检索结果-南通市图书馆

Armoring lithium metal anode with soft±rigid gradient interphase toward high-capacity and long-life all-solid-state battery

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Green Energy & Environment 2024年第8期9卷 1279-1289页

作者： Rui Zhang Biao Chen Yuhan Ma Yue Li Junwei Sha Liying Ma Chunsheng Shi Naiqin Zhao School of Materials Science and engineering and Tianjin Key Laboratory of Composite and Functional Materials Tianjin University Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University department of chemical and Biomolecular engineering National University of Singapore Collaborative Innovation Centre of chemical Science and engineering

Solid polymer electrolytes （SPEs） are highly promising for realizing high-capacity,low-cost,and safe Li metal ***,the Li dendritic growth and side reactions between Li and SPEs also plague these ***,a fluorinated lithium salt coating （FC） with organicinorganic gradient and soft-rigid feature is introduced on Li surface as an artificial protective layer by the in-situ reaction between Li metal and fluorinated carboxylic *** FC layer can improve the interface stability and wettability between Li and SPEs,assist the transport of Li ions,and guide Li nucleation,contributing to a dendrite-free Li deposition and long-lifespan Li metal *** symmetric cell with FC-Li anodes exhibits a high areal capacity of 1 mAh cm-2at 0.5 mA cm-2,and an ultra-long lifespan of 2000 h at a current density of 0.1 m A ***,the full cell paired with the LiFePO4cathode exhibits improved cycling stability,remaining 83.7%capacity after 500 cycles at 1 *** matching with the S cathode,the FC layer can prevent the shuttle effect,contributing to stable and high-capacity Li-S *** work provided a promising way for the construction of stable all-solid-state lithium metal batteries with prolonged lifespan.

关键词： All-solid-state battery Solid polymer electrolyte Li metal anode Li nucleation Interface stability

Investigating the impact of dynamic structural changes of Au/rutile catalysts on the catalytic activity of CO oxidation

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Carbon Energy 2024年第4期6卷 222-232页

作者： Xiaochun Hu Qianwenhao Fan Mingwu Tan Yuqing Luo Xianyue Wu Manoel Y.Manuputty Jie Ding Tej S.Choksi Markus Kraft Rong Xu Zhiqiang Sun Wen Liu School of Energy Science and engineering Central South UniversityChangshaChina School of Chemistry Chemical Engineering and BiotechnologyNanyang Technological UniversitySingaporeSingapore Cambridge Centre for Advanced Research and Education SingaporeSingapore Institute of Sustainability for chemicals Energy and EnvironmentJurong IslandSingapore College of Chemistry and chemical engineering Central South UniversityChangshaChina department of chemical engineering and Biotechnology University of CambridgeCambridgeUK

The surface properties of oxidic supports and their interaction with the supported metals play critical roles in governing the catalytic activities of oxide‐supported metal *** metals are supported on reducible oxides,dynamic surface reconstruction phenomena,including strong metal–support interaction(SMSI)and oxygen vacancy formation,complicate the determination of the structural–functional relationship at the active ***,we performed a systematic investigation of the dynamic behavior of Au nanocatalysts supported on flame‐synthesized TiO_(2),which takes predominantly a rutile phase,using CO oxidation above room temperature as a probe *** analysis conclusively elucidated a negative correlation between the catalytic activity of Au/TiO_(2) and the oxygen vacancy at the Au/TiO_(2) *** the reversible formation and retracting of SMSI overlayers have been ubiquitously observed on Au/TiO_(2) samples,the catalytic consequence of SMSI remains *** functional theory suggests that the electron transfer from TiO_(2) to Au is correlated to the presence of the interfacial oxygen vacancies,retarding the catalytic activation of CO oxidation.

关键词： CO oxidation electronic metal-support interactions flame‐synthesis metal-support interactions oxygen vacancy strong metal-support interaction

Direct 4D printing of functionally graded hydrogel networks for biodegradable,untethered,and multimorphic soft robots

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

International Journal of Extreme Manufacturing 2024年第2期6卷 407-416页

作者： Soo Young Cho Dong Hae Ho Sae Byeok Jo Jeong Ho Cho department of chemical and Biomolecular engineering Yonsei UniversitySeoul 03722Republic of Korea department of Mechanical engineering Virginia TechBlacksburgVA 24061United States of America School of chemical engineering Sungkyunkwan UniversitySuwon 16419Republic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan UniversitySuwon 16419Republic of Korea

Recent advances in functionally graded additive manufacturing(FGAM)technology have enabled the seamless hybridization of multiple functionalities in a single *** robotics can become one of the largest beneficiaries of these advances,through the design of a facile four-dimensional(4D)FGAM process that can grant an intelligent stimuli-responsive mechanical functionality to the printed ***,we present a simple binder jetting approach for the 4D printing of functionally graded porous multi-materials(FGMM)by introducing rationally designed graded multiphase feeder *** graded cross-linking agents gradually form stable porous network structures within aqueous polymer particles,enabling programmable hygroscopic deformation without complex mechanical ***,a systematic bed design incorporating additional functional agents enables a multi-stimuli-responsive and untethered soft robot with stark stimulus *** biodegradability of the proposed 4D-printed soft robot further ensures the sustainability of our approach,with immediate degradation rates of 96.6%within 72 *** proposed 4D printing concept for FGMMs can create new opportunities for intelligent and sustainable additive manufacturing in soft robotics.

