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Tuning the interfacial reaction environment via pH-dependent and induced ions to understand C–N bonds coupling performance in NO3- integrated CO2 reduction to carbon and nitrogen compounds over dual Cu-based N-doped carbon catalyst

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Journal of Energy Chemistry 2025年第1期100卷 273-285页

作者： Tianhang Zhou Chen Shen Zhenghao Wu Xingying Lan Yi Xiao College of Carbon Neutrality Future Technology State Key Laboratory of Heavy Oil Processing China University of Petroleum (Beijing) Institute of Materials Science TU Darmstadt department of Chemistry Xi'an Jiaotong-Liverpool University department of Mechanical and mechatronics engineering and Waterloo Institute of Nanotechnology University of Waterloo Waterloo

Dual atomic catalysts （DAC）,particularly copper （Cu2）-based nitrogen （N） doped graphene,show great potential to effectively convert CO2and nitrate （NO3-） into important industrial chemicals such as ethylene,glycol,acetamide,and urea through an efficient catalytical process that involves C–C and C–N ***,the origin of the coupling activity remained unclear,which substantially hinders the rational design of Cu-based catalysts for the N-integrated CO2reduction reaction （CO2RR）.To address this challenge,this work performed advanced density functional theory calculations incorporating explicit solvation based on a Cu2-based N-doped carbon (Cu2N6C10) catalyst for *** calculations are aimed to gain insight into the reaction mechanisms for the synthesis of ethylene,acetamide,and urea via coupling in the interfacial reaction *** to the sluggishness of CO2,the formation of a solvation electric layer by anions （F-,Cl-,Br-,and I-） and cations (Na+,Mg2+,K+,and Ca2+) leads to electron transfer towards the Cu *** process significantly accelerates the reduction of *** results reveal that*CO intermediates play a pivotal role in N-integrated ***,the Cu2-based N-doped carbon catalyst examined in this study has demonstrated the most potential for C–N coupling to *** findings reveal that through the process of a condensation reaction between*CO and NH2OH for urea synthesis,*NO3-is reduced to*NH3,and*CO2to*CCO at dual Cu atom *** dual-site reduction facilitates the synthesis of acetamide through a nucleophilic reaction between NH3and the ketene ***,we found that the I-and Mg2+ions,influenced by pH,were highly effective for acetamide and ammonia synthesis,except when F-and Ca2+were ***,the mechanisms of C–N bond formation were investigated via ab-initio molecular dynamics simulations,and we found that adjusting the micro-environment can change the dominant side reaction,shift

关键词： pH-dependent micro-environments C–N coupling Dual Cu-based nitrogen carbon catalysts Explicit solvation model Ion stabilizer AIMD

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Easy calibration method of vision system for in-situ measurement of strain of thin films

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中国有色金属学会会刊：英文版 2009年第B09期19卷 243-249页

作者： Jun-Hyub PARK Dong-Joong KANG Myung-Soo SHIN Sung-Jo LIM Son-Cheol YU Kwang-Soo LEE Jong-Eun HA Sung-Hoon CHOA department of mechatronics engineering Tongmyong University School of Mechanical engineering Pusan National University department of automotive engineering Hoseo University department of automotive engineering Seoul National University of Technology department of Nano/IT engineering Seoul N ational University of Technology

An easy calibration method was presented for in-situ measurement of displacement in the order of nanometer during micro-tensile test for thin films by using CCD camera as a sensing device. The calibration of the sensing camera in the system is a central element part to measure displacement in the order of nanometer using images taken with the camera. This was accomplished by modeling the optical projection through the camera lens and relative locations between the object and camera in 3D space. A set of known 3D points on a plane where the film is located on is projected to an image plane as input data. These points, known as a calibration points, are then used to estimate the projection parameters of the camera. In the measurement system of the micro-scale by CCD camera, the calibration data acquisition and one-to-one matching steps between the image and 3D planes need precise data extraction procedures and repetitive user's operation to calibrate the measuring devices. The lack of the robust image feature extraction and easy matching prevent the practical use of these methods. A data selection method was proposed to overcome these limitations and offer an easy and convenient calibration of a vision system that has the CCD camera and the 3D reference plane with calibration marks of circular type on the surface of the plane. The method minimizes the user's intervention such as the fine tuning of illumination system and provides an efficient calibration method of the vision system for in-situ axial displacement measurement of the micro-tensile materials.

