and 35°C were 5.4 and 5.6 mg Ni/g MLSS, 4.6 and 3.5 mg Ni/g MLSS, and 9.1 and 2.7 mg Ni/g MLSS, respectively. In addition, chronic toxicity of nickel to nitrification of low ammonia synthetic wastewater was investigated at 10°C in two sequencing batch reactors(SBRs). Long-term SBRs operation and short-term batch tests were comparable with respect to the extent of inhibition and corresponding Ni/MLSS ratio. The μ_(max), b, and K_o of AOB were 0.16 day^(-1), 0.098 day^(-1) and 2.08 mg O_2/L after long-term acclimatization to nickel of 1 mg/L at 10°C, high dissolved oxygen(DO)(7 mg/L) and long solids retention time(SRT) of 63–70 days. Acute nickel toxicity of nitrifying bacteria was completely reversible.

关键词： Nickel inhibition Temperature Nitrifying culture Activated sludge Toxicity

Role of quantum dots nanoparticles in the chemical treatment of colored wastewater: Catalysts or additional pollutants

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2011年第9期23卷 1479-1485页

作者： Hrvoje Kusic Danuta Leszczynska Natalija Koprivanac Igor Peterne civil and environmental engineering department Jackson State University Faculty of chemical engineering and Technology University of Zagreb

The objective of the study was to investigate the presence and the activity of quantum dots nanoparticles in colored *** special interest is devoted to the investigation of their role in the typical treatment of water or wastewater,studying their influence on the effectiveness of applied treatments *** standard chemical processes for water treatment and disinfection （direct UV photolysis and direct ozonation） were applied for the degradation of colored organic pollutant,reactive azo dye,in the presence/absence of CdSe/ZnS core-shells quantum *** obtained results indicated that investigated nanoparticles inhibit the overall efficiency of applied processes,especially in the case of direct UV photolysis,although catalytic effect might be expected in part due to the semiconductor nature of quantum *** results lead to a conclusion that CdSe/ZnS nanoparticles behave as additional pollutants in the *** should be removed from the system prior the treatment,because their presence could decrease the efficiency,i.e.,prolong the time of treatment and correspondingly increase the costs of the treatment process.

关键词： wastewater treatment CdSe/ZnS core-shells reactive azo dye UV irradiation ozone

Spouting behaviour of binary mixtures in square-based spouted beds

在线全文

学校读者我要写书评

暂无评论

Particuology 2019年第2期17卷 193-201页

作者： Cristina Moliner Filippo Marchelli Massimo Curti Barbara Bosio Giorgio Rovero Elisabetta Arato department of civil Chemical and Environmental Engineering (DICCA) University of Genova (UNIGE) Genova Italy Faculty of Science and Technology Free University of Bolzano (UNIBZ) Bolzano Italy department of Applied Science and Technology (DISAT) Polytechnic University of Turin (POLITO) Turin Italy

From experime nts, the influe nee of the physical characteristics of different bin ary mixtures of solids on the spouting regime of a pyramidal square-based spouted bed reactor is assessed. The applied methodology permits a more precise evaluation of the effects of the tested variables (diameter, density, sphericity) on the response variables (minimum air flows at which spouting begins and at which to maintain spouting con ditions). The associated pressure drops along the bed of particles a nd the height of the formed fountai n are analysed in each case. During the initial stages of fluidisation, binary mixtures containing different density ratios show dead zones. Segregation becomes more evident at large-size and high-density ratios. The lack of sphericity was found to be the main reason leading to blocking, channelling, and start-up problems when system failures occur. Nevertheless, the extent of segregation in all cases decreases with increasing the spouting velocity. In addition, a computational fluid dynamic model based on the discrete element method, previously validated for a single solid bed, is proposed as a tool to predict and evaluate potential segregation phenomena in binary mixtures. This model reproduced with high accuracy the encountered segregation phenomena. Its use may help define the technical limts inherent in the pyramidal spouted bed reactor.

关键词： Spouted bed reactor Segregation Computational fluid dynamics

Coagulation enhanced electrokinetic settling of mature fine oil sands tailings

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

International Journal of Mining Science and Technology 2019年第2期29卷 199-208页

作者： Shriful Islam Julie Q.Shang department of civil and environmental engineering The University of Western Ontario department of civil and environmental engineering Shahjalal University of Science and Technology

The mature fine oil sand tailings(MFT) remain as slurry in the tailings pond for long time. The dewatering and consolidation of MFT for sustainable management is an important task for the mining industry. The objective of this study is to accelerate electrokinetic settling of MFT solids in suspensions in presence of optimal coagulant. In the first phase, optimal coagulant and coagulant dosage for settling of suspension are identified, i.e., ferric chloride at 350 mg/L. It is found that the chemical treatment is not much effective; the final solid content of the sediment is only 6.48% from an initial of 5%. In the second phase,combined coagulation and electrokinetic treatment is carried out to enhance the settling effect. The direct electric current is applied in continuous and intermittent modes on MFT suspensions placed in electrokinetic cell. The results show the final solid content reaches 23.74% under the combined application of350 mg/L ferric chloride and 218.75 V/m applied voltage gradient in the continuous mode. The intermittent current mode with 40% save in power consumption produces a settled sediment having 20.84% final solid content.

