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Helmholtz decomposition with a scalar Poisson equation in elastic anisotropic media

petroleum Science 2024年第3期21卷 1597-1610页

作者： Xin-Yu Fang Gang Yao Qing-Qing Zheng Ping-Min Zhang Di Wu Feng-Lin Niu State Key Laboratory of petroleum Resources and Engineering China University of Petroleum (Beijing) Unconventional petroleum Research Institute China University of Petroleum (Beijing) department of Mathematics College of Science China University of Petroleum (Beijing) College of Geophysics China University of Petroleum (Beijing) department of Earth Environmental and Planetary Sciences Rice University

P-and S-wave separation plays an important role in elastic reverse-time migration. It can reduce the artifacts caused by crosstalk between different modes and improve image quality. In addition, P-and Swave separation can also be used to better understand and distinguish wave types in complex media. At present, the methods for separating wave modes in anisotropic media mainly include spatial nonstationary filtering, low-rank approximation, and vector Poisson equation. Most of these methods require multiple Fourier transforms or the calculation of large matrices, which require high computational costs for problems with large scale. In this paper, an efficient method is proposed to separate the wave mode for anisotropic media by using a scalar anisotropic Poisson operator in the spatial domain.For 2D problems, the computational complexity required by this method is 1/2 of the methods based on solving a vector Poisson equation. Therefore, compared with existing methods based on pseudoHelmholtz decomposition operators, this method can significantly reduce the computational cost. Numerical examples also show that the P and S waves decomposed by this method not only have the correct amplitude and phase relative to the input wavefield but also can reduce the computational complexity significantly.

关键词： Anisotropic media Scalar anisotropic Poisson equation Improved elastic wavefield decomposition

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New insights into the deposition of natural gas hydrate on pipeline surfaces:A molecular dynamics simulation study

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petroleum Science 2024年第1期21卷 694-704页

作者： Jun Zhang Hai-Qiang Fu Mu-Zhi Guo Zhao Wang Li-Wen Li Qi Yin You-Guo Yan Wei Wei Wei-Feng Han Jie Zhong School of Materials Science and Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina School of petroleum Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina department of Alternative Energy PetroChina Research Institute of Petroleum Exploration&DevelopmentLangfang 065007HebeiChina

Natural gas hydrate(NGH)can cause pipeline blockages during the transportation of oil and gas under high pressures and low temperatures.Reducing hydrate adhesion on pipelines is viewed as an efficient way to prevent NGH blockages.Previous studies suggested the water film can greatly increase hydrate adhesion in gas-dominant system.Herein,by performing the molecular dynamics simulations,we find in water-dominant system,the water film plays different roles in hydrate deposition on Fe and its corrosion surfaces.Specifically,due to the strong affinity of water on Fe surface,the deposited hydrate cannot convert the adsorbed water into hydrate,thus,a water film exists.As water affinities decrease(Fe>Fe_(2)O_(3)>FeO>Fe_(3)O_(4)),adsorbed water would convert to amorphous hydrate on Fe_(2)O_(3)and form the ordered hydrate on FeO and Fe_(3)O_(4)after hydrate deposition.While absorbed water film converts to amorphous or to hydrate,the adhesion strength of hydrate continuously increases(Fe

关键词： Deposition Natural gas hydrate Pipelines Water affinity Adhesion strength

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Experimental investigation into effects of the natural polymer and nanoclay particles on the EOR performance of chemical flooding in carbonate reservoirs

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petroleum Science 2024年第2期21卷 951-961页

作者： Amir Mohammad Zamani Ashkan Moslemi Kamran Hassani department of petroleum Engineering Islamic Azad University Science and Research BranchTehranIran Institute of petroleum Engineering University of TehranTehranIran

