检索结果-南通市图书馆

Green Energy & Environment 2024年第3期9卷 544-555页

作者： Hengyuan Liu Xingjiang Wu Yuhao Geng Xin Li Jianhong Xu The State Key Laboratory of chemical Engineering Department of Chemical EngineeringTsinghua UniversityBeijing100084China

Electrocatalytic nitrogen reduction reaction(NRR)is considered as a promising candidate to achieve ammonia synthesis because of clean electric energy,moderate reaction condition,safe operating process and harmless ***,the chemical inertness of nitrogen and poor activated capacity on catalyst surface usually produce low ammonia yield and faradic ***,the microfluidic technology is proposed to efficiently fabricate enriched iridium nanodots/carbon *** to in-situ co-precipitation reaction and microfluidic manipulation,the iridium nanodots/carbon nanomaterials possess small average size,uniform dispersion,high conductivity and abundant active sites,producing good proton activation and rapid electrons transmission and moderate adsorption/desorption *** a result,the as-prepared iridium nanodots/carbon nanomaterials realize large ammonia yield of 28.73 μg h^(-1) cm^(-2) and faradic efficiency of 9.14%in KOH ***,the high ammonia yield of 11.21 μg h^(-1) cm^(-2) and faradic efficiency of 24.30%are also achieved in H_(2)SO_(4) *** microfluidic method provides a reference for large-scale fabrication of nano-sized catalyst materials,which may accelerate the progress of electrocatalytic NRR in industrialization field.

关键词： Iridium nanodots Carbon Microfluidic technology Efficient synthesis Electrocatalytic nitrogen fixation

Anisotropic extensions of isotropic Finch–Skea metric in the charged modified gravity

在线全文

学校读者我要写书评

暂无评论

Communications in Theoretical Physics 2024年第9期76卷 118-140页

作者： Tayyab Naseer M Sharif department of Mathematics and Statistics The University of Lahore1-Km Defence RoadLahore 54000Pakistan

In this study,we explore the Finch–Skea perfect fluid solution and extend its domain to three distinct anisotropic interior models within the framework of the f(R,T)theory,incorporating the influence of an electromagnetic *** assume a static spherical spacetime initially coupled with an isotropic matter *** then introduce a Lagrangian corresponding to an additional gravitating source,taking into account its role in inducing pressure anisotropy within the original fluid *** deriving the field equations for the combined matter setup,we applied a radial component transformation,which yielded two distinct systems of *** addition,we consider a charged exterior spacetime to determine the three constants associated with the Finch–Skea solution at the *** findings suggest that under certain parametric choices,all three resulting models exhibited physical relevance within this modified theory.

关键词： anisotropy modified gravity gravitational decoupling

Redefining biofuels:Investigating oil palm biomass as a promising cellulose feedstock for nitrocellulose-based propellant production

在线全文

学校读者我要写书评

暂无评论

defence Technology（防务技术） 2024年第7期37卷 111-132页

作者： Khoirul Solehah binti Abdul Rahim Alinda binti Samsuri Siti Hasnawati binti Jamal Siti Aminah binti Mohd Nor Siti Nor Ain binti Rusly Hafizah binti Ariff Nur Shazwani binti Abdul Latif Centre for Tropicalization(CENTROP) Defence Research InstituteUniversiti Pertahanan Nasional MalaysiaKem Sungai Besi57000 Kuala LumpurMalaysia department of Chemistry and Biology Centre for Defence Foundation StudiesUniversiti Pertahanan Nasional MalaysiaKem Sungai Besi57000 Kuala LumpurMalaysia

This review paper explores the potential of oil palm biomass as a valuable cellulose source for the production of nitrocellulose-based propellants,contributing to the green revolution and sustainable energy *** highlights the availability of the corresponding biomass in Malaysia and in line with global studies,the chemical compositions,as well as a brief description of current technologies for converting biomass of oil palm into value added products specifically *** to achieve maximum utilization of biomass from oil palm industry for cellulose production and prospective source for nitrocellulose-based propellant are also *** methodology section outlines the pretreatment of lignocellulosic fibres,cellulose extraction,and nitrocellulose production ***,the review underscores the prospective of palm oil biomass as a sustainable cellulose source for propellant manufacturing,while acknowledging the need for further research and advancements in the field.

