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Weakly Polarized Organic Cation-Modified Hydrated Vanadium Oxides for High-Energy Efficiency Aqueous Zinc-Ion Batteries

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Nano-Micro Letters 2024年第7期16卷 169-186页

作者： Xiaoxiao Jia Chaofeng Liu Zhi Wang Di Huang Guozhong Cao department of Materials science and engineering University of WashingtonSeattleWA 98195USA School of Materials science and engineering Tongji UniversityShanghai 201804People’s Republic of China

Vanadium oxides,par-ticularly hydrated forms like V_(2)O_(5)·nH_(2)O(VOH),stand out as promising cathode candidates for aqueous zinc ion batteries due to their adjustable layered structure,unique electronic characteristics,and high theoretical ***,challenges such as vanadium dissolution,sluggish Zn^(2+)diffusion kinetics,and low operating voltage still hinder their direct *** this study,we present a novel vanadium oxide([C_(6)H_(6)N(CH_(3))_(3)]_(1.08)V_(8)O_(20)·0.06H_(2)O,TMPA-VOH),developed by pre-inserting trimethylphenylammonium(TMPA+)cations into *** incorporation of weakly polarized organic cations capitalizes on both ionic pre-intercalation and molecular pre-intercalation effects,resulting in a phase and morphology transition,an expansion of the interlayer distance,extrusion of weakly bonded interlayer water,and a substantial increase in V^(4+)*** modifications synergistically reduce the electrostatic interactions between Zn^(2+)and the V-O lattice,enhancing structural stability and reaction kinetics during *** a result,TMPA-VOH achieves an elevated open circuit voltage and operation voltage,exhibits a large specific capacity(451 mAh g^(-1)at 0.1 A g^(-1))coupled with high energy efficiency(89%),the significantly-reduced battery polarization,and outstanding rate capability and cycling *** concept introduced in this study holds great promise for the development of high-performance oxide-based energy storage materials.

关键词： Zinc-ion battery Vanadium oxide V_(2)O_(5)·nH_(2)O Pre-intercalation Interlayer engineering

Photoswitchable Spiropyridine Enabled Photoactuation of Polymeric Hydrogels under Physiological pH Conditions

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Chinese Journal of Polymer science 2024年第10期42卷 1602-1609,I0015页

作者： Cong Liao Meng-Qi Du Chuang Li Key Laboratory of Precision and Intelligent Chemistry Department of Polymer Science and EngineeringUniversity of Science and Technology of ChinaAnhui230026China

The incorporation of molecular switches into polymer networks has been a powerful approach for the development of functional polymer materials that display macroscopic actuation and function enabled directly by molecular ***,such materials sometimes require harsh conditions to perform their functions,and the design of new molecular photoswitches that can function under physiological conditions is highly ***,we report the design and synthesis of a spiropyridine-based photoswitchable hydrogel that exhibits light-driven actuation at physiological *** to its high p Ka,spiropyridine maintains its ring-open protonated form at neutral pH,and the resulting hydrogel remains in a swollen *** irradiation with visible light,the ring closure of spiropyridine leads to a decrease in the charge and a reduction in the volume of the *** contracted gel could spontaneously recover to its expanding state in the dark,and this process is highly dynamic and reversible when the light is switched on and ***,the hydrogel shows switchable fluorescence in response to visible *** deformation is observed in the hydrogel thin films upon irradiation from one ***,the independence of this spiropyridine hydrogel from the acidic environment makes it biotolerant and shows excellent *** biocompatible spiropyridine hydrogel might have important biorelated applications in the future.