This paper aims to investigate the tragacanth gum potential as a natural polymer combined with natural clay mineral(montmorillonite,kaolinite,and illite)nanoparticles(NPs)to form NP-polymer suspension for enhanced oil recovery(EOR)in carbonate reservoirs.Thermal gravimetric analysis(TGA)tests were conducted initially in order to evaluate the properties of tragacanth gum.Subsequently,scanning electron microscopy(SEM)and energy-dispersive X-ray(EDX)tests were used to detect the structure of clay particles.In various scenarios,the effects of natural NPs and polymer on the wettability alteration,interfacial tension(IFT)reduction,viscosity improvement,and oil recovery were investigated through contact angle system,ring method,Anton Paar viscometer,and core flooding tests,respectively.The entire experiment was conducted at 25,50,and 75℃,respectively.According to the experimental results,the clay minerals alone did not have a significant effect on viscosity,but the addition of minerals to the polymer solution leads to the viscosity enhancement remarkably,resulting mobility ratio improvement.Among clay NPs,the combination of natural polymer and kaolinite results in increased viscosity at all temperatures.Considerable wettability alteration was also observed in the case of natural polymer and illite NPs.Illite in combination with natural polymer showed an ability in reducing IFT.Finally,the results of displacement experiments revealed that the combination of natural polymer and kaolinite could be the best option for EOR due to its substantial ability to improve the recovery factor.

关键词： Chemical flooding Tragacanth gum Clay nanoparticle Wettability IFT

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A contrasting analysis of CO_(2)and N_(2)foam flood for enhanced oil recovery and geological storage of CO_(2)

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petroleum Research 2024年第1期9卷 55-60页

作者： Alireza Roozbahani Farshad Soofivan Ali Sagban Hassoon Al-Tameemi Hadi Abdollahi Sogand Saatchi Abdolhamid Ansari petroleum Engineering department Faculty of Chemical EngineeringTarbiat Modares UniversityTehranIran School of Chemical and petroleum Engineering Shiraz UniversityShirazIran School of Chemical and petroleum Engineering Shiraz BranchIslamic Azad UniversityShirazIran department of petroleum Engineering Science and Research BranchAzad UniversityTehranIran department of Chemistry and Chemical Engineering Rasht BranchIslamic Azad UniversityRashtIran department of petroleum Engineering Lamerd BranchIslamic Azad UniversityLamerdIran

Foam flooding using CO_(2)has emerged as a promising method for both enhanced oil recovery(EOR)and the storage of CO_(2)in geological reservoirs.This study conducts a thorough analysis of the behavior of CO_(2)and N_(2)foams in bulk and porous media,utilizing bubble-scale analyses and foam flooding experiments.The study compares the foamability and longevity of CO_(2)and N_(2)foams,with findings indicating that N_(2)foam bubbles tend to be smaller and less varied in size than CO_(2)foam bubbles,leading to increased foam stability.Additionally,the study compares the half-lives of CO_(2)and N_(2)foams generated through sparging and winding methods,showing that N_(2)foam has half-lives 22 and 10 times greater than CO_(2)foam when produced using the sparging and winding methods,respectively.Furthermore,CO_(2)foam generated through the sparging method had a lower foaming volume than N_(2)foam due to CO_(2)'s solubility.In the foam flooding experiments,N_(2)foam proved more effective in recovering oil from porous media than CO_(2)foam,thus demonstrating the effectiveness of the foam injection procedure.These results offer valuable insights into the differing performance of N_(2)and CO_(2)foam floods for EOR and CO_(2)geological storage.

关键词： CO_(2)storage Foam flood Enhanced oil recovery N_(2)foam CO_(2)foam

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Comparative study between three carbonaceous nanoblades and nanodarts for antimicrobial applications

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Journal of Environmental Sciences 2024年第2期136卷 594-605页

作者： Mohamed S.Selim Ahmed M.Azzam Mohamed A.Shenashen Shimaa A.Higazy Bayaumy B.Mostafa Sherif A.El-Safty National Institute for Materials Science(NIMS) 1-2-1 SengenTsukuba-ShiIbaraki-Ken 305-0047Japan petroleum Application department Egyptian Petroleum Research InstituteNasr City 11727Egypt department of Environmental Research Theodor Bilharz Research InstituteGizaEgypt