关键词： Biopolymer Cellulose nitrate Energetic materials Green technology Palm oil

Smart materials for safe lithium-ion batteries against thermal runaway

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第7期94卷 360-392页

作者： Yu Ou Pan Zhou Wenhui Hou Xiao Ma Xuan Song Shuaishuai Yan Yang Lu Kai Liu department of chemical Engineering Tsinghua UniversityBeijing 100084China

In recent years,the new energy storage system,such as lithium ion batteries(LIBs),has attracted much *** order to meet the demand of industrial progress for longer cycle life,higher energy density and cost efficiency,a quantity of research has been conducted on the commercial application of ***,it is difficult to achieve satisfying safety and cycling performance *** may be thermal runaway(TR),external impact,overcharge and overdischarge in the process of battery abuse,which makes the safety problem of LIBs more *** this review,we summarize recent progress in the smart safety materials design towards the goal of preventing TR of LIBs reversibly from different abuse *** from smart responsive materials and novel structural design,the safety of LIBs can be improved a *** expect to provide a comprehensive reference for the development of smart and safe lithium-based battery materials.

关键词： Lithium ion batteries(LIBs) Thermal runaway(TR) Smart materials Safe batteries Solid electrolyte interface(SEI)

Strategies for flame-retardant polymer electrolytes for safe lithiumbased batteries

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第10期17卷 8754-8771页

作者： Xiao Ma Yang Lu Yu Ou Shuaishuai Yan Wenhui Hou Pan Zhou Kai Liu department of chemical Engineering Tsinghua UniversityBeijing 100084China

The advancement of lithium-based batteries has spurred anticipation for enhanced energy density,extended cycle life and reduced capacity ***,these benefits are accompanied by potential risks,such as thermal runaway and explosions due to higher energy ***,liquid organic electrolytes are the predominant choice for lithium batteries,despite their limitations in terms of mechanical strength and vulnerability to *** development of polymer electrolytes,with their high Young’s modulus and enhanced safety features,offers a potential solution to the drawbacks of traditional liquid *** these advantages,polymer electrolytes are still susceptible to burning and *** address this issue,researchers have conducted extensive studies to improve their flame-retardant properties from various *** review provides a concise overview of the thermal runaway mechanisms,flame-retardant mechanisms and electrochemical performance of polymer *** also outlines the advancements in flame-retardant polymer electrolytes through the incorporation of various additives and the selection of inherently flame-retardant *** review aims to offer a comprehensive understanding of flame-retardant polymer electrolytes and serve as a guide for future research in this field.

关键词： lithium batteries polymer electrolyte thermal runaway flame-retardant additives energy storage materials

Recent advances in the microfluidic generation of shape-controllable hydrogel microparticles and their applications

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Green chemical Engineering 2024年第1期5卷 16-30页

作者： Yingzhe Liu Zhuo Chen Jianhong Xu The State Key Lab of chemical Engineering Department of Chemical EngineeringTsinghua UniversityBeijing100084China

Hydrogel microparticles,generally accepted as significant green materials,have been widely used in chemical,biological,and biomedical fields owing to their excellent biocompatibility,biodegradability,and *** these,non-spherical hydrogel microparticles with diverse shape anisotropy have great potential in applications such as drug delivery,cellular interaction,micromotors,*** from their shapes,their functionalities in such fields cannot be satisfied by the typical spherical ***,microfluidics with precise control and domination of fluids at microflow sizes has emerged as a powerful method for synthesizing shape-controllable hydrogel microparticles with good monodispersity and unique *** this review,we tried to provide an overview of the production of non-spherical microparticles composed of green hydrogel materials,emphasizing the microfluidic ***,a brief introduction to their current applications is also presented.

关键词： Microfluidics Hydrogel Microparticles Non-spherical Anisotropic Green materials

Novel self-assembled porous yolk-shell NiO nanospheres with excellent electrochromic performance for smart windows

在线全文

学校读者我要写书评

暂无评论

Particuology 2024年第1期84卷 72-80页

作者： Baoshun Wang Ya Huang Siming Zhao Run Li Di Gao Hairong Jiang Rufan Zhang Beijing Key Laboratory of Green chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing100084China

With the rapid development of optoelectronics,electrochromic(EC)materials(ECMs)with the advan-tages of low power consumption,easy viewing,high contrast ratio,etc have attached more and more attention from the fields of smart windows,electronic billboards,emerging wearable and portable electronics,and other next-generation *** oxide(NiO)is a promising candidate for high-performance ECMs because of its neutral-colored states and low ***,NiO-based ECMs still face the problem of slow switching speed due to their low electrical conductivity and small lattice ***-organic frameworks(MOFs)are promising candidates to fabricate hollow and porous transition metal oxides(TMOs)with high ion transport efficiency,excellent specific capacitance,and electrochemical *** this work,porous yolk-shell NiO nanospheres(PYS-NiO NSs)were syn-thesized via a solvothermal and subsequent calcination process of Ni-MOF,which exhibited outstanding EC *** the large specific surface areas and hollow porous nanostructures were conducive to ionic transport,PYS-NiO NSs exhibited a fast coloring/bleaching speed(3.6/3.9 s per one coloring/bleaching cycle)and excellent cycling stability(82%of capacity retention after 3000 cycles).These superior EC properties indicated that the PYS-NiO NSs was a promising candidate for high-performance EC *** work provides a new and feasible strategy for the efficient preparation of TMOs ECMs with good EC performance,especially fast switching speed.

