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An efficient approach for the treatment of radioactive waste perfluoropolyether lubricants via a synergistic effect of thermal catalysis and immobilization

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Journal of Environmental Sciences 2024年第2期136卷 512-522页

作者： Xinhang Du Wenhua Tong Xinyu Zhou Jia Luo Yuqiu Liu Yabo Wang Panyu Li Yongkui Zhang department of Pharmaceutical&biological engineering School of Chemical EngineeringSichuan UniversityChengdu 610065China

Perfluoropolyether(PFPE)lubricants are a kind of high-molecular polymer with many excellent ***,the use of PFPEs in the nuclear industry can lead to partial decomposition and carrying radionuclides,resulting in a large amount of radioactive waste PFPE lubricants ***,radioactive waste PFPE lubricants are difficult to be effectively treated due to their high stability,the risk of possible leakage of radionuclides,and hypertoxic fluorine-containing *** this study,without any precedent,a strategy of Mn O_(2)-catalyzed decomposition and Na_(2)CO_(3)-immobilized conversion was proposed for PFPE lubricant decomposition and fluorine immobilization simultaneously based on the Lewis acid-base and oxygen vacancies concept.A high fluorine conversion efficiency of 95.4%was ***,the mechanism of decomposition suggested that Mn O_(2)mainly provided Lewis acid sites and attacked the(basic)fluorine or oxygen atoms in PFPE *** decomposition of PFPE chains was proceed down and volatile fluorine-containing gas was released by partial electron transfer,intramolecular disproportionation reaction,and unzipping ***,gas by-products could be further oxidized and then immobilized into fluoride salts by carbonate solid ***,this study provides a simple,safe,and potentially practical strategy for the harmless conversion of refractory fluorinated organic wastes,especially perfluoropolymers.

关键词： Perfluoropolyether lubricants Catalyzed decomposition Fluorine-containing gas Immobilized conversion Fluoride

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Sustainable pathways to ammonia:a comprehensive review of green production approaches

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Clean Energy 2024年第2期8卷 60-72页

作者： Hafiz Sharjeel Ahmed Zaid Yahya Waqar Ali khan Ali Faraz University of engineering and Technology(UET) LahorePakistan chemical engineering department NFC Institute of Engineering and Fertilizer ResearchFaislabadPakistan chemical engineering department Punjab UniversityLahorePakistan

Ammonia production is vital in global industries but faces increasing environmental concerns,necessitating a shift towards sustainable *** review comprehensively explores diverse hydrogen production approaches and their potential impact on sustainable ammonia *** primary focus is investigating hydrogen production methods that enhance both efficiency and sustainability in ammonia synthesis,which is crucial for reducing its environmental ***,the review highlights the pivotal role of catalysts in improving Faradaic efficiency in ammonia synthesis,emphasizing their significance in overall process *** study identifies innovative technologies that have the potential to revolutionize ammonia production while aligning with global sustainability *** a thorough examination of hydrogen production methods and catalytic advances,this review provides valuable insight into greener and more efficient ammonia production *** conclusion,it emphasizes the importance of exploring hydrogen production methods and leveraging catalysts to improve ammonia production sustainability and *** addresses a critical research gap and paves the way for an environmentally responsible and globally aligned ammonia production industry.

关键词： ammonia production green alternatives sustainability catalyst

Energy-absorbing porous materials:Bioinspired architecture and fabrication

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Nano research 2024年第2期17卷 679-690页

作者： Junheng Zhao Meng Li Jiewei Chen Weiwei Gao Hao Bai State Key Laboratory of chemical engineering College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310058China department of Polymer Science and engineering Zhejiang UniversityHangzhou 310058China

Energy-absorbing materials are widely used in transportations,sports,and the military ***,porous materials,including natural and artificial materials,have attracted tremendous attentions due to their light weight and excellent energy absorption *** review summarizes the recent progresses in the natural and artificial energy-absorbing porous ***,we review the typical natural porous materials including cuttlebone,bighorn sheep horn,pomelo peel,and sunflower stem *** architectures,energy absorption abilities,and mechanisms of these typical natural materials and their bioinspired materials are ***,we provide a review on the fabrication methods of artificial energy-absorbing porous materials,such as conventional foaming and three-dimensional(3D)***,we address the challenges and prospects for the future development of energy-absorbing porous *** importantly,our review provides a direct guidance for the design and fabrication of energy-absorbing porous materials required for various engineering applications.

