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Unraveling the Harmonious Coexistence of Ruthenium States on a Self-Standing Electrode for Enhanced Hydrogen Evolution Reaction

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Energy & environmental Materials 2024年第6期7卷 303-311页

作者： Joonhee Ma Jin Hyuk Cho Chaehyeon Lee Moon Sung Kang Sungkyun Choi Ho Won Jang Sang Hyun Ahn Seoin Back Soo Young Kim department of Materials Science and engineering Korea UniversitySeoul 02841Korea department of chemical and Biomolecular engineering Institute of Emergent MaterialsSogang UniversitySeoul 04107Korea department of Cogno-Mechatronics engineering College of Nanoscience and NanotechnologyPusan National UniversityBusan 46241Korea department of Materials Science and engineering Research Institute of Advanced MaterialsSeoul National UniversitySeoul 08826Korea School of chemical engineering and Material Science Chung-Ang UniversitySeoul 06974Korea

The development of cost-effective,highly efficient,and durable electrocatalysts has been a paramount pursuit for advancing the hydrogen evolution reaction(HER).Herein,a simplified synthesis protocol was designed to achieve a self-standing electrode,composed of activated carbon paper embedded with Ru single-atom catalysts and Ru nanoclusters(ACP/Ru_(SAC+C))via acid activation,immersion,and high-temperature *** initio molecular dynamics(AIMD)calculations are employed to gain a more profound understanding of the impact of acid activation on carbon ***,the coexistence states of the Ru atoms are confirmed via aberration-corrected scanning transmission electron microscopy(AC-STEM),X-ray photoelectron spectroscopy(XPS),and X-ray absorption spectroscopy(XAS).Experimental measurements and theoretical calculations reveal that introducing a Ru single-atom site adjacent to the Ru nanoclusters induces a synergistic effect,tuning the electronic structure and thereby significantly enhancing their catalytic ***,the ACP/Ru_(SAC+C)exhibits a remarkable turnover frequency(TOF)of 18 s^(−1)and an exceptional mass activity(MA)of 2.2 A mg^(−1),surpassing the performance of conventional Pt *** self-standing electrode,featuring harmoniously coexisting Ru states,stands out as a prospective choice for advancing HER catalysts,enhancing energy efficiency,productivity,and selectivity.

关键词： electrocatalysis electronic coupling effect hydrogen evolution reaction selfstanding electrode

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Boost the Utilization of Dense FeN_(4) Sites for High-Performance Proton Exchange Membrane Fuel Cells

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Energy & environmental Materials 2024年第3期7卷 398-405页

作者： Yanrong Li Shuhu Yin Long Chen Xiaoyang Cheng Chongtai Wang Yanxia Jiang Shigang Sun State Key Laboratory of Physical Chemistry of Solid Surfaces Engineering Research Center of Electrochemical Technologies of Ministry of EducationCollege of Chemistry and Chemical Engineering and Discipline of Intelligent Instrument and EquipmentXiamen UniversityXiamen 361005China College of Chemistry and chemical engineering Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan ProvinceHainan Normal UniversityHaikou 571158China

Iron-nitrogen-carbon(Fe-N-C)catalysts for the oxygen reduction reaction(ORR)in proton exchange membrane fuel cells(PEMFCs)have seriously been hindered by their poor ORR performance of Fe-N-C due to the low active site density(SD)and site ***,we reported a melamine-assisted vapor deposition approach to overcome these *** melamine not only compensates for the loss of nitrogen caused by high-temperature pyrolysis but also effectively etches the carbon substrate,increasing the external surface area and mesoporous porosity of the carbon *** can provide more useful area for subsequent vapor deposition on active *** prepared 0.20Mela-FeNC catalyst shows a fourfold higher SD value and site utilization than the FeNC without the treatment of *** a result,0.20Mela-FeNC catalyst exhibits a high ORR activity with a half-wave potential(E_(1/2))of 0.861 V and 12-fold higher ORR mass activity than the FeNC in acidic *** the cathode in a H_(2)-O_(2)PEMFCs,0.20Mela-FeNC catalyst demonstrates a high peak power density of 1.30 W cm^(-2),outstripping most of the reported Fe-N-C *** developed melamine-assisted vapor deposition approach for boosting the SD and utilization of Fe-N-C catalysts offers a new insight into high-performance ORR electrocatalysts.