关键词： Spiropyridine photowitch Polymer hydrogel Photoactuation Physiological pH Biocompatibility

Comparison between seismic analysis of twisting and regular 52-story towers considering soil-structure interaction

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Earthquake engineering and engineering Vibration 2024年第3期23卷 663-675页

作者： Mohamed Naguib Abouelsaad Mohammed Shaaban Salah El Bagalaty Mohamed E.El Madawy Structural engineering department Faculty of EngineeringMansura UniversityMansoura 35511Egypt Faculty of engineering Delta University for Science and TechnologyGamasa 35712Egypt

A dynamic analysis of both twisting and regular towers is carried out to determine the results of considering soil-structure interaction(SSI)on high-rise *** addition,the difference between the seismic performance of using twisting towers over regular ones is *** twisting tower is a simulation of the Evolution Tower(Moscow).The towers’skeletons consist of RC elements and rest on a reinforced concrete piled-raft *** soil model is considered as multi-layered with the same soil properties as the zone chosen for the analysis(New Mansoura City,Egypt).The only difference between both towers is their shape in *** whole system is modelled and analyzed in a single step as one full 3D model,which is known as the direct approach in *** analyses are carried out using finite-element software(Midas GTS NX).Dynamic output responses due to three records of seismic loads are proposed and presented in some *** on the results,it is concluded that SSI has a considerable effect on the dynamic response of tall buildings mainly because of the foundation flexibility,as it leads to lengthening the vibration period,increasing the story drift and the base shear for both cases.

关键词： soil-structure interaction seismic analysis twisting towers base shear story drift finite element method Midas GTS NX

Oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)particles in the air:Nonisothermal kinetic and reaction mechanism

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International Journal of Minerals,Metallurgy and Materials 2024年第8期31卷 1839-1848页

作者： Junyi Xiang Xi Lu Luwei Bai Hongru Rao Sheng Liu Qingyun Huang Shengqin Zhang Guishang Pei Xuewei Lü School of Metallurgy and Materials engineering Chongqing University of Science and TechnologyChongqing 401331China department of Materials science and engineering Seoul National UniversitySeoul 08826Rep.of Korea College of Materials science and engineering Chongqing UniversityChongqing 400044China

High-temperature oxidation behavior of ferrovanadium(FeV_(2)O_(4))and ferrochrome(FeCr_(2)O_(4))spinels is crucial for the application of spinel as an energy material,as well as for the clean usage of high-chromium vanadium ***,the nonisothermal oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)prepared by high-temperature solid-state reaction was examined by thermogravimetry and X-ray diffraction(XRD)at heating rates of 5,10,and 15 K/*** apparent activation energy was determined by the Kissinger-Akahira-Sunose(KAS)method,whereas the mechanism function was elucidated by the Malek ***,in-situ XRD was conducted to deduce the phase transformation of the oxidation mechanism for FeV_(2)O_(4)and FeCr_(2)O_(4).The results reveal a gradual increase in the overall apparent activation energies for FeV_(2)O_(4)and FeCr_(2)O_(4)during *** stages of the oxidation process are observed based on the oxidation conversion rate of each *** oxidation mechanisms of FeV_(2)O_(4)and FeCr_(2)O_(4)are complex and have distinct *** particular,the chemical reaction controls the entire oxidation process for FeV_(2)O_(4),whereas that for FeCr_(2)O_(4)transitions from a three-dimensional diffusion model to a chemical reaction *** to the in-situ XRD results,numerous intermediate products are observed during the oxidation process of both compounds,eventually resulting in the final products FeVO_(4)and V2O_(5)for FeV_(2)O_(4)and Fe_(2)O_(3)and Cr_(2)O_(3)for FeCr_(2)O_(4),respectively.

关键词： FeV_(2)O_(4) FeCr_(2)O_(4) oxidation nonisothermal kinetics mechanism

WebFLex:A Framework for Web Browsers-Based Peer-to-Peer Federated Learning Systems Using WebRTC

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Computers, Materials & Continua 2024年第3期78卷 4177-4204页

作者： Mai Alzamel Hamza Ali Rizvi Najwa Altwaijry Isra Al-Turaiki department of Computer science College of Computer and Information SciencesKing Saud UniversityRiyadhKingdom of Saudi Arabia department of Computer science and engineering Punjab Engineering CollegeChandigarhIndia