关键词： energy-absorbing porous materials natural materials natural structures bioinspired materials

Multifunctional applications of gadolinium-doped cerium oxide(Ce1-xGdxO2-?) ceramics:A review

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Journal of Rare Earths 2024年第10期42卷 1817-1834页

作者： Subhadip Das Rakesh Bhaskar Kannan Badri Narayanan department of Ceramic engineering National Institute of Technology Rourkela School of chemical engineering Yeungnam University

Cerium oxide（CeO2）,or ceria,and its doped derivatives have been extensively studied for several decades and are well-known oxides valued for their unique structural properties and wide range of *** materials play a crucial role in sustainable development within *** modification through de fect e ngineering of the highly stable cubic fluorite phase enhances the versatility of this doped ceria to a new *** the numerous dopants of the CeO2matrix,ceria doped with gadolinium（Gd）,known as Ce1-xGdxO2-?（CGO）,is gaining popularity due to its *** introduction of defect-induced vacancies in the oxygen sublattice（V_o） and a change in the average valence of cerium(Ce3+/Ce4+) are primarily responsible for the improved performance compared to pristine *** materials are currently undergoing intensive research for potential use as electrolytes in intermediate-temperature solid oxide fuel cells（IT-SOFCs） and dense oxygen-permeable membranes（OPMs）.Additionally,they are being commercially utilized for power generation and oxygen *** materials are also attracting significant attention in various fields such as optics,photocatalysis,electrostriction,spintronics,gas sensing,electrocatalysis,and biomedical *** review paper aims to compile the latest contributions to CGO materials and comprehensively cover their various application *** crystal structure,defect equilibrium in Gd3+-doped CeO2,the origin of multifunctionality,and the prospects of these materials are also exclusively discussed.

关键词： Biomedicine Gadolinium-doped CeO2 Gas sensors Photo/electrocatalysts Rare earths Spintronics

Advanced oxidation via the synergy of C-defective/C-O band modified ultrathin porous g-C3N4 and PMS for efficient photothermal degradation of bisphenol pollutants and lignin derivatives

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Green Energy & Environment 2024年第7期9卷 1159-1170页

作者： Liquan Jing Meng Xie Yuanguo Xu Chun Tong Xia Du Heng Zhao Na Zhong Huaming Li Jinguang Hu School of Chemistry and chemical engineering Jiangsu University department of chemical and Petroleum engineering University of Calgary School of Pharmacy Jiangsu University School of Material Science & chemical engineering Harbin University of Science and Technology institute for Energy research Jiangsu University

This work uses thermal polymerization of urea nitrate, oxyacetic acid and urea as the raw material to prepare ultra-thin porous carbon nitride with carbon defects and C-O band（OA-UN-CN）. Density functional theory（DFT） calculations showed OA-UN-CN had narrower band gap,faster electron transport and a new internal construction electric field. Additionally, the prepared OA-UN-CN significantly enhanced photocatalytic activation of peroxymonosulfate（PMS） due to enhanced light absorption performance and faster electron overflow. As the result, the OA-UN-CN/PMS could entirely degrade bisphenol A（BPA） within 30 min, where the photodegradation rate was 81.8 and 7.9 times higher than that of g-C3N4and OA-UN-CN, respectively. Beyond, the OA-UN-CN/PMS could likewise degrade other bisphenol pollutants and sodium lignosulfonate efficiently. We suggested possible photocatalytic degradation pathways accordingly and explored the toxicity of its degradation products. This work provides a new idea on the development of advanced photocatalytic oxidation processes for the treatment of bisphenol pollutants and lignin derivatives, via a metal-free photothermal-catalyst.

