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Journal of Energy Chemistry 2025年第2期101卷 345-384页

作者： Rasoul Salami Yimin Zeng Xue Han Sohrab Rohani Ying Zheng department of Chemical and biochemical engineering Western University Canmet MATERIALS Natural Resources Canada

The pursuit of alternative fuel generation technologies has gained momentum due to the diminishing reserves of fossil fuels and global warming from increased *** the proposed methods,the hydrogenation of CO2to produce marketable carbon-based products like methanol and ethanol is a practical approach that offers great potential to reduce *** significant volumes of methanol are currently produced from CO2,developing highly efficient and stable catalysts is crucial for further enhancing conversion and selectivity,thereby reducing process *** in-depth examination of the differences and similarities in the reaction pathways for methanol and ethanol production highlights the key factors that drive C-C *** these factors guides us toward developing more effective catalysts for ethanol *** this paper,we explore how different catalysts,through the production of various intermediates,can initiate the synthesis of methanol or *** catalytic mechanisms proposed by spectroscopic techniques and theoretical calculations,including operando X-ray methods,FTIR analysis,and DFT calculations,are summarized and *** following discussion explores the structural properties and composition of catalysts that influence C-C coupling and optimize the conversion rate of CO2into ***,the review examines recent catalysts employed for selective methanol and ethanol production,focusing on single-atom catalysts.

关键词： CO 2 hydrogenation Methanol Ethanol Catalytic mechanism Operando techniques Single atom catalyst Tandem catalyst

Numerical Study of Cavitating Flows around a Hydrofoil with Deep Analysis of Vorticity Effects

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Fluid Dynamics & Materials Processing 2025年第1期21卷 179-204页

作者： Shande Li Wen’an Zhong Shaoxing Yu Hao Wang Xichang Satellite Launch Center Wenchang571300China College of Water resources and Civil engineering China Agricultural UniversityBeijing100083China

This paper aims to numerically explore the characteristics of unsteady cavitating flow around a NACA0015 hydrofoil,with a focus on vorticity *** simulation utilizes a homogeneous mixture model coupled with a filter-based density correction turbulence model and a modified Zwart cavitation *** study investigates the dynamic cavitation features of the thermal fluid around the hydrofoil at various incoming flow *** systematically elucidates the evolution of cavitation and vortex dynamics corresponding to each velocity *** results indicate that with increasing incoming flow velocity,distinct cavitation processes take place in the flow field.

关键词： Cavitating flow hydrofoil flow velocity vorticity Computational Fluid Dynamics(CFD)

Efficient magnetic capture of PE microplastic from water by PEG modified Fe_(3)O_(4)nanoparticles:Performance,kinetics,isotherms and influence factors

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Journal of Environmental Sciences 2025年第1期147卷 677-687页

作者： Yifan Zhang Jingjing Duan Ruiqian Liu Evangelos Petropoulos Yanfang Feng Lihong Xue Linzhang Yang Shiying He College of resources and Environmental Sciences Nanjing Agricultural UniversityNanjing 210095China Key Laboratory of Agro-Environment in Downstream of Yangze Plain Ministry of Agriculture and Rural AffairsInstitute of Agricultural Resources and EnvironmentJiangsu Academy of Agricultural SciencesNanjing 210014China School of engineering Newcastle UniversityNewcastle upon Tyne NE17RUUK Stantec UK Newcastle upon Tyne NE13DYUK

Due to their resistance to degradation,wide distribution,easy diffusion and potential uptake by organisms,microplastics(MPs)pollution has become a major environmental *** this study,PEG-modified Fe_(3)O_(4)magnetic nanoparticles demonstrated superior adsorption efficiency against polyethylene(PE)microspheres compared to other adsorbents(bare Fe_(3)O_(4),PEI/Fe_(3)O_(4)and CA/Fe_(3)O_(4)).Themaximumadsorption capacity of PEwas found to be 2203 mg/g by adsorption isotherm ***/Fe_(3)O_(4)maintained a high adsorption capacity even at low temperature(5℃,2163 mg/g),while neutral pH was favorable for MP *** presence of anions(Cl^(-),SO_(4)^(2-),HCO_(3)^(-),NO_(3)^(-))and of humic acids inhibited the adsorption of *** is proposed that the adsorption process was mainly driven by intermolecular hydrogen ***,the study demonstrated that PEG/Fe_(3)O_(4)can potentially be used as an efficient control against MPs,thus improving the quality of the aquatic environment and of our water resources.