关键词： fuel cells melamine oxygen reduction reaction site density utilization

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Degradation of iopamidol in the permanganate/sulfite process:Evolution of iodine species and effect on the subsequent formation of disinfection by-products

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Journal of environmental Sciences 2024年第1期135卷 345-352页

作者： Yimin Lin Hongyu Dong Yating Zhu Gongming Zhou Junlian Qiao Xiaohong Guan State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China department of environmental Science School of Ecological and Environmental SciencesEast China Normal UniversityShanghai 200241China

Permanganate/sulfite(Mn(VII)/S(IV))process is a promising pre-oxidation technology for sequestering the emerging organic contaminants in drinking water treatment ***(IPM),a representative of iodinated X-ray contrast media,has been widely detected in water sources and has the risk of forming iodinated disinfection byproducts(I-DBPs)in water treatment *** this study,we investigated the evolution of iodine species during the IPM degradation by the Mn(VII)/S(IV)process and its effect on the subsequent formation of I-DBPs during chlorination at pH 7.0 and *** could be effectively degraded in the Mn(VII)/S(IV)process at environmentally relevant pH(pH 7.0 and 8.0).The results of quenching and competitive oxidation kinetic experiments revealed that SO^(·-)_(4)was the major reactive oxidizing species contributing to the degradation of IPM whereas the contributions of HO·and reactive manganese species were negligible in the Mn(VII)/S(IV)process.I–and IO–3were generated while no HOI was detected during the degradation of IPM in the Mn(VII)/S(IV)*** effects of IPM oxidation by Mn(VII)/S(IV)on the subsequent formation of chlorinated disinfection by-products(Cl-DBPs)during chlorination were related to the category of *** pre-oxidation of IPM by Mn(VII)/S(IV)resulted in the generation of I-DBPs during the disinfection process although no I-DBPs were detected if no pre-oxidation was *** finding of this study suggested that attention should be paid to the toxicity of DBPs when water containing iodinated organic contaminants is treated by Mn(VII)/S(IV)process or other pre-oxidation technologies.

关键词： Permanganate/sulfite Iopamidol Sulfate radical Iodinated disinfection byproducts Pre-oxidation

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Coupling Co2P nanoparticles onto N,P-doped biomass-derived carbon as efficient electrocatalysts for flexible Zn–air batteries

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Rare Metals 2024年第10期43卷 4982-4991页

作者： Shu-Qi Li Kang Sun Yan-Yan Liu Shu-Ling Liu Jing-Jing Zhou Wen-Bo Zhang Yi-Hang Lu Xiang-Meng Chen Xiao-Peng Wang Bao-Jun Li Jian-Chun Jiang College of Science Henan Agricultural University department of Chemistry Tsinghua University College of Chemistry Zhengzhou University Institute of chemical Industry of Forest Products National Engineering Lab for Biomass Chemical UtilizationKey and Open Lab on Forest Chemical EngineeringChinese Academy of ForestryState Forestry Administration

Catalysts for oxygen conversion play an important role in energy storage and conversion technologies such as metal-air *** highly active stable,and low-cost catalysts is critical for further implementation of the above ***,an efficien oxygen electrocatalyst with Co2P nanoparticles （NPs）coupling onto N,P-doped porous carbon nanosheets（Co2P@NPAC） derived from cotton stalk is successfully designed and prepared via activation,hydrothermal treatment,and pyrolysis *** excellent properties of electrical conductivity,mass transfer,and synergistic integration between Co2P and N,P-doped carbon endow Co2P@NPAC composite with superior oxygen reduction reaction/oxygen evolution reaction （ORR/OER） ***2P@NPAC catalyst achieves ORR activity with half-wave potential of 0.85 V and high OER activity with overpotential of 261 mV at 10 mA·*** flexible Zn-air batteries （ZABs） based on Co2P@NPAC catalyst revea outstanding performances with a high open-circuit voltage（1.38 V）,a peak power density of (75 mW·cm-2),and a low charge-discharge voltage gap （0.74 V,～200 cycles）The flexible ZABs express the stable discharge-charge voltage gap at various bending *** work provides interesting inspiration for the ingenious design of efficien carbon electrocatalysts from biomass with potential application of energy storage and conversion devices.