Scalability and information personal privacy are vital for training and deploying large-scale deep learning *** learning trains models on exclusive information by aggregating weights from various devices and taking advantage of the device-agnostic environment of web ***,relying on a main central server for internet browser-based federated systems can prohibit scalability and interfere with the training process as a result of growing client ***,information relating to the training dataset can possibly be extracted from the distributed weights,potentially reducing the privacy of the local data used for *** this research paper,we aim to investigate the challenges of scalability and data privacy to increase the efficiency of distributed training *** a result,we propose a web-federated learning exchange(WebFLex)framework,which intends to improve the decentralization of the federated learning *** is additionally developed to secure distributed and scalable federated learning systems that operate in web browsers across heterogeneous ***,WebFLex utilizes peer-to-peer interactions and secure weight exchanges utilizing browser-to-browser web real-time communication(WebRTC),efficiently preventing the need for a main central *** has actually been measured in various setups using the MNIST *** results show WebFLex’s ability to improve the scalability of federated learning systems,allowing a smooth increase in the number of participating devices without central data *** addition,WebFLex can maintain a durable federated learning procedure even when faced with device disconnections and network ***,it improves data privacy by utilizing artificial noise,which accomplishes an appropriate balance between accuracy and privacy preservation.

关键词： Federated learning web browser privacy deep learning

Watt-level acousto-optically Q-switched Pr:YLF laser at 639 nm

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Chinese Optics Letters 2024年第1期22卷 76-83页

作者：薛喻宸张瑞松戴征东王中玉许惠英蔡志平 department of Electronic engineering School of Electronic Science and Engineering(National Model Microelectronics College)Xiamen UniversityXiamen 361005China

We present a study on a watt-level acousto-optically Q-switched Pr:YLF laser at three different repetition rates(10 kHz,20 kHz,and 50 kHz)for the first time,to the best of our *** corresponding average output powers and pulse widths were measured to be 1.14 W,1.2 W,and 1.32 W,and 40 ns,52 ns,and 80 ns,respectively.A maximum pulse energy of0.11 mJ was obtained,corresponding to a peak power of up to 2.8 kW at a repetition rate of 10 *** simulated dynamics of a fast Q-switched Pr:YLF laser is in agreement with the *** laser's ability to generate stable pulses with high peak power and short pulse width makes it highly desirable for various practical applications,such as laser machining and material processing.

关键词： red pulsed laser Pr:YLF diode pump acousto-optical Q switching

Surface reconstruction of heterostructures in alkaline medium towards enhanced electrocatalytic hydrogen evolution

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Rare Metals 2024年第6期43卷 2636-2647页

作者： Ming-Yang Yang Ji Yuan Xue-Lian Fu Jing-Jing Chen Jing Hu Zhou-Guang Lu Chen Liu Guangdong Research Center for Interfacial engineering of Functional Materials Shenzhen Key Laboratory of Polymer Science and TechnologyShenzhen Key Laboratory of Energy Electrocatalytic MaterialsCollege of Materials Science and EngineeringShenzhen UniversityShenzhen 518060China Shenzhen Key Laboratory of Interfacial science and engineering of Materials Department of Materials Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China

Constructing heterostructures has proved to be a successful strategy to fabricate electrocatalysts with high efficiency for water ***,the structure evolution in alkaline hydrogen evolution reaction lacks investigation and the specific active center remains ***,we take the well-designed Ni_(3)S_(2)@VO_(2) heterostructures as a model to investigate the electrocatalytic activity and the surface reconstruction process of heterostructure catalysts in alkaline *** Ni_(3)S_(2)@VO_(2) heterostructures,with Ni_(3)S_(2) nanorods as the core and VO_(2) nanoflakes as the shell,coupled with the high conductive Ni_(3)S_(2),the hydrophilic VO_(2) and modulated electronic structures at the interfaces,exhibited prominent activity and superior stability at various current ***,the ex-situ characterizations confirmed that the surface reconstruction from Ni_(3)S_(2)@VO_(2) into Ni_(3)S_(2)@amorphous-Ni(OH)_(2) in alkaline media could optimize the water dissociation barrier and exposed large active area,thereby contributing to improved electrocatalytic *** study not only introduces novel high-performance electrocatalysts for hydrogen evolution reaction(HER),but also provides a new avenue for re-examining hetero-structural catalysts in alkaline solutions.