关键词：标定方法视觉系统原位测试应变薄膜松

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Web Tension Regulation of Multispan Roll-to-Roll System using Integrated Active Dancer and Load Cells for Printed Electronics Applications

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Chinese Journal of Mechanical engineering 2014年第2期27卷 229-239页

作者： ZUBAIR Muhammad PONNIAH Ganeshthangaraj YANG Young Jin CHOI Kyung Hyun department of mechatronics engineering Jeju National University

The mass production of primed electronics can be achieved by roll-to-roll（R2R） printing system, so highly accurate web tension is required that can minimize the register error and keep the thickness and roughness of printed devices in limits. The web tension of a R2R system is regulated by the use of integrated load cells and active dancer system for printed electronics applications using decentralized multi-input-single-output（MISO） regularized variable learning rate backpropagation artificial neural networks. The active dancer system is used before printing system to reduce disturbances in the web tension of process span. The classical PID control result in tension spikes with the change in roll diameter of winder and unwinder rolls. The presence of dancer in R2R system shows that improved web tension control in printing span and the web tension can be enhanced from 3.75 N to 4.75 N. The overshoot of system is less than ±2.5 N and steady state error is within ± 1 N where load cells have a signal noise of ±0.7 N. The integration of load cells and active dancer with self-adapting neural network control provide a solution to the web tension control of multispan roll-to-roll system.

关键词： roll-to-roll(R2R)system multispan printed electronics active dancer load cell artificial neural networks tension control,multi-input-single-output(MISO )

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Personalization for Massive Product Innovation Using Open Architecture

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Chinese Journal of Mechanical engineering 2018年第2期31卷 12-24页

作者： Qing-Jin Peng Yun-Hui Liu Jian Zhang Pei-Hua Gu department of Mechanical engineering University of Manitoba department of mechatronics engineering Shantou University

Product innovation is creation of new concepts to plan and realize technological and functional details in the product to satisfy market and customer needs. One of the key drivers to product innovation is reactions of the product to users’ needs. Product innovation needs a cognitive design method based on needs of variant users for the product personalization. In this paper, an open concept is introduced to provide ways to meet user’s individual need in product lifespan. It is for industries to propose product concepts based on open sources, develop and support the product on the public capability. Using the open concept in the product architecture, called open?architecture product(OAP), can improve the product personalization leading to massive product innovation. To promote this promise of the OAP, effective methods are discussed for the OAP development. This paper introduces research on OAPs using adaptable design methods to meet product personalization. Adaptable design is based on the modular structure for product adaptability using function modules and adaptable interfaces. The proposed method provides solutions for planning modules and implementation of OAPs. Methods of OAP module planning, detail and interface design are described for transformation of product concepts into physical structures. A multiple?purpose electrical car is developed in a case study to show effectiveness of the proposed method.

关键词： Product design Personalization Massive innovation Open architecture Adaptable design

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Numerical simulation of transport phenomena during strip casting with EMBr in a single belt caster

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Journal of Central South University 2014年第6期21卷 2150-2159页

作者：龚海军李新中徐达鸣郭景杰 School of Materials Science and engineering Harbin Institute of Technology College of mechatronics and automotive engineering Chongqing Jiaotong University

A theoretical investigation of fluid flow,heat transfer and solidification(solidification transfer phenomena,STP)was presented which coupled with direct-current(DC)magnetic fields in a high-speed strip-casting metal delivery *** bidirectional interaction between the STP and DC magnetic fields was simplified as a unilateral one,and the fully coupled solidification transport equations were numerically solved by the finite volume method(FVM).While the magnetic field contours for a localized DC magnetic field were calculated by software ANSYS and then incorporated into a three-dimensional(3-D)steady model of the liquid cavity in the mold by means of indirect coupling.A new FVM-based direct-SIMPLE algorithm was adopted to solve the iterations of pressure-velocity(P-V).The braking effects of DC magnetic fields with various configurations were evaluated and compared with those without static magnetic field(SMF).The results show that 0.6 T magnetic field with combination configuration contributes to forming an isokinetic feeding of melt,the re-circulation zone is shifted towards the back wall of reservoir,and the velocity difference on the direction of height decreases from 0.1 m/s to ***,the thickness of solidified skull increases uniformly from 0.45 mm to 1.36 mm on the chilled substrate(belt)near the exit.