关键词： Cotton stalk Flexible Zn–air batteries N,P-doped activated carbon Oxygen reduction reaction

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Recent advances in heterogeneous catalysis of solar-driven carbon dioxide conversion

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Journal of environmental Sciences 2024年第6期140卷 165-182页

作者： Jun Xu Farzaneh Arabpour Roghabadi Ying Luo Vahid Ahmadi Qian Wang Zheng Wang Hong He State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China College of Chemistry and chemical engineering Henan Polytechnic UniversityJiaozuoHenan 454000China department of Process engineering Faculty of Chemical EngineeringTarbiat Modares UniversityTehranIran Optoelectronics and Nanophotonics Research Group Faculty of Electrical and Computer EngineeringTarbiat Modares UniversityTehranIran Graduate School of engineering Nagoya UniversityFuro-choChikusa-kuNagoya 464-8603Japan

Solar-driven carbon dioxide(CO_(2))conversion including photocatalytic(PC),photoelectrochemical(PEC),photovoltaic plus electrochemical(PV/EC)systems,offers a renewable and scalable way to produce fuels and high-value chemicals for environment and energy *** review summarizes the basic fundament and the recent advances in the field of solar-driven CO_(2)*** the visible-light absorption is an important strategy to improve solar energy conversion *** separation and migration of photogenerated charges carriers to surface sites and the surface catalytic processes also determine the photocatalytic *** engineering including co-catalyst loading,defect engineering,morphology control,surface modification,surface phase junction,and Z-scheme photocatalytic system construction,have become fundamental strategies to obtain high-efficiency *** to photocatalysis,these strategies have been applied to improve the conversion efficiency and Faradaic efficiency of typical PEC *** PV/EC systems,the electrode surface structure and morphology,electrolyte effects,and mass transport conditions affect the activity and selectivity of electrochemical CO_(2)***,the challenges and prospects are addressed for the development of solar-driven CO_(2)conversion system with high energy conversion efficiency,high product selectivity and stability.

关键词： Solar-driven CO_(2)reduction Photocatalytic system Photoelectrochemical system Photovoltaic plus electrochemical system Surface/interface engineering

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Novel photoactive material and fabrication techniques for solar cells application:nanocellulose-based graphene oxide CdS composite

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Clean Energy 2024年第2期8卷 189-216页

作者： Hassan Oriyomi Shoyiga Stephen Okiemute Akpasi Joseph Akpan Ubani Oluwaseun Amune Sammy Lewis Kiambi Chemistry department North-West UniversityMafikengSouth Africa Material Science Innovation and Modelling(MaSIM)Research Focus Area Faculty of Natural and Agricultural SciencesNorth-West University(Mafikeng Campus)MmabathoSouth Africa Green engineering Research Group Chemical Engineering DepartmentDurban University of TechnologyDurbanSouth Africa Industrial engineering department Durban University of TechnologyDurbanSouth Africa chemical engineering department Edo State UniversityUzairueNigeria chemical engineering department Vaal University of TechnologyVanderbijlparkSouth Africa

In recent times,solar energy has become one of the largest available sources of renewable energy at our ***,the design of highly efficient solar cells is increasingly becoming crucial as there has been a surge for economically viable alternative energy sources with the lowest *** advances have been made through different routes to make photovoltaic(PV)/solar technologies economically viable,eco-friendly and consequently *** a result,cellulose nanomaterials have become one of the emerging technologies in this regard because of the advantages of high-value bio-based nanostructured materials,such as their abundance and ***-based photoactive nanocomposite materials can be made by integrating conducting photoactive and electroconductive materials with hydrophilic biocompatible *** nanoparticles,such as graphene/reduced graphene oxide cadmium sulphide quantum dots,amongst others,can be introduced into the nanocellulose matrix and can be applied either as charge transporters or photoactive materials in different types of solar ***,in this review,we highlight the optoelectronic properties of different photoactive materials,particularly nanocellulose-based graphene nanocomposites;their efficiencies and drawbacks were *** effect of doping each PV material on the PV performance is also *** is anticipated that the novel material would result in a reduction in the cost of solar cells,jointly enhancing their efficacy in generating environmentally friendly *** the fabrication techniques and equipment play a crucial role in the development of solar cells,the fabrication techniques of bulk-heterojunction(BHJ)cells containing a nanocellulose-based graphene composite and case studies of already fabricated BHJ PV cells with nanocellulose-based graphene composite are discussed.

