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All-optical neuromorphic devices: materials, working mechanism,and applications

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science China chemistry 2025年

作者： Song Wang Hao Chen Hui Huang College of Materials science and Opto-Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation CAS Key Laboratory of Vacuum Physics University of Chinese Academy of Sciences College of chemistry and molecular Engineering Peking University

Traditional von Neumann computing, with physical separation of memory and processing units, cannot satisfy the development of artificial intelligence and cloud computing. Neuromorphic computing, inspired by the human brain, has drawn much ***-optical neuromorphic (AON) devices employ optical signals as information carriers and leverage the neuromorphic functions to implement fast operation speed, low energy consumption, and high bandwidth of neuromorphic computing. Here, we discuss the recent progress in AON devices, including materials, device performance, working mechanisms, and applications. Moreover,the advantages and limitations of AON are presented and discussed. Finally, the perspective of AON devices points out the future research direction of neuromorphic computing.

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Competitive intermetallics formation in Pd-Zn-Cd system via seeded growth from ultra-thin Pd nanosheets for electrocatalytic ethanol oxidation reaction

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Nano Research 2024年第9期17卷 8552-8559页

作者： Donghao Zhang Lianxi Si Qianqian Ren Xintong Yan Shi Hu department of chemistry School of ScienceTianjin Key Laboratory of Molecular Optoelectronic ScienceTianjin UniversityTianjin 300072China

Pd-based catalysts exhibit higher catalytic activity and durability in many electrochemical ***,the electrochemical performance can be further enhanced by fine-tune of the alloy *** binary alloys have been fully studied,the multicomponent alloys are far beyond understanding,which leaves cocktail effect a compromised explanation for the high-entropy *** Pd nanosheet-seeded growth was used to synthesize a Pd-Zn-Cd ternary alloy by accurately controlling the Pd-Zn-Cd molar ratio through adjusting the amount of introduced Cd *** analysis of the crystal phase structure of PdCdZnx and PdZn_(x)Cd_(1-x),the competitive relationship of Zn and Cd in the alloying process with Pd was unveiled:Pd1Cd1 intermetallics(IMC)is thermodynamically favored over Pd_(1)Zn_(1)IMC in the ternary ***,the increased structure stability of PdCd over PdZn does not bring about increased durability in the catalytic ethanol oxidation *** morphology selection of Pd seeds is also crucial for the study,as Pd cubes,Pd tetrahedrons,and Pd octahedrons do not form PdZn in the same *** successful alloying through the seeded growth depends on the maximum diffusion depth of foreign atoms into the seed.

关键词： PdZn alloy seed growth method ethanol oxidation reaction composition control ternary alloying

Tuning the interfacial reaction environment via pH-dependent and induced ions to understand C–N bonds coupling performance in NO3- integrated CO2 reduction to carbon and nitrogen compounds over dual Cu-based N-doped carbon catalyst

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Journal of Energy chemistry 2025年第1期100卷 273-285页

作者： Tianhang Zhou Chen Shen Zhenghao Wu Xingying Lan Yi Xiao College of Carbon Neutrality Future Technology State Key Laboratory of Heavy Oil Processing China University of Petroleum (Beijing) Institute of Materials science TU Darmstadt department of chemistry Xi'an Jiaotong-Liverpool University department of Mechanical and Mechatronics Engineering and Waterloo Institute of Nanotechnology University of Waterloo Waterloo

Dual atomic catalysts （DAC）,particularly copper （Cu2）-based nitrogen （N） doped graphene,show great potential to effectively convert CO2and nitrate （NO3-） into important industrial chemicals such as ethylene,glycol,acetamide,and urea through an efficient catalytical process that involves C–C and C–N ***,the origin of the coupling activity remained unclear,which substantially hinders the rational design of Cu-based catalysts for the N-integrated CO2reduction reaction （CO2RR）.To address this challenge,this work performed advanced density functional theory calculations incorporating explicit solvation based on a Cu2-based N-doped carbon (Cu2N6C10) catalyst for *** calculations are aimed to gain insight into the reaction mechanisms for the synthesis of ethylene,acetamide,and urea via coupling in the interfacial reaction *** to the sluggishness of CO2,the formation of a solvation electric layer by anions （F-,Cl-,Br-,and I-） and cations (Na+,Mg2+,K+,and Ca2+) leads to electron transfer towards the Cu *** process significantly accelerates the reduction of *** results reveal that*CO intermediates play a pivotal role in N-integrated ***,the Cu2-based N-doped carbon catalyst examined in this study has demonstrated the most potential for C–N coupling to *** findings reveal that through the process of a condensation reaction between*CO and NH2OH for urea synthesis,*NO3-is reduced to*NH3,and*CO2to*CCO at dual Cu atom *** dual-site reduction facilitates the synthesis of acetamide through a nucleophilic reaction between NH3and the ketene ***,we found that the I-and Mg2+ions,influenced by pH,were highly effective for acetamide and ammonia synthesis,except when F-and Ca2+were ***,the mechanisms of C–N bond formation were investigated via ab-initio molecular dynamics simulations,and we found that adjusting the micro-environment can change the dominant side reaction,shift