关键词： Photothermal-catalytic G-C 3 N 4 Peroxymonosulfate Bisphenol Sodium lignosulfonate

An application of a genetic algorithm in co-optimization of geological CO_(2)storage based on artificial neural networks

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Clean Energy 2024年第1期8卷 111-125页

作者： Pouya Vaziri Behnam Sedaee institute of Petroleum engineering Chemical Engineering DepartmentCollege of EngineeringUniversity of TehranTehranIran

Global warming,driven by human-induced disruptions to the natural carbon dioxide(CO_(2))cycle,is a pressing *** mitigate this,carbon capture and storage has emerged as a key strategy that enables the continued use of fossil fuels while transitioning to cleaner energy *** saline aquifers are of particular interest due to their substantial CO_(2)storage potential,often located near fossil fuel *** this study,a deep saline aquifer model with a saline water production well was constructed to develop the optimization *** to the time-consuming nature of each realization of the numerical simulation,we introduce a sur-rogate aquifer model derived from extracted *** novelty of our work lies in the pioneering of simultaneous optimization using machine learning within an integrated *** previous studies,which typically focused on single-parameter optimiza-tion,our research addresses this gap by performing multi-objective optimization for CO_(2)storage and breakthrough time in deep sa-line aquifers using a data-driven *** methodology encompasses preprocessing and feature selection,identifying eight pivotal *** metrics include root mean square error(RMSE),mean absolute percentage error(MAPE)and R^(2).In predicting CO_(2)storage values,RMSE,MAPE and R^(2)in test data were 2.07%,1.52%and 0.99,respectively,while in blind data,they were 2.5%,2.05%and *** the CO_(2)breakthrough time,RMSE,MAPE and R^(2)in the test data were 2.1%,1.77%and 0.93,while in the blind data they were 2.8%,2.23%and 0.92,*** addressing the substantial computational demands and time-consuming nature of coup-ling a numerical simulator with an optimization algorithm,we have adopted a strategy in which the trained artificial neural network is seamlessly integrated with a multi-objective genetic *** this framework,we conducted 5000 comprehensive experi-ments to rigorously validate the development of the Pareto f

关键词： carbon capture and storage deep saline aquifer artificial neural network multi-objective optimization genetic algorithm breakthrough time geological storage

Molecular insights into oil detachment from hydrophobic quartz surfaces in clay-hosted nanopores during steam-surfactant co-injection

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Petroleum Science 2024年第4期21卷 2457-2468页

作者： Ben-Jie-Ming Liu Xuan-Tong Lei Mohammadali Ahmadi Zhangxin Chen department of chemical and Petroleum engineering University of Calgary Eastern institute of Technology

Thermal recovery techniques for producing oil sands have substantial environmental impacts. Surfactants can efficiently improve thermal bitumen recovery and reduce the required amount of steam. Such a technique requires solid knowledge about the interaction mechanism between surfactants, bitumen,water, and rock at the nanoscale level. In particular, oil sands ores have extremely complex mineralogy as they contain many clay minerals(montmorillonite, illite, kaolinite). In this study, molecular dynamics simulation is carried out to elucidate the unclear mechanisms of clay minerals contributing to the bitumen recovery under a steam-anionic surfactant co-injection process. We found that the clay content significantly influenced an oil detachment process from hydrophobic quartz surfaces. Results reveal that the presence of montmorillonite, illite, and the siloxane surface of kaolinite in nanopores can enhance the oil detachment process from the hydrophobic surfaces because surfactant molecules have a stronger tendency to interact with bitumen and quartz. Conversely, the gibbsite surfaces of kaolinite curb the oil detachment process. Through interaction energy analysis, the siloxane surfaces of kaolinite result in the most straightforward oil detachment process. In addition, we found that the clay type presented in nanopores affected the wettability of the quartz surfaces. The quartz surfaces associated with the gibbsite surfaces of kaolinite show the strongest hydrophilicity. By comparing previous experimental findings with the results of molecular dynamics(MD) simulations, we observed consistent wetting characteristics. This alignment serves to validate the reliability of the simulation outcomes. The outcome of this paper makes up for the lack of knowledge of a surfactant-assisted bitumen recovery process and provides insights for further in-situ bitumen production engineering designs.