关键词： Electrokinetics Electrophoresis Coagulation Settling Voltage gradient MFT

Preparation of cross-linked magnetic chitosan with quaternary ammonium and its application for Cr(Ⅵ) and P(Ⅴ) removal

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2014年第12期26卷 2379-2386页

作者： Wei Yao Pinhua Rao Irene M.C.Lo Wenqi Zhang Wenrui Zheng School of Chemistry and chemical engineering Shanghai University of Engineering Science department of civil and environmental engineering The Hong Kong University of Science and Technology

Pollutants that exist in anionic species are issues of concern in water treatment. Compared to cationic pollutants, the removal of anionic pollutants by adsorption is more difficult because most adsorbents carry predominantly negative charges in neutral and alkaline environments. In this study, a cross-linked chitosan derivative with quaternary ammonium and magnetic properties（QM-chitosan） was prepared and employed to remove chromium（VI） and phosphorus（V）（Cr（VI） and P（V）） from aqueous environments. The QM-chitosan was characterized by Fourier transform infrared spectrometry（FT-IR）,thermogravimetric analysis（TGA）, energy dispersive X-ray（SEM-EDX） and zeta *** experiments show that QM-chitosan can effectively remove Cr（VI） and P（V）, and the main mechanism was believed to be electrostatic interaction. A pseudosecond-order model was fitted to describe the kinetic processes of Cr（VI） and P（V） removal. The adsorption isotherms of both Cr（VI） and P（V） on the QM-chitosan were well fitted by the Langmuir isotherm equation. The saturated adsorption capacity of P（V）（2.783 mmol/g） was found to be higher than that of Cr（VI）（2.323 mmol/g）, resulting from the size of the H2PO-4ions being smaller than that of the HCr O-4ions. However, the theoretical calculation and experimental results showed that QM-chitosan had a stronger affinity for Cr（VI） than P（V）. The adsorption–desorption of the QM-chitosan was evaluated, and high regeneration rates were demonstrated.

关键词： Magnetic chitosan Quaternary ammonium Cr(VI) P(V) Adsorption

Adsorptive removal of resorcinol on a novel ordered mesoporous carbon(OMC) employing COK-19 silica scaffold:Kinetics and equilibrium study

在线全文

学校读者我要写书评

暂无评论

Journal of environmental Sciences 2019年第1期31卷 307-317页

作者： Zaki Uddin Ahmad Qiyu Lian Mark E.Zappi Prashanth R.Buchireddy Daniel Dianchen Gang department of civil engineering University of Louisiana at Lafayette Center for environmental Technology The Energy Institute of Louisiana department of chemical engineering University of Louisiana at Lafayette

Phenolic compounds and their derivatives have been found in industrial wastewater, which pose threats to the natural environment. Ordered mesoporous carbon(OMC) has been identified as an ideal adsorbent possessing high specific surface area and large pore volume to alleviate these pollutants. A novel ordered mesoporous carbon was prepared using COK-19 template with the cubic Fm3 m structure for the first time. Ordered mesoporous silica COK-19 was synthesized and reported in 2015. Sucrose as the carbon precursor was impregnated into the mesopores of silica and converted to carbon through carbonization process using sulfuric acid as a catalyst. Ordered mesoporous carbon was obtained after the removal of silica framework using hydrofluoric acid. Boric acid was employed for the preparation of OMCs with tunable pore sizes in the range of 6.9–16.6 nm. Several characterization techniques such as nitrogen adsorption–desorption isotherms, transmission electron microscope(TEM), Fourier transform infrared spectroscopy, Boehm titration and elemental analysis were employed to characterize the OMCs. The pore size analysis and TEM images confirmed that OMC has replicated the mesostructure of the COK-19. Results obtained from adsorption kinetics and isotherms suggest that the Pseudo-second-order model and Langmuir isotherm well described the experimental data.

关键词： Ordered mesoporous carbon COK-19 TEM image Resorcinol Adsorption isotherm Adsorption kinetics

Oil-in-water nanoemulsions loaded with lycopene extracts encapsulated by spray drying:Formulation,characterization and optimization

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of chemical engineering 2024年第6期70卷 73-81页

作者： Junyang Li Roberta Campardelli Giuseppe Firpo Jingtao Zhang Patrizia Perego department of civil Chemical and Environmental Engineering(DICCA)University of GenoaVia Opera Pia 15Genova 16145Italy department of Physics University of GenoaVia Dodecaneso 32Genova 16146Italy School of Food and Bioengineering Zhengzhou University of Light IndustryZhengzhou 450002China

Lycopene is very susceptible to degradation once released from the protective chromoplast *** this study,oil-in-water(O/W)nanoemulsions coupled with spray drying technology were applied for the encapsulation and stabilization of lycopene extracted from tomato *** extract was obtained by ultrasound-assisted *** were prepared by a high-speed rotor stator using isopropyl myristate as the oil phase and Pluronic F-127 as the emulsifier for the aqueous external *** effect of emulsification process parameters was *** drying of the produced emulsions was attempted to obtain a stabilized dry powder after the addition of a coating *** effect of different coating agents(maltodextrin,inulin,gum arabic,pectin,whey and polyvinylpyrrolidone),drying temperature(120-170℃),and feed flow rate(3-9 ml·min^(-1))on the obtained particles was *** revealed that the emulsion formulation of 20/80(O/W)with 1.5%(mass fraction)of Pluronic F-127 as stabilizer in the aqueous phase resulted in a stable nanoemulsion with droplet sizes in the range of 259-276 nm with a unimodal and sharp size *** extract in the nanoemulsion was well protected at room temperature with a degradation rate of lycopene of about 50%during a month of storage *** most stable emulsions were then processed by spray drying to obtain a dry *** drying was particularly successful when using maltodextrin as a coating agent,obtaining dried spherical particles with mean diameters of(4.87±0.17)μm with a smooth *** possibility of dissolving the spray dried powder in order to *** original emulsion was also successfully verified.

关键词： Emulsions Powders Stability Isopropyl myristate Lycopene Spray-drying