The design of nanostructured materials occupies a privileged position in the development and management of affordable and effective technology in the antibacterial sector.Here,we discuss the antimicrobial properties of three carbonaceous nanoblades and nanodarts materials of graphene oxide(GO),reduced graphene oxide(RGO),and single-wall carbon nanotubes(SWCNTs)that have a mechano-bactericidal effect,and the ability to piercing or slicing bacterial membranes.To demonstrate the significance of size,morphology and composition on the antibacterial activity mechanism,the designed nanomaterials have been characterized.The minimum inhibitory concentration(MIC),standard agar well diffusion,and transmission electron microscopy were utilized to evaluate the antibacterial activity of GO,RGO,and SWCNTs.Based on the evidence obtained,the three carbonaceous materials exhibit activity against all microbial strains tested by completely encapsulating bacterial cells and causing morphological disruption by degrading the microbial cell membrane in the order of RGO>GO>SWCNTs.Because of the external cell wall structure and outer membrane proteins,the synthesized carbonaceous nanomaterials exhibited higher antibacterial activity against Gram-positive bacterial strains than Gram-negative and fungal microorganisms.RGO had the lowest MIC values(0.062,0.125,and 0.25 mg/mL against B.subtilis,S.aureus,and E.coli,respectively),as well as minimum fungal concentrations(0.5 mg/mL for both A.fumigatus and C.albicans).At 12 hr,the cell viability values against tested microbial strains were completely suppressed.Cell lysis and death occurred as a result of severe membrane damage caused by microorganisms perched on RGO nanoblades.Our work gives an insight into the design of effective graphene-based antimicrobial materials for water treatment and remediation.

关键词： Antimicrobial properties Nanoblades Mechano-bactericidal effect RGO nanosheets Gram-positive bacteria Cell viability

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A molecular insight into coke formation process of vacuum residue in thermal cracking reaction

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petroleum Science 2024年第3期21卷 2130-2138页

作者： Ji-Guang Li Xin Guo Huan-Di Hou Heavy Oil Processing department Sinopec Research Institute of Petroleum Processing Co. Ltd

Understanding the coking behaviors has been considered to be really essential for developing better vacuum residue processing technologies. A battery of thermal cracking tests of typical vacuum residue at410°C with various reaction time were performed to evaluate the coke formation process. The total yields of ideal components including naphtha, atmospheric gas oil(AGO) and vacuum gas oil(VGO) of thermal cracking reactions increased from 10.89% to 40.81%, and the conversion ratios increased from8.05% to 43.33% with increasing the reaction time from 10 to 70 min. The asphaltene content increased from 12.14% to a maximum of 22.39% and then decreased, and this maximum of asphaltene content occurred at the end of the coking induction period. The asphaltenes during the coking induction period,at the end and after coking induction period of those tested thermal cracking reactions were characterized to disclose the structure changing rules for coke formation process, and the coke formation pathways were discussed to reveal the coke formation process at molecular level.

关键词： Vacuum residue Thermal cracking Asphaltene Coking induction period Sulfur Nitrogen

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A Minimum Residual Based Gradient Iterative Method for a Class of Matrix Equations

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Acta Mathematicae Applicatae Sinica 2024年第1期40卷 17-34页

作者： Qing-qing Zheng department of Mathematics College of ScienceChina University of Petroleum-BeijingBeijing102249China

In this paper, we present a minimum residual based gradient iterative method for solving a class of matrix equations including Sylvester matrix equations and general coupled matrix equations. The iterative method uses a negative gradient as steepest direction and seeks for an optimal step size to minimize the residual norm of next iterate. It is shown that the iterative sequence converges unconditionally to the exact solution for any initial guess and that the norm of the residual matrix and error matrix decrease monotonically. Numerical tests are presented to show the efficiency of the proposed method and confirm the theoretical results.

关键词： Sylvester matrix equation coupled matrix equation minimum residual gradient descent convergence analysis

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Implications of electrode modifications in aqueous organic redox flow batteries

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Journal of Energy Chemistry 2024年第8期95卷 499-510页

作者： Zahid Manzoor Bhat Mohammad Furquan Muhammad Aurang Zeb Gul Sial Umair Alam Atif Saeed Alzahrani Mohammad Qamar Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management(IRC-HTCM) King Fahd University of Petroleum & Minerals(KFUPM) department of Materials Science and Engineering King Fahd University of Petroleum and Minerals Interdisciplinary Research Center for Sustainable Energy Systems(IRC-SES) King Fahd University of Petroleum and Minerals