关键词： single belt casting electromagnetic brake (EMBr) flow field direct-SIMPLE algorithm

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A genetic algorithm based lookup table approach for optimal stepping sequence of open-loop stepper motor systems

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控制理论与应用（英文版） 2013年第1期11卷 35-41页

作者： Suleiman BANIHANI Khalid AL-WIDYAN Ahmad AL-JARRAH Mohammad ABABNEH mechatronics engineering department The Hashemite University

Stepper motor driven systems are widely used in industrial applications. They are mainly used for their low cost open-loop high performance. However, as dynamic systems need to be increasingly faster and their motion more precise, it is important to have an open-loop system which is accurate and reliable. In this paper, we present a novel technique in which a genetic algorithm （GA） based lookup table approach is used to find the optimal stepping sequence of an open-loop stepper motor system. The optimal sequence objective is to minimize residual vibration and to accurately follow trajectory. A genetic algorithm is used to find the best stepping sequence which minimizes the error and improves the system performance. Numerical simulation has showed the effectiveness of our approach to improve the system performance for both position and velocity. The optimized system reduced the residual vibration and was able to follow the trajectory with minimal error.

关键词： Stepper motor Open-loop Genetic algorithm Optimal Stepping sequence Control

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Experimental Investigation on Cooling/Heating Characteristics of Ultra-Thin Micro Heat Pipe for Electric Vehicle Battery Thermal Management

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Chinese Journal of Mechanical engineering 2018年第3期31卷 179-188页

作者： Fei-Fei Liu Feng-Chong Lan Ji-Qing Chen Yi-Gang Li School of Mechanical&automotive engineering Guangdong Key Laboratory of Automotive EngineeringSouth China University of Technology School of mechatronics&Vehicle engineering East China Jiaotong UniversityNanchang 330013China

Due to the heat pipes’ transient conduction,phase change and fluid dynamics during cooling/heating with high frequency charging/discharging of batteries,it is crucial to investigate in depth the experimental dynamic thermal characteristics in such complex heat transfer processes for more accurate thermal analysis and design of a BTMS. In this paper,the use of ultra?thin micro heat pipe(UMHP) for thermal management of a lithium?ion battery pack in EVs is explored by experiments to reveal the cooling/heating characteristics of the UMHP pack. The cooling performance is evaluated under di erent constant discharging and transient heat inputs conditions. And the heating e ciency is assessed under several sub?zero temperatures through heating films with/without UMHPs. Results show that the pro?posed UMHP BTMS with forced convection can keep the maximum temperature of the pack below 40 °C under 1 ~ 3 C discharging,and e ectively reduced the instant temperature increases and minimize the temperature fluctuation of the pack during transient federal urban driving schedule(FUDS) road conditions. Experimental data also indicate that heating films stuck on the fins of UMHPs brought about adequate high heating e ciency comparing with that stuck on the surface of cells under the same heating power,but has more convenient maintenance and less cost for the BTMS. The experimental dynamic temperature characteristics of UMHP which is found to be a high?e cient and low?energy consumption cooling/heating method for BTMSs,can be performed to guide thermal analysis and optimiza?tion of heat pipe BTMSs.

关键词： Electric vehicle Lithium?ion battery Thermal management Ultra?thin micro heat pipe

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Role of heat balance on the microstructure evolution of cold spray coated AZ31B with AA7075

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Journal of Magnesium and Alloys 2021年第4期9卷 1467-1478页

作者： Bahareh Marzbanrad Mohammad Hadi Razmpoosh Ehsan Toyserkani Hamid Jahed Mechanical and mechatronics engineering department University of WaterlooCanada

A promising solid-state coating mechanism based on the cold spray technique provides highly advantageous conditions on thermal-sensitive magnesium *** study the effect of heat balance in cold spray coating on microstructure,experiments were designed to successfully coat AA7075 on AZ31B with two different heat balance conditions to yield a coated sample with tensile residual stress and a sample with compressive residual stress in both coating and *** effects of coating temperature on the microstructure of magnesium alloy and the interfaces of coated samples were then analyzed by SEM,EBSD,TEM in high-and low-heat input coating *** interface of the AA7075 coating and magnesium alloy substrate under both conditions consists of a narrow-band layer with very fine grains,followed by columnar grains of magnesium that have grown perpendicular to the *** higher temperatures,this layer became *** intermetallic phase was detected at the interface under either *** is shown that the microstructure of the substrate was affected by coating temperature,leading to stress relief,dynamic recrystallization and even dynamic grain growth of magnesium under high *** the heat input and increasing the heat transfer decreased microstructural changes in the substrate.