关键词： Condensation reactions

Interfacial Zn2+-solvation regulator towards reversible and stable Zn anode

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Journal of Energy chemistry 2025年第1期100卷 684-692页

作者： Miao Zhou Xiongbin Luo Hang Li Shan Guo Zhuang Tong Xiaotao Zhou Xu Li Zhaohui Hou Shuquan Liang Guozhao Fang College of Mechanical Engineering Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and Technology School of Materials science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University College of Materials and Metallurgy Guizhou University National Energy Metal Resources and New Materials key laboratory Central South University

Aqueous zinc-ion batteries （AZIBs） are fundamentally challenged by the instability of the electrode/electrolyte interface,predominantly due to irreversible zinc （Zn） deposition and hydrogen ***,the intricate mechanisms behind the electrochemical discrepancies induced by interfacial Zn2+-solvation and deposition behavior demand comprehensive *** molecules endowed with special functional groups （such as hydroxyl,carboxyl,etc.） have the potential to significantly optimize the solvation structure of Zn2+and regulate the interfacial electric double layer （EDL）.By increasing nucleation overpotential and decreasing interfacial free energy,these functional groups facilitate a lower critical nucleation radius,thereby forming an asymptotic nucleation model to promote uniform Zn ***,this study presents a pioneering approach by introducing trace amounts of n-butanol as solvation regulators to engineer the homogenized Zn （H-Zn） anode with a uniform and dense *** interfacial reaction and structure evolution are explored by in/ex-situ experimental techniques,indicating that the H-Zn anode exhibits dendrite-free growth,no by-products,and weak hydrogen evolution,in sharp contrast to the bare ***,the H-Zn anode achieves a remarkable Zn utilization rate of approximately 20% and simultaneously sustains a prolonged cycle life exceeding 500 ***,the H-Zn//NH4V4O10（NVO） full battery showcases exceptional cycle stability,retaining 95.04%capacity retention after 400 cycles at a large current density of 5 A *** study enlightens solvation-regulated additives to develop Zn anode with superior utilization efficiency and extended operational lifespan.

关键词： Solvation

Multicomponent polymerization of elemental sulfur,difluoromethylene phosphobetaine and aryl silyl ethers toward aromatic poly(O,O′-monothiocarbonate)s

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science China chemistry 2025年

作者： Yongjiang Yu Rongrong Hu Ben Zhong Tang State key laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates South China University of Technology School of science and Engineering Shenzhen Institute of Aggregate Science and Technology The Chinese University of Hong Kong AIE Institute

Polythiocarbonates with similar structures to polycarbonates, have emerged as a group of promising sulfur-containing polymers with a range of practical applications, taking advantages of their excellent optical properties, good thermal stability and filmforming ability, and so on. However, the synthesis of polythiocarbonates generally suffered from mixed isomeric structures of repeating units, and hazardous sulfur-containing reagents. In this work, an efficient multicomponent reaction of elemental sulfur,difluoromethylene phosphobetaine（PDFA）, and aryl silyl ethers was designed with the assistance of organic base 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene（MTBD） to produce 12 kinds of O,O′-monothiocarbonate compounds in up to 93% yields,taking advantages of the unique chemical property of difluorocarbene, and the deprotection of silyl group by F-generated from PDFA. Most importantly, the MTBD-assisted multicomponent polymerization of bis（aryl silyl ether）s, elemental sulfur, and PDFA was developed, affording 12 kinds of poly（O,O′-monothiocarbonate）s with well-defined structures, high Mws of up to16900 g/mol and high yields（up to 99%）. These poly（O,O′-monothiocarbonate）s possessed good film-forming properties and thermal stability, high light refractive indices and transmittance. The facile synthesis of these polymonothiocarbonates might pave the way for the development of promising sulfur-containing polymer materials.

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2D conductive metal-organic frameworks for electronics and spintronics

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science China chemistry 2020年第10期63卷 1391-1401页

作者： Xiaoyu Song Jingjuan Liu Ting Zhang Long Chen department of chemistry Institute of Molecular PlusTianjin Key Laboratory of Molecular Optoelectronic ScienceTianjin UniversityTianjin 300072China

Two-dimensional(2D)materials showcase great potentials in both fundamental research and technology development,thanks to their unique chemical and physical properties that are usually not available in corresponding bulk *** an emerging class of 2D materials,2D conductive metal-organic frameworks(2D c-MOFs)exhibit the characteristics of pre-designable and tunable structures,excellent crystallinity,intrinsic porosity and superior *** the past decade,2D c-MOFs have been rapidly developed in electronics,sensors,energy storage devices,*** this review,the electrical,magnetic and quantum properties of 2D c-MOFs are surveyed in *** applications in semiconductor,metal,superconductor,topological insulator and porous magnet are *** envision that the combination of 2D c-MOFs with quantum materials could evoke rich physics,flexible chemistry and potential applications in both electronics and spintronics.