关键词： intelligent and sustainable additive manufacturing multi-material four-dimensional printing untethered soft robot multi-stimuli-responsive soft robot biodegradable soft robotics

维普期刊数据库

Advanced 3D ordered electrodes for PEMFC applications: From structural features and fabrication methods to the controllable design of catalyst layers

在线全文

学校读者我要写书评

暂无评论

Green Energy & Environment 2024年第09期9卷 1336-1365页

作者： Kaili Wang Tingting Zhou Zhen Cao Zhimin Yuan Hongyan He Maohong Fan Zaiyong Jiang School of Chemistry & chemical engineering and Environmental engineering Weifang University Beijing Key Laboratory of Ionic Liquids Clean Process State Key Laboratory of Multiphase Complex Systems CAS Key Laboratory of Green Process and Engineering Institute of Process Engineering Chinese Academy of Sciences College engineering and Physical Sciences and School of Energy Resources University of Wyoming

The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, ionomer, and Pt nanoparticles, all immersed together and sprayed with a micron-level thickness of CLs. They have a performance trade-off where increasing the Pt loading leads to higher performance of abundant triple-phase boundary areas but increases the electrode cost. Major challenges must be overcome before realizing its wide commercialization. Literature research revealed that it is impossible to achieve performance and durability targets with only high-performance catalysts, so the controllable design of CLs architecture in MEAs for PEMFCs must now be the top priority to meet industry goals. From this perspective, a 3D ordered electrode circumvents this issue with a support-free architecture and ultrathin thickness while reducing noble metal Pt loadings. Herein, we discuss the motivation in-depth and summarize the necessary CLs structural features for designing ultralow Pt loading electrodes. Critical issues that remain in progress for 3D ordered CLs must be studied and characterized. Furthermore, approaches for 3D ordered CLs architecture electrode development, involving material design, structure optimization, preparation technology, and characterization techniques, are summarized and are expected to be next-generation CLs for PEMFCs. Finally, the review concludes with perspectives on possible research directions of CL architecture to address the significant challenges in the future.

关键词： PEMFC 3D ordered electrode Structural features Preparation technology Ultralow Pt loading

Flexible Covalent Organic Frameworks:Design,Synthesis,and Applications

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

CCS Chemistry 2024年第4期6卷 856-881页

作者： Chunqing Ji Chengjun Kang Bidhan Chandra Patra Dan Zhao department of chemical and Biomolecular engineering National University of SingaporeSingapore 117585

Structural flexibility is an intriguing characteristic observed in materials that endows them with dynamic properties,allowing for intelligent adaptation and deformation in response to varying *** organic frameworks(COFs),a promising class of crystalline porous polymers,have garnered significant attention due to their unique features,including well-ordered,predesignable,and tunable structures,as well as their light-weighted nature and high thermal/chemical *** flexibility into COFs offers a captivating pathway for developing advanced materials with dynamic properties and versatile *** flexible COF field is currently experiencing rapid expansion,and there is a growing need for systematic review articles that offer a comprehensive overview of the developments in this *** this mini-review,we delve into the factors that contribute to structural flexibility in COFs from the point of structural *** summarize and categorize various modes of achieving flexibility across different dimensions,and discuss the potential applications of flexible COFs in vapor/gas adsorption,sensing,and smart membrane separations;further,we highlight their prospects and future research advancement.

关键词： covalent organic frameworks framework flexibility inducing factors flexibility modes smart materials

The principle and amelioration of lithium plating in fast-charging lithium-ion batteries

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第10期97卷 453-459页

作者： Yi Yang Xia-Lin Zhong Lei Xu Zhuo-Lin Yang Chong Yan Jia-Qi Huang School of Materials Science and engineering Beijing Institute of Technology Advanced Research Institute of Multidisciplinary Science Beijing Institute of Technology Beijing Key Laboratory of Green chemical Reaction engineering and Technology Department of Chemical Engineering Tsinghua University Yangtze River Delta Graduate School of Beijing Institute of Technology

Fast charging is restricted primarily by the risk of lithium（Li） plating,a side reaction that can lead to the rapid capacity decay and dendrite-induced thermal runaway of lithium-ion batteries（LIBs）.Investigation on the intrinsic mechanism and the position of Li plating is crucial to improving the fast rechargeability and safety of ***,we investigate the Li plating behavior in porous electrodes under the restricted transport of Li+.Based on the theoretical model,it can be concluded that the Li plating on the anodeseparator interface（ASI） is thermodynamically feasible and kinetically ***,the prior deposition of metal Li on the ASI rather than the anode-current collector interface（ACI） is verified *** order to facilitate the transfer of Li+among the electrode and improve the utilization of active materials without Li plating,a bilayer asymmetric anode composed of graphite and hard carbon（GH） is *** and simulation results suggest that the GH hybrid electrode homogenizes the lithiated-rate throughout the electrode and outperforms the pure graphite electrode in terms of the rate performance and inhibition of Li *** work provides new insights into the behavior of Li plating and the rational design of electrode structure.