关键词： nanocellulose-based composite bulk heterojunction graphene composite photoactive materials fabrication techniques solar energy power conversion efficiency

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Determining the planting year of navel orange trees in mountainous and hilly areas of southern China:a remote sensing based method

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Journal of Mountain Science 2024年第10期21卷 3293-3305页

作者： LEI Juncheng WANG Sha WANG Yuandong LUO Wei School of Geography and environmental engineering Gannan Normal UniversityGanzhou 341000China School of Chemistry and chemical engineering Gannan Normal UniversityGanzhou 341000China

Remote sensing has demonstrated validity in determining the planting year of deciduous fruit trees;however,its effectiveness in ascertaining the planting year of evergreen fruit trees remains ***,the sources of error associated with using remote sensing to determine the planting year of fruit trees remain *** study investigates several cultivated sweet orange(Citrus sinensis)varieties,which are extensively cultivated throughout subtropical *** analyzed Landsat time series data from 132 navel orange orchards in Gannan,covering the period from 1993 to *** each orchard,Google Earth Engine was employed to extract three vegetation indices—Enhanced Vegetation Index(EVI),Normalized Difference Vegetation Index(NDVI),and Normalized Burn Ratio(NBR)—for each available date,thereby generating three distinct vegetation index time *** planting year of navel orange trees was identified based on abrupt changes observed in these time *** principal sources of error in determining the planting year were investigated using the Wilcoxon signed-rank test,Spearman's correlation analysis,and Kruskal-Wallis H *** findings include:(1)Following the planting of navel orange trees,EVI,NDVI,and NBR exhibited fluctuations and a gradual increase over time,peaking approximately 10 to 15 years later.(2)The vegetation index time series derived from Landsat imagery effectively determined the planting year of evergreen navel orange trees in orchards,even within highly fragmented *** these indices,NDVI and NBR time series outperformed the EVI time ***,the average determination errors for EVI,NDVI,and NBR time series were 6.4,1.8,and 2.8 years,respectively.(3)Major sources of error included the methods used to construct the time series,the selection of vegetation indices,and the orchard management ***,this study provides a viable method for determining the planting year of evergreen navel orange trees in f

关键词： Time series Remote sensing Google Earth Engine Gannan Subtropics

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Revealing the role of electrode potential micro-environments in single Mn atoms for carbon dioxide and oxygen electrolysis

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Nano Research 2024年第9期17卷 7957-7966页

作者： Pengcheng Liu anyi Liu Kaili Wang Shuai Shi Mengmeng Jin Jingxiu Liu Tao Qin Qian Liu Xijun Liu Jia He Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical EngineeringInstitute of New-Energy Materials and Low-Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China School of Chemistry and chemical engineering and environmental engineering Weifang UniversityWeifang 261061China department of Electrical engineering and Automation Luoyang Institute of Science and TechnologyLuoyang 471023China Institute for Advanced Study Chengdu UniversityChengdu 610106China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China

Elucidation the relationship between electrode potentials and heterogeneous electrocatalytic reactions has attracted widespread *** we construct the well-defined Mn single-atom(MnSA)catalyst with four N-coordination through a simple thermal pyrolysis preparation method to investigate the electrode potential micro-environments effect on carbon dioxide reduction reactions(CO_(2)RR)and oxygen reduction reactions(ORR).MnSA catalysts generate higher CO production Faradaic efficiency of exceeding 90%at-0.9 V for CO_(2)RR and higher H_(2)O_(2)yield from 0.1 to 0.6 V with excellent ORR *** functional theory(DFT)calculations based on constant potential models were performed to study the mechanism of MnSA on CO_(2)*** thermodynamic energy barrier of CO_(2)RR is lowest at-0.9 V *** hydrogen electrode(RHE).Similar DFT calculations on the H_(2)O_(2)yield of ORR showed that the H_(2)O_(2)yield at 0.2 V was *** study provides a reasonable explanation for the role of electrode potential micro-environments.