关键词： Cold spraying Heat balance Microstructural analysis Coating interface Magnesium Alloy AZ31B Residual Stress

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An Intelligent Harmonic Synthesis Technique for Air-Gap Eccentricity Fault Diagnosis in Induction Motors

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Chinese Journal of Mechanical engineering 2017年第6期30卷 1296-1304页

作者： De Z.Li Wilson Wang Fathy Ismail department of Mechanical engineering Lakehead University department of Mechanical & mechatronics engineering University of Waterloo

Induction motors （IMs） are commonly used in various industrial applications. To improve energy con- sumption efficiency, a reliable IM health condition moni- toring system is very useful to detect IM fault at its earliest stage to prevent operation degradation, and malfunction of IMs. An intelligent harmonic synthesis technique is pro- posed in this work to conduct incipient air-gap eccentricity fault detection in IMs. The fault harmonic series are syn- thesized to enhance fault features. Fault related local spectra are processed to derive fault indicators for IM air- gap eccentricity diagnosis. The effectiveness of the pro- posed harmonic synthesis technique is examined experi- mentally by IMs with static air-gap eccentricity and dynamic air-gap eccentricity states under different load conditions. Test results show that the developed harmonic synthesis technique can extract fault features effectively for initial IM air-gap eccentricity fault detection.

关键词： Air-gap eccentricity Current signal Faultdetection Induction motor

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Alternative Strategy for Development of Dielectric Calcium Copper Titanate‑Based Electrolytes for Low‑Temperature Solid Oxide Fuel Cells

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Nano-Micro Letters 2025年第1期17卷 310-332页

作者： Sajid Rauf Muhammad Bilal Hanif Zuhra Tayyab Matej Veis MAKYousaf Shah Naveed Mushtaq Dmitry Medvedev Yibin Tian Chen Xia Martin Motola Bin Zhu College of mechatronics and Control engineering Shenzhen UniversityShenzhen 518060People’s Republic of China department of Inorganic Chemistry Faculty of Natural SciencesComenius University BratislavaIlkovicova684215 BratislavaSlovakia Energy Storage Joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing 210096People’s Republic of China Hydrogen Energy Laboratory Ural Federal University620002 EkaterinburgRussia Laboratory of Electrochemical Devices Based on Solid Oxide Proton Electrolytes Institute of High Temperature Electrochemistry620066 EkaterinburgRussia School of Microelectronics Hubei UniversityWuhan 430062People’s Republic of China

The development of low-temperature solid oxide fuel cells(LT-SOFCs)is of significant importance for realizing the widespread application of *** has stimulated a substantial materials research effort in developing high oxide-ion conductivity in the electrolyte layer of *** this context,for the first time,a dielectric material,CaCu_(3)Ti_(4)O_(12)(CCTO)is designed for LT-SOFCs electrolyte application in this *** individual CCTO and its heterostructure materials with a p-type Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ)(NCAL)semiconductor are evaluated as alternative electrolytes in LT-SOFC at 450–550℃.The single cell with the individual CCTO electrolyte exhibits a power output of approximately 263 mW cm^(-2) and an open-circuit voltage(OCV)of 0.95 V at 550℃,while the cell with the CCTO–NCAL heterostructure electrolyte capably delivers an improved power output of approximately 605 mW cm^(-2) along with a higher OCV over 1.0 V,which indicates the introduction of high hole-conducting NCAL into the CCTO could enhance the cell performance rather than inducing any potential short-circuiting *** is found that these promising outcomes are due to the interplay of the dielectric material,its structure,and overall properties that led to improve electrochemical mechanism in CCTO–***,density functional theory calculations provide the detailed information about the electronic and structural properties of the CCTO and NCAL and their heterostructure CCTO–*** study thus provides a new approach for developing new advanced electrolytes for LT-SOFCs.

关键词： LT-SOFCs Dielectric CaCu_(3)Ti_(4)O_(12) Semiconductor Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ) Ionic conductivity Heterostructure electrolyte

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