关键词： Electrochromic Nickel oxide Metal-organic frameworks Hollow structure Smart windows

When mRNA meets gene editing

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第8期17卷 7337-7356页

作者： Weijie Li Chen Wang Yuan Lu Key Laboratory of Industrial Biocatalysis Ministry of EducationDepartment of Chemical EngineeringTsinghua UniversityBeijing 100084China department of chemical Engineering Tsinghua UniversityBeijing 100084China

The critical challenge of gene therapy lies in delivering gene editing *** with DNA,while RNA is less stable and more accessible to degrade,it comes with the benefit of lower off-target effects since permanent insertion is not *** review focuses on mRNA-based delivery of gene editing agents,highlighting novel mRNA delivery *** provide context,a comparison is made between three main gene editing agents:programmable nucleases,base editors,and prime *** potential of Cas\pi and transposons is also discussed in this ***,a summary of four main barriers to mRNAbased in vivo delivery is ***,this review detailedly introduced different delivery systems,both viral(lentivirus)and non-viral vectors(genome editing via oviductal nucleic acids delivery,lipid nanoparticles,polymer-based nanoparticles,viruslike-particles,extracellular vesicles,and migrasome).Each delivery strategy is assessed by comparing its advantages and disadvantages to offer a comprehensive and objective overview of the delivery ***,we emphasized the vital role of the protein corona as a critical regulator for ***,we concluded the challenges of mRNA-based gene editing strategies(RNA stability,targeting,potential immunogenicity,cytotoxicity,heterogeneity,and rational design).The purpose of this review is to guide further research and provide a comprehensive analysis of mRNA-based in vivo delivery of gene editing agents in this promising field.

关键词： gene editing mRNA delivery viral vectors non-viral vectors CRISPR

Experimental investigation of viscous oil-water-sand flow in horizontal pipes:Flow patterns and pressure gradient

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Petroleum 2024年第2期10卷 275-293页

作者： Tarek Ganat Petroleum and chemical Engineering department Sultan Qaboos University

Fluid production from unconsolidated reservoirs often leads in sand production,which poses a number of *** deposition in flowlines can result in significant pressure dips,pipe and facility damage,and obstructions that decrease *** research is needed to understand the movement and deposition of sand in oil-water-sand（O-W-S） *** article focuses on O-W-S flows in a 6-meter-long horizontal pipe with an inner diameter of 0.0381 *** study looks at the flow behavior of high viscosity oil-water（O-W）,water-sand（W-S）,and oil-water-sand（O-W-S） *** were carried out at 250 psig pressure in a laboratory flow test facility using various heavy synthetic oils（viscosities ranging from 3500 cP to 7500 cP at 25℃） and tap *** sand concentration varied from 1% to 10%,with an average sand particle diameter of 145 μm and material density of 2630 kg/*** cuts ranged from 0.0 to *** experimental results revealed a minor change in pressure gradient between（O-W） and（O-W-S） ***,increasing the sand concentration in（O-W-S） flow resulted in higher pressure *** reduction factor of pressure gradient indicated that the highest decrease in pressure drop occurred at higher superficial oil ***,a direct relationship was observed between the reduction factor and the decrease in water *** results also showed that the minimum required transportation velocity for sand slurry decreased with increasing superficial oil velocity,while the minimum transportation condition increased with higher sand *** comparison between the expected pressure gradient from Bannwart and McKibben et *** the actual experimental data demonstrated significant accuracy for the oil viscosities and superficial oil velocities used in the study.

关键词： Slurry velocity Flow pattern Pressure gradient High viscosity Minimum transport condition

A novel strategy for ionomer coating of Ag nanoparticles used for the electrochemical reduction of CO2 to CO in a membrane electrode assembly

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

National Science Review 2024年第2期11卷 94-95页

作者： Alexis T.Bell department of chemical and Biomolecular Engineering University of California

The electrochemical reduction of the CO2reaction （CO2RR） offers an attractive means for converting the carbon content of CO2, released from a stationary source or the atmosphere, into fuels and chemicals [1]. Utiliz...

关键词：