关键词： electrode potential micro-environments Mn single-atom catalyst carbon dioxide reduction reaction oxygen reduction reaction constant potential models

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Incorporation of Ionic Conductive Polymers into Sulfide Electrolyte-Based Solid-State Batteries to Enhance Electrochemical Stability and Cycle Life

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Energy & environmental Materials 2024年第6期7卷 4-12页

作者： Juhyoung Kim Woonghee Choi Seong-Ju Hwang Dong Wook Kim Advanced Materials Division Korea Research Institute of Chemical Technology(KRICT)Daejeon 34114Korea department of Material Science and engineering Yonsei UniversitySeoul 03722Korea department of Material Science and engineering Seoul National UniversitySeoul 08826Korea Advanced Materials and chemical engineering University of Science and Technology(UST)Daejeon 34113Korea

Sulfide-based inorganic solid electrolytes are promising materials for high-performance safe solid-state *** high ion conductivity,mechanical characteristics,and good processability of sulfide-based inorganic solid electrolytes are desirable properties for realizing high-performance safe solid-state batteries by replacing conventional liquid ***,the low chemical and electrochemical stability of sulfide-based inorganic solid electrolytes hinder the commercialization of sulfide-based safe solid-state ***,the instability of sulfide-based inorganic solid electrolytes is intensified in the cathode,comprising various *** this study,carbonate-based ionic conductive polymers are introduced to the cathode to protect cathode materials and suppress the reactivity of sulfide *** instruments,including electrochemical spectroscopy,X-ray photoelectron spectroscopy,and scanning electron microscopy,confirm the chemical and electrochemical stability of the polymer electrolytes in contact with sulfide-based inorganic solid ***-based solid-state cells show stable electrochemical performance over 100 cycles when the ionic conductive polymers were applied to the cathode.

关键词： composite cathode electrochemical stability ionic conductive polymer solid-state battery sulfide solid electrolyte

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Direct 4D printing of functionally graded hydrogel networks for biodegradable,untethered,and multimorphic soft robots

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International Journal of Extreme Manufacturing 2024年第2期6卷 407-416页

作者： Soo Young Cho Dong Hae Ho Sae Byeok Jo Jeong Ho Cho department of chemical and Biomolecular engineering Yonsei UniversitySeoul 03722Republic of Korea department of Mechanical engineering Virginia TechBlacksburgVA 24061United States of America School of chemical engineering Sungkyunkwan UniversitySuwon 16419Republic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan UniversitySuwon 16419Republic of Korea

Recent advances in functionally graded additive manufacturing(FGAM)technology have enabled the seamless hybridization of multiple functionalities in a single *** robotics can become one of the largest beneficiaries of these advances,through the design of a facile four-dimensional(4D)FGAM process that can grant an intelligent stimuli-responsive mechanical functionality to the printed ***,we present a simple binder jetting approach for the 4D printing of functionally graded porous multi-materials(FGMM)by introducing rationally designed graded multiphase feeder *** graded cross-linking agents gradually form stable porous network structures within aqueous polymer particles,enabling programmable hygroscopic deformation without complex mechanical ***,a systematic bed design incorporating additional functional agents enables a multi-stimuli-responsive and untethered soft robot with stark stimulus *** biodegradability of the proposed 4D-printed soft robot further ensures the sustainability of our approach,with immediate degradation rates of 96.6%within 72 *** proposed 4D printing concept for FGMMs can create new opportunities for intelligent and sustainable additive manufacturing in soft robotics.

关键词： intelligent and sustainable additive manufacturing multi-material four-dimensional printing untethered soft robot multi-stimuli-responsive soft robot biodegradable soft robotics

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