关键词： conductive metal-organic framework charge spin quantum material

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Li,Na,and Cs-based metal-organic frameworks for room temperature phosphorescence applications

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science China chemistry 2025年

作者： Jiaqi Ma Rui Feng Yanyuan Jia Mingshi Zhang Shuo Guo College of chemistry and Chemical Engineering Inner Mongolia University School of Materials science and Engineering Smart Sensing Interdisciplinary Science Center Nankai University & TKL of Metal and Molecule Based Material Chemistry key laboratory of Advanced Energy Materials chemistry (Ministry of Education) Nankai University department of chemistry and Biochemistry University of California San Diego

The conventional design of metal-organic frameworks (MOFs) with room-temperature phosphorescence (RTP) mostly relies on using heavy metals,as the heavy atom effect can effectively increase the efficiency of intersystem crossing (ISC) to get a better phosphorescence *** the first time,we reported the highly efficient RTP of a lithium-based MOF IMU-101 with a lifetime (τ) of 299 ms and a quantum yield (QY) of 4.91%.In addition,MOFs IMU-102 and IMU-103,with sodium and cesium as metal nodes,were successfully *** phosphorescence properties of this series of alkali metal MOFs were systematically studied and *** crystallography and computational calculation show that the mechanism for achieving RTP for this material lies in the ultrashort coordination bond of Li,which enables the reduction of non-radiative ***-101,as a cheap and environmentally friendly room-temperature phosphorescent material,has been further developed into composite polymer inks and bulk *** makes them promising for applications in anti-counterfeiting and information encryption.

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通过诱导P(NDI2OD-T2)薄膜形成D-A堆积结构提高OFETs的高温电学性能稳定性（英文）

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science China Materials 2025年第1期 117-124页

作者：肖雪涛李文豪周青吴锃左小婵马荣徐一飞王思纯赵岩 laboratory of molecular Materials and Devices Department of Materials Science Fudan University State key laboratory of molecular Engineering of Polymers and department of Macromolecular science Fudan University

有机场效应晶体管（OFETs）的电学性能在高温条件下能保持稳定是确保其在特殊环境条件下长期可靠运行的关键.给体-受体（D-A）共轭聚合物的堆积结构与OFETs的电学性能稳定性密切相关.我们选择了聚[[N,N′-双（2-辛基十二烷基）-萘-1,4,5...

有机场效应晶体管（OFETs）的电学性能在高温条件下能保持稳定是确保其在特殊环境条件下长期可靠运行的关键.给体-受体（D-A）共轭聚合物的堆积结构与OFETs的电学性能稳定性密切相关.我们选择了聚[[N,N′-双（2-辛基十二烷基）-萘-1,4,5,8-双（二羧亚胺）-2,6-二基]-交替-5,5′-（2,2′-联噻吩）] P（NDI2OD-T2）作为研究对象,探究了分子堆积结构与高温环境下电学性能稳定性之间的关系.结果表明, D-A单元沿着π-π方向交替堆积的薄膜相比常规的给体-给体（D-D）堆积薄膜具有更好的电学性能温度稳定性. D-A堆积给体和受体单元在面外方向上交替排列,而D-D堆积则是给体与给体单元、受体与受体单元分别堆叠.在225–250°C温度区间,观测到了不可逆的从D-D堆积向D-A堆积的结构转变.由于D-A沿π-π和层状方向的堆积更紧密,薄膜的电子迁移率平均值达到了0.23 cm2/V·s,比D-D堆积薄膜提高了50%.此外,在温度循环测试中, D-A堆积薄膜表现出卓越的电学稳定性, 250°C时依然保有100%的初始迁移率.这一结果表明,通过调控共轭聚合物的紧密D-A堆积结构可以显著提高半导体器件的热稳定性和耐久性.

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Thermally triggered topological polymerization in diacetylene-functionalized covalent organic framework toward enhanced memristive properties

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science China chemistry 2025年

作者： Panke Zhou Yuxing Huang Ziyue Yu Cong Zhang Qian Chen Yiping Li Chao Lin Xiong Chen State key laboratory of Photocatalysis on Energy and Environment Key Laboratory of Advanced Carbon-Based Functional MaterialsCollege of Chemistry Fuzhou University

The development of stimuli-responsive switching memory devices and the elucidation of their switching mechanisms in specific environments are crucial for advancing the field of molecular electronics. Herein, we propose two distinct two-dimensional covalent organic frameworks (COFs), namely Py-EDA and Py-BDA, incorporating acetylene (-C≡C-) or diacetylene(-C≡C-C≡C-) moieties, respectively, targeting fabricate memory devices exhibiting stimuli-responsive switching *** findings demonstrate that the incorporation of acetylene units effectively modulates the electronic band structure and enhances the degree ofπ-conjugation, resulting in devices that exhibit typical bipolar nonvolatile memory performance. Notably,upon thermal treatment, the memory behavior of the ITO/Py-BDA/Ag device transitions to a write-once-read-many-times(WORM) mode, displaying decreased SET voltage, increased ON/OFF current ratio, and remarkable retention reliability and cycle stability. This switching behavior is attributed to the occurrence of interlayer solid-state topological polymerization at 350℃, leading to the transformation of diacetylene columnar arrays into enyne chains within Py-BDA, thereby further promoting interlayer charge transfer and separation.

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