关键词： Clay minerals Bitumen Contact angle Interaction energy Surfactant Molecular dynamics

Surface morphologies of Mg-Gd alloy particle during its reactions with O_(2) and Teflon

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Defence Technology（防务技术） 2024年第3期33卷 209-221页

作者： Yifan Li Hongtao Yang Aifeng Jiang Dongming Song Yanchun Li department of chemical engineering Nanjing University of Science and TechnologyNanjing 210097China Xi'an Modern Chemistry research institute Xi'an 710065China Southwest Technology and engineering research institute Chongqing 400039China

Mg-Gd alloy particle has exhibited its unique combustion properties as the fuel of Mg/Teflon/Viton(MTV).Mg-Gd alloy/Teflon/Viton(MGTV)could burn at lower ambient pressure than *** further investigate the reaction of MGTV in air,it was investigated via thermo gravity-differential scanning calorimetry(TG-DSC).Meanwhile,the morphologies and element distributions on the alloy surface during the reaction of MGTV in air were investigated via scanning electronic microscope-mapping-electronic differential ***,a similar experimental protocol on the Mg-Gd alloy particle during oxidation was also *** results showed that owning to a protective oxide shell,the onset oxidation temperature of Mg-Gd alloy is higher than ***,the onset oxidation temperature of the exceeded Mg-Gd alloy in MGTV is significantly lower than that of the exceeded Mg in *** was due to the existence of GdOF,which could significantly lower the oxidation temperature of the exceeded ***,a possible reaction mechanism was *** fascinating oxidation properties of Mg-Gd alloy suggested its promising applications in energetic materials.

关键词： Mg-Gd alloy Energetic materials Morphology EDS GdOF

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Acetylacetone-TiO_(2) Promoted Large Area Compatible Cascade Electron Transport Bilayer for Efficient Perovskite Solar Cells

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Energy & Environmental Materials 2024年第2期7卷 221-228页

作者： Hyong Joon Lee Jin Kyoung Park Jin Hyuck Heo Sang Hyuk Im department of chemical and biological engineering Korea University145 Anam-ro Seongbuk-guSeoul 17104Korea

In designing efficient perovskite solar cells(PSCs),the selection of suitable electron transport layers(ETLs)is critical to the final device performance as they determine the driving force for selective charge ***_(2)nanoparticles(NPs)based ETLs have been a popular choice for PSCs due to superior electron mobility,but their relatively deep-lying conduction band energy levels(ECB)result in substantial potential ***,TiO_(2)NPs establish favorable band alignment owing to shallower ECB,but their low intrinsic mobility and abundant surface trap sites impede the final *** this reason,constructing a cascaded bilayer ETL is highly desirable for efficient PSCs,as it can rearrange energy levels and exploit on advantages of an individual *** this study,we prepare SnO_(2)NPs and acetylacetone-modified TiO_(2)(Acac-TiO_(2))NPs and implement them as bilayer SnO_(2)/Acac-TiO_(2)(BST)ETL,to assemble cascaded energy band ***_(2)contributes to rapid charge carrier transport from high electron mobility while Acac-TiO_(2)minimizes band-offset and effectively suppresses interfacial ***,the optimized BST ETL generates synergistic influence and delivers power conversion efficiency(PCE)as high as 23.14%with open-circuit voltage(V_(oc))reaching 1.14 ***,the BST ETL is transferred to a large scale and the corresponding mini module demonstrates peak performance of 18.39%PCE from 25 cm^(2)aperture ***,the BST-based mini module exhibit excellent stability,maintaining 83.1%of its initial efficiency after 1000 h under simultaneous 1 Sun light-soaking and damp heat(85℃/RH 85%)environment.

关键词： acetylacetone large area perovskite solar cells TiO_(2)

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