关键词： Microplastic removal Adsorption Magnetic nanoparticles Wastewater Surface modification

Disordered hyperuniformity and thermal transport in monolayer amorphous carbon

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Science China(Physics,Mechanics & Astronomy) 2025年第2期68卷 145-152页

作者： Nianjie Liang Yuxi Wang Bai Song department of Energy and resources engineering Peking UniversityBeijing 100871China department of Advanced Manufacturing and Robotics Peking UniversityBeijing 100871China

Disordered hyperuniformity(DHU)is a recently discovered novel state of amorphous systems characterized by strongly suppressed density fluctuations at large length scales as in crystalline materials,which offers great potential for achieving unusual mechanical,electronic,and photonic ***,despite the fundamental and technological importance of thermal transport in amorphous solids,the effect of DHU remains largely ***,we theoretically study thermal transport in a class of two-dimensional DHU materials—monolayer amorphous carbon(MAC).Beginning with a perfect graphene lattice,we continuously apply Stone-Wales transformations to generate a series of MAC models with varied degrees of disorder and defects,which are quantified through comprehensive structural analysis including the so-called hyperuniformity index(H),where a smaller H indicates a higher degree of ***,we conduct molecular dynamics simulations to obtain the thermal conductivity(κ).A significant correlation between the thermal transport behavior and degree of hyperuniformity is observed,with the room-temperatureκdecreasing from 26.3 to 5.3 W m^(-1)K^(-1)while H is tuned from 0.0004 to ***,two distinct transport regimes are identified,including a nearly-DHU regime at small H(<0.005)whereκdrops sharply and a non-DHU region at larger H whereκbecomes relatively ***-resolved analysis reveals longer lifetime and higher participation ratio for the heat carriers in nearly-DHU MAC,implying that the hidden long-range correlations could support extended modes that enhance *** work highlights the impact of DHU on the thermal properties of amorphous materials and represents a conceptual advancement that is worthy of future exploration.

关键词： disordered hyperuniformity thermal transport amorphous material two-dimensional monolayer amorphous carbon

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Quantifying and Mapping the Effects of Ecosystem Services on agricultural Competitiveness:A Case Study in Shandong Province, China

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Chinese Geographical Science 2025年第2期 326-342页

作者： ZHONG Jiali SUN Qian QI Wei YU Xinyang College of resources and Environment Shandong Agricultural University School of Information Science and engineering Shandong Agricultural University Institute of Geographic Sciences and Natural resources Research Chinese Academy of Sciences

Quantifying and mapping how ecosystem services impact agricultural competitiveness is crucial for attaining the Sustainable Development Goals of United Nations. However, few study quantified agricultural competitiveness and mapped the effects of ecosystem services on agricultural competitiveness using multiple models. In this study, multi-source data from 2000 to 2020 were utilized to establish the indicator system of agricultural competitiveness; five ecosystem services were quantified using computation models; Geographic Information System(GIS) spatial analysis was used to explore the spatial patterns of agricultural competitiveness and ecosystem services; geographic detector models were applied to investigate the effects and driving mechanisms of ecosystem services on agricultural competitiveness. Shandong Province of China was selected as the case study area. The results demonstrated that: 1) there was a significant increase in agricultural competitiveness during the study period, with high levels observed mainly in the east region of the study area. 2) The spatial distribution patterns of ecosystem services and agricultural competitiveness primarily exhibited High-High and Low-Low Cluster types. 3) Habitat quality emerged as the main driving factor of agricultural competitiveness in 2000 and 2020, while water yield played a substantial role in 2010.4) The coupling of two ecosystem services exerted a greater effect on agricultural competitiveness compared to individual ecosystem service. The innovations of this study are constructing an indicator system to quantify agricultural competitiveness, and exploring the effects of ecosystem services on agricultural competitiveness. This study proposed an indicator system to quantify agricultural competitiveness, which can be applied in other regions, and explored the effects of ecosystem services on agricultural competitiveness. The findings of this study can serve as valuable insights for policymakers to formulate tail

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Civil aviation emissions in China in 2019:Characteristics and abatement potential

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Journal of Environmental Sciences 2025年第5期151卷 225-237页

作者： Haowen An Yu Wang Yaxin Wang Jun Liu Xiaolong Tang Honghong Yi department of Environmental engineering School of Energy and Environmental EngineeringUniversity of Science and Technology BeijingBeijing 100083China Key Laboratory of Beijing Municipal Industry Pollutant resources Processing Beijing 100083China