Aqueous organic redox flow batteries(RFBs) exhibit favorable characteristics, such as tunability, multielectron transfer capability, and stability of the redox active molecules utilized as anolytes and catholytes, making them very viable contenders for large-scale grid storage applications. Considerable attention has been paid on the development of efficient redox-active molecules and their performance optimization through chemical substitutions at various places on the backbone as part of the pursuit for high-performance RFBs. Despite the fact that electrodes are vital to optimal performance, they have not garnered significant attention. Limited research has been conducted on the effects of electrode modifications to improve the performance of RFBs. The primary emphasis has been given on the impact of electrode engineering to augment the efficiency of aqueous organic RFBs. An overview of electron transfer at the electrode–electrolyte interface is provided. The implications of electrode modification on the performance of redox flow batteries, with a particular focus on the anodic and cathodic half-cells separately, are then discussed. In each section, significant discrepancies surrounding the effects of electrode engineering are thoroughly examined and discussed. Finally, we have presented a comprehensive assessment along with our perspectives on the future trajectory.

关键词： Electrode modification Organic redox molecules Outer sphere and inner sphere Redox flow batteries

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Partially-Observed Maximum Principle for Backward Stochastic Differential Delay Equations

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IEEE/CAA Journal of Automatica Sinica 2024年第6期11卷 1524-1526页

作者： Shuang Wu department of Applied Mathematics China University of PetroleumQingdao 266580China

Dear Editor,This letter investigates a partially-observed optimal control problem for backward stochastic differential delay equations(BSDDEs).By utilizing Girsanov’s theory and convex variational method,we obtain a maximum principle on the assumption that the state equation contains time delay and the control domain is convex.The adjoint processes can be represented as the solutions of certain time-advanced stochastic differential equations in finite-dimensional spaces.Linear backward stochastic differential equation(BSDE)was first introduced by Bismut in[1],while general BSDE was given by Pardoux and Peng[2].Since then,the theory of BSDEs developed rapidly.The corresponding optimal control problems,whose states are driven by BSDEs,have also been widely studied by some authors,see[3]-[5].

关键词： stochastic backward convex

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A multi-mechanism numerical simulation model for CO2-EOR and storage in fractured shale oil reservoirs

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petroleum Science 2024年第3期21卷 1814-1828页

作者： Yuan-Zheng Wang Ren-Yi Cao Zhi-Hao Jia Bin-Yu Wang Ming Ma Lin-Song Cheng College of petroleum Engineering China University of Petroleum (Beijing) John & Willie Leone department of Energy & Mineral Engineering The Pennsylvania State University

Under the policy background and advocacy of carbon capture, utilization, and storage（CCUS）, CO2-EOR has become a promising direction in the shale oil reservoir industry. The multi-scale pore structure distribution and fracture structure lead to complex multiphase flow, comprehensively considering multiple mechanisms is crucial for development and CO2storage in fractured shale reservoirs. In this paper, a multi-mechanism coupled model is developed by MATLAB. Compared to the traditional Eclipse300 and MATLAB Reservoir Simulation Toolbox（MRST）, this model considers the impact of pore structure on fluid phase behavior by the modified Peng—Robinson equation of state（PR-EOS）, and the effect simultaneously radiate to Maxwell—Stefan（M—S） diffusion, stress sensitivity, the nano-confinement（NC） effect. Moreover, a modified embedded discrete fracture model（EDFM） is used to model the complex fractures, which optimizes connection types and half-transmissibility calculation approaches between non-neighboring connections（NNCs）. The full implicit equation adopts the finite volume method（FVM）and Newton—Raphson iteration for discretization and solution. The model verification with the Eclipse300 and MRST is satisfactory. The results show that the interaction between the mechanisms significantly affects the production performance and storage characteristics. The effect of molecular diffusion may be overestimated in oil-dominated（liquid-dominated） shale reservoirs. The well spacing and injection gas rate are the most crucial factors affecting the production by sensitivity analysis. Moreover, the potential gas invasion risk is mentioned. This model provides a reliable theoretical basis for CO2-EOR and sequestration in shale oil reservoirs.

关键词： CO 2 -EOR CO 2 storage Shale oil reservoir Complex fracture model Multiple mechanisms

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