关键词： Heterostructures Ni_(3)S_(2)@VO_(2) Surface reconstruction Water dissociation Alkaline hydrogen evolution

What can we learn from quality assurance badges in open-source software?

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science China(Information sciences) 2024年第4期67卷 146-163页

作者： Feng LI Yiling LOU Xin TAN Zhenpeng CHEN Jinhao DONG Yang LI Xuanzhi WANG Dan HAO Lu ZHANG MoE Key Lab of HCST School of Computer SciencePeking University department of Computer science Purdue University School of Computer science & engineering Beihang University(BUAA) department of Computer science University College London(UCL)

In the development of open-source software(OSS), many developers use badges to give an overview of the software and share some key features/metrics conveniently. Among various badges, quality assurance(QA) badges make up a large proportion and are the most prevalent because QA is of vital importance in software development, and ineffective QA may lead to anomalies or defects. In this paper, we focus on QA badges in open-source projects, which present quality assurance information directly and instantly,and aim to produce some interesting findings and provide practical implications. We collect and analyze 100000 projects written in popular programming languages from GitHub and conduct a comprehensive empirical study both inside and outside QA badges. Inside QA badges, we build a category classification for all QA badges based on the properties they focus on, which shows the types of QA badges developers use. Then,we analyze the frequency of the properties that QA badges focus on, and property combinations, too, which present their use status. We find that QA badges focus on various properties while developers give different preferences to different properties. The use status also differs between different programming languages. For example, projects written in C focus on Security to a great extent. Our findings also provide implications for developers and badge providers. Outside QA badges, we conduct a correlation analysis between QA badges and some software metrics that have potential relationships with code quality, contribution quality, and popularity. We find that QA badges have statistically significant correlations with various software metrics.

关键词： quality assurance badge open-source software code quality empirical study

Plasmonic quantum dots modulated nano-mineral toward photothermal reduction of CO_(2)coupled with biomass conversion

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Nano Research 2024年第6期17卷 5061-5072页

作者： Guangbiao Cao Haoran Xing Haoguan Gui Chao Yao Yinjuan Chen Yongsheng Chen Xiazhang Li National-local Joint engineering Research Center of biomass Refining and High-quality Utilization Changzhou UniversityChangzhou 213164China School of Civil and Environmental engineering Georgia Institute of TechnologyAtlantaGA 30332-0373USA

Simultaneous conversion of CO_(2)and biomass into value-added chemicals through solar-driven catalysis holds tremendous importance for fostering a sustainable circular ***,plasmonic Bi quantum dots were immobilized on phosphoric acid modified attapulgite(P-ATP)nanorod using an in-situ reduction-deposition method,and were employed for photocatalytic reduction of CO_(2)coupled with oxidation of biomass-derived benzyl *** revealed that Bi atoms successfully integrated into the basal structure of P-ATP,forming chemically coordinated Bi-O-Si bonds that served as efficient transportation channels for *** incorporation of high-density monodispersed Bi quantum dots induced a surface plasmon resonance(SPR)effect,expanding the light absorption range into the near-infrared *** a consequence,the photo-thermal transformation was significantly accelerated,leading to enhanced reaction ***,50%Bi/P-ATP nanocomposite exhibited the highest plasmon-mediated photocatalytic CH4 generation(115.7μmol·g^(−1)·h^(−1))and CO generation(44.9μmol·g^(−1)·h^(−1)),along with remarkable benzaldehyde generation rate of 79.5μmol·g^(−1)·h^(−1)in the photo-redox coupling system under solar light *** hydrogen protons released from the oxidation of benzyl alcohol facilitated the incorporation of more hydrogen protons into CO_(2)to form key CH_(3)O−*** work demonstrates the synergistic solar-driven valorization of CO_(2)and biomass using natural mineral based catalyst.

关键词： photothermal catalysis clay mineral plasmon CO_(2)reduction biomass conversion