Civil aviation is one of the industries facing the greatest challenge in reaching carbon neutrality by the middle of this century,and this sector also contributes to adverse impacts on the regional air quality and human *** exhibits the second highest air passenger turnover *** understanding of civil aviation emissionsmust be urgently enhanced,and themitigation potential should be *** this study,on the basis of real domestic flight information for 2019,we built a greenhouse gas and air pollution emission inventory for the civil aviation sector in China with the fuel flowmethod based on the cruise and other *** thoroughly analyzed emissions by region,aircraft and engine types,and aircraft age,based on which we designed four measures to evaluate the abatement *** found that the hydrocarbon(HC),CO,NO_(x),SO_(2),particulate matter(PM)and CO_(2)emissions in 2019 reached 79.9 kt(95%CI[51.6–114.5]),176.3 kt(95%CI[114.5–248.2]),304.2 kt(95%CI[203.4–420.7]),23.2 kt(95%CI[14.2–33.7]),1.0 kt(95%CI[0.61–1.44])and 87.0 Mt(95%CI[57.4–119.6]),*** cruise phase was the major emission phase,accounting for 67%-87%of the total pollutant *** four measures were jointly implemented,the HC,CO,NO_(x),SO_(2),PM and CO_(2)emissions could be reduced by 61%,54%,55%,45%,32%and 38%,*** lower-emission aircraft and switching travel modes could substantially reduce civil aviation emissions in China.

关键词： Emission inventory Fuel flow method Cruise emission Age structure Reduction measures

Spatio-temporal evolution of complex agricultural land use and its drivers in a super-large irrigation district (Hetao) of the upper Yellow River Basin (2000–2021)

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Journal of Geographical Sciences 2025年第2期35卷 273-301页

作者： LI Xinyi SUN Chen XIAO Xue LI Zhengzhong MA Xin WANG Jun XU Xu Chinese-Israeli International Center for Research and Training in Agriculture College of Water Resources &Civil Engineering China Agricultural University Institute of Environment and Sustainable Development in Agriculture Chinese Academy of Agricultural Sciences Shahaoqu Experimental Station Jiefangzha Department Inner Mongolia Hetao Irrigation District Water Resources Development Center Water resources Research Institute of Inner Mongolia College of Economics & Management China Agricultural University

Accurate spatio-temporal land cover information in agricultural irrigation districts is crucial for effective agricultural management and crop production. Therefore, a spectralphenological-based land cover classification(SPLC) method combined with a fusion model(flexible spatiotemporal data fusion, FSDAF)(abbreviated as SPLC-F) was proposed to map multi-year land cover and crop type(LC-CT) distribution in agricultural irrigated areas with complex landscapes and cropping system, using time series optical images(Landsat and MODIS). The SPLC-F method was well validated and applied in a super-large irrigated area(Hetao) of the upper Yellow River Basin(YRB). Results showed that the SPLC-F method had a satisfactory performance in producing long-term LC-CT maps in Hetao, without the requirement of field sampling. Then, the spatio-temporal variation and the driving factors of the cropping systems were further analyzed with the aid of detailed household surveys and statistics. We clarified that irrigation and salinity conditions were the main factors that had impacts on crop spatial distribution in the upper YRB. Investment costs, market demand, and crop price are the main driving factors in determining the temporal variations in cropping distribution. Overall, this study provided essential multi-year LC-CT maps for sustainable management of agriculture, eco-environments, and food security in the upper YRB.

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Foliar-applied zinc promotes cadmium allocation from leaf surfaces to grains in rice

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Journal of Environmental Sciences 2025年第5期151卷 582-593页

作者： Ya-Ting Liu Bo-Fang Yan Xuan Cai Hong-Xiang Zheng Rong-Liang Qiu Ye-Tao Tang School of Environmental Science and engineering Sun Yat-sen UniversityGuangzhou 510006China Institute of Facility Agriculture Guangdong Academy of Agricultural SciencesGuangzhou 510640China Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology Sun Yat-sen UniversityGuangzhou 510006China Guangdong Provincial Key Laboratory of agricultural&Rural Pollution Abatement and Environmental Safety College of Natural Resources and EnvironmentSouth China Agricultural UniversityGuangzhou 510642China

The accumulation of Cd by rice poses significant health *** fertilizationwith Zn can reduce grain Cd contents in rice grown in Cd-contaminated ***,atmospheric deposition on leaves is another vector of Cd contamination,and it remains unclear how Zn application affects the allocation of such *** conducted an experiment where the flag leaves of rice plants were treated with solutions with various Zn concentrations and a constant Cd *** 111Cd stable isotope was used to trace the flux of foliarapplied *** levels of foliar-applied Zn enhanced Cd efflux and grain *** is attributed to limited sequestration of foliar-applied Cd in the leaf cell symplasm and increased Cd desorption from leaf cell walls when a high Zn^(2+)concentration occurs in the *** Zn oxide nanoparticlesmitigated these ***,the expressions of OsLCT1 and OsZIP7 in flag leaves and OsHMA2 and OsZIP7 in the uppermost nodes were upregulated under high-Zn^(2+)treatment,which may facilitate Cd phloem loading and grain *** is advised in using foliar Zn in areas with high atmospheric Cd due to potential grain-contamination risks.