关键词： Fast charging Graphite Hard carbon Lithium plating Lithium-ion batteries

Synchrotron X-ray micro-computed tomography imaging of solid bridges between potash particles near contact points

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Particuology 2024年第9期92卷 24-29页

作者： Mojtaba Nabipoor Hassankiadeh Mohammad Mehdi Heydari Carter Blocka Lifeng Zhang department of chemical and Biological engineering University of SaskatchewanSKS7N 5A9SaskatoonCanada

chemical fertilizers,such as potash,have a strong tendency to cake when exposed to *** this work,a novel synchrotron-based X-ray tomography 3D-imaging technique was for the first time employed to investigate the solid bridge formation from 2D and 3D *** processing and a theoretical model were presented to demonstrate recrystallization near contact points between potash particles during a conventional drying *** effect of initial moisture content on the water activity of surface surrounding the contact points was *** results showed that by increasing the moisture content of particles(3%–5%),the dissolution of sylvite increased and the solid bridge length between potash particles was enlarged from 28μm to 44μm due to supersaturation *** addition,the external porosity of potash particles at the end of drying process decreased from 25.3%to 19.5%for 3%and 5%moisture content,respectively.

关键词： Potash fertilizer Solid bridge Recrystallization Synchrotron X-ray micro-CT imaging Drying process

Numerical Analysis of PRISM-PY Calculations for Hard-and Soft-Core Generic Polymer Models

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第4期42卷 532-543页

作者： Qiang Wang department of chemical and Biological engineering Colorado State University1370 Campus DeliveryFort CollinsCO80523-1370USA

Generic polymer models capturing the chain connectivity and excluded-volume interactions between polymer segments can be classified, according to whether or not the 3D integral of the latter diverges, into hard- and soft-core models. Taking homogeneous systems of compressible homopolymer melts (or equivalently homopolymer solutions in an implicit, good solvent) in the continuum as an example, we recently compared the correlation effects on the structural and thermodynamic properties of the hard- and soft-core models given by the polymer reference interaction site model (PRISM) theory with the Percus-Yevick (PY) closure (Polymers 2023, 15, 1180). Here we analyzed in detail the numerical errors and behavior of the interchain pair correlation functions (PCFs) given by the PRISM-PY calculations of these models using an efficient numerical approach that we proposed. Our numerical approach has the least number of independent variables to be iteratively solved, analytically treats the discontinuities caused by the non-bonded pair potential (such as that of the hard spheres) and takes only the inverse Fourier transform of the interchain indirect PCF between polymer segments (which is continuous and decays towards 0 with increasing wavenumber much faster than both the interchain direct and total PCFs), and is essential for us to accurately solve the PRISM-PY theory for chain length N as large as 106. To capture the correlation-hole effect, the real-space cut-off in the PRISM calculations should be proportional to the square root of N.

关键词： Generic polymer models Soft potentials Polymer reference interaction site model theory

维普期刊数据库

Volumetric and viscometric properties of aqueous 1,2-dimethylethylenediamine solution for carbon capture application

在线全文

学校读者我要写书评

暂无评论

Petroleum 2024年第2期10卷 326-337页

作者： Hossein Haghani Teerawat Sema Pipat Na Ranong Thanthip Kiattinirachara Benjapon Chalermsinsuwan Hongxia Gao Zhiwu Liang Paitoon Tontiwachwuthikul department of chemical Technology Faculty of Science Chulalongkorn University Center of Excellence on Petrochemical and Materials Technology Chulalongkorn University department of chemical engineering Faculty of Engineering Mahidol University Joint International Center for CO Clean Energy Technologies Research Institute (CETRi) Faculty of Engineering and Applied Science University of Regina

The present work investigates the volumetric and viscometric properties of an aqueous solution of 1,2-dimethylethylenediamine(DEEDA) over an entire concentration range and an absorber operating temperature range of 313.15K-333.15K at atmospheric pressure. The investigated volumetric properties included the density, excess molar volume, partial molar volume, and the investigated viscometric properties included the viscosity, viscosity deviation, free energy for activation of viscous flow, excess free energy for activation of viscous flow, and excess entropy for activation of viscous flow. The results indicated that there are strong intermolecular interactions and suitable molecular packing in the binary DEEDA-water mixture. Hence, the mixture was found to deviate from a real mixture according to the calculated excess properties. The DEEDA solvent's preliminary volumetric and viscometric properties revealed convincing potential as a novel amine for carbon capture. Additionally, the Redlich-Kister-based correlations showed favorable correlative performance for excess molar volume, viscosity deviation, and excess entropy for activation of viscous flow.

关键词： Density Viscosity Excess property Amine Carbon capture