关键词： Atmospheric deposition Isotope labelling Metal interaction Phloem Cell wall

A novel and visible ratiometric fluorescence determination of carbaryl based on red emissive carbon dots by a solvent-free method

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Chinese Chemical Letters 2025年第2期36卷 314-318页

作者： Meiling Xu Xinyang Li Pengyuan Liu Junjun Liu Xiao Han Guodong Chai Shuangling Zhong Bai Yang Liying Cui College of resources and Environment Jilin Agricultural University State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University Key Laboratory of Straw biology and Utilization The Ministry of Education Jilin Agricultural University

In this study, a simple and effective ratiometric fluorescence method has been developed for carbaryl detection, utilizing red emissive carbon dots（R-CDs）. The underlying principle of this proposed strategy relies on the rapid hydrolysis of carbaryl under an alkaline condition and production of 1-naphthol with blue-emission at 462 nm. Furthermore, the as-synthesized R-CDs（Em. 677 nm）, serve as a reference, enhancing the visual tracking of carbaryl through the transformation of fluorescent color from red to *** concentration of carbaryl exhibits a commendable linear correlation with the ratio of fluorescence intensity, ranging from 0 to 20 μg/m L（R2= 0.9989） with a low detection limit of 0.52 ng/m L. Additionally, the described methodology can be used for the enzyme-free visual assay of carbaryl, even in the presence of other carbamate pesticides and metal ions, in tap water and lake water samples with excellent accuracy（spiked recoveries, 94%–106.1%）, high precision(relative standard deviation（RSD） ≤ 2.42),and remarkable selectivity. This fast and highly sensitive naked-eye ratiometric sensor holds immense promise for carbaryl detection in intricate environments and food safety fields.

关键词： Carbaryl detection Carbon dots Fluorescence sensor Quantum yield Visual detection

Distribution and Hydrogeochemical Characteristic of High Iodine Groundwater in Oasis Zone in the Tarim Basin in Xinjiang,China

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Journal of Earth Science 2025年第1期36卷 173-183页

作者： Ying Sun Yinzhu Zhou Jinlong Zhou Yanyan Zeng Yuanyuan Ji Mi Lei College of Hydraulic and Civil engineering Xinjiang Agricultural UniversityUrumqi 830052China Xinjiang Hydrology and Water resources engineering Research Center Urumqi 830052China Xinjiang Key Laboratory of Hydraulic engineering Security and Water Disasters Prevention Urumqi 830052China Center for Hydrogeology and Environmental Geology China Geological SurveyTianjin 300304China Xinjiang agricultural Professional Technological College Changji 831100China

Groundwater is the main water supply source in the Tarim Basin in *** disease caused by high iodine(I)groundwater in the Tarim Basin was reported ***,it is crucial to systematically identify the distribution and genesis of groundwater *** on hydrochemical analysis of 717 groundwater samples collected in 2015–2018,spatial distribution and hydrogeochemistry characteristic of high I groundwater in different aquifers were *** showed that groundwater I ranged between100.00μg/L)accounted for 7.25%of the total ***,groundwater I significantly increased from recharge zone(RZ)to transition zone(TZ)and to evaporation zone(EZ).Vertically,groundwater in shallow confined aquifer(SCA)had the greatest I concentration,followed by single-structure phreatic aquifer(SSPA),phreatic aquifer in confined groundwater area(PACGA),while groundwater in deep confined aquifer(DCA)generally had low I *** I enrichment in SSPA was mainly affected by organic matter(OM)decomposition and that in SCA was mainly affected by evaporite mineral dissolution,OM decomposition under alkaline *** I enrichment in groundwater of PACGA was restrained under neutral *** sedimentary environment was crucial for I enrichment in ***,fine-grained lithology of aquifer,smooth topographic slope,shallow buried depth of groundwater,weak alkaline and reducing environment,reductive dissolution of iron oxide/hydroxide minerals and OM decomposition were advantageous to I enrichment in groundwater.

关键词： high iodine groundwater hydrogeochemical processes depositional environment hydrogeological condition Tarim Basin

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